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P-Block Elements
VIA Group Elements
Sub Topic-I
The atomic number of sulphur is 16, in the ground state of sulphide ion, the
electronic configuration is
2. 1s 2 2s 2 2 p 6 3s 2 3 p 4
3. 1s 2 2s 2 2 p 6 3s 2 3 p 6
2.
4. 1s 2 2 s 2 2 p 6 3s 2 3s 4 3 p 6
hi
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3.
ed
uc
at
io
n.
1. 1s 2 2s 2 2 p 6 3s 2 3 p 2
3. S Te Se Po
4. Te Se S Po
Which one of the following bonds has the highest bond energy?
2. S S
3. Se Se
1. O O
4. Te Te
w
w
5.
2. Se S Te Po
.s
a
1. S Se Te Po
4.
co
m
1.
sequence
1. H 2O, H 2 S , H 2 Se, H 2Te
2. H 2Te, H 2 Se, H 2 S , H 2O
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1. H 2 S , H 2O, H 2Te, H 2 Se
3. H 2Te, H 2 Se, H 2 S , H 2O
4. H 2 S , H 2 Se, H 2Te, H 2O
TeCl4 is expected to be
1. Tetrahedral
8.
2. sp 3
2. 1050
3. Sp
4. sp 3d
3. 1200
4. 600
hi
1. H 2O H 2 S H 2 Se Te
ks
3. H 2 Se H 2Te H 2O H 2 S
2. H 2Te H 2 Se H 2 S H 2O
4. H 2 S H 2O H 2 Se H 2Te
.s
a
11.
4. Trigonal bipyramid
10.
3. Octahedral
9.
2. Square planar
co
m
7.
ed
uc
at
io
n.
6.
members is
w
w
12.
2. SO3
3. CO2
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is
4. N 2
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13.
14.
2. O Se S Te
3. O Te Se S
4. O Se Te S
co
m
ed
uc
at
io
n.
Oxygen is always divalent whereas sulphur can form 2, 4 and 6 bonds. This is
because
ks
16.
hi
.s
a
w
w
17.
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2. Decrease in bond pair-bond pair repulsion.
3. Decrease in electro negativity of the central atom.
4. Increase in electro negativity of the central atom.
19.
The oxidation number of oxygen in K 2O, K 2O2 and KO2 respectively are
1. -2, -1, -1/2
20.
2. -1/2, -1, -2
4. -2, -1/2, -1
2. H 2O2 O3 O2
3. O3 O2 H 2O2
4. O3 H 2O2 O2
hi
2. 3 , 3
ks
1. 3 , 4
3. 4 , 2
4. 2 , 2
The oxidation states of the most electronegative element in the product of the
.s
a
22.
21.
co
m
ed
uc
at
io
n.
18.
3. -2 and 0
w
w
1. 0 and 1
23.
4. -2 and +1
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4. Ozone protects the earths inhabitant by absorbing gamma-radiations.
1. : O = O O : 2.
26.
4. : O = O O :
3.
When Ozone reacts with which one of the following there is decrease in
volume
2. K 4 Fe CN 6
1. PbS
3. Ag
4. HCl
hi
27.
co
m
25.
ed
uc
at
io
n.
24.
ks
.s
a
surface.
3. Excess of sodium thiosulfate reacts with Auric chloride from Na3 Au S2O3 2
w
w
28.
Oleum is
1. H 2 SO4 SO3
29.
2. H 2 SO4 SO2
3. H 2 SO4 H 2O2
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4. H 2 SO4 H 2 S2
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2. Sulphurous acid
3. Hydrosulphuric acid
4. Thiosulphurous acid
31.
2. Super oxide
33.
4. Mono oxide
The products of the chemical reaction between Na2 S2O3 , Cl2 and H 2O are
1. S HCl Na2 S
32.
3. Peroxide
co
m
1. Oxide
ed
uc
at
io
n.
30.
1. Sulphuric acid
2. S 2O62
3. S 2O52
4. S 2O32
The reason why conc. H 2 SO4 is used largely to prepare other acids, that conc.
H 2 SO4
hi
1. Is highly ionized
ks
2. Is dehydrating agent
.s
a
Pick out the ideal condition for H 2 SO4 manufactured by contact process
w
w
34.
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35.
With a dilute solution of hypo, silver nitrate gives a white precipitate which
immediately turns black. The white precipitate and black precipitates are
respectively
2. Ag 2 S 2O3 and Ag 2 S
3. Ag 2 S 2O3 and Ag 2O
co
m
36.
1. Ag 2 S 2O3 and Ag
ed
uc
at
io
n.
hi
37.
3. 1
4. 0
Compounds A and B are treated with dil. HCl separately. The gases liberated
.s
a
38.
2. 2
ks
1. 3
w
w
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39.
4. Se
List-I
List-II
A)
O3 H 2O2
1) Blue
B)
O3 starch KI H3PO3
2) Tailing
C)
O3 Hg
3) HlO3
D)
O3 I 2 H 2O H4P2O6
ed
uc
at
io
n.
40.
2. S
co
m
1. O
4) O2 H 2O
5) Hl
1.
hi
2.
3.
w
w
4.
.s
a
ks
41.
1. It is insoluble in water
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42.
A pale yellow substance (A) when heated with conc- HSO3 liberates a brown
coloured gas (B). The substance (A) also dissolves in sodium sulphite solution
on heating, a clear solution (C) is formed which on acidification gives a turbid
solution and a pungent smelling gas in obtained.
are respectively
C
1.
NO2
2.
Br2
3.
NO
4.
NO2 2
ed
uc
at
io
n.
Na2 S 2O3
SO2
Na2 SO3
SO2
Na2 S 2O3
SO2
Na2 S 2O3
SO3
a) SCl4 4 H 2O X HCl
hi
43.
co
m
(A) When heated in air gives (D) Solution (C) decolorizes I2. Then A, B, C, D
ks
b) X Y H 2O , here anhydride Y is
2. SO2
.s
a
1. S 2O
List-I
44.
O3
w
w
A)
3. SO3
List-II
B)
Hypo
C)
H 2O
D)
H2S
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4. H 2 SO3
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1.
2.
3.
4.
ed
uc
at
io
n.
co
m
VI A Group Elements
Sub Topic-I (Key)
2) 3
3) 1
11) 1
12) 2
13) 3
21) 1
22) 2
23) 4
31) 3
32) 1
33) 4
41) 4
42) 1
4) 2
5) 2
6) 4
7) 4
8) 2
9) 2
10) 2
14) 4
15) 3
16) 2
17) 3
18) 2
19) 1
20) 2
24) 2
25) 3
26) 4
27) 2
28) 1
29) 2
30) 3
36) 3
37) 4
38) 1
39) 3
40) 2
hi
1) 3
35) 2
ks
34) 1
44) 2
w
w
.s
a
43) 2
4.
Sulpher is octationic
7.
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Cl
Cl
Te
Cl
co
m
Cl
ed
uc
at
io
n.
12.
O
6 p p
S
p d
6
O p d O
6
Cl
.s
a
ks
Cl
hi
14.
Cl
Cl
w
w
Sp 3d , Trigonal bipyramidal.
21.
22.
N C C N
3 , 4
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28.
31.
38.
43.
SCl4 4 H 2 O
4 HCl
H 2 SO3
H 2O
Y
w
w
.s
a
ks
hi
S OH 4
S OH 4
ed
uc
at
io
n.
co
m
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Sub Topic-II
1.
co
m
ed
uc
at
io
n.
1. H 2O H 2 S H 2 Se H 2Te
2. H 2O H 2Te H 2 Se H 2 S
3. H 2Te H 2 Se H 2 S H 2O
4. H 2 S H 2O H 2Te H 2 Se
hi
3.
The boiling points of H 2O2 , H 2 S , H 2 Se and H 2Te are in the following order
ks
i) The order of volatility ii) The order of B.P. iii) The order of bond angles
H 2O H 2Te H 2 Se H 2 S
.s
a
H 2O H 2Te H 2 Se H 2 S
H 2O H 2 S H 2 Se H 2Te
w
w
4.
2. Only ii is correct 3. ii & iii are correct 4. i & iii are correct
List-I
List-II
A)
SO3
1) 119.50 ,Angular
B)
SO2
2) 1090.28' , Tetrahedron
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C)
H 2O
D)
O3
1.
2.
3.
4.
ed
uc
at
io
n.
5.
co
m
5) 116.50 Angular
hi
dioxide.
ks
.s
a
w
w
6.
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4. Rhombic sulphur can be converted in to monoclinic sulphur but the reverse is
not
7.
possible.
By passing SO2 in solution of K 2Cr2O7 , it turns green due to the formation of:?
8.
2. Chromic acid
3. Chromium sulphate
4. None
co
m
1. K 2Cr2O4
2. S 2
1. CO32
9.
3. SO32
4. NO2
The Springs reaction for the preparation of sodium thiosulphate involve the
following reactants
1. Na2 SO3 S
hi
A and B are two salts, A reacts both with dil H 2 SO4 and conc. H 2 SO4 to give
ks
10.
ed
uc
at
io
n.
.s
a
reddish brown vapours. However B reacts only with conc. H 2 SO4 to give
similar vapours. Hence A and B are respectively?
1. H 2O and Hbr
12.
3. NaNO2, NaBr
4. NaBr, NaNO2
w
w
11.
2. NaNO3, NaBr
1. NaBr,NaNO3
2. H 2 SO4 HBr
3. HBr and S
4. S and H 2O
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13.
14.
15.
ed
uc
at
io
n.
co
m
2) Orthophosphoric Acid
4) Metaphosphoric Acid
White phosphorus on reaction with line water gives calcium salt of a acid (A)
hi
along with a gas (A) along with a gas (X). Which of the following statement is
ks
.s
a
w
w
16.
The number of lone pairs and the number of S S bonds in S8 molecules are
respectively
1) 8, 8
17.
2) 16, 8
3) 8, 16
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4) 8, 4
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(i) It acts both a proton donor as well as proton acceptor
(ii) It reacts readily with basic and acidic oxides
(iii) It oxidises Fe at its boiling point.
18.
2) SiO2
3) H 2O
Which of the following solutions does not change its colour on passing ozone
ed
uc
at
io
n.
through it?
2. H 2 S1 , H 2 S3
hi
3. H 2 S2O3
4. H 2O S
.s
a
3. One
4. Zero
Oleum is
w
w
1. Fuming H 2 SO4
23.
4. CS2 , NH 2CSNH 2
ks
2. H 2 SO4
1. Three
22.
3. H 2 SO4
1. H 2 SO3
21.
20.
4) CO2
co
m
1) P2O5
2. Oil of vitriol
3. Castor oil
4. Caros acid
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S S bond is present in
1. (a) SO3 n
2. CaC2 CaCN 2
3. CaC2 Ca3 P2
4. Ca3 P2 CaCN 2
2. Heating NH 4 NO2
4. H 2 S2O8
26.
3. H 2 S2O3
co
m
25.
2. S3O9
ed
uc
at
io
n.
24.
A Student accidently splashes few drops of conc H 2 SO4 on his cotton shirt,
after a while, the splashed parts blacken and holes appear. This is happened
because sulphuric acid
hi
ks
.s
a
28.
w
w
form of
1. Milk of sulphur
29.
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1. If both assertion and reason are correct, and reason is the correct explanation of
the assertion.
2. If both assertion and reason are correct, but reason is not the correct explanation
ed
uc
at
io
n.
30.
co
m
of the assertion.
1. If both assertion and reason are correct, and reason is the correct explanation of
the assertion.
of the assertion.
hi
2. If both assertion and reason are correct, but reason is not the correct explanation
ks
31.
.s
a
2. Ba2O3
3. BaO
w
w
1. Ba
32.
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4. Ba OH 3
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4. Red phosphorus is more stable in air than white phosphorus.
33.
co
m
1. Both Assertion and Reason are true and Reason is the correct explanation of
Assertion.
2. Both Assertion and Reason are true but Reason is not the correct explanation of
ed
uc
at
io
n.
Assertion.
1. H 2O H 2 S H 2 Se H 2Te
2. H 2O H 2 S H 2 Se H 2Te
3. H 2 S H 2O H 2 Se H 2Te
4. H 2 Se H 2 S H 2O H 2Te
hi
35.
w
w
1. H 2 S2O4
37.
3. Cr2O3
4. CrO3
36.
2. Fe2O3
.s
a
1. V2O5
ks
34.
2. H 2 S2O6
3. H 2 S2O5
4. H 2 S2O7
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1. Both Assertion and Reason are true and Reason is the correct explanation of
Assertion.
2. Both Assertion and Reason are true but Reason is not the correct explanation of
Assertion.
co
m
2. NH 4Cl
H 2 S2O8 is
1. Pyrosulphuric Acid
3. Oleum
3. NH 4 2 SO4
4. NH 4OH
2. Marshalls acid
4. All of these
hi
Leblanc process
Birkeland-Eyde process
ks
.s
a
40.
ed
uc
at
io
n.
38.
Solvay process
w
w
Manufacture of ammonia
41.
2. 1, 2, 3 and 4
3. 1 and 2
4. 1, 3 and 4
2) Hydrogen peroxide
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3) Ozone
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Among these compounds indentify those that can act as bleaching agent
1. 1 and 3
42.
2. 2 and 3
4. 1, 2 and 3
3. 50%H 2 SO4
4. 20%H 2 S 2O7
co
m
1. 80%H 2 SO4
43.
3. 1 and 2
Sulphur reacts with chlorine in 1:2 ratio and forms X. Hydrolysis of X gives a
anion of Y?
1. sp 3
44.
2. sp
2. Dark blue
4. sp 3d
3. Pale yellow
4. Pale blue
ks
hi
1. S O2 SO2
2. SO2 H 2O H 2 SO4
4. None of the above
.s
a
3. 2SO2 O2 2SO3
46.
3. sp 2
45.
ed
uc
at
io
n.
w
w
2O3 ; H 284.5kJ
1) 3O2
Disch arg e
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co
m
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VI A Group Elements
2) 2
3) 1
11) 2
12) 4
13) 2
21) 4
22) 1
23) 2
31) 3
32) 3
33) 2
41) 4
42) 2
43) 1
4) 3
5) 2
6) 2
7) 3
8) 3
9) 2
10) 3
14) 1
15) 2
16) 2
17) 3
18) 3
19) 2
20) 4
24) 3
25) 4
26) 2
27) 4
28) 4
29) 2
30) 1
34) 2
35) 1
36) 2
37) 3
38) 1
39) 2
40) 4
44) 4
45) 3
46) 1
ks
hi
1) 1
ed
uc
at
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n.
.s
a
w
w
S
O
O
2
5.
2 Fe SO 2 2 FeO Fe S
9.
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S
S
S
S
S
18.
co
m
16.
Ozone does not react with acidified solution of K 2Cr2O7 Thus, does not change it
20.
SO2 2 H 2 S 2 H 2O 3S
24.
HO
OH
26.
ed
uc
at
io
n.
colour.
N 2 Cr2O3 4 H 2O
NH 4 2 Cr2O7
Conc H 2 SO4 has dehydration properties, when cellulose comes in contact with
ks
27.
hi
N 2 4H 2O
NH 4 2 NO2
.s
a
conc H 2 SO4 , it removes water from Cohon leaving only black carbon.
w
w
31.
ConH 2 SO4
C6 H12O6
6C 6H 2O
32.
33.
Molecular nitrogen is less reactive than that of oxygen because nitrogen has high
dissociation energy in comparison to oxygen so, its reactivity is less. Also bond
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length of nitrogen is shorter oxygen because of presence of triple bond between
nitrogen atoms. So, both are true but not correct explanation.
34.
The acidic nature increases from H 2O to H 2Te. The increase in acidic character of
hydrides on moving down the group may be explained in terms of bond length of
H M bond, larger is bond-length, lesser is bond energy and thus easier is
H 2O H 2 S H 2 Se H 2Te
35.
co
m
Even at 400-5000C, the rate of reaction is very low. Therefore, to increase the
ed
uc
at
io
n.
reaction velocity a suitable catalyst is used. Now a days most of the sulphuric
acid plants use V2O5 as a catalyst.
36.
Dithionous acid
H 2 S2O6
Dithionic acid
H 2 S2O5
Disulphurous acid
H 2 S2O7
Disulphuric acid
hi
38.
H 2 S2O4
H 2 SO4 SO3
H 2 S 2O7
ks
pyrosulphuric acid
.s
a
40.
w
w
41.
39.
H 2O2 H 2O O
O3 O2 O
The nascent [H] and [O] thus product, bleaches the coloured articles.
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42.
98% H 2 SO4 is used for absorbing dense form of acid which is formed by
dissolving SO3 in water. Hence, 98% H 2 SO4 is the most efficient reagent for
absorption of SO3 .
43.
When sulphur reacts with chlorine in 1: 2 ratio the SCl4 (sulphur tetra chloride) is
co
m
obtained which on hydrolysis gives sulphurous acid H 2 SO3 . So, the compound X
is SCl4 and Y is H 2 SO3
S 2Cl2 SCl4
ed
uc
at
io
n.
SCl4 4 H 2O S OH 4 4 HCl
unstable
S OH 4 H 2 SO3 H 2O
sulphurous acid
Oxygen changes into pale blue liquid when cooled up to 1830 C .Liquid oxygen is
used as oxidizer in rockets and the launching of satellites.
hi
45.
ks
.s
a
46.
3O2
Silent electric
disch arg e
2O3 ;
H 284.5 kJ
w
w
reaction.
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