Vous êtes sur la page 1sur 25

Plagiarism Checker Tool

Abstract50% Unique Content


#

String

Uniqueness

investigated. The various natural products from the extract

Already Exists

respectively. UV-visible spectra show the absorption peak

Good

CuO and ZnO NPs, respectively. Crystalline nature of the

Good

XRD analysis. TEM images showed average size of ~ 17 nm

Good

respectively. The FTIR spectrum of plant leaf extract

Already Exists

groups such as, -OH, -C-N, and N-H, which are responsible

Good

CuO and ZnO NPs. Interestingly, the synthesized CuO and ZnO

Already Exists

dinucleotide (NADH). The current method provides a new path for

Already Exists

Introduction 66% Unique Content


#

String

Uniqueness

characteristic catalytic, electronic and optical properties (Falcaro

Good

(Falcaro et al. 2016). Various physical, chemical and biological

Already Exists

nanoparticles. The most accepted method for the synthesis

Good

2007; Ihsan et al. 2015). However in most of chemical methods

Already Exists

are expensive, toxic, high pressures, high energy requirement,

Already Exists

String

Uniqueness

energy requirement, difficult to separation and highly dangerous.

Already Exists

highly dangerous. Hence, in recent years green methods for

Already Exists

plants such as, Calotropis gigantea (Elumalai et al. 2015),

Good

(Elumalai et al. 2015), Tamarindus indica (Sharma et al.

Good

10

(Sharma et al. 2015), Thymus vulgaris (Nasrollahzadeh et

Good

11

(Nasrollahzadeh et al. 2016), Gloriosa superba (Raja Naika et al.

Good

12

(Raja Naika et al. 2015), Tinospora cordifolia (Udayabhanu

Already Exists

13

(Udayabhanu et al. 2015), Hibiscus subdariffa (Bala et al.

Good

14

subdariffa (Bala et al. 2015) and Pongamia pinnata (Sundrarajan

Good

15

pinnata (Sundrarajan et al. 2015) have been already reported.

Already Exists

16

of fields like, electronics, ceramics, polymers, inks, metallics,

Good

17

ceramics, polymers, inks, metallics, lubricant oil, coatings

Already Exists

18

lubricant oil, coatings and health care products, personal

Good

19

care products, personal care products, biosensors, catalysis

Good

20

products, biosensors, catalysis and biomedical applications (Collins

Good

21

(Collins et al. 2012; Elumalai et al. 2015; Sharma et al.

Already Exists

String

Uniqueness

22

Sharma et al. 2015; Song et al. 2014). Lingaraju and his

Good

23

(Lingaraju et al. 2015). The leaf extract of Calotropis gigantea

Good

24

(Sharama et al. 2015). Suresh and co-workers reported the

Good

25

(suresh et al. 2015). Ramesh at al. (2015) suggested the

Good

26

capping agent. There has been no report available so far

Already Exists

27

Camellia japonica (C. japonica) for the synthesis of CuO and ZnO

Good

28

CuO and ZnO NPs. The C. japonica is used locally to create

Already Exists

29

applications (Jeng et al. 2007; Nasrollahzadeh et al. 2016). Literature

Good

30

et al. 2016). Literature study show that this plant leaf

Good

31

several triterpenes, flavonoids and phenolic compounds (Zhang

Good

32

(Zhang et al., 2011; Salinero et al., 2012), which could

Already Exists

33

et al., 2012), which could have the ability to induce and

Good

34

nanoparticles. The plants extracts which contain the secret

Good

35

nanoparticles. The presence of capping agents during the

Good

36

and Durn 2015). The advantage of plant leaves extract based

Already Exists

37

ZnO NPs using C. japonica leaf extract which acted as inductive

Good

38

stabilizing agent. Interestingly, the synthesized CuO and ZnO

Good

String

Uniqueness

39

and selectivity. Experiments displays that the CuO and ZnO

Good

40

such as Fe3+, Ni2+, Mn2+, Hg2+, Cd2+, K+, Pb2+, and Cr3+

Already Exists

41

Cd2+, K+, Pb2+, and Cr3+ these can readily interact with

Already Exists

42

(Ohodnicki et al. 2013; Bindhu and Umadevi 2014). There have

Good

43

Umadevi 2014). There have been no reports so far about

Good

44

biological molecules. Thus, a sensitive and selective method for

Good

45

developed areas. The main advantages of the optical sensors

Already Exists

46

include sensitivity, selectivity, linearity, resolution, accuracy,

Already Exists

47

linearity, resolution, accuracy, reproducibility, dynamic range,

Good

48

dynamic range, and limit of detection (Ozbay, 2006).

Good

49

detection (Ozbay, 2006).

Good

50

cysteine and NADH. The various optical sensing methodologies

Already Exists

51

the literature, the optical sensor for metal ions and biomolecules

Good

52

reported early. The demonstrated optical sensor can distinguish

Good

53

experimental conditions. Such sensing characteristics of the present

Good

54

present sensor, point out the sensing capabilities of the

Good

55

biological sensors. In the present study, the synthesis and

Good

String

Uniqueness

56

extract of C. japonica has been described. The synthesized

Already Exists

57

characterized using UV, FTIR, XRD, SEM, TEM and EDS analysis. The

Already Exists

58

EDS analysis. The sensing of metal ions (Li+ and Ag+)

Good

Methodology 48% Unique Content


#

String

Uniqueness

aqueous extract. All chemicals used in this work were of

Already Exists

analytical grade. Cupric nitrate (Cu(NO3)23H2O) and zinc

Good

chemicals (China). All different metal ion salts, Iron sulfate,

Good

metal ion salts, Iron sulfate, Nickel nitrate, Lithium Hydroxide

Good

Hydroxide hydrate, Manganese II chloride, Mercury nitrate,

Already Exists

Mercury nitrate, Cadmium chloride, Pottasium carbonate, lead

Good

Pottasium carbonate, lead acetate, Silver nitrate and Chromium

Good

Chromium nitrate, in the form of chloride or nitrate were

Good

purification. The stock solutions of each metal ion were

Already Exists

10

deionized water. Two biomolecules like cysteine and -nicotinamide

Already Exists

11

deionized water, cut into small pieces and then transferred

Already Exists

12

deionized water. Then the extract was prepared by boiling

Already Exists

String

Uniqueness

13

on hot plate. The yellow color extract thus obtained was

Already Exists

14

through Whatman No. 1 filter paper. The extract was stored and

Good

15

Sharma et al., (2015). In brief, 100 mL of C. japonica

Already Exists

16

brief, 100 mL of C. japonica leaves extract was taken and boiled

Already Exists

17

with oil path. Later, about 10 g cupric nitrate (Cu(NO3)23H2O)

Good

18

using oil path. After complete dissolution of the mixture,

Already Exists

19

of the mixture, the solution was boiled until it was changed

Already Exists

20

colored paste. The paste was collected in a ceramic crucible

Good

21

Elumalai et al., (2015). In brief, 100 mL of C. japonica

Good

22

brief, 100 mL of C. japonica leaf aqueous extract was taken

Good

23

using oil path. When the temperature of the solution was

Good

24

reached at 60 C, 10g of zinc nitrate hexahydrate (Zn(NO3)26H2O)

Good

25

(Zn(NO3)26H2O) was added. Then the mixture was boiled until it becomes

Already Exists

26

colored paste. Then, it was transferred to a ceramic crucible

Good

27

400 C for 3 h. Finally obtained light yellowish white colored

Already Exists

28

spectroscopy (Shimadzu, UV-1750), fourier transform infrared (FTIR)

Already Exists

29

4000-400 cm1. X-ray diffraction (XRD) measurements were

Good

String

Uniqueness

30

radiation ( = 1.54178 A). The morphology and composition

Already Exists

31

microscopy (SEM, Hitachi S-4800) and SEM coupled energy-dispersive

Good

32

spectroscopy (EDS). The CuO and ZnO NPs size and surface morphology

Already Exists

33

microscopy (TEM, Hitachi JEM-2100).

Good

34

NPs solution, 0.5 mL of the freshly synthesized CuO and

Already Exists

35

blank solution. For the optical detection of metals ions

Already Exists

36

metals ions (Fe3+, Ni2+, Li+, Mn2+, Hg2+, Cd2+, K+, Pb2+, Ag+

Good

37

Hg2+, Cd2+, K+, Pb2+, Ag+ and Cr3+), appropriate amount

Good

38

volume 4 mL). The solution was checked for the color change

Already Exists

39

NADH (Scheme 2). In a typical procedure, an aqueous solution

Already Exists

40

absorbance value of 1. The observed changes in the optical absorption

Already Exists

Results and Discussion 52% Unique Content


#

String

Uniqueness

nanoparticles. The spectrum curves of the mono dispersed

Good

shown in Fig. 1. The optical absorbance was very sensitive

Already Exists

the particles, their inter particle distances, the surrounding

Good

particle distances, the surrounding media and the nature (Mulvaney

Good

String

Uniqueness

(Mulvaney 1996). The room temperature spectra exhibited strong

Good

NPs and ZnO NPs, respectively. FTIR spectroscopy analysis

Already Exists

nanoparticles . The FTIR spectra of C. japonica leaf extract

Already Exists

extract (Fig. 2a) has shown absorption bands at 3378 and

Good

alkane group. The absorption peak is located around 1628

Already Exists

10

aromatic rings. Stretching vibrations present at 1453 and

Already Exists

11

vibrations of polyols, respectively. Stretching vibrations are

Already Exists

12

was of amines, respectively. These bands indicate polyols

Already Exists

13

and flavonoids), terpenoids, and protein compounds are abundant

Already Exists

14

abundant in C. japonica leaf extract.

Good

15

synthesized CuO NPs. The spectrum showed bands at 480 cm-1 corresponding

Good

16

metaloxygen (MO). Strong bands were observed at 1096, 1138

Already Exists

17

observed at 1096, 1138 and 1372 cm1 and have been referred

Good

18

phenolic groups, CN stretching vibrations of aliphatic and

Good

19

and Kagel 1971), respectively. The peaks around 1618 cm1

Already Exists

20

(Tingfa 1989). The bands obtained at 2347 and 3420 cm1

Good

String

Uniqueness

21

alkanes and amines. FTIR spectra of biologically synthesis ZnO

Good

22

ZnO NPs (Fig. 2c) have shown absorption band at 3540,

Good

23

band at 3540, 2357, 1382, 1004 and 446 cm1, respectively.

Good

24

and 446 cm1, respectively. The peaks in the region between

Good

25

(ZnO) (Tas et al. 2002). The band at 446 cm1 confirms stretching

Already Exists

26

zinc oxide NPs. The shift observed in FTIR spectra of ZnO

Already Exists

27

participation of polyols, terpenoids, and proteins having functional

Good

28

groups of amines, alcohols, ketones, and carboxylic acid in

Good

29

bio-inducing reactions. Terpenoids are poorly water-soluble and

Good

30

the reaction. However, proteins seem to exhibit little

Good

31

nanoparticles. Therefore, water soluble phenolic acid and

Already Exists

32

role in reaction. But, the possible mechanism is still unclear

Good

33

investigation.The crystalline size and structural properties

Already Exists

34

X-ray diffraction. The XRD patterns of biologically synthesized

Already Exists

35

extract of C. japonica are shown in Fig. 3. The CuO NPs

Good

36

shown at (110), (002), (111), (202), (020), (202), (113),

Good

37

(020), (202), (113), (311) and (113) respectively in

Good

String

Uniqueness

38

respectively in Fig 3a. The diffraction reflection are well indexed

Already Exists

39

with JCPDS No. 45-0937 (Sharma et al. 2015), corresponding

Good

40

other phases. The XRD pattern of biologically synthesized

Already Exists

41

reflection value (100), (002), (101), (102), (110), (103), (112),

Good

42

(110), (103), (112), and (201) respectively as shown in

Already Exists

43

shown in Fig. 3b. the result of the XRD pattern coincide

Already Exists

44

with JCPDS No. 36-1451 (Elumalai et al. 2015). The strong

Already Exists

45

et al. 2015). The strong and narrow diffraction peak of

Good

46

crystalline nature. SEM analysis is used to determine the size

Good

47

nanoparticles. SEM images of biologically synthesized CuO

Already Exists

48

shown in Fig. 4. From the images (Fig. 4a, b) it is evident

Already Exists

49

aggregation observed. Fig. 4c, d shows different magnification

Good

50

size of ~17 nm. The plant leaf extract was responsible for

Already Exists

51

larger particles. The individual particles are well separated

Good

52

were observed. The particles are found to be agglomerated

Good

53

of the CuO NPs. The EDS spectrum shows that the chemical

Good

54

percent of 50.92 % for Cu and 49.08 % for O and thickly

Already Exists

String

Uniqueness

55

shown in Fig. 4e. Further, the EDS spectrum, Cu atom exhibited

Good

56

EDS spectrum, Cu atom exhibited strong signal, along with

Already Exists

57

strong signal, along with the small signal was exhibited

Already Exists

58

exhibited from O atom. The results indicated that the reaction

Already Exists

59

purity CuO NPs. Fig. 5a, b shows the SEM images of synthesized

Already Exists

60

magnifications. The SEM study provides the information on

Good

61

present exploration. We observed the synthesized ZnO NPs are

Already Exists

62

(Zhang et al. 2002; Azizi et al. 2014). The TEM analysis

Good

63

shown in Fig. 5c, d. The CuO NPs size was calculated from

Good

64

boundaries were found. The EDS spectrum shows that the chemical

Already Exists

65

percent of 54.35 % for Zn and 45.65 % for O and thickly

Good

66

shown in Fig. 5e. Further, the EDS spectrum, Zn atom exhibited

Already Exists

67

EDS spectrum, Zn atom exhibited strong signal, along with

Good

68

strong signal, along with the small signal was exhibited

Already Exists

69

exhibited from O atom. The results indicated that the reaction

Already Exists

Result and Discussion continue:89% Unique Content

String

Uniqueness

various metal (Fe3+, Ni2+, Li+, Mn2+, Hg2+, Cd2+, K+, Pb2+, Ag+

Already Exists

Hg2+, Cd2+, K+, Pb2+, Ag+ and Cr3+). 0.5 mL of (3 mM) salts

Already Exists

various metal (Fe3+, Ni2+, Li+, Mn2+, Hg2+, Cd2+, K+, Pb2+, Ag+

Already Exists

added into 3.5 ml of CuO NPs by drop by drop and stirred

Already Exists

stirred for 2 min. The UV-vis spectrum (Fig. 6a) of CuO NPs

Good

Hg2+, Cd2+, K+, Pb2+, Ag+ and Cr3+). 0.5 mL of (3 mM) salts

Good

of metal ions, after 2 min of interaction. It was observed

Good

added into 3.5 ml of CuO NPs by drop by drop and stirred

Good

color change. UV-vis spectrum of these metals ions interacted

Good

stirred for 2 min. The UV-vis spectrum (Fig. 6a) of CuO NPs

Good

shown in Fig. 6a. It was observed that for Li+ gave whitish

Good

of metal ions, after 2 min of interaction. It was observed

Already Exists

blue color (Fig. 6a inset) and there was no prominent peak

Already Exists

color change. UV-vis spectrum of these metals ions interacted

Already Exists

characteristics of CuO NPs, various concentrations of aqueous solution

Already Exists

shown in Fig. 6a. It was observed that for Li+ gave whitish

Already Exists

10

ions was added. The UV-vis absorption spectrum of CuO NPs

Good

String

Uniqueness

blue color (Fig. 6a inset) and there was no prominent peak

Good

11

room temperature, changes in the absorbance strength at peak

Already Exists

characteristics of CuO NPs, various concentrations of aqueous solution

Good

12

were monitored. Upon addition of 100 M Li+ solution to

Good

10

ions was added. The UV-vis absorption spectrum of CuO NPs

Already Exists

13

NPs solution, the light blue color disappeared and the

Good

11

room temperature, changes in the absorbance strength at peak

Already Exists

14

concentration. So the concentration of Li+ was limited

Good

12

were monitored. Upon addition of 100 M Li+ solution to

Good

15

notable band (Fig. 6b). After addition of Li+ to the biologically

Already Exists

13

NPs solution, the light blue color disappeared and the

Already Exists

16

synthesized CuO NPs, Li+ ions bound to the CuO NPs surface to

Good

14

concentration. So the concentration of Li+ was limited

Already Exists

17

compounds from C. japonica leaf extract away from the copper

Already Exists

15

notable band (Fig. 6b). After addition of Li+ to the biologically

Good

18

surface; as a result, a redox reaction between copper and lithium

Good

16

synthesized CuO NPs, Li+ ions bound to the CuO NPs surface to

Good

String

Uniqueness

19

(Takeda et al. 1985). It was also observed that the optical

Already Exists

17

compounds from C. japonica leaf extract away from the copper

Already Exists

20

concentration of Li+ ions. The main reason for optical broadening is

Already Exists

18

surface; as a result, a redox reaction between copper and lithium

Good

21

El-Sayed 2000). The observed band broadening of the optical

Good

19

(Takeda et al. 1985). It was also observed that the optical

Good

22

copper surface. The linear variation of absorbance (A290

Already Exists

20

concentration of Li+ ions. The main reason for optical broadening is

Good

23

shown in Fig. 6c. This plot can be fit by a linear equation

Good

21

El-Sayed 2000). The observed band broadening of the optical

Already Exists

24

equation y = 0.0023x +0.3511, R2 = 0.9894.

Already Exists

22

copper surface. The linear variation of absorbance (A290

Good

25

metal ions (Fe3+, Ni2+, Li+, Mn2+, Hg2+, Cd2+, K+, Pb2+, Ag+

Already Exists

23

shown in Fig. 6c. This plot can be fit by a linear equation

Already Exists

26

Hg2+, Cd2+, K+, Pb2+, Ag+ and Cr3+), 0.5 mL (3 mM) of stock

Already Exists

24

equation y = 0.0023x +0.3511, R2 = 0.9894.

Already Exists

27

added into the 3.5 mL of ZnO NPs solution. Upon interaction

Good

String

Uniqueness

25

metal ions (Fe3+, Ni2+, Li+, Mn2+, Hg2+, Cd2+, K+, Pb2+, Ag+

Good

28

various metal ions, the color of Ag+ solution changed from light

Good

26

Hg2+, Cd2+, K+, Pb2+, Ag+ and Cr3+), 0.5 mL (3 mM) of stock

Good

29

colorless (Fig. 7a inset. UV-vis spectra of interacted various

Already Exists

27

added into the 3.5 mL of ZnO NPs solution. Upon interaction

Already Exists

30

shown in Fig. 7a. It was observed that the optical bands

Good

28

various metal ions, the color of Ag+ solution changed from light

Good

31

of the ZnO NPs. To evaluate the sensitivity of this method,

Already Exists

29

colorless (Fig. 7a inset. UV-vis spectra of interacted various

Already Exists

32

of this method, various concentration of aqueous solution

Already Exists

30

shown in Fig. 7a. It was observed that the optical bands

Already Exists

33

room temperature. Fig. 7b shows the UV-vis absorption spectrum

Already Exists

31

of the ZnO NPs. To evaluate the sensitivity of this method,

Good

34

silver sensor. With increasing concentration from 10 M

Already Exists

35

M to 100 M, the intensity of the peak centered at 301

Good

32

of this method, various concentration of aqueous solution

Already Exists

33

room temperature. Fig. 7b shows the UV-vis absorption spectrum

Already Exists

String

Uniqueness

36

decreases gradually. When silver nitrate added to the synthesized

Good

34

silver sensor. With increasing concentration from 10 M

Good

37

nanoparticles, Ag+ ions interact with the biomolecules

Good

35

M to 100 M, the intensity of the peak centered at 301

Good

38

nanoparticles, in that way aggregation of nanoparticles

Already Exists

36

decreases gradually. When silver nitrate added to the synthesized

Already Exists

39

had taken place. In addition of 10-100 M Ag+ to the ZnO

Already Exists

37

nanoparticles, Ag+ ions interact with the biomolecules

Already Exists

40

NPs solution, causes color change from light yellow to

Good

38

nanoparticles, in that way aggregation of nanoparticles

Already Exists

41

to colorless. The observed color changes and absorbance

Already Exists

39

had taken place. In addition of 10-100 M Ag+ to the ZnO

Already Exists

42

were negligible, suggesting the formation of stable aggregates.

Good

40

NPs solution, causes color change from light yellow to

Already Exists

43

stable aggregates. So the concentration of silver was limited

Already Exists

41

to colorless. The observed color changes and absorbance

Good

44

notable band. The variations of absorbance at 301 nm shown

Already Exists

String

Uniqueness

42

were negligible, suggesting the formation of stable aggregates.

Already Exists

45

shown in Fig. 7c. The linear variation of absorbance (A301

Good

43

stable aggregates. So the concentration of silver was limited

Good

46

shown in Fig. 7c. This plot can be fit by a linear equation

Good

44

notable band. The variations of absorbance at 301 nm shown

Already Exists

47

equation y = 0.0132x +1.2664, R2 = 0.9882. Hence the CuO

Already Exists

45

shown in Fig. 7c. The linear variation of absorbance (A301

Already Exists

48

and silver ions, which is otherwise a spectroscopically silent

Good

46

shown in Fig. 7c. This plot can be fit by a linear equation

Already Exists

49

marine water. Table 1 summarized the comparison of analytical

Already Exists

47

equation y = 0.0132x +1.2664, R2 = 0.9882. Hence the CuO

Already Exists

50

of metal ions. The performance of the CuO and ZnO NPs based

Good

48

and silver ions, which is otherwise a spectroscopically silent

Already Exists

51

sensor is compared. Saha et al. (2012) reported the gold nanoparticles

Good

49

marine water. Table 1 summarized the comparison of analytical

Good

52

observed from Pb2+, Cd2+ and Hg2+ of 400 M, whereas Zn2+ displayed

Already Exists

50

of metal ions. The performance of the CuO and ZnO NPs based

Already Exists

String

Uniqueness

53

assay process. Chen and co-workers (Lin et al. 2006) reported

Already Exists

51

sensor is compared. Saha et al. (2012) reported the gold nanoparticles

Good

54

co-workers (Lin et al. 2006) reported the gold nanoparticles based

Good

52

observed from Pb2+, Cd2+ and Hg2+ of 400 M, whereas Zn2+ displayed

Good

55

Cd2+ and Hg2+. Mirkin and coworkers (Lee et al. 2007) have

Good

53

assay process. Chen and co-workers (Lin et al. 2006) reported

Good

56

coworkers (Lee et al. 2007) have employed DNA factionalized gold

Already Exists

54

co-workers (Lin et al. 2006) reported the gold nanoparticles based

Already Exists

57

detection of Hg2+. Ihsan et al. (2015) reported the green synthesis

Good

55

Cd2+ and Hg2+. Mirkin and coworkers (Lee et al. 2007) have

Already Exists

58

Zn2+ of 400 M. Farhadi et al. (2011) used the silver nanoparticles

Already Exists

56

coworkers (Lee et al. 2007) have employed DNA factionalized gold

Good

59

10 M ?00 M), decreases the absorption band. The present

Already Exists

57

detection of Hg2+. Ihsan et al. (2015) reported the green synthesis

Good

60

absorption band. The present two metal oxide nanoparticles

Already Exists

58

Zn2+ of 400 M. Farhadi et al. (2011) used the silver nanoparticles

Already Exists

61

Ag+ metal ions. The present two metal oxide nanoparticles

Already Exists

String

Uniqueness

59

10 M ?00 M), decreases the absorption band. The present

Already Exists

60

absorption band. The present two metal oxide nanoparticles

Already Exists

61

Ag+ metal ions. The present two metal oxide nanoparticles

Already Exists

Results and Discussion continue 90% Unique Content


#

String

Uniqueness

water environment. The CuO and ZnO NPs optical sensing system

Good

cost efficiency, accurate and reproducibility compare with

Good

water environment. The CuO and ZnO NPs optical sensing system

Good

sensing systems.Fig. 8 a, c shows the absorption spectral

Good

cost efficiency, accurate and reproducibility compare with

Already Exists

5 M cysteine. The absorption spectrum obtained for CuO

Already Exists

sensing systems.Fig. 8 a, c shows the absorption spectral

Already Exists

respectively (Fig. 8a, c). The absorption band intensity of

Good

5 M cysteine. The absorption spectrum obtained for CuO

Already Exists

cysteine (Fig. 8a (b-f) and 8c (b-f)). The isosbestic point

Already Exists

respectively (Fig. 8a, c). The absorption band intensity of

Already Exists

with CuO NPs. The decrease in the absorption intensity

Already Exists

String

Uniqueness

cysteine (Fig. 8a (b-f) and 8c (b-f)). The isosbestic point

Already Exists

assembly of CuO NPs. Cysteine can easily be bound on the surface

Already Exists

with CuO NPs. The decrease in the absorption intensity

Good

Jamshidi 2007). It has been reported that first a decrease

Good

assembly of CuO NPs. Cysteine can easily be bound on the surface

Good

10

NPs occurred. The extent of the shift in the optical absorption

Good

Jamshidi 2007). It has been reported that first a decrease

Already Exists

11

the solution. The corresponding calibration plot of absorbance

Already Exists

10

NPs occurred. The extent of the shift in the optical absorption

Good

12

shown in Fig. 8b, d. The calibration curve showed a good

Already Exists

11

the solution. The corresponding calibration plot of absorbance

Already Exists

13

of CuO NPs 0.9727 and ZnO NPs 0.9862) in the range of

Good

12

shown in Fig. 8b, d. The calibration curve showed a good

Already Exists

14

found to be 5 M. The obtained selective sensing of cysteine

Good

13

of CuO NPs 0.9727 and ZnO NPs 0.9862) in the range of

Already Exists

15

significant molecules.The absorption spectra were recorded for

Good

String

Uniqueness

14

found to be 5 M. The obtained selective sensing of cysteine

Already Exists

16

shown in Fig. 9a, c. The optical absorption intensity

Already Exists

15

significant molecules.The absorption spectra were recorded for

Good

17

M NADH (Fig. 9a, c) due to the adsorption of NADH molecules

Already Exists

16

shown in Fig. 9a, c. The optical absorption intensity

Already Exists

18

nanoparticles. The anchoring of NADH on the nanoparticle

Already Exists

17

M NADH (Fig. 9a, c) due to the adsorption of NADH molecules

Already Exists

19

(Maduraiveeran, and Ramaraj 2011; Muniz-Miranda et al. 2010).

Already Exists

18

nanoparticles. The anchoring of NADH on the nanoparticle

Already Exists

20

Muniz-Miranda et al. 2010). With each addition of NADH to the

Good

19

(Maduraiveeran, and Ramaraj 2011; Muniz-Miranda et al. 2010).

Already Exists

21

NPs solution, the optical absorption intensity of the

Already Exists

20

Muniz-Miranda et al. 2010). With each addition of NADH to the

Good

22

significantly (Fig. 9a, c). The isosbestic point was observed

Already Exists

21

NPs solution, the optical absorption intensity of the

Already Exists

23

with CuO NPs. The decrease in the optical absorption intensity

Already Exists

22

significantly (Fig. 9a, c). The isosbestic point was observed

Already Exists

String

Uniqueness

24

nanoparticles. A decrease in the optical absorbance was

Already Exists

23

with CuO NPs. The decrease in the optical absorption intensity

Good

25

addition of NADH. A change in the electron density on metal

Already Exists

24

nanoparticles. A decrease in the optical absorbance was

Good

26

Meisel 1998). Such interaction leads to a decrease in

Already Exists

25

addition of NADH. A change in the electron density on metal

Already Exists

27

biomolecules. The interaction of NADH with metal oxide

Already Exists

26

Meisel 1998). Such interaction leads to a decrease in

Good

28

2007; Li et al. 2010). The NADH molecules are adsorbed on

Good

27

biomolecules. The interaction of NADH with metal oxide

Already Exists

29

to each other. The calibration plot against the NADH concentration

Good

28

2007; Li et al. 2010). The NADH molecules are adsorbed on

Already Exists

30

straight line (Fig. 9b, d). The experimental limit of detection

Already Exists

29

to each other. The calibration plot against the NADH concentration

Good

31

found to be 10 M. A good linear relationship (correlation

Already Exists

30

straight line (Fig. 9b, d). The experimental limit of detection

Already Exists

32

CuO NPs was 0.9773 and ZnO NPs was 0.9693) between the

Already Exists

String

Uniqueness

31

found to be 10 M. A good linear relationship (correlation

Good

33

range of 10 ?0 M. The present metal oxide (CuO and ZnO) nanoparticles

Good

32

CuO NPs was 0.9773 and ZnO NPs was 0.9693) between the

Good

34

(Cysteine and NADH). It is interesting to note that the present

Good

33

range of 10 ?0 M. The present metal oxide (CuO and ZnO) nanoparticles

Good

35

biomolecules. Fig. 9. (a and c) absorption spectral changes

Good

34

(Cysteine and NADH). It is interesting to note that the present

Good

36

10 M of NADH, (b and f) corresponding calibration plot

Good

35

biomolecules. Fig. 9. (a and c) absorption spectral changes

Already Exists

37

concentration. Table 2 summarized the comparison of analytical

Already Exists

36

10 M of NADH, (b and f) corresponding calibration plot

Already Exists

38

biological molecules. The performance of CuO and ZnO NPs based

Already Exists

37

concentration. Table 2 summarized the comparison of analytical

Good

39

were reported. Tseng and co-workers (Wu et al. 2008) reported

Good

38

biological molecules. The performance of CuO and ZnO NPs based

Good

40

co-workers (Wu et al. 2008) reported the gold nanoparticles based

Already Exists

39

were reported. Tseng and co-workers (Wu et al. 2008) reported

Already Exists

String

Uniqueness

41

of 5 ?00 M). Mirkin and co-workers (Lee et al. 2008)

Good

40

co-workers (Wu et al. 2008) reported the gold nanoparticles based

Already Exists

42

co-workers (Lee et al. 2008) detected 50 nM cysteine (with linearity

Already Exists

41

of 5 ?00 M). Mirkin and co-workers (Lee et al. 2008)

Already Exists

43

nanoparticle-based sensor. Wei et al. (2010) demonstrated the carboxymethyl

Good

44

of 10 ?00 M). Willner and coworkers (Zayats et al. 2002)

Already Exists

42

co-workers (Lee et al. 2008) detected 50 nM cysteine (with linearity

Good

45

(Zayats et al. 2002) reported the detection of 100 M NADH

Good

43

nanoparticle-based sensor. Wei et al. (2010) demonstrated the carboxymethyl

Good

46

100 M ?0 mM). The present two metal oxide nanoparticles

Good

44

of 10 ?00 M). Willner and coworkers (Zayats et al. 2002)

Already Exists

47

such as uridine, glycine, guanine, and guanosine, and the

Already Exists

45

(Zayats et al. 2002) reported the detection of 100 M NADH

Already Exists

48

and guanosine, and the detection of cysteine is the lowest

Good

46

100 M ?0 mM). The present two metal oxide nanoparticles

Good

49

other reports. The present two metal oxide nanoparticles

Good

47

such as uridine, glycine, guanine, and guanosine, and the

Good

String

Uniqueness

48

and guanosine, and the detection of cysteine is the lowest

Already Exists

49

other reports. The present two metal oxide nanoparticles

Good

Conclusion 50% Unique Content


#

String

Uniqueness

extract of C. japonica. The synthesized nanoparticles

Good

like Li+ and Ag+. The synthesized nanoparticles have found

Already Exists

lithium and silver. The CuO and ZnO NPs based optical sensing

Good

experimental condition. The limits of detection (LOD) of the metal

Already Exists

cysteine and NADH, respectively. The detection of metal ions

Good

systems like silver, gold nanoparticles and their composites.

Already Exists

their composites. To the best of our knowledge, the metal

Good

biomolecules. The sensing capability of metal oxide (CuO

Already Exists

Vous aimerez peut-être aussi