Académique Documents
Professionnel Documents
Culture Documents
",
IIT.JEE, 2012
& PHYSICS
CHEMISTRY, MAtHEMATICS
Q.
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Examination
INSTRUCTIONS
carefully.
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1. Ensure matching of OMR sheet with the Question paper before you start marking your answers
on OMR sheet
2. On the OMR sheet. darken the appropriate bubble with HB pencil for each character of your
Enrolment No., and write in ink your Name, Test Centre and other details af the designated
places.
3. OMR sheet contains alphabets. numerals & special characters.for marking 'answers.
,;'::
, (i)
ell
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Section-A (01 - 07) contains 7 muttiple choice questions which have only one correct answer ..
Each question carries +3 marks for correct answer and -1 mark for wrong answer.
Sectlon-A (08 - 11) contains 4 muttiple choice questions which have more than one correct
answer. Each question carries +4 marks for correct answer. There is no negative marking.
00
~N
n.
Sectlon.-A (12 ~ 16) contains 2 paragraphs. Based upon paragraph, 2 and 3 mu~iple choice
questions have to be answered. Each question has only one correct answer and carries
+3 marks for correct, answer and - 1 mark for wrong answer.
Q.
0
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(II) .Section-e (01 - 07) contains 7 Numerical based questions with answers as numerical value and
each question carries +4 marks for correct answer. 'There is no negative marking .
Q.
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Useful Data
. PHYSICS
, Acceleration due to gravny
9 = 10m/s2
h = 6.6 x10-34J-s
Planck constant
Charge of electron
Mass of electron
R = 8.314 J~'
mol-'
CHEMISTRY
Gas Constant
Avogadro's Number N.
Planck's constant . h
1 Faraday
1 calorie
1 amu
1 eV
=
=
=
=
=
=
=
=
=
=
Atomic No:
m,,"
Ltcf., rzrrJXB Bau.e,.29-A, Kal" Saral, Saruapriya Vlhar, Ncr :o.Jhl .Jl.ooJII5. Ph 46J06000.
_Nne: 1llWID.JiftJ-.t:om
,26S6SJ493.Tax ,26513942
.Claemistry
PART-I
SECTION-A
Straijlht
Objective
Type
This section contains 7 multiple choice questions numbered 1 to 7. Each question has 4 choices (A), (B),
(C) and (D), out of which ONLY ONE is correct.
(H3C)3C8CHPPh
The product [X) is
(A)
(B)
CH2
/\
(D)
(C)
(CHJlC-HC-CH-OPh
o
II
2.
OH
II
H2C = CH-C-OEt+Me
-C-H
II
Et3N )Me-CH-C-C-OEt
II
CH2
N acts as catalyst
catalytic action?
(A) It will attack on carbonyl carbon of aldehyde
(B) It removes the acidic ct.-hydrogen of unsaturated ester to generate carbanion nucleophile.
(C) It will attack on carbonyl carbon of ester.
(D) It undergoes conjugate addition on unsaturated ester
3.
dilute, aqueous oxalic acid and dilute sulphuric acid, the rate of reaction suddenly
increases considerably
the reaction
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r
4
(f0
4.
NaND, )? [X]
? [Y]
Hydrolysis)
Hel
M is
~)
e
x:
(C)()NOH
The end product
..
\
5.
Mg38,
[X] + MgC/,
HCllao
[X]+Hp
For [X] and
M the
incorrect choice is
(A) [X] is
Bel,
and
(B) [X] is
B,H6
and
?[Y]+H,
HCII",,)
M is H,BO,
M is H,BO,
M on strong heating
M, B completes
~s octet by removing
OH-
In the extraction of silver, leaching of Ag,S is done with NaCN to convert it into soluble complex,
Na[Ag(CN),). A stream of air is also passed in the leaChing process. The purpose of stream of air
is to
(A) oxidizes Na,S formed into Na,S,03 and SO,.
(B) oxidizes Na,S formed into Na,SO. andS.
(C) oxidizes Na,S into Na,O and S.
(D) acts as catalyst.
7.
N,O. (g)
If this equilibrium mixture is a darker colour at high temp. and at low pressure, which of these
statements about the reaction is true?
(A) The reaction endothermic and NO, is darker in colour than N,O .
(B) The reaction endothermic and N,O. is darker in colour than NO,.
(C) The reaction exothermic and N,O. is darker in colour than NO,.
(D) The reaction exothermic and NO, is darker in colour than N,O .
. ...
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Rough Work
I..
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I
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oxoxm
. (~Q
00
(C) PF3CI2
9.
(D) PC'13F2
(D) (CH3)2CH-C
10.
II
\
OEt
0)
S)
(D) "'H~tom>O(OC=S)+O(O=CS)
[ D stands for bond dissociation energy]
11.
Which of the following is/are correct explanation for why Ketone have an unfavorable equilibrium
in an aldol reaction with sodium hydroxide base?
- (A). Ketones are less electrophilic due to a carbonyl carbon that is more stabilized by two electron
releasing alkyl groups.
(B) The Ketone group is stabilized by allylic interactions with the adjacent Pi system.
(C) There is less Ketone enolate is formed because the alpha protons are less acidic
.
(D) Steric hindrance at the carbonyl carbon of a ketone due to two alkyl groups; makes enolate
addition more difficult.
Rough Work
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'~.7
AITS-CRT -I(Paper-1)-CMP-lIT
JEE/12
Comprehension
Type
This section contains 2 paragraphs. Based upon the first paragraph 2 muhiple choice questions and
based upon the second paragraph 3 muhiple choice questions have to be answered. Each of these
questions has four choices A), B), C) and 0) out of WHICH ONLY ONE IS CORRECT.
Paragraph
for Question
Nos. 12 to
13
Silicones are organo-silicon synthetic polymers. These are fonned by the. hydrolysis of alkyl or aryl
substituted chiaro silanes and their subsequent Polymerisation. The alkyl and aryl substituted chiaro
silanes are prepared by the reaction of Grignard reagent and SiCI . The lower silicones are oily liquids
but higher members containing long chains or ring structures are waxy and rubber like solids. They are
stable to heat and are non-toxic. They are good electrical insulators and are used in making Vaseline like
greases which are used as lubricants in aeroplanes.
12.
liner silicones
(C) When water is eliminated from the tenninal -QH groups of linear silicones, cross linked
silicones are fonned
(0) RSiCh on hydrolysis gives cross linked silicones
13.
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Paragraph
Nos. 14 to 16
for question
One of the nicest applications of reduction potential diagrams is the prediction of the products of reactions
involving elements having several oxidation states. Consider the reactions of iodide with permanganatein
acid solution.
IO~
1.14V
) HOI
1.45V
0.54 V
)1;
I
1.20v
O.56V
MnO- 4
)MnO;-
2.26V
)Mn02
I
1.69v
1.0V
Mn3+
1.5V
1.239 v
ct'
Mn2+ -1.20 v Mn
Another application ofthe above diagram is to predict the species which are unstable toward
disproportionation.
14.
15.
16.
(A)
I;
and MnO~-
(C)
I;
and Mn2'
When iodide is added dropwise to an acidic permanganate solution. the products of reaction are
2
(6) HOI and Mn '
(A)
I;
(C)
and Mn02
(A) I~.HOI.Mn'+
n.
... F
Rough Work
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SECTION-C
Integer Answer Type
x
This section contains 7 questions. The answer to each of the questions is a single-digij
integer, ranging from 0 to 9. The appropriate bubbles below. the respective question
numbers in the ORS have to be darkened. For example, if the correct answers to question
numbers X, Y, Z a.nd W (say) are 6, 0, 9 and 2, respectively, then the correct darkening of
bubbles will look like the as shown.
.
0@0o
000'
000w
000'
000'
000'
@00'
000'
000'
000'
o~
CI
....,c .....
1.
'o~
....,c
CI
(CH,)2 NH,
Excess
/-0
c""
1) LiAIH,
Mel
2)~O
Excess
Ag,o
CI
_h_ea_t ~) [Xl
How many
2.
7t
ZnFe204 adoptspinel
[Xl?
1 -1. 15
-:
Y
3.
2 part of available
x
Ka of 02N-CH2COOH
than 1.68
(I)
is 1.68. How many compounds given below have a pKa value greater
. (II)
M
Rough Work
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4.
Some reaction conditions a~ given below. How many of these leads to evolution of N2 gas?
(i).
(ii).
NH4N02-~
(iii).
BaN3
!:>.
!:>.
II
(iv).
(v).
R-C-N3
-OH/HzO
---~~
-+
(vi).
NH3 + (excess)+CI2
(vii).
Urea + HN02 -+
(viii).
(ix).
5.
The algebraic sum of the P-H bonds in H3PO., H3P03 and H3P02 is/are
6.
7.
'(X'"if"c'wuw",xwwW'Sff1"fiff
'Wi
"H"
.".t.wy
"SS"f(WW
..
_('W
'(((('wgN
. "T
w.c.s
,.".,
s'""ws.
Rough Work
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10
Mathematics
PART - II
SECTION-A
Single Correct Choice Type
This section contains 7 mu~iple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out which ONLY ONE is correct.
1,
The absolute value of the difference of the real roots of the equation';
2(24017_1)=Ois
'
W2
~1
_ 220'ox + Ix _ 220091+
~3
~4
2.
2
If the area bounded by the curve Ixl + IYI = c (c,> 0) is 2c , then the area bounded by lax + byl +
2
2
Ibx - aYI = c where a + b =.1 is
2
(A) Bc
(B) 4c2
2
(C) 2c
(D) c2
3.
If A = [:
~J;
:
y
(A) 3(3t
(C) (31)
4,
Define
Pt =
'
(e + l)t!
(B) 2(3y2
(D) (3!)
and q, =
PI
P2
+ ... +
Pt. Let
P100
q,oo
=!,
(A) 9B
(B) 99
(D) 101
(C) 100
Rough work
r
fIRJU LirI.,
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11
'Y" .,"
Tangent to hyperbola xy. = c2 at point P interSectsthe x-axis at T and the y-axis at T'. Nonnal to
hyperbola at P intersects the x-axis at N and the y-axis at N'. If the area of triangles PNT and
S.
+..!/;'
is equal to
(8) ~
c2
2
(C) _1
(D) ~
c2
.(
6.
Given 2006 vectors on a plane. Sum of every 2005 vectors is a scalar muRipleof the other vector.
Not all vectors are scalar multiple of each other. The sum of all these vectors is of magnnude
(A) 0
(8) 2005
(C) 2006
(D) (2005)2
7.
If fIX)
= IIlxl-21
1
1
and g(x)
Ilxl-;-31
.
(A) no solution
(C) atleast 1 solution
This section contains 4 muRiplechoice questions. Each question has 4 choices (A), (8), (C) and (D) for ns
answer, out which ONE OR MORE is/are correct.
8.
'-'j
If the coordinates of the vertices of the triangle are rational number, then which of the following
points of the triangle will always have rational coordinates
(A) centroid
(8) incentre
(C) circumcentre
(D) orthocentre
.
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CWiSW'
Tcr-c
Fe
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'NiCWW
iSS
wne
_n
Wi'
'YeW1
emWeZT"
Rough work
.. -
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12
9.
If DA = ii, AB =
that I ii 1=17,
6,
Ixyl = 4 , then
k is equal to
-!.
(B) ~
(C) 25
(D) ~
(A)
17
17
17
17
10.
A and B are two non-singular square matrices of order 3 x 3 such that AB = A and BA = B, then
(A) IA + BI = 0
(B) IA + BI = 8
(C)l.A. - BI = 0
(D) IA + BI = 2
11.
a, b, c are three distinct complex numbers such that (a - b)5 + (b - C)5+ (c _a)5 = 0, then
. (A) arg(a-b)=~
b-c
6
(C) la - bl = Ib - cl
(B) arg(b-C)=
211
c-a
3
(D) none of these
Comprehension
Type
Nos. 12 to 13
for Question
In a certain problem, if we differentiate (f(x) g(x)} as f'(xl g'(x) instead of f(x) g'(x) + f'(x) g(x) , then we get
1
3
correct result if f(x) = x and g(Ol = -.
'
12.
(A) IX:3
(B) IX~313
27
(D) Ix-313
(C) IX~313
Rough work
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13
13.
= 100 is
(8) 1
(0) 2
for Question
Nos. 14 to 16
If Zois complex number and c is a real number, then Zoz + Zoz + c = 0 represents a straight line. Its
complex slope is - ~
by complex
Zo
numbers z, and
Z2
is defined by m =
z_2 -z_'.
Z2 -Z,
(1)
(2)
p, q are complex
m, = ~m,
15.
(A) m2
(8) m2~
(C) m~ = ~
(D) m, + 2m2 = 0
16.
If line az+az+ib=O
= m,~
(A) 2J2
(C) 2(1 - i)
- 2 a) is
a
(8) 2J2 i
(D) - 2(1 + i)
Rough work
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U~
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AITS'-CRT-I(Paper-1)'-CMP~IT
14
JEE/12
SECTION-C
Integer Answer Type
Z W
0@l0('
This section contains. 7 questions. The answer to each of the questions is a single digrt
integer, ranging from 0 to 9. The appropriate bubbles below the respective question
numbers in the ORS have to be dar1<ened. For example, if the correct answers to question
numbers X, Y, Z and W (say) are 6, 0, 9 and 2, respectively,. then the correct dar1<ening of
bubbles will look like the following:
000.
0004
000'
000('
000('
@)00'
000'
000'
000'
1.
Tangents to the circumcircle of MBC at points A, Band C meet the sides BC, CA and AB at
points P, 0 and R respectively, then the area of triangle formed by P, 0 and R is
_
3.
a, b, c are real roots of the cubic equation f(x) = 0 such that (x - 1)' is a factor off(x) + 2 and (x +
1)' is factor of f(x) - 2, then b + bc + ca is equal to
_
4.
A circle is described whose centre is the vertex and whose diameter is three quarters of the latus
rectum of the parabola y' = 4ax. If PO is the common chod of the circle and the parabola and L,L,
is the latus rectum, then area of the trapezium PL,L,O is a'(k -
the value of k is
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15
5.
If a function y = f(x) is such that f'(x) < 0, then the number of integral values of 'a' for which the
major axis of ellipse f(a + 11)x2 + f(a2 + 2a + 5)y2 = f(a + 11)f(a2 + 2a + 5) becomes x-axis, is
6.
The roots of equation x4 + x3 + x2 + X + 1 =-0 are vertices of a quadrilateral whose area equals to
(sin(~~ )+sin(23~k))( cos(~~ )-cos(~25k)),
an.dAS is
j
Consider two skew lines 7 = ji + Aa and 7 = (j + ).Iii, where P (ji) and Q (j) be points on the two
lines. Also the shortest distance between the skew lines is unity and area of parallelogram whose
adjacent sides are unit vectors and iiis 0.5 units. If angle between line of shortest distance
7.
jj
w'
i,
then.the value of AS is
uyw'Ws
.... - iq"
W"SW:WWWWWS
"C
_
rWWWiSWiSO'WNW!'
Z"Kwwj'
S' "' __
'S
sWsSw '''e __
iSYSS"Sh
wsw
Rough work
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rTq
r-.
AITS-CRT-I(Paper-1)-CMP-lIT
Physics
JEE/12
16
PART -III
SECTION-A
Single Correct Choice Type
This section contains 7 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out which ONL Y ONE is correct.
1.
Two balls are dropped from the same point after an interval of 1 second. Their separation 3
second after the release of the second ball. (g = 10 m/s2)
(A) 25 m
(B) 30 m
(C) 35 m
(0) 40 m
2.
The upper half of an inclined plane of inclination e is perfectly smooth while .the lower half is
rough. A block starting from rest at the top of the plane will come to rest at the bottom if the
coefficient of friction between the block and the lower half of the plane is
(A) f1 2 tan e
(B) f1 tan e
3.
(C)f1 = _2_
tane
(0) f1 = _1_
tane
V~
.(0)
~.
VO\
4.
WM
(C)A2M
~mA
(0) AM2
Rough work
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17
S.
AITS-CRT -/(Paper-1)-CMP-/ITJEE/12
A meteor of mass M breaks up into two parts. The mass of one part is m. For a given separation r
the mutual gravitational force between the two parts will be maximum if
(A) m = (M/2)
(C)
(8) m = (M/3)
=~
(D)
,,2
m = Mr,:;
2,,2
6.
A wire breaks when subjected to a stress S. If p is the density of the material of the wire and g,
the acceleration due to gravity, then the length of the wire-so that it breaks by its own weight is
(A) pgs
.
. (8) pg/s
(C) gs/p
(D).s/pg
7.
A cylinder has a radius r. To what height h should it be filled with water so that the thrust on its
walls is equal to that on its bottom
.
(A) h = 2r
(C) h
(8) h = r
= (r/2)
Multiple
. (D) h
= (r/4)
Correct Answers
Type
This section contains 4 multiple choice questions. Each question has 4 choices (A), (B), (e) and (D) for its
answer, out which ONE OR MO~E is/are correct.
.
8.
A particle having mass m and positive charge q whirls along vertical circle of radius R. At tlie
centre of circle, another positive charge 2q is fixed.
(A) The minimum velocity given at the lowest point to complete vertical circular motion is less
than JSgR for motion in gravity.
_.
(8) For any value of velocity given in horizontal direction at the lowest point in gravity free space it
will perform vertical circular mOtion.
_
(C) Tension in gravity free space cannot becomes zero at any point during motion.
(D) If the charge at the centre is removed and considering the motion in gravity tension will also
be function of charge on particle.
9.
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by
18
10.
A cubical block is floating in a liquid with one third of n's volume immersed in the liquid. When the
whole system accelerates upwards wnh acceleration of g/2.
(A) The fraction of volume immersed in the liquid will change.
(8) The buoyancy force on the block will change.
(C) The buoyancy force will increase by 50 percent.
(0) The pressure in the liquid will increased.
11.
Two concentric metallic shell's of radius Rand 2R, out of which the inner shell is having charge 0
and outer shell is uncharged. If they are connected wnh a conducting wire. Then,
(A) 0 amount of charge will flow from inner to outer shell.
(8) Q/e number of electrons will flow from outer to inner shell, where e charge on electron.
(C) K4~' amount of heat is produced in the wire
(0) KO' amount of heat is produced in the wire.
2R
.
Comprehension
Type
This section contains 2 paragraphs. Based upon the paragraph 2 multiple choIce questions and based
upon the paragraph 3 multiple choice questions have to be answered. Each of these questions has 4
choices (A), (B), (C) and (D) out of which ONLY ONE is correct .
. Paragraph
for Question
Nos. 12 to 13
Three metallic plates out of which middle is given charge 0 as shown in the
figure. The outer plates can be earthed wnh the help of switches 51 and 52'
The area of each plates is same.
Answer the following question based on the following passage.
d
3d
s,
12.
(A)-(0/2)
(C)0
13.
(8)(Q/2)
(0)-0
The charge that will flow to earth when only switch 51 is connected to earth is
(A)-(0/2)
(C)0
(8)(Q/2)
(0)-0
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19
14.
The wavelength of the pulse when it reaches the other end of the rope is
(A) .J3Ao
(B) ~Ao
(C)Nl
(0) 1.0
2
15.
(B) ~~9f
(C) ~~9f
(0)
2 .
16.
If
The lime taken by the pulse to reach the other end of the rope is
. (A) 2~(.J3
(C) 2~
-1)
-,/2)
Roughworlc
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AITS-CRT-l(Paper-1)-CMP-lIT JEE/12
SECTION-C
Integer Answer Type
Y Z W
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1.
2.
Two block of masses m and M are connected by means of a metal wire passing over a
9
2
frictionless fIXed pulley. The area of cross-section of the wire is 6.5 x 10- m and its breaking
stress is 2 x 109 Nm-2 If m = 1 kg, if the maximum value of M is K x 1.86 kg for which the wire will
not break. Find the value of K. (g = 10 m/s2)
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Rough work
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21
3.
AITS-CRT-I(Paper-1)-CMP-/IT
(I'
=!)
JEE/12
4cm
1 rad/sec
in a hOlizontal plane
about its axis. The time is 10.JK sec after which the blocks will start motion
2
with respect to table. Find the value of K. (Take g = 10 mls ) Assume the
size of block slightly smaller then the width of groove.
4.
S.
Two particles of mass M = 3 kg each are kept on a horizontal circular platfonn on two mutually
perpendicular radii at equal distance R = 1 m from the centre of the table. The particles are
connected with a string, which .is just taught when the platfonn is not rotating. Coefficient of
friction between the platfonn'and block is I' = 0.1. Then the maximum angular speed (0) in rad/sec)
of platfonn about its centre so that the blocks remain stationary relative to platfonn. (take g = 10
2
m/s )
. A unifonn cylinder of radius R(= 3m) is spin about its axis at an angular
"'0
velocity
(= 40"ln rad/sec) and placed between two perpendicular wall.
The coefficient of friction between the walls and cylinder is 1'(= 2). Then,
2S K turns will the cylinder make before it stops. Find the value of K.
6.
A long horizontal rod has a bead which can slide along its length and initially placed at a distance
L( = 3 rn) from one end A of the rod. The rod is set in angular motion about A with constant
angular acceleration c<(= 1 rad/seC2). If the coefficient of friction between the rod and the bead is
1'(=1) and gravity is neglected; then find the time (in sec) after which. bead starts slipping.
7.
ofK.
Rough work
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