Académique Documents
Professionnel Documents
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Outline
Background and motivation
Objectives
Materials and methods
Results and discussion
Conclusion
MechEng
History
Projections
33%
250
Oil
200
27%
38%
Coal
26%
150
Share of
World
Total
24%
Natural Gas
100
24%
8%
50
5%
Nuclear
6%
0
1980
9%
Renewables
1985
1990
1995
2000
2005
2010
2015
2020
2025
2030
www.eia.doe.gov
119th Annual Meeting of the Iowa Academy of Sciences
MechEng
MechEng
Objectives
A new type of thermosetting polymers can be prepared through cationic
copolymerization of soybean oil and other types of biodegradable oil.
Changing the concentration of its constituents these polymers can range
from elastomer to tough and rigid plastic.
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Materials
Three low saturated soybean (LSS) oil based-polymers with
styrene (ST) as the monomer and divinyl benzene (DVB) as
the crosslinking agent. Boron triflouride diethyl etherate
(BFE) modified with Norway fish oil ethyl ester (NFO) is used
as the initiator1.
Samples are designated as LSS DVB 10, LSS DVB 15 and
LSS DVB 20.
2 F.
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Samples
Tg
(oC)
e
(moles/m3)
E (MPa)
u (MPa)
b (%)
RMS
Roughnessa
(nm)
LSS DVB 10
48
2.0 x 102
20
2.7
96.1
99 11
LSS DVB 15
61
5.3 x 102
90
6.0
64.1
102 9
LSS DVB 20
71
9.0 x 102
116
7.6
19.9
80 1
TUN DVB20
77
3.5 x 103
170
44
10.6 0.6
TUN DVB30
82
6.1 x 103
390
89
10.4 0.2
TUN DVB40
71
17 x 103
460
110
11.6 0.7
1698
21.3
2.4
111 19
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Experimental details
Reciprocating microtribometer
Load: 800 mN
Stroke length: 60
mm/cycle for 500 cycles
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Experimental details
miscellaneous
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Si3N4 Probe
Ra
76 nm
Ra
5.2 nm
Ra
8.6 nm
RMS
93 nm
RMS
11 nm
RMS
11 nm
Peak to Valley
660 nm
Peak to Valley
294 nm
Peak to Valley
244 nm
Skewness
Kurtosis
- 0.42
3.3
Skewness
0.34
Kurtosis
19
10
Skewness
- 1.6
Kurtosis
12.4
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Sample
COF
Sample
COF
LSS DVB 10
0.826
TUN DVB 20
0.078
LSS DVB 15
0.522
LSS DVB 20
0.550
TUN DVB 30
0.397
EP resin
0.701
TUN DVB 40
0.510
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13
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LSS DVB 10
LSS DVB 15
Sample
LSS DVB 10
157 14.8
LSS DVB 15
127 13.0
EP resin
2234 1221
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15
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LSS
LSS
Sample
Average wear
depth (m)
LSS DVB 10
27 1.19
LSS DVB 15
7.68 0.44
LSS DVB 20
9.92 0.42
EP resin
9.28 5.96
LSS
20
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Coeff. of
friction
against
Si3N4a
Coeff. of
friction
against
diamondb
Wear depth
with Si3N4
probec (nm)
Wear depth
with
diamond
probed (m)
Hardnesse
(GPa)
LSS DVB 10
157 14.76
27 1.19
0.035 0.004
LSS DVB 15
127 13.08
7.68 0.44
0.060 0.007
LSS DVB 20
---
9.92 0.42
0.130 0.019
TUN DVB 20
---
---
0.071 0.001
TUN DVB 30
---
---
0.091 0.002
TUN DVB 40
---
---
0.158 0.003
Epoxy (EP)
resin
2234 1221
9.28 5.96
---
For normal load range of 0.2-800 mN (LSS) and 0.2-400 mN (TUN). b For normal load range of 0.2-100 mN.
c After 500 cycles at 800 mN normal load.
d After 10 cycles at 700 mN normal load.
e Measured using nanoindenter
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Conclusions
Dry friction and wear behavior of soybean oil and tung oil-based polymers
prepared by cationic polymerization of low saturated soy-bean oil (LSS) with
divinyl benzene and polystyrene were evaluated as a function of crosslinking
density.
Crosslinking density has a large impact on friction and wear behavior of soybean
oil-based polymer:
Higher crosslinking density generally resulted in lower friction and adhesive wear.
Increased abrasive wear was observed for the lowest and highest crosslinking
densities.
Crosslinking density has an impact on the friction, but not wear, behavior for tung
oil-based samples
Higher crosslinking resulted in a higher friction
No damage on surface indicates that these brittle materials are wear resisting under
the given loading conditions.
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Acknowledgement
Chris Li, University of South Carolina
Scott Chumbly, SEM group, Iowa State University
Jerry Amenson, Material Analysis and Research Lab,
Iowa State University
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