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Re:What'sthecauseofCrookesDarkSpace&striationsindischargetubes

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Re:What'sthecauseofCrookesDarkSpace&striationsindischargetubes
Date:FriFeb917:18:402001
PostedBy:RichardBersin,Other(pls.specifybelow),SeniorTechnicalStaffMember,
EmergentTechnologies
Areaofscience:Physics
ID:980311929.Ph
Message:
DearProfessorMatthew:
Youareinquiringaboutthephenomenawhichoccuringlowdischarge
plasmas.Typicallytheseplasmasareusedatpressuresfrom~0.05torrto
~10torr.Sinceyouareusingvisualobservationforyourdetection,let
uskeepourdiscussiononthequalitativeleveltoenableustopresenta
pictureofwhatisgoingonwithoutgettingintothe"theoretically
complicated"realmwhichyoureferto.
YourreferencetotheCrooke'sdarkspacespeakstowardsexperimentswith
DCdischargeswherethevacuumenvelopeisopticallytransparent,usually
madeofquartzorpyrexglass.Twoelectrodesaresuspendedwithin,on
metalrodsvacuumsealedtogothroughtheglassandallowapplicationof
voltageacrosstheelectrodeswithinthevacuumenvironment.
Nowtheglowdischargeplasmaisknownasanonequilibriumplasma,which
meansthattheionsandneutralatomsaregenerallyatatemperatureclose
toroomtemperature,whiletheelectronsareatextremelyhigh
temperatures.Thismeanstheirkineticenergyisveryhighandtheymove,
ordriftordiffuse,atvelocitiesmanyordersofmagnitudemorerapidly
thandotheheavyionsorneutralmolecules.
Theneteffectofthisisthatwhentheplasmaisinitiallyignited,anda
largeburstoffreeelectronsandpositiveionsarecreatedfromthe
ionizationintheinitialbreakdowndischarge,thehotelectronsdiffuse
veryrapidlyawayfromthedischargetothewallsofthechamberandtothe
positiveelectrodewhichleavesacloudofpositiveionswithinthebulk
regionoftheplasma.Theplasmastabilizesasmoreionizationtakesplace
anddiffusionoutoftheglowoccursuntilasteadystateis
established(allinmicroseconds!).Thusthenegativeelectrodeassumesa
verynegativechargefromtheseelectrons,andtheinsulatingquartzwalls
ofthechamberarealsocoveredwithasurfacechargeofnegativeelectrons
whichadhere.
Theregionoftheplasmawhichisglowingglowsbecausethereareelectrons
thererecombiningwiththeionsandthismakestheneutralizediongiveoff
aphotonoflight;sowhereveryouseeaglowingregionintheplasmayou
knowtherearealotofionsandfreeelectronspresentinthesame
location.Rememberingnowthattheplasmaisacontinuousphenomenon,i.e.
wearecontinuouslyionizingatoms,makingionsandfreeelectrons,the
electronsarecontinuouslydiffusingrapidlytothewalls,andtheionsare
diffusingawayslowly,andsoasteadystatesituationisestablished.
Nowtheelectronshaveaverywidedistributionofenergies.Thenegative
electrodeisatanegativepotentialinrelationtothesomewhatpositive
glowingplasmaregionbecauseoftheexcesselectroncoverage.Therefore
althoughelectronsarecontinuouslydiffusingawayfromtheglowingregion,
onlythehigherenergyonescanreachthenegativeelectrodebecausethe
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30/06/2015

Re:What'sthecauseofCrookesDarkSpace&striationsindischargetubes

lowerenergyelectronsarerepelledbythenegativechargeonthenegative
electrode.Thusthedensityofelectronsinthespaceneartothenegative
electrodedropsconsiderablyinamannerdependentontheplasmaparameters
(pressure,gasmixture,powerlevel,electrodeshapeandspacing,etc.,)
becausethesefactorsdeterminetheenergydistributionoftheelectrons.
Andasweapproachnearerandnearertothenegativeelectrodethedensity
ofmovingelectronsdropsdowntoalowlevel.Butsincetheelectrons
collidingandrecombiningwiththeionsarethereasonfortheglowinthe
gas,iftheelectrondensityisfallingtheglowintensitywillalsofall.
Andsothedarkspacedevelopsnearthenegativeelectrode(theCrooke's
darkspace).
Nowtheglasswallsofthechamberarealsocoveredwithnegativeelectrons
(rememberthequartzisnotconductingandsotheelectronsnormallyare
trappedonthewalls)andforthesamereasontherewillbeadarkspace
allovertheinnerwallsofthechamberbecausetheseelectronsrepelthe
electronsfromtheplasmajustasthenegativeelectrodedoes.
Thisisaqualitativeexplanationofthedarkspacephenomenon.Thiscan
allbeshownquantitativelywithaverycomplexmathematicalanalysis
whichIthinkisunnecessaryforyourpurposes.
Nowwhathappenswhenyoubringyourhanduptothequartztube?Youhand
makesanelectricalcapacitybetweenthequartztubeandthegroundand
thatchangesthecouplingoftheelectricalplasmatothewallsatthe
pointofyourhandlocation.Thiscausesaredistributionoftheelectrons
onthewallofthechamberandthereforechangesthepotentialsatthewall
whichthenchangesthenumberofelectronsinthegaswhichcanreachthe
wallandsotheglowaroundthelocationofyourhandchanges.
Alsobecausetheinnerwallsofthechamberaregenerallycontaminatedwith
watervaporandothersurfacecontaminantstheelectronswhichpileupon
thewallssometimedevelopunstableconcentrationsandbuilduphigh
chargeswhichrisetoapointwheretheysuddenlyrearrangethemselvesand
causethestriationswhichyouseeintheglowastheelectronspileup,
developabigcharge,thenbecomeunstableanddischargeofftosomeother
regionofthewalls,andthiscanrepeatitselfoveranoverdependingupon
thesurfaceoftheglassandothercontaminantsintheplasma.
Thisisasimplephenomenologicalexplanationofthebehaviourofthe
dischargetubewhichIhopewillbeadequateforyourpurposes.Ifyou
wishtoaskmesomequestionsaboutthispleasesubmitthemandIwill
explainfurtherifIcan.Howeveritcangetverycomplicatedbecausea
plasmaissuchacomplexenvironment.
Bestwishes,
DickBersin....

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Re:What'sthecauseofCrookesDarkSpace&striationsindischargetubes

19952001.Allrightsreserved.

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