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SPE 27368
Temperature Sensitivity of Formation Damage in Petroleum
Reservoirs
Anuj Gupta and Faruk Civan, U. of Oklahoma
SPE Members
Copyright 1994, Society of Petroleum Engineers, Inc.
This paper was prepared for presentation at the SPE IntI. Symposium on Formation Damage Control held in Lafayette, Louisiana, 7-10 February 1994.
This paper was selected for presentation by an SPE Program Committee following review of information contained in an abstract submitted by the author(s). Contents of the paper,
as presented, have not been reviewed by the Society of Petroleum Engineers and are subject to correction by the author(s). The material, as presented, does not necessarily reflect
any position of the Society of Petroleum Engineers, ItS officers, or members. Papers presented at SPE meetings are subject to publication review by Editorial Committees of the Society
of Petroleum Engineers. Permission to copy IS restricted to an abstract of not more than 300 words. Illustrations may not be copied. The abstract should contain conspicuous acknowledgment
of where and by whom the paper IS presented. Write librarian, SPE, P.O. Box 833836, Richardson, TX 750833836, U.S.A. Telex, 163245 SPEUT.
ABSTRACT
Temperature is an important yet often ignored
variable in translating laboratory measurement of oil and
gas recovery related operations to reservoir cond~ions.
The present study addresses the variation of formation
damage potential of a reservoir w~h temperature. A
strategy for obtaining the temperature sens~iv~y of various
model parameters determining the formation damage
potential of a reservoir rock is presented.
INTRODUCTION
Rock-fluid interactions in petroleum reservoirs
frequently lead to the impairment of permeabil~y of the
porous medium, commonly referred to as the formation
damage problem. Such interactions effect the efficiency of
recovery in oil and gas production operations. AHhough
most reservoirs are at higher temperatures and most
recovery processes involve temperature shocks, formation
damage studies are usually performed at constant, ambient
temperatures in the laboratory. In a thermal recovery
process, a reservoir is subjected to a rapid temperature rise
as shown in Fig. 1, whereas, in a water flooding process, a
reservoir is subjected to a rapid temperature drop as shown
in Fig. 2. The temperature shock can cause formation
damage in a manner analogous to salin~y shock. Colloidal
processes such as fines release, migration and trapping
and related phenomena such as thin film stabil~y and
301
2
TEMPERATURE SENSITIVITY OF FORMATION DAMAGE IN PETROLEUM RESERVOIRS
SPE27368
Thus, the laboratory measurement of fines release, aggregates of varying sizes. These asphaHic aggregates
migration and trapping potential and wettability at ambient cause formation damage by plugging and bridging of the
temperatures are not directly applicable at subsurface pore-channels on the downstream side.
reservoir temperatures.
In addnion, the absolute (c) During acidizing, the injected acids dissolve a part of the
permeabilijy, relative permeabilny and capillary pressure rock matrix, usually the cementing material in sandstones.
behavior at subsurface condnions may be qune different As these acids traverse deeper into the reservoir, their pH
from the laboratory measured values.
Therefore,
increases and at some point various saHs such as
knowledge of temperature dependence of these
barium/strontium suffate precipnate out of the solution and
parameters is a prerequisne for modeling of formation
iron and silica gel may be formed.
damage resuHing from the advancement of a temperature
(d) When an incompatible brine is injected into a reservoir
step front through the reservoir.
and contacts the reservoir brine during water flooding,
Development of efficient reservoir management some low solubilny minerals precipnate out of the solution
strategies for minimization or prevention of formation causing permeabilny reduction.
damage, and for the extrapolation of laboratory (e) In thermal recovery operations, high temperature steam
measurements requires an improved understanding of the or water dissolves clay type minerals from the reservoir
rock. These minerals are precipnated out of the solution as
sensnivny of various mechanisms of the overall formation
damage to temperature.
Frequently, the important they migrate further into the reservoir and the temperature
formation damage mechanisms incorporated in popular drops.
A comprehensive formation damage model
models involve various rate parameters and empirical
coefficients. In this study, a methodology for describing the typically involves the following parameters which
temperature dependence of the governing rate parameters characterize formation damage in hydrocarbon reservoirs:
and coefficients is developed. The variation of formation
1. Fines release rate constant.
damage potential of a reservoir wnh temperature using a 2. Fines migration potential.
physico-chemical predictive model is addressed. Concepts 3. Fines attachment/retention rate constant.
from the modified electrical double layer theory1 and 4. Electrolyte activijy parameters.
correlations for variation of important properties and 5. Interfacial tension between aqueous and non-aqueous
characteristics such as interfacial tension, viscosity, ions
fluid phases.
and surface sne dissociation constants are invoked to 6. Wettabilijy parameters of the particles and the pore wall
analyze the variation of the controlling lumped parameters
surfaces.
in formation damage models.
7. Relative permeabilny and capillary pressure
parameters.
BACKGROUND AND THEORY
8. Mineral Dissolution/Precipnation Rate Constants.
Formation damage in petroleum reservoirs is a 9. Coefficient of clay swelling.
manifestation of several complicated and coupled
phenomena acting together to reduce the permeabilny.
In thermal recovery processes, reservOIr IS
Some of the well known formation damage mechanisms subjected to steam at temperatures up to 300 degree
can be summarized as follows:
Celsius. The temperature gradients in the reservoir are
(a) Aggregates of pore lining or filling clays such as steep at the start of the injection and gradually level out with
kaolinne, smectne and iIIne swell and break off from the time. Heat transfer between the injected fluid and the
pore walls when contacted by fresher brines. These
reservoir rock and fluid causes the temperature front to
swelled up aggregates can cause pore-throat plugging or travel slower compared to the fluid frontS. Therefore, the
bridging downstream.
fluids injected later in me of the process will encounter a
(b) As oil flows towards a well-bore, the pressure drops. temperature gradient as they move through the reservoir.
Also the composnion may change during the displacements The ratio of temperature and fluid front velocnies is
wnh gaseous mixture. These changes may resuH in the
governed by the thermal conductivijy and heat capacny of
precipnation of the asphaHenes in the oil in the near well- the reservoir fluids and the rock as well as the fluid injection
bore region. The asphaHenes precipnated from the oil form
rate. In the following, physical phenomena governing
302
SPE 27368
ANUJ GUPTA AND FARUK CIVAN
3
various parameters in the formation damage models are
Fines Release and Capture Rate Constants
analyzed in order to describe their temperature
Rate constants for fines release from ~nd retention
dependence.
on the pore-walls depend upon the nature of the interfacial
interaction between particles and pore surfaces separated
Variation of Permeability Wnh Temperature
by a thin layer of carrier fluid. Various forces acting on a
The volume of the rock matrix changes wnh a typical particle are shown schematically in Figure 3. Such
change in temperature. This change will cause a change in
interactions are often expressed in the form of the variation
porosny of the media, when the bulk volume of the reservoir of interfacial energylforce wnh distance of separation
rock is confined. Consequently, the absolute permeabilijy between the particle and the pore wall. These interactions
of the reservoir rock changes because of the change in the consist of London-van der Waal's(Fvw), electrostatic (FEL),
pore channel sizes. Consider that the porosny-permeability hydration (FH), and Born repulsion (FBR) interactions. In
relationship for the reservoir rock can be represented by addHion, fluid flow field near the particle resutts in an
the Carman-Kozeny equation5 given as:
addHional hydrodynamic lift force (Fd. These component
forces can be added to obtain the resutting total normal
force on the particle, FN as:
(1)
where dp is the mean grain size and 't is the tortuosny for
the reservoir rock. Tortuosny is related to the mean porechannel length (Lp) of the reservoir and the sample length
(LREV) as:
't
= (Lp / LREy)2
(2)
EOE
ap
('I'
2'1'01'1'02 x
2
2
[ 'I' + 'I'
01
02
+ 'I' )x
01
02
,i
I + exp( - x: h)) In(1 - exp( - 2x: h)]
"ll - exp( - x: h)
(5)
303
2e2no )112
lC = ( tot kT
(6)
SPE 27368
where, a is the particle concentration (grnlbulk cm3) and
<Xc is the coefficient for the colloidal force release of
particles. Hydrodynamically induced rate of release of fines
can also be expressed by a simple first order process
as3,13,16:
a=aO, att=O
(9)
304
da
dt
= ah ('t _ 'tc)As
(10)
(11)
afw = a fwo
for t = 0
(12)
(13)
=0fwoexp[-(Kcrfw(csc -cs)
+ Khrfw(Uw -Uwc}}tJ
(14)
SPE27368
ANUJ GUPTA
resistance is dependent on temperature as well. Combined
temperature sensHivHy of viscosHy and particle-wall
attraction suggests that the particle release and retention
rate constants are strong functions of temperature.
Therefore, the overall coefficient of release rate a
increases wHh increase in T. The only temperature
dependence of a formation damage parameter reported in
the IHerature is on the colloidally induced release
coefficient.
Based on the formation damage tests
conducted at three different temperature condHions (0, 30
and 60 C), Khilar and Fogler3,13,16 found a linear
relationship between 10g(aJ and vr implying an Arrhenius
type expression:
a e =A exp(-AF1kl)
(15)
Thus, the particle release rate for the particle on the pore
surface is given by, according to Eq.9:
rr =Acr1 exp(-AF1kl)
(16)
(18)
where, E is the retention efficiency, nc is the number of
collectors (pore throats) per volume, dp is the particle
diameter and v is the interstHial velocHy.
305
SPE27368
containing water wet particles (Figure 7a). In the preferred
scenario, oil will be the main flowing phase and the wetting
phase will have a very low mobiltty. If the particles are
water-wet, they will be expected to stay in the water phase
which occupies the smaller pores and exists as thin wetting
films in the oil occupied pores. As a resuH the particles will
be constrained to the smallest pore channels and the film
region in the reservoir rock. In such cases, particle
mobility will be very small and formation damage will be
signnicantly less compared to the case where particles are
oil wet and mobile along wtth the oil phase.
Another possibiltty is that the pore wall surface is
oil-wet but the particles are water wet. In this sttuation, any
mobile water saturation will be distributed in the largest
pores. In a preferred sttuation, there will be Imle mobile
water but tt will be expected to contain a signnicant
concentration of fine particles. During displacement, when
water globules are squeezed through the pore throats,
many particles try to go through the pore throats at the
same time and there is a strong possibiltty for the particles
to form bridges across such pore throats causing a
signnicant reduction in permeabiltty. This phenomenon is
usually referred to as the log jam effect. It is reasonable to
conclude that the formation damage due to fines will be
more severe in the case of oil wet reservoir when the
particles are water-wet. In a similar manner, for oil wet
particles, tt can be shown that the formation damage will be
more severe in the case of water wet reservoir rocks. To
summarize, the particle release potential and the
corresponding damage are minimized if the pore surface
and the particles have similar wettability characteristics.
When the wettability of particle and surface are significantly
dnterent, then favorable condttions exist for bridging at the
pore throats.
The case of intermediate wet particles is especially
interesting. Preferred location for such particles is at the
oiVwater interface as indicated by the micromodel studies of
particle migration in porous media by Muecke 12. During the
displacement, these particles move along the interface and
form bridges as the interface passes through pore throats.
The particle concentration at the interface will fluctuate as
the interface stretches and shrinks.
The particle
concentration will be highest for the interface moving
through the pore throat. Therefore, the formation damage
is expected to be most severe for such intermediate-wet
particles.
the aqueous phase film to contact the oil phase to form true
contact angle. A similar relationship should apply for
transfer of oil wet particle to the water phase. In Eq. (19),
the induction time ~ is related to the thinning and rupture
of the intervening wetting phase film between the
bubble/drop and the particle. Such film thinning dynamics
is controlled by the film viscosity, interfacial tension and the
nature of interaction between the electrical double layers of
two film interfaces. As discussed earlier, viscostty of any
fluid decreases wtth temperature increase. Viscosity
decrease will lead to a reduction in the induction time
which, in tum, will lead to an increased rate of transfer of
particles from one phase to the other. Thus, an increase in
temperature promotes the transfer of water-wet particles,
which are held to the surface wtth the stationary residual
water phase, to the mobile oil phase.
Interfacial Tension Between Agueous and NonAgueous Fluid Phases
Consider Figure 8 illustrating the interaction
between particles attached to the pore wall and the
interface traversing through the pore. The Drag on the
particle due to interfacial forces is proportional to the
interfacial tension (1FT) between the two fluids. The
capillary forces, which are proportional to 1FT, tend to
mobilize the particles located at the pore walls and to
destabilize any particle bridges that might exist at pore
constrictions. As the temperature increases, the interfacial
tension decreases linearly and so does the fines
mobilization driven by the interfacial drag. In a similar
manner, the ability of the interfacial forces to destabilize the
particle bridges decreases as the temperature increases.
Wtth a decrease in interfacial tension, the formation
damage due to emulsion blocking should also decrease.
Wettability of the Particles and the Pore Wall
Surfaces
Since most reservoir rocks of interest will have a
minimum of two fluid phases (oil or gas and water)
occupying the pore space, any useful formation damage
modeling effort must address the formation damage
problem in muHiphase flow. In such flow sttuations, the
wettability of the formation fines and of the pore wall
surface plays a very important role. Figure 7 depicts some
of the possible combinations of particle and surface
wettability character. Most common and the easiest
sttuation to analyze is the water wet reservoir rock
306
SPE 27368
= crcos8 '(5)
~J
(20)
a<l>
AS
P1
-=--
at
(21)
SPE 27368
In a typical scenario, formation damage tests in the
laboratory can be conducted at different temperatures. The
typical test temperatures will be 75F, 125F, 175F, 225
F, and 300F. This test range covers the temperatures
likely to be encountered in most reservoirs and in most
recovery processes except steam flooding and in-snu
combustion. The tests at higher temperatures will require
application of sufficient back pressure at core outflow end in
order to prevent steam formation wnhin the porous media
flow channels. Since a core sample is likely to be
irreversibly damaged in a formation damage test, ft is
necessary to use a new core sample in each test. To
ensure that the model parameters obtained for each core
sample are applicable to other samples, all the samples
~u~ be fro~ the same formation and must have very
Similar porosity and permeabilfty values.
The candidate model can be used to extract model
parameters representing formation damage due to various
active mechanisms at each test temperatures. Correlations
can then be developed to obtain the overall functional
dependence of each model parameter on the temperature.
Knowledge of temperature dependence of model
parameters is essential to predict formation damage at
reservoir temperature and pressure condnions. This
temperature dependence can finally be incorporated into
the predictor model in order that the formation damage
occurring in the presence of temperature shocks
encountered in water flooding and in steam flooding
operations can be accounted for correctly.
SPE 27368
ANUJ GUPTA
et al.26 The solid squares correspond to the formation
damage (permeabilHy ratio) observed at various
temperature values when saturating brine (40,000 ppm) is
the displacing phase. The hollow squares represent the
permeabilHy reduction obtained when saturating brine
containing 2% caustic is the displacing phase. The ratio is
further normalized wHh respect to the formation damage
(permeabilHy ratio at 75 F) in order to compare tt wHh our
predictions. Such normalizing allows analysis of addHional
permeabilHy reduction obtained, over and above the
reduction obtained at 75 F, when the displacement is
conducted at a higher temperature. The agreement
between the normalized experimental permeabilHy ratios
and our predictions (for 15% porosHy reservoir rock) is
remarkably good. Thus, Happears that addHional formation
damage at higher temperatures, in displacements with
40,000 ppm brine can be explained satisfactorily by the
thermal expansion of the grain matrix. However, addHional
formation damage mechanisms are active in displacements
wHh the brine containing 2% caustic as suggested by the
data at 200 F(93.3C) and 300F (-148.9C). This is to be
expected because the latter fluid reacts wHh formation
matrix and fines, causing damage which is superimposed
on thermal expansion effects.
The preliminary resuHs indicate that temperature
shock can cause formation damage in a manner similar to
the salinHy shock. In addHion, tt is found that for a given
combination of reservoir rock matrix, brine and crude oil,
the formation damage potential of the reservoir is sensttive
to temperature. Therefore, the laboratory measurement of
fines release, migration and trapping potential and
wettability at ambient temperatures are not directly
applicable at subsurface reservoir temperatures. As a
result, absolute permeabilHy, relative permeabilHy and
capillary pressure behavior at subsurface condHions may
be quHe different from laboratory measured behavior.
Translation of laboratory resuHs to sub-surface temperature
is quHe complicated and loaded wHh uncertainties. Such
methodology needs to be carefully validated using
laboratory measurements.
CONCLUSIONS
A very important result, highlighted by the
permeability reduction resuHs presented in Figure 9 and 10,
and their good agreement wHh the experimental resuHs, is
that the formation damage in the reservoir will be different
from that measured at the surface temperature. Equation 3
9
provides a simple way of translating the laboratory
measurements of formation damage to the reservoir
condHions.
The product of the ambient condHion
damaged'undamaged permeabilHy ratio and the resuH of
Eq. 3 provides a measure of the formation
damaged'undamaged permeabilHy ratio at reservoir
condHions. This method gives reasonably good agreement
wHh the experimental data available in the IHerature.
However, Eq. 3 addresses just one of the many means of
permeability reduction.
Narrower damage zones wHh severe damage are
expected at higher temperatures. WHh temperature
increase, ability of the fluids to transport fines decreases.
As a result, there will be increased potential for physical
bridging and colloidal trapping of particles. For particles
and surfaces of similar wettabilHy, the particle release
potential is minimized. However, for the particles and
surfaces of opposHe wettabilHy, condHions are favorable for
bridging. Particles of intermediate wettability tend to
concentrate at the interface, move along wHh tt and,
therefore, are relatively easy to mobilize. WettabilHy
aHerations are possible wHh temperature shocks and
greater formation damage should be expected as the
system passes through an intermediate wettabilHy state.
1.
2.
3.
4.
5.
6.
309
REFERENCES
Gupta, A. and Sharma, M.M.: "StabilHy of Thin Aqueous
Films on Solid Surfaces-II. A Model For Aqueous Films
Bounded by Dissimilar Charge Regulating Surfaces," J.
of Colloid and Interface Science, V149, p407-424,
March, 1992.
Gruesbeck, C. and Collins, A.E.: "Entrainment and
DeposHion of Fine Particles in Porous Media," paper
SPE 8430 presented at the 1979 Annual Technical
Conference and ExhibHion, Las Vegas, Sept. 23-26.
Khilar, K.C. and Fogler, H.S.: "Water SensHivHy of
Sandstones," SPEJ (Feb. 1983) 55-64.
Civan, F. and Knapp, A.M. : "Effect of Clay Swelling
and Fines Migration on Formation PermeabilHy, paper
SPE 16235 presented at the 1987 SPE Production
Operations Symposium, Oklahoma CHy, March 8-10.
Lake, L.W.: Enhanced Oil Recovery, Prentice Hall, New
Jersey (1989).
Nakomthap, K. and Evans, A.D.: "Temperature
Dependent Relative PermeabilHy and Its Effect Upon
Oil Displacement by Thermal Methods, SPE 11217
10
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21
22.
23.
24.
25
26.
27.
28.
310
SPE27368
Symposium,
SPE27368
11
APPENDIX
Permeability-Porosity-Temperature Relationship
(A-8)
Pgv
=~(dVg)
Vg d T '
(A-l)
Finally, subst~uting Eq. A-3, A-4, A-8 and A-9 into Eq. 1
leads to the following expression for the dependence of
permeabil~y on temperature:
1391 = I3gv 13
f<I> dT
$_...,..T....::.o_....,-
(A-ll )
- (T -To)
TABLE I
Coefficients of Volumetric Thermal Expansion for Rock
Matrix Materials25
(d<ll )
(A-S)
~~=-~ d T '
T(C)
20
100
200
300
(A-7)
As a result, the dependence of
given by:
poros~y
on temperature is
311
Quartz
%
Expansio
n
0
0.0036
0.0078
0.0187
Calc~e
130'1
%
Expansion
130'1
4.49E-OS
4.32E-OS
6.62E-OS
0.0010S
0.0028S
0.0076S
1.31E-OS
1.S8E-OS
2.72E-OS
12
SPE27368
.-----------------~
Hot Waterl
Steam(Ti)
Tr
FIGURE 1: Temperature Distribution in Thennal Recovery
Processes
Cold
Injection "lids
(Til
h --.
Adhesive
312
SPE 27368
13
w~
2.5 ~\---+--+---+--+---+--I
wr.%,NaOH
+-l~-+--+---t----t--i
..... --
W-WET SURFACE,
W-WET PARTICLES
-2
-4
1.5 4-~A+--+----t----t----l
(a)
-6
O-WET SURFACE,
W-WET PARTICLES
(b)
_ .. _.' 8
.---.-- 10
- - - - 12
----- 14
-16
0.5 +---+--+-~~~~~~-+--I
W-WET SURFACE,
O-WET PARTICLES
270
310
290
370
350
330
(c)
Temp(K)
Viscos~y w~h
Temperature
a-WET SURFACE,
O-WET PARTICLES
(d)
10000
\
1000
\
"-
..,
"-
..2-
"" ~
...~
u
:;:
100
~
E
c:
"
52
"""-
"-
"-
10
"-
"~
~
Temperalure(K)
14
SPE27368
1\
0.9
1\
t'
1\
1\
0.8
1\
1\
1\
Porosity
0.7
"1\
-0.05
1\1\
- -0.1
-- ---
0.6
1\
0.15
1\
- - - 0.2
--'-0.25
1\
-0.3
0.5
t'
t't' t'r-
- -
1\
- 0.35
1\
Brine (26)
2% Caustic (26)
1\
04
1\
!\
0.3
50
100
150
200
250
300
Temperature(C)
50
100
150
200
250
300
Temperature(C)
314