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1.
Temperature
2.
Work
3.
Pressure
4.
Specific volume
1.
2.
3.
4.
A system is said to be at equilibrium, if the entropy of the system has reached __________ value.
1.
minimum
2.
zero
3.
maximum
4.
none of these
At 60 C, vapour pressure of methanol and water are 84.562 kPa and 19.953 kPa respectively. An
aqueous solution of methanol at 60 C exerts a pressure of 39.223 kPa; the liquid phase and vapour phase
mole fractions of methanol are 0.1686 and 0.5714 respectively. Activity co-efficient of methanol is
1.
3.389
2.
1.9398
3.
1.572
4.
4.238
When a system is in equilibrium for all possible processes, the differential or finite change of entropy is
1.
>0
2.
<0
3.
none of these
4.
=0
1.
none of these.
2.
3.
does not need the addition of external work for its functioning.
4.
1.
reversible adiabatic
2.
reversible isothermal
3.
irreversible isothermal
4.
none of these
1.
volume
2.
pressure
3.
none of these
4.
mass
A system in which there is exchange of energy but not of mass, is called a/an __________ system.
1.
insulated
2.
isolated
3.
closed
4.
open
1.
isothermal compression
2.
adiabatic compression
3.
isothermal expansion
4.
adiabatic expansion
1.
vapor pressure
2.
partial pressure
3.
chemical potential
4.
none of these
The variation of heat of reaction with temperature at constant pressure is given by the __________ law.
1.
Kelvin's
2.
Antonie's
3.
Kirchoffs
4.
none of these
1.
none of these
2.
A = H - TS
3.
A = H + TS
4.
A = E - TS
1.
2.
For some gases, Virial equations and ideal gas equations are the same.
3.
4.
1.
Activity co-efficient
2.
Fugacity
3.
Activity
4.
Fugacity co-efficient
The point at which all the three (solid, liquid and gas) phases co-exist, is known as the __________ point.
1.
boiling
2.
freezing
3.
Boyle
4.
triple
1.
2.
heat transfer from low temperature to high temperature source is not possible without external
work.
3.
4.
none of these.
1.
2.
3.
4.
As pressure approaches zero, the ratio of fugacity to pressure (f/P) for a gas approaches
1.
unity
2.
infinity
3.
zero
4.
an indeterminate value
1.
2.
3.
4.
What is the degree of freedom for a system comprising liquid water equilibrium with its vapour ?
1.
2.
3.
4.
1.
2.
3.
4.
For an ideal gas, the internal energy depends upon its __________ only.
1.
volume
2.
temperature
3.
pressure
4.
molecular size
1.
2.
3.
4.
1.
pressure
2.
3.
temperature
4.
none of these.
1.
2.
3.
4.
1.
low T, low P
2.
low T, high P
3.
high T, low P
4.
high T, high P
1.
2.
With increase in temperature, the equilibrium constant increases for an exothermic reaction.
3.
The conversion for a gas phase reaction increases with increase in pressure, if there is a
decrease in volume accompanying the reaction.
4.
The conversion for a gas phase reaction increases with decrease in pressure, if there is an
increase in volume accompanying the reaction.
1.
second
2.
first
3.
zeroth
4.
third
1.
2.
none of these.
3.
4.
is independent of temperature.
1.
expansion in an engine
2.
3.
throttling
4.
none of these
Molar heat capacity of water in equilibrium with ice at constant pressure is __________ Kcal/kg mole . K
1.
2.
10
3.
4.
15
1.
F = E - TS
2.
F = E + TS
3.
F = H - TS
4.
F = H + TS
Entropy change for an irreversible process taking system and surrounding together is
1.
=0
2.
<0
3.
none of these
4.
>0
1.
2.
3.
4.
A gas can be liquified by pressure alone only, when its temperature is __________ its critical temperature.
1.
2.
less than
3.
more than
4.
1.
energy transfer.
2.
3.
4.
none of these.
1.
50 k cal/hr
2.
200 BTU/hr
3.
200 BTU/minute
4.
200 BTU/day
1.
more stable.
2.
3.
less stable.
4.
1.
Activity co-efficient
2.
Fugacity
3.
Free energy
4.
all of three
What is the degree of freedom for a system comprising liquid water equilibrium with its vapour ?
1.
2.
3.
4.
1.
momentum
2.
mass
3.
energy
4.
none of these
Specific __________ does not change during phase change at constant temperature and pressure.
1.
Gibbs energy
2.
internal energy
3.
entropy
4.
enthalpy
The fugacity of a gas in a mixture is equal to the product of its mole fraction and its fugacity in the pure
state at the total pressure of the mixture. This is
1.
2.
none of these
3.
4.
Henry's law
When liquid and vapour phases of one component system are in equilibrium (at a given temperature and
pressure), the molar free energy is
1.
2.
3.
4.
A gas mixture of three components is brought in contact with a dispersion of an organic phase in water.
The degree of freedom of the system are
1.
2.
3.
4.
Enthalpy changes over a constant pressure path are always zero for __________ gas.
1.
an easily liquefiable
2.
a real
3.
any
4.
a perfect
One mole of nitrogen at 8 bar and 600 K is contained in a piston-cylinder arrangement. It is brought to 1
bar isothermally against a resisting pressure of 1 bar. The work done (in Joules) by the gas is
1.
4988.4
2.
10373
3.
30554
4.
4364.9
1.
2.
3.
4.
1.
isobarically
2.
non-uniformly
3.
isothermally
4.
adiabatically
Henrys law is closely obeyed by a gas, when its __________ is extremely high.
1.
pressure
2.
solubility
3.
temperature
4.
none of these
A solute distributes itself between two non-miscible solvents in contact with each other in such a way that,
at a constant temperature, the ratio of its concentrations in two layers is constant, irrespective of its total
amount. This is
1.
2.
3.
none of these.
4.
The work done in isothermal compression compared to that in adiabatic compression will be
1.
same
2.
more
3.
less
4.
1.
boiling point
2.
triple point
3.
4.
always
1.
2.
3.
4.
Pressure-enthalpy chart is useful in refrigeration. The change in internal energy of an ideal fluid used in
ideal refrigeration cycle is
1.
zero
2.
negative
3.
infinity
4.
positive
For a thermodynamic system containing x chemical species, the maximum number of phases that can
co-exist at equilibrium is
1.
x+1
2.
x+3
3.
4.
x+2
1.
ds < 0
2.
ds > 0
3.
ds = 0
4.
ds = Constant
1.
2.
3.
none of these.
4.
For organic compounds, group contribution method can be used for the estimation of
1.
thermal conductivity.
2.
specific volume.
3.
critical properties.
4.
specific gravity.
1.
2.
3.
4.
In reactions involving solids and liquids (where change in volume is negligible), the heat of reaction at
constant pressure as compared to that at constant volume is
1.
same
2.
more
3.
4.
less
Dryness fraction of wet steam is defined as the ratio of mass of vapour in the mixture to the mass of
mixture __________ calorimeter is not used for measuring the dryness fraction of steam.
1.
Bucket
2.
Bomb
3.
Throttling
4.
Separating
Heat of reaction is
1.
2.
3.
4.
The fusion of a crystalline solid at its melting point to form a liquid at the same temperature is
accompanied by
1.
2.
decrease of entropy.
3.
4.
no change in enthalpy.
The efficiency of an Otto engine compared to that of a diesel engine, for the same compression ratio will
be
1.
more
2.
same
3.
less
4.
1.
pressure vs enthalpy
2.
pressure vs volume
3.
enthalpy vs entropy
4.
temperature vs entropy
1.
2.
3.
4.
high viscosity
1.
remains constant
2.
is decreasing
3.
is increasing
4.
Heat evolved/absorbed during conversion of a substance from one allotropic form to another is termed as
the heat of
1.
none of these
2.
vaporisation
3.
transition
4.
fusion
1.
2.
3.
4.
The entropy of a substance does not remain constant during a reversible adiabatie change.
A cylinder contains 640 gm of liquid oxygen. The volume occupied (in litres) by the oxygen, when it is
released and brought to standard conditions (0C, 760 mm Hg) will be __________ litres.
1.
448
2.
224
3.
4.
22.4
1.
2.
3.
Pressure is constant.
4.
Temperature is constant.
1.
closed
2.
open
3.
non-thermodynamic
4.
isolated
Variation of equilibrium pressure with temperature for any two phases of a given substances is given by
the __________ equation.
1.
Gibbs-Duhem
2.
Clayperon
3.
Maxwell's
4.
none of these
1.
pressure
2.
activity
3.
activity co-efficient
4.
mole fraction
1.
adiabatic
2.
isometric
3.
isothermal
4.
none of these
1.
Cooling occurs
2.
Pressure is constant
3.
Heating occurs
4.
Temperature is constant
1.
hyperbola
2.
straight line
3.
parabola
4.
sine curve
If atmospheric temperature and dew point are nearly equal, then the relative humidity is
1.
zero
2.
almost 100%
3.
50%
4.
unpredictable
1.
maximum
2.
minimum
3.
indeterminate
4.
zero