Aiats Jee Main2014 Paper 1 Test1

Test - 1 (Paper-I) (Answers & Hints)
All India Aakash Test Series for JEE (Main)-2014
TEST - 1 (Paper-I)
ANSWERS
PHYSICS
CHEMISTRY
MATHEMATICS
1.
(4)
31.
(2)
61.
(3)
2.
(3)
32.
(3)
62.
(3)
3.
(4)
33.
(1)
63.
(1)
4.
(3)
34.
(2)
64.
(3)
5.
(3)
35.
(4)
65.
(4)
6.
(1)
36.
(3)
66.
(4)
7.
(1)
37.
(1)
67.
(2)
8.
(2)
38.
(3)
68.
(3)
9.
(2)
39.
(2)
69.
(1)
10.
(2)
40.
(4)
70.
(3)
11.
(1)
41.
(3)
71.
(2)
12.
(1)
42.
(2)
72.
(3)
13.
(3)
43.
(3)
73.
(1)
14.
(2)
44.
(3)
74.
(4)
15.
(3)
45.
(2)
75.
(3)
16.
(3)
46.
(4)
76.
(4)
17.
(4)
47.
(1)
77.
(1)
18.
(1)
48.
(4)
78.
(2)
19.
(1)
49.
(4)
79.
(2)
20.
(3)
50.
(1)
80.
(1)
21.
(2)
51.
(4)
81.
(3)
22.
(2)
52.
(2)
82.
(3)
23.
(1)
53.
(3)
83.
(3)
24.
(2)
54.
(1)
84.
(3)
25.
(2)
55.
(3)
85.
(2)
26.
(4)
56.
(1)
86.
(3)
27.
(1)
57.
(3)
87.
(4)
28.
(3)
58.
(4)
88.
(3)
29.
(2)
59.
(2)
89.
(1)
30.
(4)
60.
(1)
90.
(4)
1/10
PART - A (PHYSICS)
1.
Answer (4)
4.
v = 72 km/hr = 20 m/s
Answer (3)
dv
a v
dt
0 = 20 (0.4)t
t = 50 s
Using equation v2 = u2 2as
0 = (20)2 2(0.4)s
v0
400
0.8
dv
adt
v
0
2[ v v 0 ] at
s = 500 m
v v0
After 50 s train stops and still signal is 50 m ahead.

2.
Answer (3)
c
x
dx c
dt x
c
100
v v0
c = 200
xdx = cdt
x
ct
2 x
x v 0t
ct
v 0 at 2
a2t 3
12
2
Answer (4)
Time of flight of coin
5.
2 v0
a
2 v 03/2
3 a
Answer (3)
In the given figure equation of parabola v = 3t2 6t
1
2.7 (11) t 2
2
Distance travelled
t = 0.7 s
In reference frame of ground
2
2
= (3t 6t )dt (3t 6t ) dt
ucoin = 2.4 m/s
x=4+4
At top-most point of its path its speed become zero

0 = 2.4 (9.8)t1
x=8m
6.
t1 = 0.245 s
Answer (1)
At the time of collision there x and y coordinates are
same.
0 = (2.4)2 2(9.8)h1
h1
(2.4)2
0.3 m
2(9.8)
250
250
(t t 0 )
t
2
2
h2
1
g (t t1)2
2
250
=1m
Total distance travelled = h1 + h2
= 1.3 m
2/10
... (2)
From equation (2), we get
t = 75 s
3.
a2t 2
v 0 at
4
v=0
x12
... (1)
From equation (1), we get
x
2 2
x22
at
2
3
1
250
1
t gt 2
(t t0 ) g (t t0 )2
2
2
2
2
From equation (1) and (2), we have

t0 = 11 s
... (1)
... (2)

7.
12. Answer (1)
Answer (1)
1
(8)t 2
2
Since y component will not get affected by collision

with wall
16
Gravity is only responsible for ball to let it back

at same level as it were initially.
t=2s

v u at
8.
2v 0 sin
g
= 10 j (8i 2 j)(2)
= 16i 14 j
Answer (2)

| v | 21.26 m/s
at
13. Answer (3)
an
an = gcos
at = gsin
9.
Answer (2)
Velocity of y with respect to ball should be directed

towards x.
u sin30
2u
sin
3
3
sin
4
aR
v2
3 m/s2
R
at = 4 m/s2
In the figure tan
10. Answer (2)
u
u 2 2gH
Range =
g
4
3
= 53
14. Answer (2)
15. Answer (3)
= 25.3 m
Just after cut of string DE force acting on block C

is same as before the cut
11. Answer (1)
3
3 3
hence aC = 0
16. Answer (3)
60
a/2
2T
3
3 3
sin( 60 ) sin 60
7
in3
s
g
75
1
sin( 60 )
2
50a = 50g T
60 = 30
75
= 90
a
3
2T 75g
2
4
50 g
... (1)
... (2)
On solving equation (1) and (2), we get

T = 300 N
3/10

17. Answer (4)

Since normal reaction is less than mgcos
u2
y
u1
From figure (1) aA have also one component perpendicular to the plane

gsin
Considering constrained motion

x
sin
h
x
h
sin

x
y cos t
... (1)
cos
x
tan
... (2)

On differentiating both these equation w.r.t. time we
get
ay
aA
aA g (sin )2 ay2
aA g sin
19. Answer (1)
u2 (1 + sin) = u1
mg
(Here is a variable)
here u1
dy
dt
sin
Tcos = mg
16
46
Tsin = N
dx
u2
dt
18. Answer (1)
N = mgtan
N = 163 newton
20. Answer (3)
In absolute reference frame
For ball B
T2 = mgcos30
For ball A
T1cos30 = mg
mgsin
T1 4
T 3
2
mgcos
mg
21. Answer (2)
Fig.-1
If N = mgcos
By FBD
then aA = gsin
In reference frame of B
N + maBsin = mgcos
N
maB
mg
Fig.-2
N = mgcos maBsin
4/10
T
Mg
T = mg
... (1)
N = T + Mg
... (2)
2T = N
... (3)
On solving m = 5 kg
mg
22. Answer (2)
24. Answer (2)
2 kg
25. Answer (2)
f
5 kg
Fcos
15 N
20
3 kg
5a = 15
a = 3 m/s2
mgsin N
2a = f 5
Fsin + mgcos
f = 11 N and it is within maximum friction limit.

23. Answer (1)
By FBD
NQ
N = Fsin + mgcos
Fcos = mgsin + N
60
30
ma
mg
mg (sin cos )
(cos sin )
26. Answer (4)
In FBD of cylinder
27. Answer (1)
ma is psuedo force
28. Answer (3)
Now using Lami's theorem
29. Answer (2)
mg
ma
ag
sin150 sin150
30. Answer (4)
PART - B (CHEMISTRY)
31. Answer (2)
More directionally concentrated orbitals show more
overlapping forming stronger bond.
..
..
F
F
32. Answer (3)
x = 5.5
33. Answer (1)
This is based on fact.
34. Answer (2)
Bond angle of NF3 is lower than that of NH3 because
F is more electronegative than N and bond pair of
electrons move away from central atom. Bond angle
of PF 3 is higher than that of PH 3 due to backbinding in PF3 which is not possible in PH3.
P=F
PF
.F.
+
Let the number of moles of NO2 in 10 mole of the

mixture be x
Molecular weight of the mixture = 2 33.35 = 66.70
46x (10 x)92

66.70
10
PF
BF3 and BCl3 have same bond angle i.e., 120.

Bond angle of OF2 is less than that of H2O in the
same way as NF3 has lower bond angle than NH3.
35. Answer (4)
The hybridisation of Xe in XeOF2 is sp3d. The XeOF2
molecule has trigonal bipyramid structure and Tshape with F-atoms occupying axial position. Thus,
F Xe F bond angle is 180.
36. Answer (3)
I2 + 10HNO3 2HIO3 + 10NO2 + 4H2O
Moles of HNO3 needed = 10 moles of I2
= 10
12.7
0.5
254
Mass of HNO3 needed = 0.5 63 = 31.5 g
5/10

47. Answer (1)
37. Answer (1)

Carbon and sulphur have same number of atoms. It
means they have same number of moles.
Moles of C = Moles of S
2.4
0.075
32
Mass of C = 0.075 12 = 0.90 g
Radius of n th orbit of a Bohr atom is given by

2
n
z
For 4th orbit of He+, r4 (r1)H
NaHCO3 decomposes on heating as

2NaHCO3 Na2CO3 + CO2+H2O
168 g NaHCO3 on heating loses 62 g of its mass.
Actual loss in mass = 0.62 g.
Mass of NaHCO3 in the given mixture = 1.68 g
Mass of Na2CO3 in the given mixture
38. Answer (3)
rn (r1)H
= 2.74 1.68 = 1.06 g

Mole fraction of NaHCO3
(4)2
8(r1)H
2
39. Answer (2)
0.02
0.67
0.03
48. Answer (4)

P4O10 + 6H2O 4H3PO4
rn+1 rn = rn1
Mass of water added to 100 g mixture of P4O10 and

H3PO4 = 27 g
0.53[(n + 1)2 n2] = 0.53(n 1)2
108 g H2O reacts with 284 g P4O10
On solving, n = 4
40. Answer (4)
XeF4 has two lone pairs; SiF4 has no lone pair; BrF3
has two lone pairs and SF4 has only one lone pair.
41. Answer (3)
MgS is most covalent due to higher polarisation
power of Mg2+ and higher polarisability of S2.
27 g H2O would react with
284
27 71 g
108
49. Answer (4)

Electronic configuration of N2, N2+, N2 and N22 are
N2 : 12s *12s 22s * 22s 22 px 22 py 22pz
N2 : 12s *12s 22s * 2s 22 px 22 py 21pz
42. Answer (2)

p
x
x
h
; x
2
2
4
h
1 h
1
h
; v
2
m 4x
2m 2
43. Answer (3)

Mass of 750 ml solution = 750 1.4 = 1050 g.
54
567 g
Mass of solute in it = 1050
100
44. Answer (3)
IE4
Since the ratio IE is maximum, the element
3
belongs to Group-13 of the periodic table. The
formula of its chloride would be MCl3.
45. Answer (2)
N has positive electron gain enthalpy because of its
stable electronic configuration.
46. Answer (4)
The oxides of less electropositive metals are
amphoteric.
6/10
N2 : 12s *12s 22s * 22s 22pz 22 px 22 py *12 px
N22 : 12s *12s 22s * 22s 22pz 22 px 22 py *22 px

Bond order of N2
1
[10 4] 3
2
Bond order of N2
1
[9 4] 2.5
2
Bond order of N2
1
[10 5] 2.5
2
2
Bond order of N2
1
[10 6] 2
2
Bond length is inversely proportional to bond order.

Bond length of N22 is longest.
50. Answer (1)
4th excited state of an atom is 5th orbit. There will
be three lines in the visible region of emission
spectrum due to 5 2, 4 2 and 3 2
transitions
51. Answer (4)
55. Answer (3)
It is based on (n + ) rule.
NH2 and OF2 have tetrahedral structure and angular

bent shape.
52. Answer (2)

CH3 Cl has higher dipole moment than CH3 F
due to higher bond length.
53. Answer (3)
56. Answer (1)

57. Answer (3)
58. Answer (4)
54. Answer (1)

Each S-atom of S 8 molecule undergoes sp 3
hybridisation.
59. Answer (2)

60. Answer (1)
PART - C (MATHEMATICS)
61. Answer (3)
65. Answer (4)

Let ln a = > 0
3 2i
3 2i
zz
z
z 3 0
2
2
Radius =
3 2i
2
x2 + 22x 3 = 0
D = 44 + 12 > 0 as > 0
5
3
2
Also f(1) f(2) < 0

(22 + 3) (42 + 4 3) < 0
62. Answer (3)
(2 + 3) ( 1) (2 + 3) (2 1) < 0
D = b2 + 4|a|2 > 0
But x
b D
which is complex number
2a
66. Answer (4)
63. Answer (1)

z11 1 = (z 1) (z z1) (z z2) .... (z z11)
(z z1) (z z2) ... (z z11) =
z11 1
z 1
Put z = and 2, and divide, we get
( z2 2 ) ( z3 2 ).....( z11 2 ) 22 1 1
2
.
( z2 )( z3 )..... ( z11 )
1 11 1
=
2 1 1
.
2 1 1
( 5 1)
64. Answer (3)
z2
8z3 z1
8 1
Clearly z2 divides AC in the ratio 8 : 1 externally

67. Answer (2)
3 z
4
4
|z|
z |z|
(|z| + 4) (|z| 1) 0
68. Answer (3)
For required terms
1 2 1
x x x 2
x
x2 2x(1 x) + 3[1 x]2 = 0
x
x
x 1 2 x 1 3 0
2 1
Coefficient of x1 in x 2 + Coefficient of x in
x
=0
7z2 = 8z3 z1
|z|min = 1
=1
2 1
x 2
x
1
, 1
2
x
x 1
The roots of the given equation are

and
1
7/10

73. Answer (1)
69. Answer (1)

x1 + x2 = 1, x1x2 = 2
y1 + y2 = 1, y1y2 = 2
C(2 3, 6)
x1 y1 + x2 y2 = 0
2 3
x1 + x2 = (y1 + y2) and x1x2 = y1y2

Now, (x1 y1) (x1 y2) (x2 y1) (x2 y2)
= (x12 x1(y1 + y2) + y1y2) (x22 x2(y1 + y2) + y1y2)
= (x12 x1(x1 + x2) x1x2) (x22 x2(x1 + x2) x1x2)
= (2x1x2) (2x1x2) = 16
Argument of z is least at P when OP is tangent to
the circle
70. Answer (3)
n r 1 a
1
r
x
(n 1)
a
1
x
OC 12 36 4 3
OP 48 12 6
a
x
tan( )
3
5
6
3
1
5
16
tan
T6 and T7 are the greatest terms.
2 3
2 3
1
6
3
Let I + f = (2 3)5 = 5C0.25 + 5C1.24 3 + ..... +

5
C5 ( 3)
I = 723
74. Answer (4)

< 0
and are of opposite sign

> 0 and < 0
Again, + > 0
75. Answer (3)
is 7th root of unity.
+ + = 3,
7 = 1 and 1 + + 2 + ..... + 6 = 0
+ + = 0
8/10
|| > ||
72. Answer (3)
log3 1 2 3 4 5
= log3 9 + log3|6| = 2
Numerically positive root is greater than the

negative one.
I + 1 = 2[32 + 240 + 90]
= log3|6 86|
Also, >
f (2 3)5 5 C0.25 5 C1.24 3 ..... 5 C5 .( 3)5
+ = p > 0 and = q < 0 (as p > 0, q > 0)
71. Answer (2)
1 7
+ = and so on and = 1
1
1
1
1
1
1
76. Answer (4)
80. Answer (1)
11.10C0 + 10.10C1 + 9.10C2 + ..... + 1.10C10
Let f(x) = x(4x2 x + 2)
= 1.10C0 + 2.10C1 + 3.10C2 + ..... + 11.10C10
Clearly f(x) = 0 has only one real root
x(1 +
x)10
x(10C
10C x10)
10
10C
1.x
10C
x2
+ ..... +
Differentiating both sides, we get

(1 + x)10 + 10x(1 + x)9 =
+ ..... + 11.10C10x10
10C
0
81. Answer (3)
+ 2.10C1x + 3.10C2x2
0 +2.
10.29
10 C
+ 3. 10C 2 + ..... + 11. 10C 10 = 2 10 +
Co-efficient of
= 6144
n(n 1)(n 2).....(n r 1) r

.x
r!
We get the first negative term when n r + 1 < 0
Tr 1
35C .35C
0
15
82. Answer (3)

12
2k
i 2 sin 13
12
= ie
2 k
i
13
k 1
78. Answer (2)
5!
1
3 p ( x 2 )q
General term =
p! q ! r !
x
where p + q + r = 5 and 2q r = 4
q=2
r=0 p=3
q=3
r=2 p=0
The required co-efficient of x4
5! 3
5!
.3 ( 1)2
( 1)3
2!3!
3!2!
= 260
2k
13
Let
12
i k
k 1
2
i
13
e
13th root of unity
2k
12 2 k i
i
= i e 13 , . e 13 13th root of unity
k 1
1
1
1 1
12
11
= i 2 3 ..... 12 i ( ..... )

= i
83. Answer (3)
(z1 + z2)2 = 3z1z2
Let z = |z|ei and = ||ei

i
2| |e 4
i
i
= 2 | | e .e 4
1 i
= 2
i cos
z12 + z22 = z1z2
79. Answer (2)
35C
35C
20
35
12
2k
2k
i
i sin
cos
=
13
13
k 1
38
3
r = 13
35C1.35C16 + ..... + 35C20.35C35 = 35C25
k 1
35
r 1 0
3
35C .35C
1
16 .....
50
x in (1 x2)35
= 35C25
77. Answer (1)
35C x
1
The co-efficient of x50

= 35C0.35C15 +
29.12
(x + 1)35 (1 x)35 = (1 x2)35

(35C0x35 + 35C1x34 + ..... + 35C35) (35C0
+ 35C2x2 ..... 35C35x35) = (1 x2)35
Put x = 1,
10 C
x(4x2 x + 2) = 0 also has only one real

root
2 (1 i )
4 = 3b
4
3
84. Answer (3)
t2 + 4t 5 =0
t2 + 5t t 5 = 0
(t 1) (t + 5) = 0
|x 1| = 1, |x 1| 5
x = 2, 0
9/10
85. Answer (2)
88. Answer (3)
(1 2x)n 1 + 2n
= 1 2 xx
Statement-2 is false as equality holds only when z1

and z2 are on the same side of origin
n(n 1) 2
x ..... 1 2 nx
2
Statement-1 is true as
2 n(n 1) n
C3 x 3 .....
= x
2
2 3i
4 6
196 441
i
5 5
25
Divisible by x2
| 2 3i | 13 and
86. Answer (3)

rth term from the end = (n r + 2)th term from the
beginning
4th term from the end =
1
C8 (3 5 )3
11
4 6
7 6
i | 2 3i | i
5 5
5 5
P(1) = 8 7 1 = 0
P(1) is true
k
Let P(k) is true i.e., 64 2 7k 1 = 7
= 275 5
Statement (1) is true and statement (2) is false
Now, P(k + 1) : 64
87. Answer (4)

=
1
P (1): 0! 1 , i.e., true
2
k
8.64 2
k 1
2
7(k 1) 1
7k 8
= 7.64 2 64 2 7k 1 7
k
Let P(k) be true i.e., (k 1)!
2
= 7(64 2 1) 7
which is divisible by 7.
Now to check P(k + 1)

k 1
4 6
16 36 2
i
13
5 5
25
5
89. Answer (1)
11 10 9
1
5 5 4
=
3 2 1
3
k 1
2
2 3i
637 7
13
5
5
90. Answer (4)
k!
Clearly the point 3 + i lies on the circle but there is

no point of intersection
k
2 (k 1)!

k
(3, 1)
k
,k k !
2
But clearly
/4
(2, 0)
k k 1 (k 1)k 1
2k
2k 1
When k > 2
P(n) does not hold for n = 2

10/10

Aiats Jee Main2014 Paper 1 Test1

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Test - 1 (Paper-I) (Answers & Hints)

All India Aakash Test Series for JEE (Main)-2014

All India Aakash Test Series for JEE (Main)-2014

Test - 1 (Paper-I) (Answers & Hints)

After 50 s train stops and still signal is 50 m ahead.

In reference frame of ground

ucoin = 2.4 m/s

At top-most point of its path its speed become zero

From equation (2), we get

From equation (1), we get

From equation (1) and (2), we have

Test - 1 (Paper-I) (Answers & Hints)

12. Answer (1)

Since y component will not get affected by collision

Gravity is only responsible for ball to let it back

All India Aakash Test Series for JEE (Main)-2014

13. Answer (3)

Velocity of y with respect to ball should be directed

10. Answer (2)

Just after cut of string DE force acting on block C

11. Answer (1)

On solving equation (1) and (2), we get

All India Aakash Test Series for JEE (Main)-2014

Test - 1 (Paper-I) (Answers & Hints)

Considering constrained motion

19. Answer (1)

In absolute reference frame

21. Answer (2)

Test - 1 (Paper-I) (Answers & Hints)

All India Aakash Test Series for JEE (Main)-2014

22. Answer (2)

24. Answer (2)

25. Answer (2)

f = 11 N and it is within maximum friction limit.

26. Answer (4)

27. Answer (1)

28. Answer (3)

Now using Lami's theorem

29. Answer (2)

30. Answer (4)

32. Answer (3)

Let the number of moles of NO2 in 10 mole of the

Molecular weight of the mixture = 2 33.35 = 66.70

46x (10 x)92

BF3 and BCl3 have same bond angle i.e., 120.

Mass of HNO3 needed = 0.5 63 = 31.5 g

All India Aakash Test Series for JEE (Main)-2014

37. Answer (1)

Mass of C = 0.075 12 = 0.90 g

Radius of n th orbit of a Bohr atom is given by

For 4th orbit of He+, r4 (r1)H

NaHCO3 decomposes on heating as

38. Answer (3)

Test - 1 (Paper-I) (Answers & Hints)

= 2.74 1.68 = 1.06 g

39. Answer (2)

48. Answer (4)

Mass of water added to 100 g mixture of P4O10 and

0.53[(n + 1)2 n2] = 0.53(n 1)2

108 g H2O reacts with 284 g P4O10

27 g H2O would react with

49. Answer (4)

N2 : 12s *12s 22s * 22s 22 px 22 py 22pz

N2 : 12s 12s 22s 22s 22 px 22 py 22pz

N2 : 12s 12s 22s 2s 22 px 22 py 21pz

N2 : 12s 12s 22s 22s 22pz 22 px 22 py *12 px

N22 : 12s 12s 22s 22s 22pz 22 px 22 py *22 px