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P17-15

PAPER-1

Academic Session: 2015-16

C OD E - 0
DO NOT BREAK THE SEAL WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR

MAJOR TEST (MT)


(JEE ADVANCED PATTERN)

Target : JEE (Main+Advanced) 2017


Date: 14 January, 2016 | Duration : 3 Hours | Max. Marks: 240
COURSE : VIKAAS (JA, JAZ); VIPUL (JB, JB2+); WINNER (JTA), WISDOM (JNT)
VIJETA (JP), VISHWAAS (JF)

Please read the last page of this booklet for the instructions.
(i;k

funsZ'kksa ds fy;s bl iqfLrdk ds vfUre i`"B dks i<+sA )

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P17.1

MATHEMATICS

SECTION 1 : (Maximum Marks : 64)

This section contains SIXTEEN questions


Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is(are) correct
For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
Marking scheme :
+4 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened
0 If none of the bubbles is darkened
2 In all other cases

1.

Considering the equation

2.

2 5
1
+
= , where x, y N. The number of solution of the equation is :
x y
3

(A) 6, if both x and y are even

(B) 6, if both x and y are odd

(C) 0, if x is even whereas y is odd

(D) 0, if x is odd whereas y is even

There are 8 events that can be scheduled in a week, then the total number of ways that these
events are scheduled on exactly 6 days of a week is :
(A) 210 6!

3.

(B) 7! 266

(C) 1862 6!

(D) 210 7!

The locus of the middle points of chords of the parabola y = 8x drawn through the vertex is a
parabola whose
(A) focus is (1, 0)

(B) length of latus rectum is 8

(C) focus is (0, 2)

(D) length of latus rectum is 4


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P1JAMTADV140116C0-1

MATHEMATICS

PART : I MATHEMATICS

4.

The number of ways in which we can make a garland with five identical flowers of one kind and
three identical flowers of another kind must be :
(A) 5
(B) 7
(C)

8!
5!3!

(D) Number of non negative integral solution of x + y + z = 5, where x y z


5.

(A) 18
6.

The value of sec x + cosec x + sec x cosec x can be


(B) 24

(C) 32

(D) 64

A player tosses a coin. He sets one point for head and 2 points for tail He plays till he gets sum of
points equal to n. If pn be the probability that his score becomes n, then :

7.

(A) p3 =

1
2

(B) pn =

1
1
pn1 + pn2
2
4

(C) p4 =

11
16

(D) pn =

1
(pn1 + pn2)
2

(A) 2! 3! 4! 5! 6!
8.

If p = n(n 1)(n 4)(n 9) ........ (n 100) is divisible by :


(B) (5!)

(C) (10!)

(D) 10! 11!

Let f(x) = ax + bx + c. If a, b, c are integers and f(0), f(1) are odd numbers then
(A) c is odd

(B) a + b is even

(C) a b is even

(D) c is even

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P1JAMTADV140116C0-2

MATHEMATICS

MATHEMATICS

9.

(A)

10.

(B)

(C)

2
3

(D)

5
6

Let A(0, 6), B(1, 2), C(3, 3), D(3, 2) and E(4, 2) be given points. Which of the following is (are)
TRUE ?
(A) Area of pentagon formed by these points is

73
.
2

(B) Area of triangle formed by points below x-axis is 12 square units.


1

(C) Angle subtended by BD at A is tan

32
61 .

(D) Triangle ABC is a right angled triangle.

11.

If each root of x ax b = 0, a, b R has absolute value < 1, then which of the following is/are true
(A) |b| < 1

12.

(B) a + b < 1

(C) b a < 1

(D) a b < 1

If H (3, 4) and C (1, 2) are orthocentre and circumcentre of PQR and equation of side PQ is
x y + 7 = 0, then :
2

(A) equation of circum circle (x 1) + (y 2) = 80

(B) equation of circum circle (x 1) + (y 2) = 70

5 8
(C) centroid is ,
3 3

(D) circumradius = 70

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P1JAMTADV140116C0-3

MATHEMATICS

MATHEMATICS

If 1 sin x sin2 x ......... terms 4 2 3 , (0 < x < ) and x


then x may be
2

MATHEMATICS

If the line 3x 4y k = 0 touches the circle x + y 4x 8y 5 = 0 at (a, b), then k + a + b can be


(A) 20

14.

(B) 28

(C) 20

1/2

(D) 28

1 3 5 ... (2y 1)
20
=
is (y N)
4 7 10 ... (3y 1) 7log x

(A) x = 10 , y = 10

(B) x = 10

5/7

(D) x = 10

5/7

(C) x = 10, y = 10

16.

1/4

The solution of the equations log x + log x + log x +....= y and

15.

,y=

,y=

10
7

10
7

Consider the equation sinx loge|x| = 0 then which are CORRECT ?


(A) Number of solutions are 6

(B) Product of solutions is negative.

(C) Sum of the solutions is positive

(D) Number of solutions are 4.

Let n = 700!, then :


(A) Number of zero at the end are 174
(C) It is divisible by 7!.(100!)

(B) It is divisible by (107)

(D) It is divisible by 100! (7!)

100

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P1JAMTADV140116C0-4

MATHEMATICS

13.

SECTION 2 : (Maximum Marks : 16)

This section contains TWO paragraphs


Based on each paragraph, there will be TWO questions.
Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is(are) correct
For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
Marking scheme :
+4 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened
0 If none of the bubbles is darkened
2 In all other cases
Paragraph for Question Nos. 17 to 18
There are three urns, Urn-1, Urn-2 and Urn-3. Urn-1 contains 4 red and 2 green balls, Urn-2
contains 3 red and 3 green balls and Urn-3 contains 2 red and 4 green balls. Let U1, U2 and U3 be
the events that Urn-1, Urn-2 and Urn-3 are chosen respectively.

17.

An urn is chosen and a ball is drawn from it randomly. If P(Ui) is proportional to i for each i = 1,
2, 3, then probability of the event ' the ball drawn is red ' is greater than
(A)

18.

1
9

(B)

4
9

(C)

1
3

(D)

8
9
2

An urn is chosen and two balls are drawn from it randomly. If P(Ui) is proportional toi for each
i = 1, 2, 3, then probability of the event ' the balls drawn are of different colours' is greater than
(A)

58
105

(B)

4
105

(C)

2
105

(D)

53
105

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P1JAMTADV140116C0-5

MATHEMATICS

MATHEMATICS

MATHEMATICS

Let the mirror image of the point A(5, 6) with respect to the line 2x + 3y = 15 be B. If AC is any
chord of the circle (described on AB as diameter) meeting the x-axis at D such that AD = 10DC,
then

19.

The equation of circle is


2

(B) x + y 6x 6y + 5 = 0

(D) x + y + 6x + 6y 5 = 0

(A) x + y 3x 3y + 5 = 0
(C) x + y 6x 6y 5 = 0

20.

If the number of possible chords is , then is less than


(A) 1

(B) 2

(C) 3

(D) infinite

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P1JAMTADV140116C0-6

MATHEMATICS

Paragraph for Question Nos. 19 to 20

PHYSICS

SECTION 1 : (Maximum Marks : 64)

21.

This section contains SIXTEEN questions


Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is(are) correct
For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
Marking scheme :
+4 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened
0 If none of the bubbles is darkened
2 In all other cases
Consider expansion of an ideal monoatomic gas by five different processes a,b,c,d & e as shown.
Choose the correct options :

(A) Process b is adiabatic and process d is isothermal.


(B) For process c which is above b and below d , Q > 0 and T < 0
(C) For process e which is above b and above d , Q > 0 and T > 0
(D) For process a, Q < 0 and for process d, T = 0
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P1JAMTADV140116C0-7

PHYSICS

PART - II : PHYSICS

22.

A rod of length 0.3 m having variable linear mass density from A to B as = 0x(x is distance from
A in meter), where 0 = 100 kg/m2 is suspended by two light wires of same length. Ratio of their
linear mass density is 2 : 9. Then which of the following is/are correct :

(A) Ratio of wave speed in wire1 to wire2 is 3 : 2


(B) Ratio of wave speed in wire1 to wire2 is 3 : 1
(C) Second harmonic in wire1 has same frequency as third harmonic in wire2
(D) Third overtone in wire1 has same frequency as fifth overtone in wire2
23.

A cylinder of mass M and radius R is resting on two corner edges A and B as shown in figure. The
normal reaction at the edges A and B are : (Neglect friction)

(A) NA =

2NB

(B) NB = 3NA

(C) NA =

Mg
2

(D) NB =

2 3Mg
5

Space for Rough Work

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P1JAMTADV140116C0-8

PHYSICS

PHYSICS

24.

When a capillary tube is dipped in a liquid, the liquid rises to a height h in the tube. The free liquid
surface inside the tube is hemispherical in shape. The tube is now pushed down so that the height
of the tube outside the liquid is less than h. Choose the correct option(s) :
(A) The liquid will come out of the tube like in a small fountain.
(B) The liquid will come out of the tube slowly.
(C) The liquid will fill the tube but not come out of its upper end.
(D) The free liquid surface inside the tube will not be hemispherical.

25.

In the figure shown, C is a fixed wedge on horizontal surface. Blocks A and B are of masses m and
2m respectively are kept as shown in figure. They can slide along the incline plane smoothly. The
pulley and string are massless. The inclined planes are very long. A and B are released from rest.
2 seconds after the release, B is caught for a moment and released again. Then (Take = 30 and
g = 10 m/s2 ) :Choose the correct option(s) :

(A) the speed of 'A' just before the instant when the string becomes tight again will be 10/3 m/s
(B) the speed of 'A' just before the instant when the string becomes tight again will be zero
(C) the speed of 'A' just after the instant when the string becomes tight again will be 20/9 m/s
(D) the speed of 'A' just after the instant when the string becomes tight again will be 10/3 m/s
Space for Rough Work

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P1JAMTADV140116C0-9

PHYSICS

PHYSICS

26.

In the figure shown crosssection area of holes are same and very small in comparison to area of
crosssection of water tank : (tanks are the open from the top) Choose the correct option(s):

(A) x1 : x2 : x3 =

27.

5: 6: 3

(B) x1 : x2 : x3 = 6 : 5 : 3
(C) If A1, A2, A3 are the area of cross-section of streams when it hits the ground then 12A12 : 5A22 :
4A32 = 3 : 3 : 2
(D) If A1, A2, A3 are the area of cross-section of streams when it hits the ground then 12A12 : 5A22 :
4A32 = 2 : 2 : 3
8
A rod of mass m = 2kg, length = 1m, has uniform crosssection area A = 103 m2 but its
3
density is nonuniform. It is hinged about one end and kept in water of density w = 103 kg/m3. At
the equilibrium, the rod becomes horizontal. Then (g = 10 m/s2). Choose the correct option(s) :

2
m from the hinged end
3
Space for Rough
3 Work
(B) Centre of mass of the rod is at a distance of m from the hinged end
4
20
(C) Force exerted by the rod on the hinge support is
N
3
(D) It we displace the rod slightly by rotating downwards, it will oscillate
(A) Centre of mass of the rod is at a distance of

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P1JAMTADV140116C0-10

PHYSICS

PHYSICS

28.

A ball tied to the end of a string performs (complete circle) in a vertical circle under the influence of
gravity. Choose the correct option(s)
(A) when the string makes an angle 90 with the vertical, the tangential acceleration is zero &
radial acceleration is somewhere between maximum and minimum
(B) when the string makes an angle 90 with the vertical, the tangential acceleration is maximum &
radial acceleration is somewhere between maximum and minimum
(C) at no place in the circular motion, tangential acceleration is equal to radial acceleration
(D) throughout the path whenever radial acceleration has its extreme value, the tangential
acceleration is zero.

29.

A boat moves relative to river with a velocity which is n times the river flow velocity. Choose the
correct option(s) :
(A) If n < 1, boat cannot cross the river
(B) If n = 1, boat cannot cross the river without drifting
(C) If n > 1, boat can cross the river along shortest path
(D) Boat can cross the river whatever is the value of n (excluding zero)

30.

A ladder AB is supported by a smooth vertical wall and rough horizontal floor as shown. A boy
starts moving from A to B slowly. The ladder remains at rest, then pick up the correct statement(s):
B
smooth
wall
A
///////////////////////////////
rough floor

(A) Magnitude of normal reaction by wall on ladder will increase.


(B) Magnitude of normal reaction by wall on ladder will decrease.
(C) Magnitude of normal reaction by floor on ladder will remain unchanged.
(D) Magnitude of friction force by floor on ladder at will increase.
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P1JAMTADV140116C0-11

PHYSICS

PHYSICS

31.

One end of a string of length L is tied to the ceiling of a lift accelerating upwards with an
acceleration 2g. The other end of the string is free. The linear mass density of the string varies
linearly from 0 to from bottom to top. Choose the correct option(s)
(A) The velocity of the wave in the string will be 0.
(B) The acceleration (relative to string) of the wave on the string will be 3g/4 every where.
(C) The time taken by a pulse to reach from bottom to top will be 8L / 3g .
(D) The time taken by a pulse to reach from bottom to top will be

When a sample of a gas is taken from state i to state f along path ' iaf ', heat supplied to the gas is
50 cal and work done by the gas is 20 cal. If it is taken by path ' ibf ', then heat supplied is 36 cal.
Choose the correct option(s) :

Pressure

32.

4L / 3g .

volume
(A) Work done by the gas along path ibf is 6 cal
(B) If work done upon the gas is 13 cal for the return path ' fi ', then heat rejected by the gas along
path ' fi ' is 43 cal.
(C) If internal energy of the gas at state i is 10 cal, then internal energy at state 'f' is 40 cal.
(D) If internal energy at state 'b' is 22 cal and at 'i' is 10 cal then heat supplied to the gas along
path ' ib' is 18 cal.
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P1JAMTADV140116C0-12

PHYSICS

PHYSICS

33.

In a one - dimensional inelastic collision between two identical particles A and B of equal masses,
Initially B is stationary and A has momentum P before impact.During impact B gives impulse of
magnitude J to A, then, Choose the correct option(s) :
(A) The total momentum of the "A plus B" system is P before and after the impact and (PJ)
during the impact.
(B) During the impact, A gives impulse J to B
2J
(C) The coefficient of restitution is
1
P
J
(D) The coefficient of restitution 1 is
P

34.

A rod is fixed between a vertical wall and a horizontal surface. A smooth ring of mass 1 kg is
released from rest which can move along the rod as shown. At the release point spring is vertical
and relaxed. The natural length of the spring is ( 3 1) m . Rod makes an angle of 30 with the
horizontal. Ring again comes to rest when spring makes an angle of 30 with the vertical. Choose
the correct option(s) (g = 10 m/s2) :

5
( 3 1) N/m
2
2
(B) Maximum displacement of ring is
m
3 1
(A) Force constant of the spring is

(C) Maximum extension in the spring is ( 3 1) m


for Rough
Work to rest is
(D) Normal reaction on ring due Space
to rod when
it again comes

5
( 3 1) N
2

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P1JAMTADV140116C0-13

PHYSICS

PHYSICS

PHYSICS

Which of the following statements is/are true


(A) work done by kinetic friction on an object may be positive.
(B) A rigid body rolls up an inclined plane without sliding. The friction force on it will be up the
incline. (only contact force and gravitational force is acting)
(C) A rigid body rolls down an inclined plane without sliding. The friction force on it will be up the
incline. (only contact force and gravitational force is acting)
(D) A rigid body is left from rest and having no angular velocity from the top of a rough inclined
plane. It moves down the plane with slipping. The friction force on it will be up the incline.

36.

An external force 6N is applied on a sphere of radius R = 10 cm of mass 1 kg and the sphere


moves in a liquid with a constant velocity 5 m/s making 530 with the horizontal. The coefficient of
viscosity of the liquid is 20/(6), in S.I. units. (Take g = 10 m/s2). Choose the correct option(s) :

(A) The viscous force on the body is 10N.


(B) The effective weight (weight upthrust) of the body is 8 N
(C) The direction of the external applied force must be horizontal.
(D) If the external force is suddenly removed the acceleration of the body just after the removal of
2

the force will be 6 m/s .


Space for Rough Work

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P1JAMTADV140116C0-14

PHYSICS

35.

SECTION 2 : (Maximum Marks : 16)

This section contains TWO paragraphs


Based on each paragraph, there will be TWO questions.
Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is(are) correct
For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
Marking scheme :
+4 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened
0 If none of the bubbles is darkened
2 In all other cases

Paragraph for Question Nos. 37 to 38


A uniform ring of radius R placed on a rough horizontal surface is given a sharp impulse as in
figure. As a consequence it acquires a linear velocity of v m/s. If coefficient of friction between the
ring & the horizontal surface be . Then answer the following questions based on given
information. (Use g = 10 m/s2)

37.

Based on above information choose the correct option(s) (A) The velocity of centre of mass after which the ring will start pure rolling is 1 m/s if initial velocity
is 2 m/s and radius R = 4 cm
(B) The velocity of centre of mass after which the ring will start pure rolling is 4 m/s if initial velocity
is 8 m/s and radius R = 10 cm
(C) Work done by kinetic friction is 4J if initial speed is 2 m/s and mass of ring is 4kg.
(D) Work done by kinetic friction is 8J if initial speed is 2 m/s and mass of ring is 8kg.

38.

Based on above information choose the correct option(s) (A) The time after which the ring will start pure rolling is 2 sec if v is 20 m/s and is 0.5
Rough
(B) The time after which the ring Space
will startfor
pure
rollingWork
is 2 sec if v is 10 m/s and is 0.25
(C) The time after which the ring will start pure rolling is 4 sec if v is 20 m/s and is 0.5
(D) friction will change its direction if v= 20 m/s and = 0.5
Space for Rough Work

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P1JAMTADV140116C0-15

PHYSICS

PHYSICS

PHYSICS

A small steel ball B is at rest on the edge of table of height 1 meter. Another steel ball A used as
the bob of one meter long simple pendulum is released from rest. The pendulum oscillates in
vertical plane as shown in the figure. The masses of the balls are identical and the collision is
elastic. Considering the motion of ball B only up to until the moment it first hits the ground at point
P. (Take g = 10 m/s2)

39.

Based on above information choose the correct option(s)


(A) time of motion of ball A is more than time of motion of ball B (untill it hits the ground for first
time)
(B) during motion of A its vertical speed first increases then decreases.
(C) during motion of A its horizontal acceleration continously increases.
(D) tension in the string continuously increases till it strikes with B.

40.

Based on above information choose the correct option(s)


(A) total distance travelled by A is greater than total distance travelled by B
(B) total distance travelled by A is less than total distance travelled by B

d | vA |
d | vB |

(C)

is valid atleast once.


dt 0 t t
dt t t t
1
1
2

dv A
dv B
Space
for once.
Rough Work

(D)

is valid
at max
dt 0 t t
dt t t t
1
1
2
Space for Rough Work

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P1JAMTADV140116C0-16

PHYSICS

Paragraph for Question Nos. 39 to 40

CHEMISTRY

Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75,
Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]

SECTION 1 : (Maximum Marks : 64)

This section contains SIXTEEN questions

Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is(are) correct
For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
Marking scheme :
+4 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened
0 If none of the bubbles is darkened
2 In all other cases

41.

The correct graphical representation for the real gas at given conditions are

(intermolecular forces
are negligible)

(A) Z = 1

(B)

(for hydrogen gas at


very low temperature)

(C)

Z=1

(for Hydrogen gas at


moderate temperature)

Z
(D)

Z=1
P
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P1JAMTADV140116C0-17

CHEMISTRY

PART : III CHEMISTRY

CHEMISTRY

42.

Which of the following is/are correct ?

(B) At constant pressure, for a definite quantity of an ideal gas graph of VT v/s T will be parabolic.
(C) In going from A to B for definite quantity of an ideal gas pressure increase.

V
A

T
(D) At constant volume, for a definite quantity of an ideal gas graph of

P
2
v/s T will be straight
T

line.
43.

Which of the following amount of H2SO4 can be taken to prepare a 0.25 M aqueous solution of
H2SO4 :

44.

(A) 49 g

(B) 0.25 g-molecule

(C) (NA/4) molecules

(D) 24.5 g

How many are not visible to human eye


(A) Electron whose debroglie wavelength is 5000 .
+

(B) Photon coming due to 4 to 2 transition in He


nd

2+

(C) 2 line of lyman series in Li


st

(D) 1 line of humphry series in H

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P1JAMTADV140116C0-18

CHEMISTRY

(A) At constant volume, for a definite quantity of an ideal gas graph of PT v/s T will be parabolic.

CHEMISTRY

0.2 Moles of M

(Cd

2+

or Co

2+

or Zn

2+

2+

or Ni ) ions are added separately to 1 litre A 0.1 M HCl

solution which is saturated with 0.05 M H2S solution. Which of the following will be precipitated?
Ka1 Ka2 for H2S= 4 10
(A) CdS (Ksp = 8.0 10
(C) ZnS (Ksp = 2 10

46.

21

27

(B) CoS (Ksp = 4.0 10

25

(D) NiS (Ksp = 2 10

21

21

For the given reaction


A(g)

2B(g) H = 30KJ/mole

If CP, A = 20J/mole-K

S = 150J/mole at 300K

CP, B = 20J/mole-K

Which of the following statement is/are correct?


(A) H will increase on increasing temperature.
(B)H will decrease on increasing temperature.
(C) At 300K, G is negative.
(D) At 300K, G is positive.

47.

For weak monobasic acid, HA, the dissociation constant is 2 10 , which of the following is/are
6

14

correct regarding this acid? (log2 = 0.3) (KW = 10

(A) A (aq)
H2O

HA(aq) + OH(aq)
Keq = 5 10

(B) The equilibrium constant for the reaction of HA with a very strong base in water in 2 10

(C) The pH of 0.1M HA solution is 3.35


(D) The pH of 0.1M NaA solution is 9.35

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P1JAMTADV140116C0-19

CHEMISTRY

45.

2+

CHEMISTRY

48.

A liquid confined inside an adiabatic container is suddenly taken from state 1 to state 2 by a

2P0

CHEMISTRY

single step process as shown


1

P0

V0
4V0
Select correct option(s)
(A) U = 3P0V0
49.

(B) H = P0V0

(C) W = 3P0V0

(D) q = 0

Which of the following IUPAC name is/are correct?

(A)

Benzene carbonyl chloride

(B)

3-Cyano benzenamide

(C)

Phenyl ethanoate

(D)

Ethanoic propanoic anhydride


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P1JAMTADV140116C0-20

CHEMISTRY

Select the correct relationship.

OH

OH
(A)

(B)

and

(D)

51.

are chain isomers.

and

are chain isomers.

and

are metamers.

Which of the following will give only 2-Methyl propane-1,3-dial on reaction with O3/Zn (H2O) ?

(A)

52.

are fuctional isomers.

and

(C)

CHEMISTRY

50.

(B)

(C)

(D)

Which of the following give brown coloured gas on heating


(A) LiNO3

(B) Mg(NO3)2

(C) KNO3

(D) Pb(NO3)2

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P1JAMTADV140116C0-21

CHEMISTRY

53.

The dipole moment of AX3, BX3 and CX3 are 1.5 D, 0.5 D and 0 D respectively. The possible

CHEMISTRY

shapes of molecules may be : (consider 'C' has no lone pair).


(A) pyramidal, T-shape, Trigonal planar respectively
(B) T-shape, pyramidal, Trigonal planar respectively
(C) pyramidal, pyramidal, Pyramidal respectively
(D) T-shape, T-shape, Trigonal planar respectively
54.

If RCl is allowed to react with Si, following chloro alkyl silanes are obtained
(A) RSiCl3

55.

56.

(B) SiCl4

(C) R2SiCl2

(D) R3SiCl

Which of the following orders of bond angle is/are correct.


(A) NH3 PH3 AsH3

(B) Cl 2O OF2 H 2O

(C) CH 4 SiH 4 GeH 4

(D) CH4 > NH3 > H2O

Stability of different carbocations shown by graph represent correctly :


A

PhCPh

P.E

Ph
III

II

Reaction
Co-ordinate

Match the potential energy curve with carbocation.


I

II

III

(A)

(C)

II

III

(B)

(D)

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P1JAMTADV140116C0-22

CHEMISTRY

This section contains TWO paragraphs

Based on each paragraph, there will be TWO questions.

Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is(are) correct

For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS

Marking scheme :
+4 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened
0 If none of the bubbles is darkened
2 In all other cases

Paragraph for Question Nos. 57 to 58


3
A 10 M solution of AgNO3 is made 0.2 M in NH3.

Given

57.

Ag(NH3 )2

Ag(NH3 ) + NH3

K1 = 1.5 10

Ag(NH3 )

Ag NH3

K2 = 4 10

Select correct options:


9
(A) [Ag ]eq = 10 M

7
(B) [Ag(NH3 ) ]eq = 7.5 10 M

3
(C) [Ag(NH3 )2 ]eq = 10 M

8
(D) K f [Ag(NH3 )2 ] = 6 10

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P1JAMTADV140116C0-23

CHEMISTRY

SECTION 2 : (Maximum Marks : 16)

CHEMISTRY

If KSP AgCl = 10

, In which of the following cases there will be precipitation of AgCl (consider no

new moles of Ag are produced from [Ag(NH3)2] and [Ag(NH3)] on mixing of following solutions)
(A) 1L of above solution + 1L of 0.2M NaCl solution.
(B) 0.5 L of above solution +1L of 0.4 M NaCl solution.
(C) 1L of above solution + 2L of 0.2M CaCl2 solution.
(D) 1L of above solution + 4L of 0.1M KCl solution.

Paragraph for Question Nos. 59 to 60


A gas (A) burns in air to produce a glassy solid (B) and an easily condensible gas (C). (A) reacts
with water to liberate another gas (D) and a solid (E). (D) can also burn with a pop-sound to form
(C). Both (C) and (D) are neutral towards litmus. Then, answer the following questions.

59.

(A) may be
(A) PH3

60.

(B) CO

(C) C2H6

(D) B2H6

(B) B & C

(C) A & C

(D) C & D

Heating (E) can give


(A) A & B

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P1JAMTADV140116C0-24

CHEMISTRY

58.

10

PAPER-1

DATE : 14-01-2016

MAJOR TEST (MT) (JEE ADVANCED PATTERN)


COURSE : VIKAAS (JA, JAZ); VIPUL (JB, JB2+); WINNER (JTA); WISDOM (JNT)
VIJETA (JP), VISHWAAS (JF)

C OD E - 0

Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
GENERAL %
1.
2.
3.
4.
5.
6.

The sealed booklet is your Question Paper. Do not break the seal till you are instructed to do so.
The question paper CODE is printed on the right hand top corner of this sheet and the right hand top corner
of the back cover of this booklet.
Use the Optical Response Sheet (ORS) provided separately for answering the question.
Blank spaces are provided within this booklet for rough work.
Write your Name and Roll Number in the space provided on the below cover.
After the open booklet, verify that the booklet contains all the 60 questions along with the options are legible.

QUESTION PAPER FORMAT AND MARKING SCHEME :


7.
8.
9.

The question paper has three parts : Mathematics, Physics and Chemistry. Each part has two sections.
Carefully read the instructions given at the beginning of each section.
Section 1 contains 16 multiple Choice question with one or more than one correct option.
Marking scheme: +4 for correct answer, 0 if not attempted and 2 in all other cases.

10.

Section 2 contains 2 "paragraph" type questions. Each paragraph describes an experiment, a situation or a
problem. Two multiple choice questions will be asked based on this paragraph. One or more than one option
can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and 2 in all other cases.

OPTICAL RESPONSE SHEET :


11.
12.
13.
14.

Darken the appropriate bubbles on the original by applying sufficient pressure.


The original is machine-gradable and will be collected by the invigilator at the end of the examination.
Do not tamper with or mutilate the ORS.
Write your name, roll number and the name of the examination centre and sign with pen in the space
provided for this purpose on the original. Do not write any of these details anywhere else. Darken the
appropriate bubble under each digit of your roll number.

DARKENING THE BUBBLES ON THE ORS :


15.

Use a BLACK BALL POINT to darken the bubbles in the upper sheet.

16.

Darken the bubble COMPLETELY.

17.

Darken the bubble ONLY if you are sure of the answer.

18.

The correct way of darkening a bubble is as shown here :

19.

There is NO way to erase or "un-darkened bubble.

20.

The marking scheme given at the beginning of each section gives details of how darkened and not
darkened bubbles are evaluated.

NAME OF THE CANDIDATE : ..


ROLL NO. : ..
I have read all the instructions
and shall abide by them

------------------------Signature of the Candidate

I have verified the identity, name and roll number


of the candidate.

------------------------Signature of the Invigilator

Resonance Eduventures Ltd.


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