MSDS 116

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Welding Alloys USA Inc.

Material Safety Data Sheet

This Material Safety Data Sheet (MSDS) was prepared according to
OSHAs Hazard Communication Standard, 29 CFR Part 1910.1200, for the identified product(s).

Section 1 : PRODUCT IDENTIFICATION

HARDFACE B-G, HARDFACE B-O, HARDFACE B-S
HARDFACE BUF-O, HARDFACE BUF-S,
HARDFACE P-O, HARDFACE P-S, HARDFACE P-S MOD,
HARDFACE R25-S, HARDFACE R35-S, HARDFACE R40-S,
HARDFACE R45-S, HARDFACE R50-S, HARDFACE R55-S,
Product Identity(s):
HARDFACE R-O, HARDFACE R-S,
HARDFACE T-G, HARDFACE T-O, HARDFACE T-S,
HARDFACE T-S MOD, HARDFACE TL-O,
HARDFACE 250-O, HARDFACE 250-S, HARDFACE 350-S
BU2, WA 515-G, WA8620, SPEEDARC 4130-S
Product Type:
Manufacturer:
Address:
Telephone No.:
Emergency Tel. No.:
Date Prepared:

Tubular welding wire

Welding Alloys USA Inc.
8535 Dixie Highway, Florence, KY 41042
859-525-0165
859-525-0165 (8:30 5:00 PM, Mon Fri)
March 26, 2013

Section 2 : HAZARDOUS INGREDIENTS / CHEMICALS

The term Hazardous in Hazardous Ingredients should be interpreted as a term required and defined in OSHA Hazard
Communication Standard (29 C.F.R. 1910.1200). Hazard refers to an inherent property of a substance that is capable of causing an
adverse effect. Considerable differences may exist in the risk posed by a substance, depending on how the substance is contained
or handled, personal protective measures used, and other conditions that result in or limit exposure.
This section, Section 2, covers materials from which the product was produced.
Section 5 covers the hazardous fumes and gases produced during welding (normal use).

Hazardous Ingredients

CAS No.

Wt.
%

OSHA PEL

ACGIH TLV

TWA (mg/m)

TWA (mg/m)

Aluminum and
15 total metal dust;
7429-90-5
0-3
Aluminum Alloys (Al)
5 respirable metal dust
1317-65-3
0-3
15 total dust; 5 respirable
Calcium Carbonate (CaCO)
Chromium and Chromium alloys
1 metal; 0.5 Chromium II;
7440-47-3
1-9
or Compounds (as Cr)
0.5 Chromium III; 0.005 Chromium VI
Fluorides (as F)
15096-52-3
0-1
2.5
Fluorides (as F)
7789-75-5
0-12
2.5
Iron (Fe)
7439-89-6
85-100 15 total dust; 5 respirable dust; 5 fume
Magnesium Oxide
1309-48-4
0-3
15 total particulate
Manganese (Mn)
7439-96-5
1-4
C 5 dust, C 5 fume
Molybdenum (Mo)
7439-98-7
0-3
15 total dust; 5 respirable dust; 5 fume
Nickel (Ni)
7440-02-0
0-2
1
Silicon (Si)
7440-21-3
0-2
15 total dust, 5 respirable
14808-60-7
0-2
0.1 respirable
Silicon dioxide (SiO)
Titanium (Ti)
7440-32-6
0-3
15 total dust; 5 respirable dust; 5 fume
13463-67-7
0-5
15 total dust
Titanium dioxide (TiO)
Zirconium Alloys (as Zr)
7440-67-7
0-1
15 total dust, 5 respirable dust, 5 fumes
Zirconium Silicate
14940-68-2
0-1
5
Note: PEL and TLV values are TWA unless otherwise noted with C or STEL.
CAS No: Chemical Abstract Service registry number.
OSHA: Occupational Health and Safety Administration.
ACGIH: American Conference of Governmental Industrial Hygienists.
PEL: Permissible Exposure Limit.
EPCRA: Emergency Planning and Community Right-to-Know Act.

10 metal dust; 5 fume

10 particulate matter
0.5 metal; 0.5 Chromium III;
0.01 Chromium VI
2.5
2.5
10 total dust, 5 fumes
10 inhalable
0.2 dust, 0.2 fume
10 inhalable, 3 respirable
1.5 inhalable
10
0.025 respirable
10 total dust, 5 fumes
10
5, STEL 10
5, STEL 10

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TLV: Threshold Limit Value the airborne concentration of substances which is believed that nearly all workers may be repeatedly exposed day
after day without adverse health effects.
TWA: 8-Hour Time Weighted Average the time weighted average concentration of exposure that should not be exceeded for any 8-hour work
shift of a 40-hour work week.
STEL: Short Term Exposure Limit a 15-minute time weighted average concentration of exposure that should not be exceeded at any time
during a workday even if the 8-hour TWA is within limits.
C: Ceiling Value concentration that should not be exceeded during any part of the working exposure.

Section 3 : PHYSICAL/CHEMICAL CHARACTERISTICS

Freezing/Melting Point
Density
Specific gravity
Solubility
Appearance
Smell

Approx. 1200 1500C

Approx. 7000 8000 kg/cu m
Approx. 7.0 8.0 (water = 1)
Insoluble
Form is in solid state. Color is metallic gray. Shape is tubular with metal and sometimes mineral
powder filling.
No odor until welded. Welding fumes have a metallic odor.
Other physical and chemical characteristics are not applicable.

Section 4 : FIRE & EXPLOSION HAZARD DATA

FIRE AND EXPLOSION HAZARD DATA
The products identified on this MSDS are Non-Flammable, NonReactive, Non-Explosive, and essentially non-hazardous until welded. However, welding arc, sparks, molten metal, slag, and hot
work surfaces can ignite combustibles or cause explosions. Refer to the American National Standard Z49.1 Safety in Welding and
Cutting, published by the American Welding Society, 550 N.W. LeJeune Road, Miami, Florida 33126, for information regarding
fire prevention, fire protection, hot work authorization, welding and cutting of containers, and industrial applications for fire
prevention and protection. Follow workplace specific safety procedures in the event of a fire.

Section 5 : REACTIVITY DATA

REACTIVITY The products identified on this MSDS are Non-Reactive in the delivered state. Welding consumables stand up
well to severe conditions of storage and do not generally degrade or react dangerously. However, as with any metallic product, the
consumables should be kept out of contact with strong acids, which may liberate flammable gases, and kept out of contact with
oxidizing agents, which may start or feed a fire. Hazardous reaction or decomposition products are produced during welding.
HAZARDOUS DECOMPOSITION PRODUCTS PRODUCED DURING WELDING
Fumes and gases produced during welding are chemically very complex, and cannot be classified simply. Their composition and
quantity are dependent upon the welding consumables used, the metal being welded, the welding process, current level, arc length,
and other process factors. Other conditions which also influence the composition and quantity of the fumes and gases to which
workers may be exposed include: ancillary materials such as fluxes or gases, coatings which may be present on the metal being
welded (such as paint, plating, or galvanizing), the number of welders in operation and the volume of the work area, the quality and
amount of ventilation, the position of the welders head with respect to the fume plume, as well as the presence of contaminants in
the atmosphere (such as chlorinated hydrocarbon vapors from cleaning and degreasing products). When the electrode is consumed,
the fumes and gas decomposition products generated are different in percent and form from the ingredients listed in Section 2. The
composition of these fumes and gases are the concerning matter. Decomposition products include those originating from the
volatilization, reaction, or oxidation of the ingredients shown in Section 2, plus those from the base metal, coating and the other
factors noted above. Reasonably expected fume constituents include: Fluorides and oxides, silicates, or carbonates formed from the
ingredients. Ultraviolet radiation given off by welding can also react with chlorinated hydrocarbon vapors from cleaning and
degreasing products to form phosgene gas, as well as react with oxygen and nitrogen to produce ozone and nitrogen oxides. Other
gaseous reaction products may include carbon monoxide, carbon dioxide, and fluorine. Established OSHA exposure limits for the
hazardous ingredients are listed in Section 2. The ACGIH-1985 preface states: The TLV-TWA should be used as guides in the
control of health hazards and should not be used as fine lines between safe and dangerous concentrations.

Section 6 : HEALTH HAZARD DATA

WELDING SMOKE (DUST, FUMES, and GASES)
Dust, fumes, smoke, and gases produced during welding or cutting or grinding are dangerous to your health. The health effects of
welding exposure are difficult to list because they are dependent upon the conditions of welding (base material, coatings, process,
etc.). The individual components of welding smoke can affect just about any part of the body. Common route of entry is
inhalation, but can also occur through eye contact and ingestion. Any part of the wire, or products produced during welding should
not be ingested.

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Short term (acute) exposure to welding smoke may cause coughing, wheezing, bronchitis, pulmonary edema, pneumonitis,
dizziness, headaches and irritation of the eyes, nose, chest, and respiratory tract. Metal Fume Fever can also result from exposure
with additional flu-like symptoms such as fever, chills, shortness of breath, muscles pain, thirst, vomiting, chest soreness,
gastrointestinal pain, fatigue and a metallic taste in the mouth. Pre-existing respiratory problems, such as asthma or emphysema,
may be aggravated. Gaseous reaction products can cause death at high doses. Chromium (VI) compounds can cause severe
irritation of the bronchial tubes and lungs, burn eyes, and continued inhalation of could cause loss of consciousness and death.
Ingesting Chromium (VI) salts may cause injury or death. Chromium compounds may cause an allergic reaction in some people.
Nickel oxides present in the fume may cause tightness around the chest, fever and allergic reaction in some people.
Long-term (chronic) exposure to welding fumes may lead to respiratory problems including coughing, wheezing, siderosis (iron
deposits in lung), bronchitis, asthma, pneumonia, emphysema, pneumoconiosis, decreased lung capacity, silicosis, and is believed
to affect pulmonary function. Repetitive exposure to fluoride fumes and/or gases may cause excessive calcification of the bones
and ligaments of the ribs, pelvis and spinal column. Manganese exposure can affect the central nervous system resulting in
impaired speech and movement. Constant inhalation of Chromium (VI) compounds may cause an ulceration and perforation of the
nasal septum as well as liver and kidney damage. Repetitive exposure to nickel oxides may lead to lung fibrosis or
pneumoconiosis. Workers exposed to Chromium (VI) compounds and/or nickel oxides have a higher incidence of lung and nasal
cancers. NTP, the National Toxicology Program, listed Hexavalent Chromium Compounds, Nickel Compounds as carcinogens;
Nickel is a reasonably anticipated carcinogen. IARC concluded that welding fumes are possibly carcinogenic to humans.
Chromium and nickel compounds are on the IARC (International Agency for Research of Cancer) list as posing a carcinogenic risk
to humans.
WARNING: This product contains or produces a chemical known to the State of California to cause cancer and birth defects (or
other reproductive harm), California Health and Safety Code Section 25249-5 et seq. (The State of California supports this warning
for products with stainless steel, or containing thorium, chromium, Nickel, Cobalt, Cadmium, antimony, carbon black, and
submerged arc fluxes with crystalline silica of respirable size).
ARC RAYS (RADIATION)
Arc rays can burn skin and injure eyes. Skin cancer has been reported and Ultraviolet Radiation is listed as a carcinogen by NTP.
ELECTRIC SHOCK
Electric shock from equipment can kill or cause severe burns.
ELECTRO MAGNETIC FIELDS
Electromagnetic fields produced during electric arc welding process can affect electrical medial devices such as pacemakers. Do
not go near welding or cutting operation until you have consulted your physician and obtained information from the manufacturer
of the device.
EMERGENCY FIRST AID PROCEDURES
Call for medical assistance. Avoiding harm to rescuer, remove worker from further exposure and implement appropriate
emergency procedures. Use first aid procedures recommended by the American Red Cross. If breathing is difficult, give oxygen.
If not breathing, use CPR (cardiopulmonary resuscitation). Consult a physician if irritation of the eyes and skin or flash burns occur
after exposure.

Section 7 & 8 : CONTROL MEASURES & PRECAUTIONS FOR SAFE HANDLING & USE
Reference American National Standard Z49.1, Safety in Welding and Cutting, published by the American Welding Society, 550
N.W. LeJeune Road, Miami, Florida 33126. And OSHA Health and Safety Standards (29 CFR 1910) from the U.S. Department of
Labor, Washington, DC 20210.
HYGENIC PRACTICES
Do not eat, drink, use tobacco products, apply cosmetics, or take medication where welding fumes are generated.
PROTECTIVE MEASURES
Avoid breathing dust, fumes, and gases to keep exposure low and protect your respiratory system. Train welder to keep his/her
head out of the dust, fumes, and gases. Use enough ventilation, exhaust at the arc, or both to keep dust, fumes, and gases from
breathing zone and general area. Where ventilation is questionable have exposure measured for the composition and quantity of
dust, fumes and gases to which workers are exposed by taking an air sample inside the welders helmet, if worn, or in the workers
breathing zone. See ANSI/AWS F1.1, F1.2, F1.3, F1.4, and F1.5 available from the American Welding Society, P.O. Box 351040,
Miami FL 33135. When necessary wear an approved mask or respirator. Never perform welding within 200 feet of degreasing
equipment or solvents.
PERSONAL PROTECTIVE EQUIPMENT
Wear approved head, hand and body protection, which help to prevent injury from radiation, sparks and electrical shock. See ANSI
Z-49.1. This would include wearing welders gloves and a protective face shield with filter lens and may include arm protectors,
apron, hats, shoulder protection, as well as dark substantial clothing. Welders should be trained not to allow electrically live parts
to contact the skin or wet clothing.

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WASTE DISPOSAL METHOD

Prevent waste from contaminating surrounding environment. Discard any product, residue, container, or liner in an environmentally
accepted manner approved by Federal, State and Local regulations.

Section 9 : REGULATORY INFORMATION

The product identified in section 1 contains one or more chemicals subject to the reporting requirements of section 313, 312, 311 of
Emergency Planning and Community Right-to-know Act (EPCRA) of 1986 (40 CFR 372 and 370). This product may contain the
following chemicals subject to section 313 reporting: Chromium, Nickel, Manganese, Aluminum, Aluminum Oxide, Barium
Compounds, Cobalt, and Copper; refer to section 2. If you are unsure whether you are subject to the reporting requirements of
EPCRA section 313, or need more information, call the EPAs EPCRA Call center at 800 424-9346 or 703 412-9810.
This data is believed to be accurate and was obtained from recognized technical sources, but no warranties are expressed or implied.