1. Calculate the AU, and determine whether the ENTIRE process is endothermic or exothermic for each case (1 pt each) (@) asystem releases 113 kJ of heat to the surroundings and does 39 kJ of work on the surroundings (b) q= 1.62 kd and w= -874 J (c) the system absorbs 77.5 kJ of heat while doing 63.5 kJ of work on the surroundings 2. Indicate if the following processes below show an increase in entropy ofthe system or decrease. (1 pt each) (a) the melting ofthe ice cubes at -5°C and 1 atm pressure (b) dissolution of sugar in a cup of hot coffee (©) the reaction of nitrogen atoms to form Nz molecules at 25°C and 1 atm (d) alignment of the iron filings in a magnetic field 3. Describe and discuss the AG® values and spontaneity conditions for each of the following reactions. (2 pts each) (a) No(g) + F2(g) > NF3 (a) AH? = -249 kd (b) Noe (g) > NF2(g) AHo = +85 kd 4, Use the standard entropies and heats of formation to calculate the AG for the formation of 1 mole of each species at standard thermochemical conditions (25°C and 1 bar) (3 points each) (2) Ammonium nitrate (s) Beek mor [Se J molt (b) Chloroform (CHC) () i - oa Hag) 0 130.7 Cla 0 223.4 Comma) 0 574 or) 7.90 2.38 NHsNOse) 365.6 151.4 CHCl 1344 1005 §,) Given the following thermodynamic values: Substance ‘AHe (kumole) Se (imole-K) Solid Ring Se(s) 10.2 90.40 ‘Gaseous Ring sulfur, Safa) 101.25 430.20 Monoctinic sulfur, S(s monoclinic) 0 33.05 Gaseous sulfur, (a) 1533 205.61 a) Which is the standard state of sulfur? b) The structure of the 8-atom sulfur molecule is a ring of sulfur atoms attached to each other with single S-S bonds as shown below. Determine the bond enthalpy of a single S-S bond in kJ/mole. -S-SN. oe Sunes °) For the transformation 8S) > Sag, Is work done by the system or on the system? Calculate the work involved. Explain with solutions 4) Determine the change in internal energy forthe reaction 8S) -> Sug) inb),