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CICLO: 2010 - I
2.
0
5
15
35
660 330 165 82.5
4.
500 C
P(kN/m2)
7.33
8.53
10.5
11.9
t(min)
0
2.0
6.0
10.0
520 C
P(kN/m2)
7.33
9.67
12.3
13.6
t(min)
0
2.0
6.0
540 C
P(kN/m2)
7.33
11.2
13.9
SOLUCION 1
TIEMPO
(SEG)
a
(mol/lt)
a-x
(mol/lt)
Ln(a/(a-x))
x/(a(a-x))
900
1800
3180
3900
1
1
1
1
0.8350
0.6800
0.5000
0.4300
0.1803
0.3857
0.6931
0.8440
0.1650
0.3200
0.5000
0.5700
0.1976
0.4706
1.0000
1.3256
ORDEN CERO
X =Kt
Ko=
0.0001347
r o=
0.99529
PRIMER ORDEN
Ln(a/(a-x))= Kt
K1=
r 1=
0.0002216 SEG-1
0.99990
SEGUNDO ORDEN
x/(a(a-x))= Kt
K2=
r 2=
0.0003763 LT*MOL-1*SEG-1
0.99763
SOLUCION 2
TIEMPO
Po
a-x
Ln(a/(a-x))
(hr)
(mmHg
Pr
Ln(Po/Pr)
x=Po-Pr
x/(a(a-x))
(PoPr)/PoPr
0
5
15
35
660
660
660
660
660.0000
330.0000
165.0000
82.5000
0.0000
0.6931
1.3863
2.0794
0.0000
330.0000
495.0000
577.5000
0.0000
0.0015
0.0045
0.0106
ORDEN CERO
X =Kt
Ko=
13.917391
r o=
0.84348
PRIMER ORDEN
Ln(a/(a-x))= Kt
K1=
0.0554518 SEG-1
r 1=
0.95917
SEGUNDO ORDEN
x/(a(a-x))= Kt
K2=
0.000303 LT*MOL-1*SEG-1
r 2=
1.00000
SOLUCION PROB.4
773K
Po= 7.33
(kN/m2)
TIEMPO
(min)
Ln (Po/Pr)
Pt
Prd=Pt-Po
Pr=Po-Prd
0
1.2
3.17
4.57
Pr=2Po-Pt
7.33
6.13
4.16
2.76
0
2
6
10
(kN/m )
7.33
8.53
10.5
11.9
0.0000
0.1788
0.5665
0.9767
PRIMER ORDEN
0.0978786 min-1
0.99971
Ln(Po/Pr)= Kt
K=
r 1=
793K
Po= 7.33
TIEMPO
(min)
Pt
0
2
6
10
(kN/m2)
7.33
9.67
12.3
13.6
(kN/m2)
Ln (Po/Pr)
Prd=Pt-Po
Pr=Po-Prd
0
2.34
4.97
6.27
Pr=2Po-Pt
7.33
4.99
2.36
1.06
0.0000
0.3845
1.1333
1.9337
PRIMER ORDEN
0.1927798 min-1
0.99989
Ln(Po/Pr)= Kt
K=
r 1=
813K
Po= 7.33
TIEMPO
(min)
Pt
0
2
6
(kN/m2)
7.33
11.2
13.9
(kN/m2)
Ln (Po/Pr)
Prd=Pt-Po
Pr=Po-Prd
0
3.87
6.57
Pr=2Po-Pt
7.33
3.46
0.76
PRIMER ORDEN
Ln(Po/Pr)= Kt
k=Ae-E*/RT
K=
r 1=
0.3779055 min-1
1.00000
0.0000
0.7507
2.2664
ln k = ln A + (-E*/R) (1/T)
k
ln k
0.0979
0.1928
0.3779
-2.3240
-1.6462
-0.9731
T
(K)
773
793
813
1/T
0.001294
0.001261
0.001230
-42038.2 CAL/MOL
-176429 J/MOL
PREGUNTA 5
k1= 0.0002597 seg-1
T1=
648 K
T2=
673 K
k2= ??
E*=
211300 J/K*mol
K1
1 1
T2 T1
K2
E*
Ln(
Ln (
K1
K2
Ln(
0.0002597
) 1.45693245
K2
0.0002597/k2 = 0.232949766
k2 = 0.0002597/0.232949766
k2=
0.001115 seg-1
1
1
T2
T1
8.314
1
1
673 648
0.0002597
) 211300/
K2
) E * /
Ln(