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Salt Tables
The following salt tables came from three sources. The
potassium chloride table is from the CRC Handbook of
Chemistry and Physics, 62nd edition. The sodium chloride
table is from Staples and Nuttall, Journal of Physical
Chemistry Reference Data, 1977, Volume 6. The calcium
chloride table is from Clarke and Grew, Journal of Physical
Chemistry Reference Data, 1985, Volume 14. The tables are
divided into the following columns.
1. Percent Wt = the anhydrous solute weight percent, g
solute/l00 g solution.
2. Specific Gravity = the ratio of the density of a body to
the density of an equal volume of water at 4C. Specific
Gravity is dimensionless.
3. Density = the ratio of the mass of a sample to its volume
at the same temperature. The density of water is
assumed to be 8.33 lbm/gal.
4. lbm of salt/bbl of solution = the pounds of salt in a
barrel solution of the given density.
5. Gallons of water per barrel of solution = the gallons of
water to make up one barrel of solution of the given
density.
6. Salt, mg/L = the concentration of salt in 1 liter (L) of
solution.
7. Chlorides, mg/L = concentration of chlorides in 1 liter
(L) of solution.
8. Volume Increase Factor = the volume increase that
will occur when the specified weight of salt is added to
the specified volume of freshwater. The value in table
column 8a is used for retort corrections.
9. Crystallization Point, F = the crystallization point of a
solution containing the specified concentration of salt.
10. AW = the activity of the solution. This value has also
been called Formation Activity Coefficient (F.A.C.) in
previous manuals. This value, regardless of the term
applied to it, is a measure of the fluid's potential to
absorb water. (See Chapter 3, Oil- and Synthetic-Base
Drilling Fluids.)
5-32
Engineering Handbook
1.005
1.011
1.017
1.024
1.030
1.037
1.044
1.050
1.057
1.063
1.070
1.077
1.084
1.091
1.097
1.104
1.111
1.119
1.126
1.111
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
10.0
11.0
12.0
13.0
14.0
15.0
16.0
17.0
18.0
19.0
20.0
9.20
9.26
9.32
9.38
9.44
8.90
8.97
9.03
9.08
9.12
8.64
8.69
8.75
8.80
8.86
8.37
8.42
8.47
8.53
8.59
3
Density
(lbm/gal)
61.9
66.1
70.5
74.9
79.3
41.2
45.3
49.4
53.5
57.6
21.8
25.6
29.4
33.3
37.3
3.5
7.1
10.7
14.4
18.1
4
KCl
(lbm/bbl)
38.9
38.7
38.5
38.3
38.0
40.0
39.8
39.6
39.4
39.1
40.9
40.7
40.5
40.4
40.2
41.8
41.6
41.4
41.3
51.1
5
H2 O
(gal/bbl)
176,700
188,900
201,300
213,900
226,600
117,700
129,200
140,900
152,700
164,600
62,200
73,000
84,000
95,100
106,300
10,000
20,200
30,500
41,000
51,500
6
KCl
(mg/L)
84,038
89,840
95,737
101,730
107,770
55,977
61,447
67,011
72,623
78,282
29,582
34,718
39,950
45,229
50,556
4,756
9,606
14,506
19,499
24,493
7
Chlorides
(mg/L)
1.078
1.084
1.090
1.097
1.104
1.050
1.055
1.061
1.066
1.072
1.026
1.031
1.035
1.039
1.045
1.005
1.009
1.013
1.017
1.022
8*
Vol. Incr.
Factor
17.0
16.0
15.0
14.0
13.0
22.4
21.4
20.4
20.0
18.5
26.9
26.1
25.2
24.3
23.4
31.2
30.3
29.5
28.6
27.8
9
Crystallization
Point (T)
* Sacked KCl contains a trivial amount of water, therefore, the vol. increase from sack additions is the same as the retort correction factor.
2
Specific
Gravity
1
Percent
Wt
5-33
5-34
2
Specific
Gravity
1.140
1.147
1.155
1.162
1
Percent
Wt
21.0
22.0
23.0
24.0
83.9
88.4
93.1
97.7
4
KCl
(lbm/bbl)
37.8
37.6
37.4
37.1
5
H2 O
(gal/bbl)
239,500
252,400
265,700
278,900
6
KCl
(mg/L)
FORMULAS:
METRIC CONVERSIONS:
9.51
9.56
9.64
9.68
3
Density
(lbm/gal)
114,000
120,040
126,473
132,643
7
Chlorides
(mg/L)
1.111
1.117
1.125
1.132
8
Vol. Incr.
Factor
22.0
34.0
48.0
59.0
9
Crystallization
Point (T)
S.G.
(20C)
Density
lb/gal
K2CO3
mg/L
K+
mg/L
CO3=
K2CO3
lb/bbl
Water
gal/bbl
1.01
8.42
10,100
5,715
4,386
3.535
41.88
1.02
8.49
20,300
11,487
8,815
7.105
41.83
1.03
8.57
30,800
17,429
13,374
10.78
41.77
1.04
8.64
41,400
23,427
17,977
14.49
41.71
1.05
8.72
52,200
29,539
22,667
18.27
41.64
1.05
8.80
63,200
35,763
27,443
22.12
41.57
1.06
8.87
74,300
42,045
32,263
26.005
41.49
1.07
8.95
85,700
48,496
37,213
29.995
41.40
1.08
9.03
97,300
55,060
42,250
34.055
41.31
10
1.09
9.11
109,000
61,680
47,331
38.15
41.22
11
1.10
9.19
121,000
68,471
52,541
42.35
41.12
12
1.11
9.27
133,200
75,375
57,839
46.62
41.01
13
1.12
9.35
145,500
82,335
63,180
50.925
40.90
14
1.13
9.43
158,100
89,465
68,651
55.335
40.79
15
1.14
9.52
170,900
96,708
74,209
59.815
40.66
16
1.15
9.60
183,800
104,008
79,811
64.33
40.54
17
1.16
9.68
197,000
111,477
85,542
68.95
40.41
18
1.17
9.77
210,500
119,117
91,405
73.675
40.27
19
1.18
9.85
224,100
126,813
97,310
78.435
40.13
20
1.19
9.94
238,000
134,678
103,346
83.3
39.98
22
1.21
10.11
266,300
150,693
115,634
93.205
39.66
24
1.23
10.29
295,700
167,329
128,401
103.495
39.32
26
1.26
10.47
325,900
184,419
141,514
114.065
38.96
28
1.28
10.66
357,100
202,074
155,062
124.985
38.57
30
1.30
10.84
389,400
220,352
169,088
136.29
38.16
32
1.32
11.03
422,600
239,139
183,504
147.91
37.71
34
1.35
11.22
456,800
258,492
198,354
159.88
37.24
36
1.37
11.42
492,000
278,411
213,639
172.2
36.74
38
1.39
11.62
528,300
298,952
229,401
184.905
36.20
40
1.42
11.81
565,600
320,059
245,598
197.96
35.63
Engineering Handbook
5-35
5-36
2
Specific
Gravity
1.007
1.014
1.021
1.029
1.036
1.043
1.050
1.058
1.065
1.073
1.080
1.088
1.095
1.103
1.111
1.118
1.126
1.134
1.142
1.150
1
% Wt
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
10.0
11.0
12.0
13.0
14.0
15.0
16.0
17.0
18.0
19.0
20.0
9.33
9.40
9.46
9.53
9.60
9.01
9.08
9.14
9.20
9.27
8.70
8.76
8.83
8.89
8.95
8.40
8.46
8.52
8.58
8.65
3
Density
(lbm/gal)
62.7
67.1
71.5
76.0
80.6
41.6
45.7
49.9
54.1
58.4
21.9
25.8
29.7
33.6
37.6
3.5
7.1
10.7
14.4
18.2
4
NaCl
(lbm/bbl)
39.44
39.25
39.03
38.85
38.64
40.38
40.19
40.00
39.85
39.66
41.10
41.02
40.86
40.70
40.54
41.87
41.75
41.63
41.46
41.34
5
H2O
(gal/bbl)
178,912
191,420
204,102
216,980
229,960
118,800
130,512
142,350
154,392
166,650
62,586
73,500
84,624
95,850
107,260
10,070
20,286
30,630
41,144
51,800
6
NaCl
(mg/L)
108,524
116,112
123,804
131,616
139,489
72,062
79,166
86,347
93,651
101,087
37,963
44,584
51,331
58,141
65,062
6,108
12,305
18,580
24,957
31,421
7
Chlorides
(mg/L)
1.065
1.070
1.076
1.081
1.087
1.040
1.045
1.050
1.054
1.059
1.020
1.024
1.028
1.032
1.036
1.003
1.006
1.009
1.013
1.016
8
Vol. Incr.
Factor
10.6
8.7
6.7
4.6
2.4
18.8
17.3
15.7
14.1
12.4
25.3
24.1
22.9
21.5
20.2
31.0
30.0
28.8
27.7
26.5
9
Crystallization
Point (T)
0.882
0.872
0.861
0.850
0.839
0.927
0.919
0.910
0.901
0.892
0.964
0.957
0.950
0.943
0.935
0.996
0.989
0.983
0.976
0.970
10
Aw
Engineering Handbook
9.66
9.73
9.80
9.87
9.94
10.01
1.158
1.166
1.174
1.183
1.191
1.199
21.0
22.0
23.0
24.0
25.0
26.0
85.2
89.9
94.6
99.5
104.4
109.3
4
NaCl
(lbm/bbl)
7
Chlorides
(mg/L)
147,508
155,600
163,789
172,147
180,609
189,143
6
NaCl
(mg/L)
243,180
256,520
270,020
283,800
297,750
311,818
5
H2 O
(gal/bbl)
38.43
38.22
37.97
37.74
37.50
37.27
1.09
1.099
1.106
1.113
1.120
1.127
8*
Vol. Incr.
Factor
FORMULAS:
METRIC CONVERSIONS:
3
Density
(lbm/gal)
2
Specific
Gravity
1
% Wt
0.0
2.5
5.2
+11.4
+15.0
+25.0
9
Crystallization
Point (T)
0.827
0.815
0.802
0.788
0.774
0.759
10
Aw
5-37
Specific
Gravity
Density
(lbm/gal)
MgCl2 6H20
(lbm/bbl)
H2 O
(gal/bbl)
1.0
2.0
3.0
4.0
5.0
1.008
1.016
1.024
1.033
1.041
8.41
8.48
8.55
8.62
8.69
7.54
15.15
22.92
30.76
38.82
41.71
41.45
40.87
40.28
39.69
6.0
7.0
8.0
9.0
10.0
1.050
1.058
1.067
1.076
1.085
8.76
8.83
8.90
8.98
9.05
46.96
55.24
63.60
72.11
80.85
39.06
38.43
37.80
37.17
36.50
11.0
12.0
13.0
14.0
15.0
1.094
1.103
1.112
1.121
1.130
9.13
9.20
9.28
9.35
9.43
89.73
98.61
107.76
116.90
126.35
36.16
35.83
35.13
34.44
33.73
16.0
17.0
18.0
19.0
20.0
1.139
1.148
1.157
1.167
1.176
9.50
9.58
9.66
9.73
9.81
135.79
145.53
155.27
165.28
175.28
33.01
31.48
29.95
29.13
28.31
21.0
22.0
23.0
24.0
25.0
1.186
1.196
1.206
1.216
1.227
9.90
9.98
10.06
10.15
10.24
185.66
196.03
206.78
217.53
228.58
27.47
26.63
25.77
24.91
24.00
26.0
27.0
28.0
29.0
30.0
1.237
1.248
1.258
1.269
1.279
10.32
10.41
10.50
10.59
10.67
239.63
251.02
262.40
274.12
285.84
23.10
22.18
21.25
20.29
19.32
FORMULAS:
5-38
Chlorides
(mg/L)
AW
10,080
20,320
30,720
41,320
52,050
7,502
15,123
22,863
30,752
38,738
1.001
1.002
1.004
1.006
1.009
1.007
1.013
1.028
1.043
1.058
0.985
0.981
0.978
0.974
0.970
63,000
74,060
85,360
96,840
108,500
46,887
55,118
63,528
72,072
80,750
1.012
1.014
1.017
1.020
1.023
1.075
1.093
1.111
1.130
1.151
0.964
0.958
0.952
0.943
0.934
120,340
132,360
144,560
156,940
169,500
89,562
98,508
107,587
116,801
126,149
1.026
1.029
1.033
1.036
1.040
1.161
1.172
1.195
1.220
1.245
0.924
0.913
0.901
0.888
0.875
182,240
195,160
208,260
221,635
235,200
135,630
145,246
154,995
164,950
175,045
1.044
1.048
1.052
1.057
1.061
1.272
1.334
1.403
1.442
1.484
0.862
0.846
0.830
0.813
0.795
249,060
263,120
277,380
291,840
306,625
185,360
195,824
206,437
217,199
228,203
1.066
1.071
1.076
1.081
1.087
1.529
1.577
1.630
1.686
1.750
0.778
0.760
0.737
0.713
0.691
321,620
336,825
352,240
367,865
383,700
239,362
250,679
262,151
273,780
285,565
1.092
1.098
1.103
1.110
1.116
1.818
1.894
1.976
2.070
2.174
0.669
0.647
0.625
0.604
0.582
Engineering Handbook
5-39
4a
4b
95%
CaCl2
(lbm/bbl)
5a
H20
Using
100%
CaCl2
(gal/bbl)
5b
H20
Using
95%
CaCl2
(gal/bbl)
Wt
Specific
Gravity
Density
(lbm/gal)
100%
CaCl2
(lbm/bbl)
1
2
3
4
5
1.009
1.017
1.026
1.034
1.043
8.42
8.49
8.56
8.63
8.70
3.53
7.13
10.78
14.50
18.27
3.72
7.50
11.35
15.26
19.23
41.93
41.85
41.78
41.69
41.60
41.91
41.81
41.71
41.60
41.48
6
7
8
9
10
1.051
1.060
1.068
1.077
1.085
8.77
8.84
8.91
8.98
9.05
22.11
25.99
29.94
33.95
38.03
23.27
27.36
31.52
35.74
40.03
41.49
41.38
41.27
41.14
41.01
41.35
41.22
41.08
40.93
40.77
11
12
13
14
15
1.094
1.103
1.113
1.122
1.132
9.13
9.20
9.28
9.36
9.44
42.18
46.39
50.69
55.05
59.49
44.40
48.83
53.36
57.95
62.62
40.90
40.76
40.65
40.53
40.40
40.63
40.47
40.33
40.18
40.02
16
17
18
19
20
1.141
1.151
1.160
1.170
1.180
9.52
9.60
9.68
9.76
9.85
63.98
68.55
73.18
77.91
82.72
67.35
72.16
77.03
82.01
87.07
40.25
40.10
39.95
39.80
39.65
39.85
39.67
39.49
39.31
39.13
21
22
23
24
25
1.190
1.200
1.210
1.220
1.231
9.93
10.01
10.10
10.18
10.27
87.59
92.53
97.55
102.62
107.82
92.20
97.40
102.68
108.02
113.49
39.48
39.31
39.14
38.95
38.76
38.93
38.73
38.52
38.30
38.08
26
27
28
29
30
1.241
1.252
1.262
1.273
1.284
10.36
10.44
10.53
10.62
10.71
113.09
118.44
123.85
129.39
135.00
119.04
124.67
130.37
136.20
142.11
38.57
38.37
38.16
37.96
37.75
37.86
37.62
37.38
37.14
36.90
31
32
33
34
35
1.295
1.306
1.317
1.328
1.340
10.81
10.90
10.99
11.08
11.18
140.70
146.48
152.32
158.25
164.32
148.11
154.19
160.34
166.58
172.97
37.53
37.30
37.06
36.81
36.57
36.64
36.38
36.10
35.81
35.53
36
37
38
39
40
1.351
1.363
1.375
1.387
1.398
11.27
11.37
11.47
11.57
11.67
170.47
176.76
183.13
189.53
195.99
179.44
186.06
192.77
199.50
206.31
36.32
36.06
35.81
35.53
35.23
35.24
34.95
34.65
34.33
33.99
5-40
8b**
Volume
Increase
Factor
95%
CaCl2
10
Chlorides
(mg/L)
8a*
Volume
Increase
Factor
100%
CaCl2
CaCl2
(mg/L)
Crystallization
Point
(F)
Aw
10,085
20,340
30,765
41,360
52,125
6,454
13,018
19,690
26,470
33,360
1.002
1.004
1.006
1.008
1.011
1.002
1.004
1.007
1.010
1.013
31.1
30.4
29.5
28.6
27.7
0.998
0.996
0.993
0.989
0.984
63,060
74,165
85,440
96,885
108,500
40,358
47,466
54,682
62,006
69,440
1.013
1.016
1.018
1.021
1.024
1.016
1.019
1.022
1.026
1.030
26.8
25.9
24.6
23.5
22.3
0.979
0.973
0.967
0.959
0.951
120,340
132,360
144,625
157,080
169,725
77,018
84,710
92,560
100,531
108,624
1.027
1.030
1.034
1.037
1.041
1.034
1.038
1.041
1.045
1.049
20.8
19.3
17.6
15.5
13.5
0.942
0.933
0.923
0.912
0.900
182,560
195,585
208,800
222,300
236,000
116,838
125,174
133,632
142,272
151,040
1.044
1.048
1.051
1.056
1.060
1.054
1.059
1.064
1.068
1.073
11.2
8.6
5.9
2.8
0.4
0.888
0.875
0.862
0.847
0.832
249,900
264,000
278,300
292,800
307,625
159,936
168,960
178,112
187,392
196,880
1.065
1.069
1.074
1.078
1.084
1.079
1.084
1.090
1.097
1.103
3.9
7.8
11.9
16.2
21.0
0.816
0.800
0.783
0.765
0.746
322,660
337,905
353,360
369,170
385,200
206,502
216,259
226,150
236,269
246,528
1.089
1.095
1.100
1.107
1.113
1.109
1.116
1.124
1.131
1.138
25.8
31.2
37.8
49.4
50.8
0.727
0.707
0.686
0.665
0.643
401,450
417,920
434,610
451,520
468,825
256,928
267,469
278,150
288,973
300,048
1.120
1.126
1.134
1.141
1.149
1.146
1.155
1.163
1.173
1.182
33.2
19.5
6.9
+4.3
+14.4
0.620
0.597
0.573
0.548
0.522
486,360
504,310
522,500
540,735
559,200
311,270
322,758
334,400
346,070
357,888
1.156
1.165
1.173
1.183
1.192
1.192
1.202
1.212
1.224
1.236
+24.1
+33.4
+42.1
+49.6
+55.9
0.496
0.469
0.441
0.413
0.384
Engineering Handbook
5-41
5-42
Density
lb/gal
Specific
Gravity
@ 60F
lbs NH4Cl
per bbl
Brine
bbls Water
per bbl
Brine
% Weight
Ammonium
Chloride
(NH4Cl)
8.4
1.007
7.0
0.990
1.98
8.45
1.013
10.5
0.981
3.00
8.5
1.020
19.0
0.969
5.30
8.6
1.031
30.0
0.940
8.40
8.7
1.044
42.0
0.919
11.50
8.8
1.055
53.0
0.900
14.40
8.9
1.068
65.0
0.881
17.40
9.0
1.079
77.0
0.860
20.40
9.1
1.128
88.0
0.840
23.00
9.2
1.103
100.0
0.819
25.90
9.5
1.139
135.0
0.750
33.90
Engineering Handbook
5-43
5-44
9.5
9.6
9.7
9.8
9.9
3.00
1.14
1.15
1.16
1.17
1.19
1.08
1.09
1.10
1.11
1.13
1.01
1.02
1.03
1.04
1.06
1.07
8.4
8.5
8.6
8.7
8.8
8.9
9.0
9.1
9.2
9.3
9.4
Specific
Gravity
@ 68F
Density
lb/gal
3.33
Ve* 104
0.356
0.390
0.420
0.450
0.480
0.203
0.233
0.264
0.294
0.325
0.022
0.052
0.083
0.113
0.144
0.174
bbl 11.6
CaCl2 per
bbl Brine
0.644
0.610
0.580
0.550
0.520
0.797
0.767
0.736
0.706
0.675
0.978
0.948
0.917
0.887
0.856
0.826
bbl Water
per bbl
Brine
+9
+6
+3
1
6
+21
+19
+17
+15
+12
+31
+30
+28
+27
+25
+23
Chrystallization Point,
F
Preparation of Calcium Chloride (CaCl2) Solutions Using Liquid 11.6 lb/gal CaCl2
15.0
16.0
17.0
19.0
20.0
9.0
10.0
11.0
12.0
14.0
1.0
2.0
4.0
5.0
6.0
7.0
Weight %
CaCl2
Density
lb/gal
10.0
10.1
10.2
10.3
10.4
10.5
10.6
10.7
10.8
10.9
11.0
11.1
11.2
11.3
11.4
11.5
11.6
Ve* 104
2.89
2.6
2.4
2.39
Engineering Handbook
+43
+53
37.0
38.0
32.0
33.0
34.0
35.0
36.0
15
0
+12
+23
+34
0.180
0.150
0.120
0.090
0.060
0.820
0.850
0.880
0.910
0.940
1.32
1.33
1.34
1.35
1.37
0.030
0.000
27.0
28.0
29.0
30.0
31.0
41
48
55
51
31
0.337
0.306
0.276
0.245
0.215
0.663
0.694
0.724
0.755
0.785
1.26
1.27
1.28
1.29
1.31
0.970
1.00
21.0
22.0
23.0
25.0
26.0
11
16
22
28
34
0.490
0.460
0.429
0.399
0.368
0.510
0.540
0.571
0.601
0.632
1.20
1.21
1.22
1.23
1.25
1.38
1.39
Weight %
CaCl2
Chrystallization Point,
F
bbl Water
per bbl
Brine
bbl 11.6
CaCl2 per
bbl Brine
Specific
Gravity
@ 68F
Preparation of Calcium Chloride (CaCl2) Solutions Using Liquid 11.6 lb/gal CaCl2 (continued)
5-45
bbl Water
per bbl
Brine
bbl KBr
per bbl
Brine
% KBr
Crystallization
Point, F
(LCTD)
8.3
8.6
8.7
8.8
8.9
1.000
0.985
0.980
0.974
0.967
15.1
21.9
28.1
34.8
4.2
6.0
7.6
9.3
32
30
30
29
28
9.0
9.1
9.2
9.3
9.4
0.962
0.956
0.954
0.947
0.942
40.8
47.0
52.6
58.6
64.7
10.8
12.3
13.6
15.0
16.4
27
27
26
26
25
9.5
9.6
9.7
9.8
9.9
0.937
0.932
0.928
0.922
0.916
70.6
76.6
82.3
88.5
94.8
17.7
19.0
20.2
21.5
22.8
24
23
22
22
21
10.0
10.1
10.2
10.3
10.4
0.911
0.905
0.901
0.895
0.888
100.8
106.9
112.7
119.0
125.4
24.0
25.2
26.3
27.5
28.7
19
18
17
16
15
10.5
10.6
10.7
10.8
10.9
0.883
0.878
0.872
0.865
0.858
131.4
137.6
143.8
150.6
157.0
29.8
30.9
32.0
33.2
34.3
14
12
13
20
27
11.0
11.1
11.2
11.3
11.4
11.5
0.854
0.847
0.842
0.835
0.829
0.824
162.6
169.2
175.5
181.2
188.2
194.2
35.2
36.3
37.3
38.3
39.3
40.2
33
41
49
57
66
75
Example:
To prepare 10 bbl of 10 lb/gal KBr:
10 0.911 = 9.1 bbl water; 10 100.8 = 1,008 lbs KBr
Add 1,008 lbs KBr to 9.1 bbl water.
5-46
11.6
lbm/gal
CaCl2
(bbl)
14.2
lbm/gal
CaBr2
(bbl)
94 to 97%
CaCl2 (lb)
(Flakes or
Pellets)
Crystallization
Point
(o F )
11.7
.9714
.0246
3.5
+45
11.8
.9429
.9429
6.9
+51
11.9
.9143
.0738
10.4
+52
12.0
.8857
.0984
13.9
+54
12.1
.8572
.1229
17.4
+55
12.2
.8286
.1475
20.8
+55
12.3
.8000
.1722
24.3
+56
12.4
.7715
.1967
27.8
+56
12.5
.7429
.2213
31.2
+57
12.6
.7143
.2459
34.7
+58
12.7
.6857
.2705
38.2
+58
12.8
.6572
.2951
41.7
+58
12.9
.6286
.3197
45.1
+59
13.0
.6000
.3443
48.6
+59
13.1
.5714
.3689
52.1
+60
13.2
.5429
.3935
55.5
+60
13.3
.5143
.4181
59.0
+60
13.4
.4851
.4432
62.6
+61
13.5
.4572
.4672
66.0
+61
13.6
.4286
4919
69.4
+62
13.7
.4000
.5165
72.9
+62
13.8
.3714
.5411
75.4
+63
13.9
.3429
.5656
79.8
+63
Engineering Handbook
5-47
11.6
lbm/gal
CaCl2
(bbl)
14.2
lbm/gal
CaBr2
(bbl)
94 to 97%
CaCl2 (lb)
(Flakes or
Pellets)
Crystallization
Point
(o F )
14.0
.3143
.5903
83.3
+64
14.1
.2857
.6149
86.8
+64
14.2
.2572
.6394
90.3
+64
14.3
.2286
.6640
93.7
+65
14.4
2000
.6886
97.2
+65
14.5
.1715
.7132
100.7
+65
14.6
.1429
.7378
104.2
+66
14.7
.1143
.7624
107.6
+66
14.8
.0858
.7869
111.1
+67
14.9
.0572
.8116
114.6
+67
15.0
.0286
.8361
118.0
+67
15.1
.0000
.8608
121.5
+68
Conversions
ppm CaCl2 = % wt 10, 000
ppm Cl = PPM CaCl2 .64
Formulas
When using 78% CaCl2,
( lb /bbl ) = 95% CaCl 2 1.218
m
78% CaCl 2
95% CaCl 2
( lb /bbl )
( lb /bbl )
H2 O
New H 2 O
m
m
=
-----------------------------------------------------------------8.345
( gal/bbl )
( gal/bbl )
5-48
lb CaCl2 per
bbl Brine
bbl 14.2
CaBr2 per
bbl Brine
bbl Fresh
Water
per bbl Brine
lb/gal
lb/ft3
11.7
11.8
11.9
87.52
88.26
89.01
193.39
191.00
188.42
0.0254
0.0507
0.0762
0.8163
0.7924
0.7683
12.0
12.1
12.2
12.3
12.4
89.76
90.51
91.26
92.00
92.75
185.85
183.28
180.70
178.13
175.56
0.1016
0.1269
0.1524
0.1778
0.2032
0.7443
0.7203
0.6963
0.6723
0.6483
12.5
12.6
12.7
12.8
93.50
94.25
95.00
95.74
172.99
170.41
167.83
165.27
0.2286
0.2540
0.2794
0.3048
0.6243
0.6003
0.5762
0.5523
13.0
13.1
13.2
13.3
13.4
97.24
97.99
98.74
99.48
100.23
160.12
157.54
154.97
152.40
149.82
0.3556
0.3810
0.4064
0.4318
0.4572
0.5042
0.4802
0.4562
0.4322
0.4082
13.5
13.6
13.7
13.8
13.9
100.98
101.73
102.48
103.22
103.97
147.26
144.68
142.12
139.54
136.98
0.4826
0.5080
0.5334
0.5589
0.5842
0.3842
0.3602
0.3361
0.3121
0.2882
14.0
14.1
14.2
14.3
14.4
104.72
105.47
106.22
106.96
107.71
134.40
131.84
129.26
126.68
124.11
0.6069
0.6351
0.6604
0.6858
0.7113
0.2641
0.2401
0.2161
0.1921
0.1681
14.5
14.6
14.7
14.8
14.9
108.46
109.21
109.96
110.70
111.45
121.54
118.97
116.39
113.82
111.25
0.7366
0.7620
0.7875
0.8128
0.8382
0.1441
0.1201
0.0961
0.0721
0.0481
15.0
15.1
112.20
112.95
108.67
106.10
0.8637
0.8891
00.241
0.0000
Example:
To prepare 10 bbl of 13.0 lb/gal CaBr2 from minimum 94% solid CaCl2 and
14.2 lb/gal liquid CaBr2: Add 10 160.1 = 1600 lbs of solid CaCl2 to
10 0.35 = 3.5 bbl of 14.2 lb/gal CaBr2 and 10 0.50 = 5.0 bbl of fresh water.
Engineering Handbook
5-49
lb 95% CaBr2
per bbl Brine
lb/gal
lb/ft3
11.0
11.1
11.2
11.3
11.4
82.28
83.03
83.78
84.52
85.27
0.889
0.887
0.884
0.878
0.869
150.8
155.9
160.9
167.4
174.5
11.5
11.6
11.7
11.8
11.9
86.02
86.77
87.52
88.26
89.01
0.867
0.864
0.863
0.849
0.849
179.6
184.7
188.9
198.3
202.6
12.0
12.1
12.3
12.4
8976
90.51
92.00
92.75
0.848
0.840
0.831
0.830
207.0
214.1
225.8
230.3
12.5
12.6
12.7
12.8
12.9
93.50
94.25
95.00
95.74
96.49
0.821
0.819
0.810
0.808
0.797
237.7
242.4
250.0
254.8
266.5
13.0
13.1
13.2
13.3
13.4
97.24
97.99
98.74
99.48
100.23
0.796
0.794
0.791
0.789
0.778
267.4
272.3
277.3
282.4
290.4
13.5
13.6
13.7
13.8
13.9
100.98
101.73
102.48
103.22
103.97
0.775
0.772
0.761
0.758
0.755
295.6
300.8
309.0
314.3
319.7
14.0
14.1
14.2
14.3
104.72
105.47
106.22
106.96
0.751
0.748
0.744
0.740
325.1
330.5
335.9
341.5
Example:
To prepare 10 bbl of 13.0 lb/gal CaBr2 from 95% solid CaBr2:
Add 10 267.4 = 2,675 lbs of 95% CaBr2 to 10 0.796 = 7.9 bbl of fresh
water.
5-50
Crystallization
Point (oF) (LCTD)
10.0
10.1
10.2
10.3
10.4
1.000
0.958
0.917
0.875
0.833
0.000
0.042
0.083
0.125
0.167
30
*
*
*
*
10.5
10.6
10.7
10.8
10.9
0.792
0.750
0.708
0.667
0.625
0.208
0.250
0.292
0.333
0.375
*
*
*
*
*
11.1
11.2
11.3
11.4
0.583
0.500
0.458
0.417
0.417
0.500
0.542
0.583
*
*
*
*
11.5
11.6
11.7
11.8
11.9
0.375
0.333
0.292
0.250
0.208
0.625
0.667
0.708
0.750
0.792
*
*
*
*
23
12.0
12.1
12.2
12.3
12.4
0.167
0.125
0.083
0.042
0.000
0.833
0.875
0.917
0.958
1.000
28
32
36
39
46
Engineering Handbook
5-51
bbl Water
per bbl
Brine
bbl NaCl
per bbl
Brine
lb NaBr
per bbl
Brine
Crystallization
Point, F
(LCTD)
10.0
10.1
10.2
10.3
10.4
0.886
0.883
0.880
0.877
0.874
110.0
106.0
102.0
97.8
93.7
0
9.3
18.6
27.9
37.1
30
*
*
*
*
10.5
10.6
10.7
10.8
10.9
0.871
0.868
0.865
0.862
0.859
89.6
85.6
81.5
77.4
73.4
46.4
55.7
65.0
74.3
83.6
*
*
*
*
*
11.0
11.1
11.2
11.3
11.4
0.856
0.853
0.850
0.847
0.844
69.3
65.2
61.2
57.1
52.9
92.8
102.0
111.0
121.0
130.0
*
*
*
*
*
11.5
11.6
11.7
11.8
11.9
0.841
0.838
0.835
0.832
0.829
48.8
44.8
40.7
36.6
32.6
139.0
149.0
158.0
167.0
177.0
*
*
*
*
*
12.0
12.1
12.2
12.3
12.4
0.826
0.823
0.820
0.818
0.815
28.5
24.4
20.4
16.3
12.2
186.0
195.0
204.0
214.0
223.0
37
41
47
49
53
12.5
12.6
12.7
0.812
0.809
0.806
8.1
4.1
0
232.0
242.0
251.0
56
60
63
5-52
Requirements for
1 bbl Brine
Requirements for
1 M3 of Brine
Crystal Point**
ppg
S.G.
H2 O
gals
NaBr
lbs
H2O/
M 3s
NaBr
kgs
8.4
1.007
41.81
4.08
0.996
11.65
31.0
0.6
8.5
1.019
41.66
9.60
0.992
27.38
30.0
1.1
8.6
1.031
41.51
15.07
0.988
42.99
29.0
1.7
8.7
1.043
41.35
20.60
0.984
58.77
29.0
1.7
8.8
1.055
41.18
26.15
0.981
74.62
28.0
2.2
8.9
1.067
41.02
31.70
0.977
90.44
26.0
3.3
9.0
1.079
40.85
37.39
0.973
106.68
25.0
3.9
9.1
1.091
40.69
42.92
0.969
122.45
24.0
4.4
9.2
1.103
40.51
48.55
0.965
138.52
23.0
5.0
9.3
1.115
40.34
54.20
0.961
154.64
22.0
5.6
9.4
1.127
40.17
59.84
0.956
170.72
21.0
6.1
9.5
1.139
39.99
65.52
0.952
186.92
20.0
6.7
9.6
1.151
39.81
71.21
0.948
203.15
19.0
7.2
9.7
1.163
39.64
76.91
0.944
219.42
18.0
7.8
9.8
1.175
39.46
82.58
0.939
235.62
16.0
8.9
9.9
1.187
39.27
88.33
0.935
252.01
15.0
9.4
10.0
1.199
39.09
94.05
0.931
268.34
14.0
10.0
10.1
1.211
38.90
99.81
0.926
284.75
12.0
11.1
10.2
1.223
38.72
105.56
0.922
301.18
11.0
11.7
10.3
1.235
38.53
111.33
0.917
317.62
10.0
12.2
10.4
1.247
38.34
117.09
0.913
334.07
8.0
13.3
10.5
1.259
38.16
122.86
0.909
350.52
6.0
14.4
10.6
1.271
37.97
128.62
0.904
366.96
5.0
15.0
10.7
1.283
37.78
134.41
0.900
383.48
4.0
15.6
10.8
1.295
37.59
140.19
0.895
399.98
2.0
16.7
10.9
1.307
37.40
146.02
0.890
416.62
0.0
17.8
Engineering Handbook
5-53
Requirements for
1 bbl Brine
Requirements for
1 M3 of Brine
Crystal Point**
ppg
S.G.
H2 O
gals
NaBr
lbs
H2O/
M 3s
NaBr
kgs
11.0
1.319
37.20
151.87
0.886
433.30
2.0
18.9
11.1
1.331
37.00
157.71
0.881
449.96
3.0
19.4
11.2
1.343
36.80
163.58
0.876
466.72
5.0
20.6
11.3
1.354
36.61
169.40
0.872
483.32
7.0
21.7
11.4
1.366
36.41
175.28
0.867
500.08
9.0
22.8
11.5
1.379
36.21
181.14
0.862
516.79
11.0
23.9
11.6
1.391
36.02
186.98
0.858
533.47
14.0
25.6
11.7
1.402
35.81
192.83
0.853
550.16
16.0
26.7
5-54
Engineering Handbook
20.20
30.47
40.86
51.38
62.02
72.80
83.71
94.75
105.83
117.24
128.68
140.26
151.97
163.81
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
10.0
11.0
12.0
13.0
14.0
15.0
175.79
10.05
1.0
16.0
HCOONa
(g/L)
HCOONa
(Wt%)
924.5
930.0
935.2
940.4
945.4
950.3
956.1
958.8
964.4
968.9
973.4
977.9
982.4
987.0
991.7
996.6
Initial H20
(mL/L)
1.0987
1.0921
1.0855
1.0789
1.0724
1.0668
1.0593
1.0528
1.0464
1.0400
1.0337
1.0275
1.0215
1.0157
1.0102
1.0049
Density
(S.G.)
9.152
9.097
9.042
8.987
8.933
8.878
8.824
8.770
8.716
8.663
8.611
8.559
8.509
8.461
8.415
8.371
Density
(ppg)
1.0816
1.0763
1.0693
1.0634
1.0578
1.0523
1.0470
1.0419
1.0369
1.0321
1.0273
1.0226
1.0179
1.0131
1.0083
1.0034
Correction
Factor
59424
55375
51372
47413
43600
39631
35808
32030
28297
24609
20966
17367
13813
10301
6829
3397
Sodium
(mg/L)
66.55
61.65
56.87
52.20
47.64
43.18
38.82
34.55
30.38
26.30
22.30
18.39
14.56
10.81
7.13
3.53
lbs
HCOONa
/bbl H2O
0.893
0.900
0.906
0.913
0.919
0.925
0.932
0.938
0.946
0.951
0.958
0.965
0.972
0.979
0.986
0.992
Activity
5-55
5-56
HCOONa
(g/L)
187.91
200.16
212.56
226.08
237.75
250.58
253.56
276.69
289.99
303.46
317.09
330.90
344.89
359.08
373.42
387.96
HCOONa
(Wt%)
17.0
18.0
19.0
20.0
21.0
22.0
23.0
24.0
25.0
26.0
27.0
28.0
29.0
30.0
31.0
32.0
826.9
832.7
839.3
845.9
852.4
858.9
865.2
871.5
877.8
883.9
890.0
896.0
901.9
907.7
913.5
919.1
Initial H20
(mL/L)
1.2124
1.2046
1.1969
1.1893
1.1818
1.1744
1.1671
1.1600
1.1529
1.1459
1.1390
1.1322
1.1254
1.1187
1.1120
1.1053
Density
(S.G.)
10.099
10.034
9.970
9.907
9.844
9.783
9.722
9.663
9.604
9.546
9.488
9.431
9.374
9.318
9.263
9.207
Density
(ppg)
1.2108
1.2010
1.1914
1.1822
1.1731
1.1643
1.1557
1.1474
1.1392
1.1313
1.1236
1.1160
1.1087
1.1016
1.0947
1.0880
Correction
Factor
131143
126228
121376
116586
111857
107188
102579
98027
93532
89092
84704
80369
76084
71848
67660
63519
Sodium
(mg/L)
164.41
156.96
149.73
142.70
135.87
129.22
122.75
116.46
110.33
104.36
98.54
92.87
87.34
81.95
76.69
71.56
lbs
HCOONa
/bbl H2O
0.759
0.770
0.780
0.790
0.800
0.810
0.819
0.828
0.836
0.844
0.852
0.859
0.866
0.873
0.880
0.887
Activity
Engineering Handbook
417.58
432.66
447.90
463.30
478.85
494.52
510.29
526.14
542.04
557.93
573.79
589.58
605.19
620.59
635.71
650.45
34.0
35.0
36.0
37.0
38.0
39.0
40.0
41.0
42.0
43.0
44.0
45.0
46.0
47.0
48.0
49.0
657.65
402.68
33.0
49.5
HCOONa
(g/L)
HCOONa
(Wt%)
672.1
678.2
689.9
701.1
711.7
721.9
731.6
740.9
749.9
758.5
766.8
774.9
782.7
790.3
797.7
806.0
812.1
819.0
Initial H20
(mL/L)
1.3286
1.3274
1.3244
1.3204
1.3156
1.3101
1.3041
1.2975
1.2906
1.2833
1.2757
1.2680
1.2601
1.2522
1.2442
1.2362
1.2282
1.2202
Density
(S.G.)
11.067
11.058
11.032
10.999
10.959
10.913
10.863
10.808
10.750
10.690
10.627
10.562
10.497
10.431
10.364
10.297
10.231
10.165
Density
(ppg)
1.4878
1.4746
1.4494
1.4264
1.4051
1.3863
1.3669
1.3497
1.3336
1.3184
1.3041
1.2905
1.2776
1.2654
1.2536
1.2423
1.2314
1.2210
Correction
Factor
222307
219874
214891
209782
204574
199293
193962
188601
183227
177855
172497
167165
161868
156613
151407
146253
141157
136119
Sodium
(mg/L)
342.45
335.67
322.50
309.82
297.61
286.86
274.51
263.56
252.99
242.78
232.91
223.37
214.13
205.19
196.52
188.12
179.98
172.08
lbs
HCOONa
/bbl H2O
0.616
0.617
0.619
0.622
0.626
0.630
0.636
0.643
0.651
0.660
0.670
0.680
0.691
0.702
0.713
0.725
0.736
0.748
Activity
5-57
5-58
HCOOK
(g/L)
10.06
20.25
30.55
40.97
51.51
62.16
72.92
83.79
94.78
105.88
117.11
128.45
139.91
151.49
163.21
175.05
HCOOK
(Wt%)
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
10.0
11.0
12.0
13.0
14.0
15.0
16.0
920.7
928.5
932.3
938.0
943.6
949.2
954.7
960.1
966.3
970.5
975.5
980.4
985.1
989.7
994.0
998.0
Initial H20
(mL/L)
1.0941
1.0881
1.0821
1.0762
1.0704
1.0646
1.0588
1.0531
1.0474
1.0417
1.0359
1.0302
1.0243
1.0164
1.0124
1.0063
Density
(S.G.)
9.114
9.063
9.014
8.965
8.916
8.868
8.820
8.772
8.725
8.677
8.629
8.581
8.533
8.484
8.433
8.382
Density
(ppg)
1.0862
1.0793
1.0726
1.0661
1.0597
1.0535
1.0476
1.0416
1.0359
1.0304
1.0261
1.0200
1.0161
1.0106
1.0061
1.0020
Correction
Factor
81363
75858
70413
65028
59700
54430
49214
44063
38946
33892
28890
23841
19044
14201
9411
4677
Potassium
(mg/L)
66.55
61.65
56.87
52.20
47.64
43.18
38.82
34.55
30.38
26.30
22.30
18.39
14.56
10.81
7.13
3.53
lbs
HCOOK/
bbl H2O
0.922
0.928
0.934
0.940
0.946
0.951
0.956
0.961
0.968
0.971
0.975
0.980
0.984
0.987
0.991
0.994
Activity
Engineering Handbook
199.14
211.40
223.80
236.34
249.04
261.88
274.88
288.04
301.36
314.84
328.49
342.30
356.29
370.44
18.0
19.0
20.0
21.0
22.0
23.0
24.0
25.0
26.0
27.0
28.0
29.0
30.0
31.0
384.76
187.03
17.0
32.0
HCOOK
(g/L)
HCOOK
(Wt%)
819.1
826.0
832.8
839.6
846.2
852.8
859.3
865.7
872.0
878.3
884.5
890.7
896.8
902.9
908.9
918.8
Initial H20
(mL/L)
1.2024
1.1950
1.1876
1.1804
1.1732
1.1661
1.1591
1.1522
1.1453
1.1386
1.1320
1.1254
1.1190
1.1126
1.1064
1.1002
Density
(S.G.)
10.016
9.954
9.883
9.832
9.773
9.714
9.666
9.598
9.541
9.485
9.429
9.375
9.321
9.268
9.216
9.164
Density
(ppg)
1.2209
1.2106
1.2007
1.1911
1.1817
1.1726
1.1638
1.1552
1.1467
1.1386
1.1305
1.1227
1.1151
1.1076
1.1003
1.0931
Correction
Factor
178833
172176
165599
159100
152680
146337
140071
133880
127763
121721
116750
109850
104019
98257
92561
86930
Potassium
(mg/L)
164.41
156.96
149.73
142.70
135.87
129.22
122.75
116.46
110.33
104.36
98.54
92.87
87.34
81.95
76.68
71.56
lbs
HCOOK/
bbl H2O
0.789
0.799
0.809
0.818
0.827
0.836
0.845
0.854
0.862
0.870
0.878
0.886
0.894
0.901
0.908
0.915
Activity
5-59
5-60
HCOOK
(g/L)
399.25
413.92
428.76
443.77
458.96
474.32
489.85
505.56
521.44
537.50
553.73
570.13
586.71
603.46
620.38
637.48
HCOOK
(Wt%)
33.0
34.0
35.0
36.0
37.0
38.0
39.0
40.0
41.0
42.0
43.0
44.0
45.0
46.0
47.0
48.0
691.8
700.8
709.7
718.4
726.9
735.3
743.6
751.7
759.7
767.6
775.3
782.9
790.3
797.7
804.9
812.1
Initial H20
(mL/L)
1.3281
1.3200
1.3119
1.3038
1.2958
1.2877
1.2798
1.2718
1.2639
1.2560
1.2482
1.2404
1.2327
1.2250
1.2174
1.2099
Density
(S.G.)
11.063
10.996
10.928
10.861
10.794
10.727
10.660
10.594
10.528
10.463
10.398
10.333
10.268
10.204
10.141
10.078
Density
(ppg)
1.4454
1.4269
1.4091
1.3920
1.3756
1.3599
1.3448
1.3303
1.3163
1.3028
1.2899
1.2773
1.2653
1.2536
1.2423
1.2314
Correction
Factor
296296
288348
280482
272697
264993
257369
249826
242363
234981
227679
220459
213320
206261
199283
192386
185569
Potassium
(mg/L)
322.50
309.82
297.61
285.85
274.51
263.56
252.99
242.78
232.91
223.37
214.13
205.19
196.52
188.12
179.98
172.08
lbs
HCOOK/
bbl H2O
0.627
0.638
0.648
0.658
0.668
0.678
0.689
0.699
0.709
0.719
0.730
0.740
0.750
0.760
0.770
0.780
Activity
Engineering Handbook
672.21
689.84
707.65
725.64
743.82
762.19
780.76
799.54
818.52
837.71
857.14
876.80
896.71
916.88
50.0
51.0
52.0
53.0
54.0
55.0
56.0
57.0
58.0
59.0
60.0
61.0
62.0
63.0
937.32
654.76
49.0
64.0
HCOOK
(g/L)
HCOOK
(Wt%)
528.2
539.5
550.6
561.6
572.5
583.2
593.8
604.2
614.6
624.7
634.8
644.7
654.4
664.0
673.5
682.7
Initial H20
(mL/L)
1.4646
1.4564
1.4463
1.4374
1.4286
1.4199
1.4112
1.4027
1.3942
1.3858
1.3774
1.3691
1.3609
1.3526
1.3444
1.3362
Density
(S.G.)
12.200
12.123
12.048
11.973
11.900
11.827
11.756
11.684
11.614
11.544
11.474
11.405
11.336
11.267
11.199
11.131
Density
(ppg)
1.8932
1.8537
1.8162
1.7807
1.7469
1.7147
1.6841
1.6550
1.6272
1.6007
1.5754
1.5512
1.5281
1.5081
1.4850
1.4648
Correction
Factor
435661
426167
416783
407529
398391
389363
380440
371618
362893
354262
345722
337272
328908
320630
312436
304325
Potassium
(mg/L)
621.10
594.87
570.02
546.45
52706
502.75
482.46
463.12
444.65
427.01
410.13
393.97
378.48
363.63
349.37
335.67
lbs
HCOOK/
bbl H2O
0.459
0.471
0.482
0.493
0.504
0.514
0.526
0.535
0.546
0.556
0.566
0.576
0.587
0.597
0.607
0.617
Activity
5-61
5-62
HCOOK
(g/L)
958.06
979.11
1000.49
1022.22
1044.33
1066.84
1089.79
1113.20
1137.10
1181.54
1186.56
HCOOK
(Wt%)
65.0
66.0
67.0
68.0
69.0
70.0
71.0
72.0
73.0
74.0
75.0
398.2
408.8
421.3
433.7
445.9
458.0
470.0
481.9
493.7
505.3
516.8
Initial H20
(mL/L)
1.5821
1.5697
1.5677
1.5461
1.5349
1.5241
1.5135
1.5033
1.4933
1.4835
1.4739
Density
(S.G.)
13.179
13.075
12.976
12.879
12.788
12.695
12.608
12.522
12.439
12.358
12.278
Density
(ppg)
2.5238
2.4459
2.3734
2.3058
2.2425
2.1832
2.1275
2.0751
2.0267
1.9790
1.9349
Correction
Factor
551503
539876
528517
517405
506525
495861
486397
476121
465020
455083
445300
Potassium
(mg/L)
1048.11
994.36
944.59
898.38
855.35
815.20
777.63
742.41
709.33
678.19
648.83
lbs
HCOOK/
bbl H2O
0.294
0.314
0.333
0.350
0.366
0.381
0.396
0.409
0.423
0.436
0.447
Activity
Engineering Handbook
1.012
1.019
1.026
1.033
1.040
1.047
1.054
1.061
1.068
1.075
1.082
1.090
1.097
10
11
12
13
14
1.104
1.005
Percent
Weight
15
Specific
Gravity
(g/cm3)
9.21
9.15
9.09
9.03
8.97
8.91
8.85
8.80
8.74
8.68
8.62
8.56
8.5
8.45
8.39
Density
(lb/gal)
164
152
141
129
118
106
95
84
73
62
51
41
30
20
10
85%
Ca(NO3)2
935
940
945
950
954
959
963
968
972
976
980
985
989
993
997
H2O Using
85%
Ca(NO3)2
(L/m3)
169708
157083
144657
132429
120395
108552
96898
85429
74143
63036
52105
41349
30762
20043
10089
Ca(NO3)2
(mg/L)
34160
31676
29224
26802
24411
22050
19718
17416
15142
12897
10680
8490
5327
4191
2080
Calcium
(mg/L)
1.069
1.064
1.059
1.054
1.049
1.044
1.039
1.034
1.030
1.025
1.021
1.016
1.011
1.007
1.002
Volume
IncreaseFactor
85%
Ca(NO3)2
0.960
0.963
0.966
0.969
0.972
0.974
0.977
0.980
0.983
0.985
0.988
0.990
0.993
0.995
0.998
Aw
5-63
5-64
Specifc
Gravity
(g/cm3)
1.111
1.119
1.126
1.134
1.141
1.149
1.156
1.164
1.171
1.179
1.187
1.195
1.203
1.211
1.219
Percent
Weight
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
10.17
10.10
10.04
9.97
9.91
9.84
9.78
9.71
9.65
9.58
9.52
9.46
9.40
9.34
9.27
Density
(lb/gal)
362
348
334
320
306
292
279
265
252
239
226
214
201
189
175
85%
Ca(NO3)2
852
858
865
871
876
882
888
894
899
905
910
915
920
925
930
H2O Using
85%
Ca(NO3)2
(L/m3)
385156
369169
353426
337925
322664
307538
292846
278283
263948
249836
235946
222274
208818
195573
182538
Ca(NO3)2
(mg/L)
75484
72477
69508
66576
63681
60823
58001
56215
52464
49748
47067
44419
41805
39224
36676
Calcium
(mg/L)
1.172
1.163
1.155
1.147
1.139
1.132
1.124
1.117
1.111
1.104
1.098
1.092
1.086
1.080
1.074
Volume
IncreaseFactor
85%
Ca(NO3)2
0.898
0.904
0.909
0.913
0.918
0.922
0.927
0.931
0.935
0.939
0.942
0.948
0.950
0.953
0.956
Aw
Engineering Handbook
1.235
1.243
1.252
1.260
1.268
1.277
1.286
1.294
1.303
1.312
1.321
1.33
1.339
31
32
33
34
35
36
37
38
39
40
41
42
43
44
1.348
1.227
Percent
Weight
45
Specifc
Gravity
(g/cm3)
11.25
11.17
11.10
11.02
10.95
10.87
10.80
10.73
10.66
10.59
10.51
10.44
10.38
10.31
10.24
Density
(lb/gal)
600
583
566
549
532
516
500
484
468
452
437
421
406
392
377
85%
Ca(NO3)2
745
753
761
769
776
784
791
799
806
813
820
826
833
839
846
H2O Using
85%
Ca(NO3)2
(L/m3)
656389
636370
616640
597197
578038
559159
540558
522232
504178
486392
468872
451615
434618
417878
401392
Ca(NO3)2
(mg/L)
125444
121815
118230
114690
111193
107740
104329
100961
97634
94349
91105
87901
84738
81614
78530
Calcium
(mg/L)
1.347
1.332
1.318
1.304
1.291
1.278
1.265
1.253
1.242
1.231
1.220
1.210
1.200
1.190
1.181
Volume
IncreaseFactor
85%
Ca(NO3)2
0.797
0.805
0.814
0.821
0.829
0.837
0.844
0.851
0.857
0.864
0.870
0.876
0.882
0.888
0.893
Aw
5-65
5-66
Specifc
Gravity
(g/cm3)
1.357
1.367
1.376
1.386
1.396
Percent
Weight
46
47
48
49
50
11.65
11.57
11.49
11.41
11.33
Density
(lb/gal)
689
671
653
635
617
85%
Ca(NO3)2
703
712
720
729
737
H2O Using
85%
Ca(NO3)2
(L/m3)
760933
739421
718214
697308
676701
Ca(NO3)2
(mg/L)
144271
140413
136602
132837
129117
Calcium
(mg/L)
1.428
1.410
1.394
1.377
1.362
Volume
IncreaseFactor
85%
Ca(NO3)2
0.751
0.760
0.770
0.779
0.788
Aw
Chemical Information
This section contains the following information:
International Atomic Weights
Chemical Formulas of Common Treating Agents
Moh's Hardness Scale
Specific Gravity & Hardness: Common Oil Field
Materials
pH Ranges of Common Indicators
Approximate pH of Acids, Bases, and Oil Field
Chemicals
Normality (N) of Solutions
Chemicals Required to Remove Ionic
Contaminants
Effect of Salt on Calcium Solubility @ 72F
Effect of Caustic Soda on Calcium Solubility @
72F
Engineering Handbook
5-67
Actinium
Aluminum
Americium
Antimony
Argon
Arsenic
Astatine
Barium
Berkelium
Beryllium
Bismuth
Boron
Bromine
Cadmium
Calcium
Californium
Carbon
Cerium
Cesium
Chlorine
Chromium
Cobalt
Copper
Curium
Dysprosium
Einsteinium
Erbium
Europium
Fermium
Fluorine
Francium
Gadolinium
Gallium
Germanium
Gold
Hafnium
5-68
Symbol
Atomic Number
Ac
Al
Am
Sb
Ar
As
At
Ba
Bk
Be
Bi
B
Br
Cd
Ca
Cf
C
Ce
Cs
Cl
Cr
Co
Cu
Cm
Dy
Es
Er
Eu
Fm
F
Fr
Gd
Ga
Ge
Au
Hf
89
13
95
51
18
33
85
56
97
4
83
5
35
48
20
98
6
58
55
17
24
27
29
96
66
99
68
63
100
9
87
64
31
32
79
72
Atomic Weight*
227.0278
26.9815
(243)
121.75
39.948
74.9216
(210)
137.34
(247)
9.0122
208.9804
10.81
79.904
112.40
40.08
(251)
12.011
140.12
132.9054
35.453
51.996
58.9332
63.546
(247)
162.50
(254)
167.26
151.96
(257)
18.9984
(223)
157.25
69.72
72.59
196.9665
178.49
Symbol
Atomic Number
Hahnium
Helium
Holmium
Hydrogen
Iridium
Iodine
Iridium
Iron
Krypton
Lanthanum
Lawerencium
Lead
Lithium
Lutetium
Magnesium
Manganese
Mendelevium
Mercury
Molybdenum
Neodymium
Neon
Neptunium
Nickel
Niobium
Nitrogen
Nobelium
Osmium
Oxygen
Palladium
Phosphorus
Platinum
Plutonium
Polonium
Potassium
Praseodymium
Promethium
Protactinium
Ha
He
Ho
H
In
I
Ir
Fe
Kr
La
Lr
Pb
Li
Lu
Mg
Mn
Md
Hg
Mo
Nd
Ne
Np
Ni
Nb
N
No
Os
O
Pd
P
Pt
Pu
Po
K
Pr
PM
Pa
105
2
67
1
49
53
77
26
36
57
103
82
3
71
12
25
101
80
42
60
10
93
28
41
7
102
76
8
46
15
78
94
84
19
59
61
91
Engineering Handbook
Atomic Weight*
(262)
4.0026
164.9304
1.0079
114.82
126.9045
192.22
55.847
83.80
138.9055
(260)
207.2
6.941
174.97
24.305
54.9380
(258)
200.59
95.94
144.24
20.179
237.0482
58.70
92.9064
14.0067
(255)
190.2
15.9994
106.4
30.9738
195.09
(244)
(209)
39.098
140.9077
(145)
231.0359
5-69
Symbol
Atomic
Number
Radium
Radon
Rhenium
Rhodium
Rubidium
Rutherfordium
Ruthenium
Samarium
Scandium
Selenium
Silicon
Silver
Sodium
Strontium
Sulfur
Tantalum
Technetium (Masurium)
Tellurium
Terbium
Thallium
Thorium
Thulium
Tin
Titanium
Tungsten
Uranium
Vanadium
Xenon
Ytterbium
Yttrium
Zinc
Zirconium
Ra
Rn
Re
Rh
Rb
Rf
Ru
Sm
SC
Se
Si
Ag
Na
Sr
S
Ta
Tc
Te
Tb
TI
Th
Tm
Sn
Ti
W
U
V
Xe
Yb
Y
Zn
Zr
88
86
75
45
37
104
44
62
21
34
14
47
11
38
16
73
43
52
65
81
90
69
50
22
74
92
23
54
70
39
30
40
Atomic
Weight*
226.0254
(222)
186.207
102.9055
85.4678
(261)
101.07
150.4
44.9559
78.96
28.086
107.868
22.9898
87.62
32.06
180.9479
(97)
127.60
158.9254
204.37
232.0381
168.9342
118.69
47.90
183.85
238.029
50.9414
131.30
173.04
88.9059
65.38
91.22
5-70
Aluminum stearate
Ammonium bisulfite
Anhydrite
Barite (MIL-BAR)
Calcium carbonate
Calcium chloride
Caustic soda (Sodium hydroxide)
Caustic potash (Potassium hydroxide)
Galena (Lead sulfide)
Gypsum
Lime
Potassium chloride
Phosphoric acid
Quick lime
Sodium acid pyrophosphate (SAPP)
Sodium bicarbonate
Sodium carbonate (Soda ash)
Sodium chloride
Sodium carboxymethylcellulose
Sodium sulfite
Sodium thiosulfate
Zinc carbonate (MIL-GARD)
Chemical Formula
Al(Cl8H36O2)3
(NH4)HSO3
CaSO4
BaSO4
CaCO3
CaCl2
NaOH
KOH
PbS
CaSO4 2H2O
Ca(OH)2
KCl
H3PO4
CaO
Na2H2P2O7
NaHCO3
Na2CO3
NaCl
RCH2COONa+
Na2SO3
Na2S2O3
2ZnCO3 3Zn(OH)2
Scale
Talc
Gypsum
Calcite
Flourite
Apatite
Orthoclase Feldspar
Quartz
Topaz
Corundum
Diamond
1 (softest)
2
3
4
5
6
7
8
9
10
Engineering Handbook
5-71
Anhydrite
Attapulgite
(SALTWATER GEL)
Barite (MIL-BAR)
Bentonite (MILGEL)
Calcite (Limestone)
Calcium chloride
Cement
Clay
Diesel oil
Dolomite
Feldspar
Galena
Graphite
Gypsum
Halite (Salt)
Hematite (DENSIMIX)
Illite (Clay)
Ilmenite
Magnesite
Montmorillonite (Clay)
Pyrite
Quartz
Salt
Sand
Shale
Siderite
Slate
Smithsonite
Sylvite
(Muriate of potash)
Water (Fresh)
5-72
Chemical
Formula
Specific
Gravity
Mohs
Hardness
CaSO4
2.9
2.3 - 2.7
BaSO4
CaCO3
CaCl2
CaMg(CO3)2
PbS
C
CaSO4 2H2O
NaCl
Fe2O3
FeTiO3
MgCO3
FeS2
SiO2
NaCl
FeCO3
ZnCO3
KCl
4.0 - 4.5
2.3 - 2.7
2.7 - 2.9
1.95
3.1 - 3.2
2.5 - 2.7
0.85
2.86
2.4 - 2.7
6.95
2.09 - 2.23
2.30 - 2.37
2.16 - 2.17
5.0 - 5.3
2.6 - 2.9
4.68 - 4.76
2.98 - 3.44
2.0 - 3.0
5.02
2.65
2.2
2.1 - 2.7
2.2 - 2.9
3.96
2.7 - 2.8
3.8
1.99
3.0 - 3.5
1.0 - 2.0
3.0
3.5 - 4.0
2.5 - 2.75
1.0 - 2.0
2.0
2.5
5.0 - 6.0
1.0 - 2.0
5.0 - 6.0
3.5 - 4.5
1.0 - 2.0
6.0 - 6.5
7.0
4.0 - 4.5
4.0 - 4.5
2.0
H2O
1.00
Cresol red*
Thymol blue
Metacresol purple*
Bromophenol blue
Congo red
Methyl orange
Bromocresol green
Ethyl red
Methyl red
Bromocresol purple
Bromothymol blue
Phenol red
Neutral red
* (Cresol red)
* (Metacresol purple)
Phenolphthalein
Thymolphthalein
Alizarin yellow R
2,4,6 Trinitrotoluene
1,3,5 Trinitrobenzene
Engineering Handbook
pH Range
Color
Change
0.4 - 1.8
7.0 - 8.8
1.2 - 2.8
1.2 - 2.8
7.4 - 9.0
3.0 - 4.6
3.0 - 5.0
3.2 - 4.4
3.8 - 5.4
4.0 - 5.8
4.8 - 6.0
5.2 - 6.8
6.0 - 7.6
6.6 - 8.0
6.8 - 8.0
7.0 - 8.8
7.4 - 9.0
8.2 - 10.0
9.4 - 10.6
10.1 - 12.0
11.5 - 13.0
12.0 - 14.0
Red
Yellow
Red
Red
Yellow
Yellow
Blue
Red
Yellow
Colorless
Red
Yellow
Yellow
Yellow
Red
Yellow
Yellow
Colorless
Colorless
Yellow
Colorless
Colorless
Yellow
Red
Yellow
Yellow
Purple
Blue
Red
Yellow
Blue
Red
Yellow
Purple
Blue
Red
Amber
Red
Purple
Pink
Blue
Red
Orange
Orange
5-73
Acetic, N
Acetic, 0.1N
Acetic, 0.01N
Alum, 0.1N
Boric, 0.1N
Carbonic (saturated)
Citric, 0.1N
Formic, 0.1N
Hydrochloric, N
Hydrochloric, 0.1N
Hydrochloric, 0.01N
Hydrogen sulfide, 0.1N
Orthophosphoric, 0.1N
Oxalic, 0.1N
Sulfuric, N
Sulfuric, 0.1N
Sulfuric, 0.01N
Sulfurous, 0.1N
pH
2.4
2.9
3.4
3.2
5.2
3.8
2.2
2.3
0.1
1.1
2.0
4.1
1.5
1.6
0.3
1.2
2.1
1.5
Bases
Ammonia, N
Ammonia, 0.1N
Ammonia, 0.01N
Borax, 0.1N
Calcium carbonate (saturated)
Calcium hydroxide (saturated)
Ferrous hydroxide (saturated)
Lime (saturated)
Magnesia (saturated)
Potassium hydroxide, N
Potassium hydroxide, 0.1N
Potassium hydroxide, 0.01N
Sodium bicarbonate, 0.1N
Sodium carbonate, 0.1N
Sodium hydroxide, N
Sodium hydroxide, 0.1N
Sodium hydroxide, 0.01N
5-74
pH
11.6
11.1
10.6
9.2
9.4
12.4
9.5
12.4
10.5
14.0
13.0
12.0
8.4
11.6
14.0
13.0
12.0
CHEMTROL X
FILTREX
LIGC
LIGCON
MILSTARCH
MIL-TEMP (ALL-TEMP)
NEW-DRILL HP (2% solution)
NEW-TROL
OILFOS
PERMA-LOSE HT
PROTECTOMAG M
SAPP
SHALE-TROL
*SOLTEX
UNI-CAL (3% solution)
pH
9.0 - 10.0
10.0
5.0 - 6.0
9.0 - 10.0
7.0
7.0
10.2
9.0 - 10.0
7.0
7.0
7.0
4.2
2.0 - 3.0
8.2
3.0
= ( 2 1 ) + ( 1 32 ) + ( 4 16 ) = 98
5-75
Factor
Treating Chemical
(lbm/bbl)
0.00093
Ca++
0.00074
Ca++
0.00097
Na2H2P2O7 (SAPP)
Ca++
0.00173
Mg++
0.00093
Na2CO3
Mg++
0.00116
SO4=
0.00073
BaCO3
CO3=
0.00043
Ca(OH)2 (Lime)**
CO3=
0.00100
HCO3
0.00021
Ca(OH)2**
HCO3
0.00200
PO4
0.00041
Ca(OH)2**
Example:
Titration of the filtrate shows a calcium level of 650 mg/L.
To remove all but approximately 100 mg/L, treat 550 mg/L
(650 100 = 550) of calcium with soda ash.
Therefore, soda ash required is approximately
550 0.00093 = 0.51 lbm/bbl.
5-76