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CUMULATIVE TEST-4(CT-4) Code

(JEE ADVANCED PATTERN)


TARGET : JEE (MAIN+ADVANCED) 2016

PAPER-1

P13-15

Date : 17-01-2016

COURSE : VIJAY (JR), VIJETA (JP), VISHWAAS (JF)

Time: 3 Hours

Maximum Marks : 240

1.
2.

The sealed booklet is your Question Paper. Do not break the seal till you are instructed to do so.
The question paper CODE is printed on the right hand top corner of this sheet and the right hand top corner of the
back cover of this booklet.
Use the Optical Response Sheet (ORS) provided separately for answering the question.
Blank spaces are provided within this booklet for rough work.
Write your Name and Roll Number in the space provided on the below cover.
After the open booklet, verify that the booklet contains all the 60 questions along with the options are legible.

3.
4.
5.
6.

QUESTION PAPER FORMAT AND MARKING SCHEME :


7.
8.
9.

The question paper has three parts : Mathematics, Physics and Chemistry. Each part has two sections.
Carefully read the instructions given at the beginning of each section.
Section 1 contains 5 "paragraph" type questions. Each paragraph describes an experiment, a situation or a problem. Two
multiple choice questions will be asked based on this paragraph. One or more than one option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and 2 in all other cases.

10.

Section 2 contains 10 questions. The answer to each question is a single digit integer ranging from 0 to 9 (both
inclusive).
Marking scheme: +4 for correct answer, 0 if not attempted and 2 in all other cases.

OPTICAL RESPONSE SHEET :


11.
12.
13.
14.

Darken the appropriate bubbles on the original by applying sufficient pressure.


The original is machine-gradable and will be collected by the invigilator at the end of the examination.
Do not tamper with or mutilate the ORS.
Write your name, roll number and the name of the examination centre and sign with pen in the space provided for
this purpose on the original. Do not write any of these details anywhere else. Darken the appropriate bubble
under each digit of your roll number.

DARKENING THE BUBBLES ON THE ORS :


15. Use a BLACK BALL POINT to darken the bubbles in the upper sheet.
16. Darken the bubble COMPLETELY.
17. Darken the bubble ONLY if you are sure of the answer.
18. The correct way of darkening a bubble is as shown here :
19. There is NO way to erase or "un-darkened bubble.
20. The marking scheme given at the beginning of each section gives details of how darkened and not darkened
bubbles are evaluated.

NAME OF THE CANDIDATE : ..


ROLL NO. : ..
I have read all the instructions
and shall abide by them
------------------------Signature of the Candidate

I have verified the identity, name and roll number


of the candidate.
------------------------Signature of the Invigilator

Resonance Eduventures Ltd.


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P13.1
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DO NOT BREAK THE SEAL WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR

Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
GENERAL %

MATHEMATICS

SECTION 1 : (Maximum Marks : 40)

This section contains FIVE paragraphs

Based on each paragraph, there will be TWO questions.

Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is(are) correct
For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
Marking scheme :
+4 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened
0 If none of the bubbles is darkened
2 In all other cases

Paragraph for Question Nos. 1 to 2


Let f(x) be a twice differentiable function defined on (,) such that f(x) = f (2 x) and

1
1
f = f = 0. Then answer the following question.
2
4
1.

The minimum number of roots of f(x) = 0 in [0, 2] is


(A) least composite number
(C) least prime number

(B) 2
(D) 4

2.

f '(1 x) x

e x dx is equal to

(B)

(A) even number

(C) 2

(D) 0

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P1JRCT4170116C0-1

MATHEMATICS

PART : I MATHEMATICS

MATHEMATICS

Consider the ellipse

3.

MATHEMATICS

Paragraph for Question Nos. 3 to 4


x2 y2
2
2
= 1 and circle x + y = 16.

25 9

If the area enclosed by all possible common tangents of circle and ellipse is

3 7

, then which of

the following is/are TRUE.

4.

(A) sum of digits of is 8

(B) is divisible by 64

(C) is divisible by 80

(D) sum of digits of is 7

th

If the equation of common tangent in IV quadrant is expressed in the form of 3y =


determine the value of ( + )

x then

(where , N)

(A) 21

(B) 22

(C) 23

(D) 24

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P1JRCT4170116C0-2

MATHEMATICS

If f(x) = 2x 3 (p 3) x + 6 px + p + 2 x R is cubic equation is x. Then answer the following


3

questions.

5.

The value of p for which f(x) has exactly one local maxima and one local minima, may belongs to
interval

6.

(A) p (, 1)

(B) p (9, )

(C) p [1, 9]

(D) p (1, 9)

The range of values of p for which f(x) has local minima at some negative real x.
(A) p (0, 1)
(B) p (, 3) [1, )
(C) p (, 0) [1, )
(D) p (3, 1)

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P1JRCT4170116C0-3

MATHEMATICS

Paragraph for Question Nos. 5 to 6

MATHEMATICS

Tangents are drawn to the parabola y = 4x from the point P(6, 5) to touch the parabola at Q and
R. C1 is a circle which touches the parabola at Q and C2 is a circle which touches the parabola at
R. Both the circles C1 and C2 pass through the focus of the parabola. Given that y-coordinate of R
is greater than y-coordinate of Q.

7.

Area of the PQR equals


(A)

8.

1
2

(B) 1

(C) 2

(D)

1
4

(where N) then which of the following is/are TRUE.

If radius of circle C2 is
(A) is divisible by 25
(B) is divisible by 20
(C) is divisible by 50
(D) is divisible by 10

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P1JRCT4170116C0-4

MATHEMATICS

Paragraph for Question Nos. 7 to 8

MATHEMATICS

Consider a polynomial y = f(x) of the least degree passing through A (1, 1) and whose graph has
two point of inflection B(1,2) and C with abscissa zero. Tangent to the curve at point C is inclined
to the positive x-axis by an angle cos

9.

If

f(x)

dx =

in anticlockwise direction.
2

(where and t are coprime natural numbers)

(A) + t = 46

(B) t = 27

(C) t = 16

(D) t = 23

10.

The area of ABC is


(A)

1
2

(B)

1
4

(C)

1
6

(D)

1
8

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P1JRCT4170116C0-5

MATHEMATICS

Paragraph for Question Nos. 9 to 10

MATHEMATICS

This section contains TEN questions

The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive

For each question, darken the bubble corresponding to the correct integer in the ORS

Marking scheme :
+4 If the bubble corresponding to the answer is darkened
0 If none of the bubbles is darkened
2 In all other cases

11.

Let y is a function of x, given that y(0) = 2000 and

value of

12.

A
.
5

1 3 / 2
Let A =
; B=
2
1

tr (AB) C

4 3
and Cr =
2
2

50

If

dy
2
= 32000 20y . If lim y = A, then find the
x
dx

r 3r

2r
be given matrices.
(r 1)3r

51

= a + b.3 . (Where tr(A) denotes trace of matrix A), then find the value of

r=1

(b 15a). [where a and b are coprime natural number]

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P1JRCT4170116C0-6

MATHEMATICS

SECTION 2 : (Maximum Marks : 40)

MATHEMATICS

An equilateral triangle ABC is inscribed in the parabola y = x and one of the sides of the
equilateral triangle has the gradient 2. If the sum of x-coordinates of all the vertices of the triangle
is expressed in the form of

p
(where p & q are co prime natural number), then find the value of
q

|p q|.

14.

Let F(x) be a non-negative continuous function defined on R such that F(x) + F x = 3.


2

Find the value of F(x) dx .


0

15.

If the minimum value of the function f(x) = x 2 x

3
2

4 x for all permissible real x, is then


x

find the value of ( + 13).

16.

Let h(x) = f(x) sin x, where f(x) is twice differentiable function on ( , ), such that f() = 1. Find
the value of |h()|.

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P1JRCT4170116C0-7

MATHEMATICS

13.

MATHEMATICS

17.

If the value of definite integral I =

1 | cos x | dx is equal to , then find the value of .

18.

Find the value of definite integral

(sinx + cosx + 2

19.

dx
sinx cosx ) sinx cosx

If the locus of the point (h, 2k 3), where (h, k) lies on the curve x y = 16 is a conic C, then find
the square of the eccentricity of the conic C.

20.


2
2
If a , b be any two unit vectors, then find the least value of the expression 2 2 .
| a b | | a b |

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P1JRCT4170116C0-8

MATHEMATICS

PHYSICS

SECTION 1 : (Maximum Marks : 40)

This section contains FIVE paragraphs


Based on each paragraph, there will be TWO questions.
Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is(are) correct
For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
Marking scheme :
+4 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened
0 If none of the bubbles is darkened
2 In all other cases

Paragraph for Question Nos. 21 to 22


A string fixed at both the ends of length 2 m, vibrating in its 7th overtone. Equation of the standing
wave is given by y = A sin kx cos (t + /3), All the symbols have their usual meaning. Mass per
unit length of the string is 0.5 gm/cm. Given that A = 1 cm and = 100 rad/sec. Answer the
following 2 questions based on information given (Use 2 = 10)
21.

Staring from t = 0, energy of vibration is completely potential at time t, where t is :


(A)

22.

1
sec.
150

(B)

1
sec.
60

(C)

3
sec
100

(D)

11
sec.
300

Starting from t = 0, energy of vibration is completely kinetic at time t, where t is :


(A)

1
sec.
600

(B)

5
600

(C)

19
600

(D)

25
sec.
6000

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P1JRCT4170116C0-9

PHYSICS

PART - II : PHYSICS

PHYSICS

A charged particle having charge +q and mass m enters in a region where magnetic field varies
with x-coordinate as :
0

B = k

x<0
0 < x < d1
d1+ d2 > x > d1

x > d1+ d2

where and are positive constants with appropriate dimension. If in the region x < 0 and x > d1 + d2

charge particle has velocity v v 0 i. Answer the following two questions based on above information.
23.

If T1 is the time spent in region 0 < x < d1 and T2 is the time spent in region d1 < x < d1 + d2, then
choose the correct options :
(A) T1 =

m
1 qd1
sin

q
mv 0

(B) T2 =

(D) T1 = T2

(C) T1 = T2
24.

m
1 q d2
sin

q
mv 0

Let the average force on the charge particle during the time spent in region 0 < x < d1

is F1 and during the time spent in region d1 < x < d1 + d2 is F2 , choose the correct options

(A) F1 F2

(B) | F1 | | F2 |

(C) F1 F2

(D) | F1 | | F2 |

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P1JRCT4170116C0-10

PHYSICS

Paragraph for Question Nos. 23 to 24

PHYSICS

Consider a L C oscillation circuit. Circuit elements has zero resistance. Initially at t = 0 all the
energy is stored in the form of electric field and plate-1 is having positive charge. Answer the
following two questions based on above information.

25.

Choose the correct option(s) :


(A) at time t =

2
LC plate-2 attains half of the maximum +ve change for the first time.
3

(B) at time t =

LC plate-2 attains half of the maximum +ve change for the first time.
3

LC energy stored in the form of electric field and energy stored in the form of
4
magnetic field is same.

(C) at time t =

(D) at time t =

2
LC energy stored in the form of electric field is twice the energy stored in the
3

form of magnetic field.


26.

Choose the correct option(s) regarding emf induced across inductor :


(A) at time t = LC , magnitude of emf induced across inductor is maximum.
Space for Rough Work

LC , magnitude of emf induced across inductor is maximum.


(B) at time t =
2
(C) when energy stored in inductor is maximum, magnitude of emf induced across inductor is also
maximum.
(D) when energy stored in inductor is minimum, magnitude of emf induced across inductor is also
maximum.
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P1JRCT4170116C0-11

PHYSICS

Paragraph for Question Nos. 25 to 26

PHYSICS

A true balance is one whose pans are of equal masses and arms are of equal lengths. When this
happens, the net moment of forces about point of suspension is zero and beam remains horizontal
without any weight i.e., for the true balance P1 = P2 and 1 = 2 also P1 1 P2 2 (mass of beam is
negligible).
1

P1

P2
Mass of pan
A shopkeeper uses a false balance to weigh articles. Both arms and pans of this false balance are
different, but beam become horizontal without any weight.
27.

P1 P2 and 1 2 but P11 P2 2 .

Choose the correct option(s) :


(A) If mass of pan P2 is less than mass of pan P1 and Shopkeeper puts weight W on P1, and article

2 1
.
2

on the pan P2. In this weight gain to the shopkeeper is W

(B) If mass of pan P2 is less than mass of pan P1 and Shopkeeper puts weight W on P1, and

2 1
.
2

article on the pan P2. In this weight loss to the shopkeeper is W

(C) If mass of pan P2 is less than mass of pan P1 and Shopkeeper puts weight W on P2, and
1
article on the pan P1. In this weight loss to the shopkeeper is W 2
.
1
(D) If mass of pan P2 is less than mass of pan P1 and Shopkeeper puts weight W on P2, and
Space for Rough Work
1
article on the pan P1. In this weight gain to the shopkeeper is W 2
.
1
28.

Shopkeeper use a weight W to weigh an article by false balance. In two weighing, by using
alternating pans, let W 1 and W 2 are the weights of the article given to the customer i.e., customer
gets (W 1 + W 2) weight of article. Loss or gain to the shopkeeper is :
(A)

( 2 1 ) 2
( 1 ) 2
gain (B) W 2
loss (C) No gain, no loss
1 2
1 2

(D) Data insufficient

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P1JRCT4170116C0-12

PHYSICS

Paragraph for Questions 27 and 28

PHYSICS

A point object is located at a distance 100 cm from the screen. A lens of focal length 23 cm
mounted on a movable frictionless stand is kept between the object and screen. The stand is
attached to massless spring of natural length 50 cm and spring constant 800 N/m as shown in the
figure. Mass of the stand with lens is 2 kg. Initially spring is in its natural length. Now a sharp
impulse J is given to the stand. Answer the following questions.

29.

It is observed that a real image of the object S is formed on the screen after a fixed time gap (four
times in an oscillation). This time gap is :
(A)

30.

sec
10

(B)

sec
20

(C)

sec
30

(D)

sec
40

Choose the correct option(s):


(A) Impulse J imparted to the stand is 8 kg m/sec
(B) Impulse J imparted to the stand is 6 kg m/sec
(C) Difference between extreme positions of lens is 40 cm
(D) Difference between extreme positions of lens is 60 cm
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P1JRCT4170116C0-13

PHYSICS

Paragraph for Questions 29 and 30

SECTION 2 : (Maximum Marks : 40)

This section contains TEN questions


The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive
For each question, darken the bubble corresponding to the correct integer in the ORS
Marking scheme :
+4 If the bubble corresponding to the answer is darkened
0 If none of the bubbles is darkened
2 In all other cases

31.

Consider a long solenoid of radius R which has n turns per unit length. A time dependent current
= 0 sin t flows in solenoid, magnitude of electric field at a perpendicular distance r < R, from the

axis of symmetry of solenoid is found to be E =


0 n0r cost, where is pure number and
4
0 is permability of free space. Find :

32.

A particle with mass m and charge q, moving with a velocity v, enters a region of uniform magnetic
field B, as shown in the figure above. The particle strikes the wall at a distance d from the entrance
slit. If the particle's velocity stays the same but its charge to mass ratio is doubled, distance from
d
the entrance slit where the particle strike the wall is , then find n.
n
B

d
v

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P1JRCT4170116C0-14

PHYSICS

PHYSICS

33.

Given system is in equilibrium. All surfaces are smooth. Spring is ideal and blocks are sticked at
the ends of spring. Now F0 is removed. Average normal contact force between wall and mass m1 upto the
time spring attains its natural length for the first time in Newton is : (Given that F0 = 2 Newton)

34.

In figure below if
Find

X L X C and reading of AC ammeter is 1 A. Source voltage is V Volt.

V
in Volt.
20
XL

XC

1
H

R = 80

V, 30 Hz

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P1JRCT4170116C0-15

PHYSICS

PHYSICS

PHYSICS

The intensities of two sound sources are in the ratio 16 : 9. The ratio of the intensities of maxima to

PHYSICS

35.

minima in the interference pattern is 7. Find

36.

A lamina is made by removing a small disc of diameter 2R from a bigger disc of uniform mass
density and radius 2R, as shown in figure. A second similar disc is made but instead of hole a disc
of triple the density as of first it filled in the hole. Centre of mass is calculated in both the cases and

was found at a distance r1 & r2 from centre O respectively. Find the ratio

2r2
.
r1

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P1JRCT4170116C0-16

The speed of block B (in m/s) is 4x. Find x. (Pulley P1 , P2 and P3 are movable. All other pulleys are
fixed).

38.

The chain of length L is released from rest on a smooth fixed incline with x = 0 as shown in the
4
figure. Determine velocity v of the chain when a half of the length has fallen (Take L =
m)
25
in m/s. (Neglect edge effect of inclined).

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P1JRCT4170116C0-17

PHYSICS

PHYSICS

37.

39.

A car while travelling produces noise of intensity level of 94 decibel. At a particular point on road
maximum permissible level of noise is 100 decibel. Find how many such identical cars can be
allowed to pass through that point simultaneously if sound waves emitted by all cars are in same
phase at that point? (Use log 2 = 0.3)

40.

In a uniform constant magnetic field of induction B, two long conducting wires ab and cd are kept
parallel to each other at distance with their plane perpendicular to B. The ends a and c are
connected together by an ideal inductor of inductance L. A conducting slider wire PQ of mass m is
imparted speed v0 at time t = 0. The situation is as shown in the figure. At time t

value of current through the wire PQ is

mL
, the
4B

mv 02
. Here is integer. Find (Ignore any resistance,
L

electrical as well as mechanical)

v0

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P1JRCT4170116C0-18

PHYSICS

PHYSICS

CHEMISTRY

Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75,
Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]

SECTION 1 : (Maximum Marks : 40)

This section contains FIVE paragraphs


Based on each paragraph, there will be TWO questions.
Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is(are) correct
For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
Marking scheme :
+4 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened
0 If none of the bubbles is darkened
2 In all other cases
Paragraph for Question Nos. 41 to 42
A neutral four coordinated complex, nickelbis(salicyladoximate) in which each ligand coordinate to
central metal ion through N and O, forms colourless crystals and is diamagnetic. But it yields a
green solution in pyridine, in which the addition of two solvent molecules as ligands occurs
(

41.

salicyladoximate structure.)

Which of the following is/are correct for green colored complex?


2+
3 2
(A) Hybridization of Ni is sp d .
(B) Magnetic moment is 2.83 BM.
(C) It is square planar.
(D) Magnetic moment is 0 BM.
Space for Rough Work

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CHEMISTRY

PART - III : CHEMISTRY

CHEMISTRY
2+

It is given that when only salicyladoximate binds to Ni , it adopt a trans-orientation, forming six
membered rings. Which of the following is/are correct?
(A) The trans-isomer contain 4 NNiO bond angles.
(B) When two pyridine binds to it, without disturbing square planar orientation, optically active
complex obtained.
(C) The oxidation number of nickel in both diamagnetic crystals and green crystal is +2.
(D) The structure of diamagnetic complex is same as of Ni(CO)4.
Paragraph for Question Nos. 43 to 44
Some measurable properties in dilute solution of non-volatile solute in volatile solvent can be
distinguished into two types.
(i) Colligative

(ii) Constitutional

Colligative properties : Depend on concentration of actual solute particles in solution, but


independent of their nature or form i.e. ions, monomer, dimer etc.
Constitutional properties : These properties depend on nature of solute particle and its form, apart
43.

Which of the following properties is/are colligative properties?


(A) Resistance of solution
(B) Boiling point.
(C) P (P = vapour pressure of solvent vapour pressure of solution)
(D) Osmotic pressure
Space for Rough Work

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P1JRCT4170116C0-20

CHEMISTRY

42.

CHEMISTRY

The boiling point of a solution of a non volatile solute in water is 101C, Which is/are correct for
this solution ? (Pexternal = 1 atm)
Kb = 0.5 K Kg/mol, Kf = 1.80 K Kg/mol.
(A) If the degree of association or dissociation of solute remain unchanged with temperature, then

Tb K b

.
Tf K f
(B) The vapour pressure of solution at boiling point is 760 torr.
(C) The vapour pressure of solution at boiling point of solvent is nearly 734 torr.
(D) The RLVP of solution is

9
.
259

Paragraph for Question Nos. 45 to 46


Nitric acid undergoes a series of chemical reaction. It is a strong acid, and a good oxidant. It is
reduced to a number of different oxidation states on reduction.
45.

Conc. HNO3 liberates NO2 vigorously and dissolves which of the following metals?
(A) Al

46.

(B) Cu

(C) Fe

(D) Au

Which of the following reagents will liberate at least one oxide of nitrogen in significant quantity?
(A) Ag + conc. HNO3

(B) Cr + conc. HNO3

(C) Sn + cold, dil. HNO3

(D) P4 + hot conc. HNO3

Space for Rough Work

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P1JRCT4170116C0-21

CHEMISTRY

44.

CHEMISTRY

Observe the reactions I and II.

( HBr )

47.

48.

( HBr )

Q (major)

P (major)

The compounds P and Q are


(A) Identical

(B) Homologous

(C) Stereoisomers

(D) Structural isomers

What is/are true about the given two reactions?


(A) The I reaction is a elimination reaction.
(B) Both are antielimination reactions.
(C) Both are bimolecular elimination reactions
(D) The II reaction is an elimination reaction.

Space for Rough Work

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CHEMISTRY

Paragraph for Question Nos. 47 to 48

CHEMISTRY

Effect of nature of substrate on SN2 reaction:


Branching at the and carbon decreases the rate of SN2 reaction due to increase in steric
crowding around the reaction site.
Unsaturation at the carbon (i.e. in allylic or benzylic systems) increases rate of SN2 reaction due
to resonance stabilisation in transition state.
Unsaturtation at carbon (i.e. vinylic, acetylenic and aryl substrates) are unreactive towards SN2
reaction.
When electron withdrawing groups (like RO, RS,

C=O ) are present at carbon, rate of SN2

also increases.
49.

For each pair of compounds, state which compound is the better SN2 substrate.
(a) CH3OCHCH3 and CH3CH2CHCH3
Br

(b)

and
Br

Br

Br

CH2Br
(c) CH3CCH2Br and CH3CH2CH2Br

(d)

CH2Br
and

(A) a-I
50.

(B) b-II

(C) c-II

(D) d-II

Which of the following R-X compound is better alkylating agent in the reaction shown?

O
R
+ RX

CH3CH2ONa

Space for
O Rough Work

O
(A) (CH3)3CBr
(C)

(B) CH2=CHBr
CH2Br

(D) PhCH=CHCH2

Br

Space for Rough Work

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CHEMISTRY

Paragraph for Question Nos. 49 to 50

CHEMISTRY

This section contains TEN questions

The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive

For each question, darken the bubble corresponding to the correct integer in the ORS

Marking scheme :
+4 If the bubble corresponding to the answer is darkened
0 If none of the bubbles is darkened
2 In all other cases

51.

The solubility product of CuCl is 2 10 . The equilibrium constant for the reaction :
2+
+
Cu + Cu (aq) 2Cu (aq)
7
2+

is 9.6 10 . Find |ECell| 20 for the reaction Cu(s) + Cu (aq) + 2Cl 2CuCl(s).

(Round off your answer to nearest whole number) (log 3 = 0.48, log 2 = 0.3,

52.

2.303RT
0.06 )
F

In a cubic lattice, the closed packed structure of mixed oxides the lattice is made up of oxide ions ;

1
1
2+
of the tetrahedral voids are occupied by divalent ions (A ) while
of the octahedral voids are
x
y
3+

occupied by trivalent ions (B ). Considering one type of ion occupies only one type of void, find
|x y|

Space for Rough Work

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P1JRCT4170116C0-24

CHEMISTRY

SECTION 2 : (Maximum Marks : 40)

CHEMISTRY

How many molecules have d-orbitals participating in -bond?


OPF3, HClO4, Mn2(CO)10, P4O10, S3O9, N(SiH3)3, Fe(CO)5; SO2.

54.

1 mole mixture of Li2CO3 and K2CO3 on strongly heating gave 0.25 mol of CO2. What is ratio of
moles of K2CO3 to Li2CO3.

55.

A detergent (C12H25SO4Na) solution becomes a colloidal solution at a concentration of 10


13

On an average 10

mol/lit.

colloidal particles are present in 1 mm . If on an average, number of


23

C12H25SO4Na in one colloidal particle is 12 a, find a. Take NA= 6 10


56.

The following ball-and-stick molecular model is a representation of acetaminophen.

(Acetaminophen)

The lines between atoms indicate connection only, not whether the bonds are single, double or
triple.
Space for Rough Work
2
How many atoms have sp hybridisation ?

Space for Rough Work

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P1JRCT4170116C0-25

CHEMISTRY

53.

CHEMISTRY

Write the number of the group which will form more stable carbocation in given compound by
rearrangement ?

58.

How many species are aromatic -

CHEMISTRY

57.

H
N

59.

O
N

N
N

D3C C C CH3
Find the value of (x + y)

60.

How many of the following give 3 alcohol with excess Grignard reagent.
Space for Rough Work
HCHO

CH3CHO

CH3 COOC2H5
O

HCOCMe3
||
O

Space for Rough Work

Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
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P1JRCT4170116C0-26

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