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Transmix feed
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Feed pump
Feed-overhead exchanger
Feed-bottoms exchanger
Distillation tower
Gasoline trim condenser
Reflux accumulator
Gasoline product pump
Gasoline product cooler
Reboiler
Diesel product pump
Diesel product cooler
H Y D R O C A R B O N P R O C E S S I N G / MAY 2000
Transmix feed
product
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20
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product (
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TIT
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14
Gasoline product
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1 Feed pump
2 Feed-primary tower
overhead exchanger
3 Feed-low-sulfur diesel
product exchanger
4 Feed-secondary tower
overhead exchanger
5 Feed-high-sulfur diesel
product exchanger
6 Primary distillation tower
7 Gasoline trim condenser
8 Gasoline reflux
accumulator
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Transmix does not behave hke a mixture of straightrun petroleum components; i t is a mixture of finished
products that have been subjected to various downstream processes. These finished products may also
contain additives that will not distill with the product.
The volume of transmix generated per shipment
is relatively small. Although the total volume is significant, transmix is accumulated slowly at individual
terminal facilities. Transmix tanks are often operated w i t h fewer than 12 turnovers per year. As the
transmix sits i n the tank, i t weathers. Some of the
lighter-gasoline components evaporate. The diesel
fuel in the transmix will also darken due to oxidation
and nitrification.
Mixtures of different grades of finished products can
also affect the ability to make best-quality products.
Transmixcontaining mostly reformulated gasoline
with some conventional gasolinewill probably not
produce a reformulated-gasoline product. Also, transmix containing low-sulfur diesel fuel with some highsulfur will most likely not make a low-sulfur dieselfuel product. This can adversely affect the processors'
ability to market these products.
H Y D R O C A R B O N P R O C E S S I N G / MAY 2000
possibilities. The first tower can be operated to optimize the quality of the gasoline product. Lower gasoline endpoints can be achieved, and jet-fuel components can be eliminated. The bottoms product from
the first tower w i l l contain diesel fuel and components that were eliminated from the gasoline. The
bottoms will have too low of a flash temperature for
diesel fuel. I n the second tower, the diesel fuel w i l l
be stabilized by removing lighter compounds. The
overhead product will be an off-specification gasoline
or kerosine product. The bottoms product will be lowsulfur or high-sulfur diesel fuel depending on the
transmix feed. A minimum amount of kerosine product w i l l be produced.
Another outgrowth of the process is to make custom
products from transmix. The second tower can be used
to make very high-flash diesel fuels. High-sulfur diesel
fuel can also be produced from low-sulfur transmix.
Custom solvents can also be produced for asphalt emulsions applications. The process can also be used to separate transmix that contains products other than just
gasoline and diesel fuel.
With the increased process flexibility, a change i n
philosophy occurs. By separating transmix into various fractions and blending them into the highest quality finished products, transmix processors will be able
to optimize the product slate from a transmix supply.
Design procedure. The first integrated two-tower
transmix plant was built i n El Mirage, Arizona. The
unit design had to allow for maximum flexibility and
to process a wide range of possible transmix feedstocks. The unit was constructed at an existing transmix-processing plant. I t had a single-tower unit that
was becoming uneconomical to operate. This facility
did have an advantageit was a source of design data
for transmix.
Transmix usually is about 40% gasoline and 60%
diesel fuel. This split is reflective of the way transmix
is separated from products at the pipeline terminals
and of the tolerances of these products for impurities. A
small amount of diesel i n gasoline is better tolerated
than gasoline i n diesel fuel, which will ruin the flash.
Transmix does not have set specifications; i t can be
nearly all gasoline or all diesel fuel.
An obvious approach when designing a transmix
plant would be to obtain transmix samples from a variety of pipeline sources at varying times. This approach
would yield a large number of samples w i t h similar
characteristics. To design this facility, some transmix
samples were used, but samples were also obtained of
unmixed pipeline products. These could then be used in
the laboratory to form transmix samples that spanned
the anticipated range of characteristics.
The transmix samples were distilled and analyzed to
generate design data. The laboratory samples were also
distilled in a bench-top machine to prove the feasibility
of producing a low-sulfur diesel product i n the overhead stream from a borderline high-sulfur diesel fuel.
Design parameters were tested in a process simulator using laboratory transmix data and simulated mixtures based on unmixed product data. The latter
allowed a wider range of mixtures to be simulated with
fewer input data requirements. Because of the wide
H Y D R O C A R B O N P R O C E S S I N G / MAY 2000
challenges, but it will also bring new marketing opportunities. Newer, more complex processes will allow processors to produce more saleable products.
Copyriglit 2000 by Gulf Publishing Company. All rights reserved. Printed in USA.
JohnDJones
ENGINEERING,
INC.