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2
Explosive Science
2.1
Introduction
Velocity of detonation (VOD) are in excess of 1800 m/s. Most commercial explosives
and especially the ammonium nitrate (AN) based belong to the high explosives
category due to their high detonation and gas pressures.
Explosives can also be classied as homogeneous and heterogeneous. Usually
primary and secondary explosives are present in the former, whereas in the latter
tertiary explosives which are mixtures of chemicals are found.
Ammonium Nitrate Explosives for Civil Applications: Slurries, Emulsions and Ammonium Nitrate Fuel Oils,
First Edition. E.G. Mahadevan.
2013 Wiley-VCH Verlag GmbH & Co. KGaA. Published 2013 by Wiley-VCH Verlag GmbH & Co. KGaA.
2 Explosive Science
Detonation zone
CJ plane
Shock front
Unreacted
explosive
Explosion state
Pressure
spike
Pressure
Surface of
undetonated
explosive
Explosion pressure
Figure 2.1 Schematic representations of zones and pressure variations along a detonating
explosive charge.
Reaction front
Reaction front
Gas energy
Figure 2.2
Cartridge of
high explosive
Pressure
Cartridge of
low explosive
Pressure
Shock
energy
Gas
energy
2.2
Initiation and Detonation
2.2.1
Mechanism
2.3
Propagation and Detonation
2.3.1
Propagation
2 Explosive Science
propagation is a must. The mechanism of propagation has also been the subject
of study by many [11, 12].
Initiation per se does not ensure propagation. Attaining a steady-state detonation
with a constant measurable velocity is a sure sign of propagation. For propagation
to continue there must be continuity in the decomposition of the explosive till the
end. This is achieved best when the losses due to conduction to the sides in a
cylindrical charge is much less than the heat evolved as the wave travels through
a cylindrical charge. There is net heat energy gain which accelerates the chemical
reaction following Arrhenius equation. This heat generation is a self-sustaining
multiplying situation as long as the heat transfer rate cannot keep pace with
the exothermic heat produced by the reaction. Pressure and temperature rapidly
increase leading to detonation in the direction of the shock wave. These conditions
are especially critical in small diameter explosive charges.
2.3.2
Detonation
Unreacted
explosive
Detonation
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2 Explosive Science
Table 2.1
Unconned
Conned
Water gel
25 m diameter
AN/FO
100 mm diameter
Emulsion
25 mm
35004000
50005300
40004200
50005300
22002500
40004200
45005000
52005500
The two terms are interlinked in the form of a cause and effect situation and this
relationship is given in Eq. (2.1).
2
2
(PD
)/4 where PD
D2
2
PD = PD
/R + 1
(2.1)
Partition of energy.
Explosive
Density
Bubble energy
Shock energy
Energy split
AN/FO
Emulsion
Water gel
0.80
1.3
1.2
1.36
2.44
1.68
2.2
2.03
0.77
0.52
0.5
0.57
76/24
75/25
81/19
78/22
2.4
Reaction Chemistry in Explosives
2.4.1
Heat of Reaction
(2.2)
11
12
2 Explosive Science
The concept arises out of the oxidation reaction, which is basis for explosive energy.
The explosive energy tied up with production of heat/gaseous products depends on
the oxygen balance present in the explosive. This is applicable to chemical mixtures
acting as an explosive composition also.
Knowledge of oxygen balances inuence on explosive properties will help in
formulating an explosive with optimum performance.
Heat of reaction of an explosive reaches its maximum when it has just enough
oxygen to convert all its fuel (C, H) to this higher oxidation state (CO2 , H2 ).
Calculations of oxygen balance are well standardized as shown in Eq. (2.3). Using
Eq. (2.3), the oxygen balance for ammonium nitrate is derived to be 20.
%OB =
O 2C 12 H
1600
MW
(2.3)
References
where
O = oxygen,
C = carbon,
H = hydrogen, and
MW = molecular weight.
We have seen that for maintaining oxygen balance of an explosive we may have
to add fuel if it is oxygen-rich or add oxygen-giving substance (oxidant oxidizer)
if it is oxygen-decient. In order to calculate fuel values, the same hierarchical
process is used in reverse. The molecular weight of compound is divided by the
oxygen deciency using Eq. (2.4).
Fuel value =
MW
1
2C + 2H
O
(2.4)
where
MW = molecular weight,
C = carbon, and
H = hydrogen.
Oxidizer value is calculated using Eq. (2.5).
Oxidizer value =
MW
O 2C
(2.5)
1
2H
where
MW = molecular weight,
C = carbon, and
H = hydrogen.
It is to be noted that these values are not always correct as derived from the above
formulas as other competing reactions like hydrogen combining with chlorine or
sodium getting oxidized and giving a solid residue are not taken into account.
References
1. Konya, C.J. (1995) Blast Design, Inter-
2.
3.
4.
5.
7.
8.
9.
10.
13
14
2 Explosive Science
11. Riggs, R.S. Elements of Explosive Behav-