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Chapter 1
H : Be : H
H
..
H:B:H
..
H
H
..
H:N:H
..
H
..
H:N:H
..
H
H
..
H:O:H
..
II
III
IV
A)
B)
C)
D)
E)
4.
A)
B)
C)
D)
E)
1s
2sp3 2sp3 2sp3 2sp3
the ground state of boron.
the sp3 hybridized state of carbon.
the sp3 hybridized state of nitrogen.
the ground state of carbon.
an excited state of carbon.
A)
B)
C)
D)
E)
CH3
CH3
A)
B)
C)
D)
E)
+2
+1
0
-1
-2
7. In which structure(s) below does the oxygen have a formal charge of +1?
H
..
O
..
O:
..
I
I only
II only
I and III
I and IV
I, III, and IV
s
A)
B)
C)
D)
E)
..
H3C
..
CH3
III
II
IV
CH3
Chapter 1
Chapter 1
I and II
III and IV
V
II
I and V
D) All of these
E) None of these
9. Which of the following molecules or ions has a nitrogen with a formal charge of -1?
(Charges on ions have been omitted.)
..
A) : N H
H
B) H
..
N
D) H3C
E) H3C
..
C) H
.H.
O
..
CH3
H
C
N:
CH2
..
.O.
..
F:
..
..
O
H
. .. .
:O H
B
:O
.. H
E) None of these
H3C
..
N
..
..
N
..
.OH
.
H3C
..
NH2
A)
B)
C)
D)
E)
D)
CH3
13. Listed below are electron dot formulas for several simple molecules and ions. All
valence electrons are shown; however, electrical charges have been omitted deliberately.
10. In which structure(s) below does nitrogen have a formal charge of +1?
H3C
..
H
H
H
B)
C) H
H3C
..
N
CH3
II
III
I
II and IV
III and V
I and V
V
IV
H
..
H:B:H
..
H
H
..
H:N:H
..
H
..
H:N:H
..
H
H
..
H:O:H
..
II
III
IV
A)
B)
C)
D)
E)
H : Be : H
CH3
Chapter 1
Chapter 1
14. Which compound contains a nitrogen atom with a formal positive charge?
A)
B)
C)
D)
E)
H
N
II
III
I
II
III
More than one of the above
None of the above
15. In which of these cases does the central atom have a zero formal charge?
A) HFH
H
B)
C)
H3C O
F
F
B
F
D)
H3C
CH3
H
N
CH3
H
CH3
E)
H3C
CH3
CH3
O H
17. Expansion of the valence shell to accommodate more than eight electrons is possible
with:
A) Fluorine
B) Nitrogen
C) Carbon
D) Sulfur
E) Beryllium
18.
A)
B)
C)
D)
E)
Based on VSEPR theory, which of the following would have a trigonal planar shape?
CH3)3N
HCN
NH4+
CH3!
CH3+
19.
A)
B)
C)
D)
E)
20.
A)
B)
C)
D)
E)
21.
A)
B)
C)
D)
E)
What would be the spatial arrangement of the atoms of the methyl anion, :CH3-?
Octahedral
Tetrahedral
Trigonal planar
Linear
Trigonal pyramidal
22.
A)
B)
C)
D)
E)
A)
B)
C)
D)
E)
0
-1
+1
-2
+2
Chapter 1
Chapter 1
28.
A)
B)
C)
D)
E)
24.
A)
B)
C)
D)
E)
25.
A)
B)
C)
D)
E)
26.
A)
B)
C)
D)
E)
27. Which is the shortest of the carbon-carbon single bonds indicated by arrows in the
following compounds?
A)
29.
A)
B)
C)
D)
E)
The greatest degree of ionic character is anticipated for the bond between:
H and C
H and Cl
C and Cl
H and Br
Br and Cl
C O
H
E) CH3CH3
Topic: Atomic Orbitals, Lewis structures, Resonance
31. Which of the structures below is not expected to contribute to the CO2 resonance
hybrid?
A)
O
C
C
O
O
H3C
CH3
B) O
C) O
D)
H3C
E)
H3C
CH
B)
C)
CH
CH2
C
C
O
O
D)
HC
CH
E) H2C
HC
C CH
Chapter 1
Chapter 1
Topic: General
36. Credit for the first synthesis of an organic compound from an inorganic precursor is
usually given to:
A) Berzelius
B) Arrhenius
C) Kekule
D) Wohler
E) Lewis
..
H 3C
Topic: Isomerism
37. CH3CH2OCH2CH3 and CH3CH2CH2CH2OH are examples of what are now termed:
A) Structural isomers
B) Resonance structures
C) Functional isomers
D) Empirical isomers
E) Constitutional isomers
C)
..
..
and
..
..
B)
..
.
:
H 3C
and
..
:
..
What is the empirical formula for cyclohexane? (Its molecular formula is C6H12.)
CH
CH2
C2H4
C6H6
C2H2
34. A compound consists only of carbon, hydrogen and oxygen. Elemental analysis gave:
C, 70.5%, H, 13.8%. The molecular weight of the compound was found to be 103 +/- 3.
What is the molecular formula for the compound?
A) C6H12O
B) C5H12O2
C) C3H2O4
D) C3H6O3
E) C6H14O
Topic: Isomerism
Br
A)
B)
C)
D)
E)
Br
Topic: Hybridization
38. What is the approximate hybridization state of the oxygen molecule in ethanol,
C2H5OH?
A) sp
B) sp2
C) sp3
D) p3
E) d2sp3
Br
II
III
I and II
II and III
I, II, and III
II, III, and IV
I, III, and IV
IV
A)
B)
C)
D)
E)
I
I and II
I and III
I, II, and III
I, II, III, and IV
II and III
II
III
10
IV
Chapter 1
Chapter 1
Topic: Isomerism
Topic: Isomerism
O
O
OH
A)
B)
C)
D)
E)
I
II
III
I
II
III
IV
All of the above are isomers of each other.
IV
and Br
H
Br
D)
H
Br
Br
and
A)
B)
C)
D)
E)
Br
CH3CH2CH2CH2CH=CH2
II
CH3CH=CHCH2CH2CH3
III
CH2=CHCH2CH2CH2CH3
IV
45.
A)
B)
C)
D)
E)
CH3CH2CH2CH=CHCH2CH2CH3
I
A)
B)
C)
D)
E)
CH3CH2CH2CH2CH2CH2CH=CH2
II
CH3CH2CH=CHCH2CH2CH2CH3
CH2=CHCH2CH2CH2CH2CH2CH3
III
IV
Which structures can exist as cis-trAns: isomers?
I and II
I and III
I and IV
II and III
I alone
11
A)
B)
C)
D)
E)
sp2, sp2
sp2, sp
sp2, sp3
sp3, sp2
sp, sp2
12
Chapter 1
Chapter 1
A)
B)
C)
D)
E)
I
II
III
IV
V
II
III
IV
13
Frga
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
Svar
B
C
C
C
E
B
E
B
A
A
D
A
B
D
E
A
D
E
C
B
E
D
B
D
C
D
D
A
B
A
D
C
B
E
E
D
E
C
B
C
A
D
B
E
C
E
C
E
D
E
Rtt/Fel
14
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