Académique Documents
Professionnel Documents
Culture Documents
Version: 1.0
SECTION 1: IDENTIFICATION
Product Identifier
Product Form: Mixture
Product Name: Bullseye- Power Pistol - BE-86 - E3 - Pro Reach - 20/28 Steel - Unique - Smokeless Powders
Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)
GHS01
GHS06
GHS07
GHS08
GHS09
: Danger
: H203 - Explosive; fire, blast or projection hazard.
H300+H310+H330 - Fatal if swallowed, in contact with skin or if inhaled.
H317 - May cause an allergic skin reaction.
H373 - May cause damage to organs through prolonged or repeated exposure.
H401 - Toxic to aquatic life.
H411 - Toxic to aquatic life with long lasting effects.
Precautionary Statements (GHS-US) : P210 - Keep away from extremely high or low temperatures, ignition sources, and
incompatible materials. - No smoking.
P240 - Ground/bond container and receiving equipment.
P250 - Do not subject to friction, grinding, shock.
P260 - Do not breathe dust, fume.
P262 - Do not get in eyes, on skin, or on clothing.
P264 - Wash hands, forearms, and other exposed areas thoroughly after handling.
P270 - Do not eat, drink or smoke when using this product.
03/11/2015
EN (English US)
1/12
Other Hazards
Accidental firing or explosion is likely to cause severe injury or death. Electrostatic charges generated by emptying package in or near
flammable vapor may cause flash fire. Overexposure may cause methemoglobinemia. Initial manifestation of methemoglobinemia is
cyanosis, characterized by navy lips, tongue and mucous membranes, with skin color being slate grey. Further manifestation is
characterized by headache, weakness, dyspnea, dizziness, stupor, respiratory distress and death due to anoxia. Exposure may
aggravate those with pre-existing eye, skin, or respiratory conditions.
Unknown Acute Toxicity (GHS-US) Not available
Product Identifier
(CAS No) 9004-70-0
(CAS No) 55-63-0
% (w/w)
54 - 60, 60 - 96
4 - 10, 10 - 30, 30 - 40
Rosin
<0.1, 0.1 - 1, 1 - 4
Diphenylamine
<0.1, 0.1 - 1
03/11/2015
EN (English US)
Classification (GHS-US)
Expl. 1.1, H201
Unst. Expl, H200
Acute Tox. 2 (Oral), H300
Acute Tox. 2 (Dermal), H310
Acute Tox. 2 (Inhalation:dust,mist), H330
STOT RE 2, H373
Aquatic Acute 2, H401
Aquatic Chronic 2, H411
Comb. Dust
Skin Sens. 1, H317
Aquatic Acute 2, H401
Acute Tox. 3 (Oral), H301
Acute Tox. 3 (Dermal), H311
Acute Tox. 3 (Inhalation:dust,mist), H331
Eye Irrit. 2A, H319
2/12
STOT RE 2, H373
Aquatic Acute 1, H400
Aquatic Chronic 1, H410
Urea, N,N'-diethyl-N,N'-diphenyl(CAS No) 85-98-3
<0.1, 0.1 - 1
Acute Tox. 4 (Oral), H302
Aquatic Acute 3, H402
Aquatic Chronic 3, H412
More than one of the ranges of concentration prescribed by Controlled Products Regulations has been used where necessary, due to
varying composition.
Full text of H-phrases: see section 16
EN (English US)
3/12
Protection During Firefighting: When controlling fire before involvement of explosives, fire-fighters should wear positive pressure
self-containing breathing apparatus (SCBA) and full turnout gear.
Hazardous Combustion Products: Carbon oxides (CO, CO2). Nitrogen oxides. Metal oxides.
Environmental Precautions
Prevent entry to sewers and public waters. Hazardous waste due to potential risk of explosion.
03/11/2015
EN (English US)
4/12
1.9 mg/m
0.02 ppm
0.05 ppm
0.05 ppm
1.86 mg/m
0.2 ppm
0.15 ppm
0.05 ppm
2 mg/m
0.2 ppm
2 mg/m
0.2 ppm
10 mg/m
Not Classifiable as a Human Carcinogen
10 mg/m
10 mg/m
10 mg/m
10 mg/m
10 mg/m
10 mg/m
10 mg/m
EN (English US)
5/12
Nunavut
Nunavut
Northwest Territories
Northwest Territories
Ontario
Prince Edward Island
Qubec
Saskatchewan
Saskatchewan
Yukon
Yukon
Rosin (8050-09-7)
USA ACGIH
Qubec
20 mg/m
10 mg/m
20 mg/m
10 mg/m
10 mg/m
10 mg/m
10 mg/m
20 mg/m
10 mg/m
20 mg/m
10 mg/m
dermal sensitizer
0.1 mg/m
Exposure Controls
Appropriate Engineering Controls: Proper grounding procedures to avoid static electricity should be followed. Emergency eye wash
fountains and safety showers should be available in the immediate vicinity of any potential exposure. Product to be handled in a
closed system and under strictly controlled conditions. Ensure all national/local regulations are observed.
Personal Protective Equipment: Gloves. Protective clothing. Safety glasses. Insufficient ventilation: wear respiratory protection.
Materials for Protective Clothing: For explosive-handling workers, caps and coveralls for full body (arms and legs) protection are
recommended. Cotton coveralls, underwear, socks and conductive shoes are recommended to avoid human static discharge.
Hand Protection: Wear chemically resistant protective gloves.
Eye Protection: Chemical goggles or safety glasses.
Skin and Body Protection: Wear suitable protective clothing. Wear long sleeves.
Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to
protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in
accordance with regulatory requirements and NIOSH standards. For high airborne concentrations, use an approved supplied-air
respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen
levels are inadequate, gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded.
Environmental Exposure Controls: Do not allow the product to be released into the environment.
Consumer Exposure Controls: Do not eat, drink or smoke during use
:
:
:
:
:
:
:
:
:
:
:
:
Solid
Small black/gray flakes
Not available
Not available
Not available
Not available
Not available
Not available
Not available
Not available
Not available
Not available
EN (English US)
6/12
:
:
:
:
:
:
:
:
:
:
Not available
Not available
Not available
Negligible at 20 C (68 F)
Not available
1.5 (approximate)
Negligible at 20 C (68 F)
Not available
Not available
Explosives, Division 1.3 - Chemicals and items which have a fire hazard and
either a minor blast hazard or a minor projection hazard or both, but not a
mass explosion hazard
Sensitive to mechanical impact
Static discharge could act as an ignition source.
EN (English US)
7/12
100 mg/kg
> 280 mg/kg
0.05 mg/l/4h
5000 mg/kg
Diphenylamine (122-39-4)
ATE US (oral)
ATE US (dermal)
ATE US (dust, mist)
Urea, N,N'-diethyl-N,N'-diphenyl- (85-98-3)
ATE US (oral)
Rosin (8050-09-7)
LD50 Oral Rat
LD50 Dermal Rabbit
Bioaccumulative Potential
Diphenylamine (122-39-4)
BCF Fish 1
Log Pow
Mobility in Soil Not available
51 - 253
3.5
03/11/2015
EN (English US)
8/12
:
:
:
:
Packing Group
Marine Pollutant
ERG Number
: I
: Marine pollutant
: 133
:
:
:
:
:
:
POWDER, SMOKELESS
1
UN0161
1.3C
F-B
S-Y
Marine pollutant
: Marine pollutant
:
:
:
:
:
: Marine pollutant
EN (English US)
9/12
US State Regulations
Nitroglycerin (55-63-0)
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
U.S. - Pennsylvania - RTK (Right to Know) List
Nitrocellulose (9004-70-0)
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) List
Diphenylamine (122-39-4)
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
U.S. - Pennsylvania - RTK (Right to Know) List
Canadian Regulations
Bullseye- Power Pistol - BE-86 - E3 - Pro Reach - 20/28 Steel - Unique - Smokeless Powders
WHMIS Classification
Note: Explosives are not regulated under WHMIS. They are subject to the regulations of the
Explosives Act of Canada.
Nitroglycerin (55-63-0)
Listed on the Canadian DSL (Domestic Substances List)
WHMIS Classification
Note: Explosives are not regulated under WHMIS. They are subject to the regulations of the
Explosives Act of Canada.
Nitrocellulose (9004-70-0)
Listed on the Canadian DSL (Domestic Substances List)
WHMIS Classification
Note: Explosives are not regulated under WHMIS. They are subject to the regulations of the
Explosives Act of Canada.
Diphenylamine (122-39-4)
Listed on the Canadian DSL (Domestic Substances List)
Listed on the Canadian IDL (Ingredient Disclosure List)
IDL Concentration 0.1 %
WHMIS Classification
Class D Division 1 Subdivision B - Toxic material causing immediate and serious toxic effects
Class D Division 2 Subdivision B - Toxic material causing other toxic effects
Urea, N,N'-diethyl-N,N'-diphenyl- (85-98-3)
Listed on the Canadian DSL (Domestic Substances List)
WHMIS Classification
Uncontrolled product according to WHMIS classification criteria
Rosin (8050-09-7)
Listed on the Canadian DSL (Domestic Substances List)
WHMIS Classification
Class D Division 2 Subdivision B - Toxic material causing other toxic effects
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the SDS
contains all of the information required by CPR.
03/11/2015
EN (English US)
10/12
: 03/11/2015
: This document has been prepared in accordance with the SDS requirements of the OSHA
Hazard Communication Standard 29 CFR 1910.1200.
Acute toxicity (dermal) Category 2
Acute toxicity (inhalation:dust,mist) Category 2
Acute toxicity (oral) Category 2
Acute toxicity (dermal) Category 3
Acute toxicity (inhalation:dust,mist) Category 3
Acute toxicity (oral) Category 3
Acute toxicity (oral) Category 4
Hazardous to the aquatic environment - Acute Hazard Category 1
Hazardous to the aquatic environment - Acute Hazard Category 2
Hazardous to the aquatic environment - Acute Hazard Category 3
Hazardous to the aquatic environment - Chronic Hazard Category 1
Hazardous to the aquatic environment - Chronic Hazard Category 2
Hazardous to the aquatic environment - Chronic Hazard Category 3
Combustible Dust
Explosive Category 1.1
Explosive Category 1.3
Serious eye damage/eye irritation Category 2A
Skin sensitization Category 1
Specific target organ toxicity (repeated exposure) Category 2
Unstable explosives
Unstable explosives
Explosive; mass explosion hazard
Explosive; fire, blast or projection hazard
May form combustible dust concentrations in air
Fatal if swallowed
Toxic if swallowed
Harmful if swallowed
Fatal in contact with skin
Toxic in contact with skin
May cause an allergic skin reaction
Causes serious eye irritation
Fatal if inhaled
Toxic if inhaled
May cause damage to organs through prolonged or repeated exposure
Very toxic to aquatic life
Toxic to aquatic life
Harmful to aquatic life
Very toxic to aquatic life with long lasting effects
Toxic to aquatic life with long lasting effects
Harmful to aquatic life with long lasting effects
EN (English US)
11/12
03/11/2015
EN (English US)
12/12