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cn
Qing Liu
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Chuangji Han
Metallurgy Research Center, School of Metallurgical and Ecological Engineering,
University of Science and Technology Beijing, 30 Xueyuan Road, Beijing 100083 P.R.China
Tel.: 0086-10-62332358
Fax: 0086-10-62322845
E-mail: chuanjihan@metal.ustb.edu.cn
Kaike Cai
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FOREWORD
Composition and temperature control of molten steel are extremely important in modern continuous casting production. Quality
control of casting slab is closely related with the control of temperature, composition and its cleanliness level. Moreover,
appropriate casting temperature is an important precondition of stable operation, safe production and high quality acquirement.
Therefore, every factor working on molten steel temperature is to be researched.
As the equipment of liquid steel refining and its temperature adjusting, ladle keeps the smooth production of steelmaking and
continuous casting, and makes it more agile for production schedule. Also each process from tapping to casting is carried out in
the ladle, whose state has become a main factor influencing the liquid steel temperature. There were many studies on heat transfer
in ladle for many years1-4, early research were mainly real temperature measurement and physical simulation5-7, while along with
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the incessant progress in science and technology, mathematical simulation was applied more and more to establish many kinds of
mathematical models so as to research the different factors in heat loss of ladle and optimize the hot cycling technology of ladle in
continuous casting process, sequentially to reduce the heat loss.
MATHEMATICAL MODELS
Thermal state of ladle influences molten steel temperature greatly during the course of RH-MFB refining, so the thermal state of
ladle should be researched deeply for further exact control and prediction temperature of molten steel.
Heat transfer in ladle
After liquid steel being poured into the ladle, its heat quantity would be taken in the wall and the bottom of the ladle, as well as the
free surface of molten steel itself. The expression of heat transfer is shown as the formula (1).
dTm
1
[qb ( ) Ab + qW ( ) AW + q s ( ) AS ]
=
d Wm C p (m )
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would only be transfered from inside to outside along the vertical direction, then the equation of heat transfer was a
one-dimensional unsteady heat conduction, The expression of heat conduction is shown as the formula (2).
WRH CpW ( RH )
TW ( RH )
1
r W ( RH ) ( ) W ( RH )
r
r r
Fig 1 Structure and material of the bottom and the wall of ladle
Initial conditions:
=0
r( RH ) r rw( RH ) T( RH ) (r ,0) = T( RH ) (r , )
Boundary conditions:
T( RH ) (r , ) = T( RH ) ( )
(1) > 0
r = r( RH )
(2) > 0
(3) > 0
r1( RH )
= s A
Tb
r
1
r r
2
+ s B
Tb
r
1
r + r
2
r = rWRH
4
4
Tb
Tb
V
Tb + 273 T f + 273
]
CP
rw( RH ) = s..
r rw( RH ) hm f s(Tb T f ) m 0 s[
2
100 100
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Table I Physical parameters of refractory on the lining and bottom of ladle & the wall and the hearth of vacuum room8,10
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Density
specific heat
Dark
(J/ms)
(kg/m3)
(J/kg)
degree
freeze(KJ/kg)
1.52-0.000186t
2500
836+0.234t
Corundum brick
2.09+0.00187t
2900
794.2+0.418t
armor plate
43.2
7700
470.00
0.80
Molten steel
23.3
7000
880
0.40
251
slag
3500
1340
0.60
453.4
Kinds of refractory
Tb
1
T
=
[ (b ( ) )]
b .Cb ( ) x
x
(7)
S (
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2TS
T
) = S Cs S
2
y
0 y L1
(8)
Initial conditions:
TS ( y,= Tm ( ) = 0
(9)
Boundary conditions:
y = L1 , TS = Tm
(10)
100
100
(11)
Ti + 273 4 T0 + 273 4
) (
) ]}
100
100
(12)
Fig 3 Comparison between calculation and survey of liquid temperature at the end of ladle cycle
Fig 4
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Fig 5 Temperature distribution in refractory of the bottom under different temperature conditions
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ladle preheating
temperature 700
ladle preheating
temperature 800
ladle preheating
temperature 900
ladle preheating
temperature 1000
ladle preheating
temperature 1100
1620
1610
1600
1590
1580
1570
1560
1550
0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 4
time min
CONCLUSIONS
1At different temperatures, temperature of refractory on the wall and at the bottom change a lot.
2Preheating temperature influences the molten steel temperature greatly, when preheating temperature rising from 700 to
1300, the temperature of molten steel would be raised by 3.5 averagely along with every 100 increase in preheating
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temperature.
3Initial heat states of ladles influenced a lot on has a lot to do with the temperature of molten steel, which would increase from
1562 to 1592 at the end of refining.
S : Density of slag, kg / m3 ;
TS : Temperature of slag, ;
q s As Density of heat flow into the slag layerJ/m2.s, area of the slag layerm2;
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q w AW Density of heat flow into the wall of the ladleJ/m2.s, area of the wallm2.
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REFERENCE
1. J. W. Hinka, T. W. Miller. Temperature Loss in Liquid-Steel-Refractory System, Iron and Steel Engineering, 1970, Issue.8,
pp.123-133.
2. Sanjib Chakraborty, Yogeshwar Sahai. Effect of Slag Cover on Heat Loss and Liquid Steel Flow in Ladels before and during
Teeming to a Continuous Casting Tundish, Metall. Transactions B, Volume 23, 1992, pp.135-150.
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3. A.Herbert, M.J. Thorndike, and G. Fawkes. Production of High Quality Continuously Cast Slabs for Hot-Rolled Coil and Weld
Tube Application, Ironmaking and Steelmaking, Volume.12, 1985, Issue.1, pp.35-36.
4. M.A.Omotani. L.J.Heaslip,A.Mclean, Ladle Temperature Control During Continuous Casting, I&SM, 1983, Issue.10,
pp.29-35.
5. S.J.Ritza. H.J.Thibodeau. Recent Steel Ladle Practices at Algomas No.2 Steelmaking Shop, I&SM, 1987, Issue.6, pp.33-37.
6. I.D.Prendergast. Practical Aspects of Refractory Selection and Performance in Steel Ladel_Part III&SM, 1988, Issue.2,
pp.18-22.
7. C.E.Tomazin, E.A.Upton and R.A.Wallis. The effect of ladle refractiries and practices on steel temperature control, I&SM,
1986, Issue.6, pp.28-34.
8. Chen Jiaxiang. Handbook of Common Diagram and Data in Steel Making, Beijing: Metallurgical Industry Press, 1984, pp.58
9. Yang Shiming. Heat Transfer, Xian: Xian Jiaotong University press, 1982,pp.168.
10.Qian Zhirong, Fan Guangju. Handbook of Refractory for Practical Use, Beijing: Metallurgical Industry Press, 1992, pp.367.
11. Zhang Xianzhao. Theory of Metallurgical Heat Transfer, Beijing: Metallurgical Industry Press, 1988, pp.436.