srivatapata Rig aes, Taree res fear Feech Preafaqurert Farah - tte cols PROFESSOR GURMEET SINGH HEAD, DEPARTMENT OF CHEMISTRY UNIVERSITY OF DELHI DELHI - 110.007, Complaints / Queries regarding MCQ of the M.Sc. Chemistry Entrance Examination 2015 1.Complaint/Queries regarding MCQ must be submitted till 5.00 p.m. on 22-06-2015. Any query submitted after stipulated time and date will not be entertained. 2.All queries may be submitted by email at admission@chemistry.du.ac.in & addressed to The Convener, M.Sc. (Chemistry) Entrance Examination 2015. 3.Hard copy of the complaint may be submitted to Mr. Rakesh Kumar, Department of Chemistry, University of Delhi, Delhi - 110 007 Professor Gurmeet Singh . Head of the Department ead, chemi Del Delhi-110007 versity of D Fane OTT 27665605; Phone: O11 27667 OT BreeCee ——EPBR OTT ‘om, Mobile 9810390540 Email: gurmoet!23ESCH SECTION A 1. 4H3AsO;)— + 3Na[BH,] > +. H;BO; + NaOH (1) As(OH)s, (2) NasAsO, — (3) AsHy, (4) As,O; LJ 2 Of the following nuclides, the one most likely to be radioactive is GNC @ SN GB) MP 4) “zn 3. Arrange the following metal-carbonyl complexes in the increasing order of the carbonyl stretching frequency: [Fe(CO),]* , [Mn(CO)g]° , and [Cr(CO)o] (1) [Mn(CO},]" < [Cx(CO).] << [Fe(CO},]*" (2) [Fe(COy]< — [CCO)] < — [Mn(CO),]" (3) [Cr(CO) < — [Mn(COy]” < _[Fe(CO),)” (9) fRe(Coysj> < EMn(COy’ < _ [C(CO)e] 4. The self-indicating silica gel (impregnated with cobalt chloride) tums pink on absorbing moisture and becomes blue on heating. The pink and blue colors are respectively due to (1) Co” and Co™* (2) [Co(H,0),}** and Co,CO, (3) [Co(HyO)@), (@) (iii), (Gi) GB) @)Gid), (6)>Gi), ()>@, [ (4) ©) Gi), ()>@), @) Gi) Among the following compounds, the most basic compound is O (on oO @ 4 oye @ fh 2a36, 35 Match the compounds (List I) with correct IR frequency 0. stretching (List II) List 1 List I ° a (a) (i) 1840 cmt ° C (b) 9 (© of (iii) 1770 em! Q) @-@), )>Gi), (ii) 2) &)>@); (iii), (€) +i) GB) @>-Gii), &)>Gi), ©)>@) © >dii), &)}>@, (Gi) (ii) 1740 cm" Among the following compounds, the most basic compound is37. 38. ESCH The reaction of cyclooctyne with HgSO, in the presence of aqueous H»SOx gives eo qd) ‘OH Oo (2) ‘OH O ot O ‘The Major product formed on nitration of N.N-dimethylaniline with cone. HSO,-HNOs mixture is NMe2 NMe, NOz ay MN Q) NMe, NO, SF Oo @) NOa (4) NOESCH 39. The major product obtained upon treatment of compound X with H.SO, at 80 °C Se, TsO x \ () Q) To G) ao @) 0 oy 40. The compound oO, (1) anti-aromatic and has no dipole moment (2)non- aromatic and has high dipole moment (3) aromatic and has high dipole moment (4) aromatic and has less dipole moment 41. Match list I with list II and select the correct answer List | List Il A. Critical temperature la B. Boyle temperature G. a C. Inversion temperature 3. = D. Reduced temperature 4 AB D BoC qg2 1° 4 3 @Q@ 4 3 2 GB) 2 3 4 I 4) 4 1 2 LJESCH 42. Which has the maximum value of mean free path? (CO, Q) ih GB) O (4) N 43. As the supercooled water freezes spontaneously, its temperature rises to 0°C, 4H for the spontaneous process is equal to 1,0 () at-10°C + H,O() at 0° (1) enthalpy of fusion (2) enthalpy of vaporization (3) enthalpy of sublimation (4) zero C] 44, 60 g of urea is dissolved in 1100 g solution. To keep ATK, as / mol/kg, water separated in the form of ice is: (1) 40g (2) 602 (3) 100g (4) 200 g 4 45. Relative decrease in vapor pressure of an aqueous NaCl is 0.167. No of moles of NaCl present is 180 g of H,O is: (1) 2mol 2) 1 mot @) 3 mol (4) 4molESCH 46. Elevation in boiling point of an aqueous urea solution is 0.52° (Ky = 0.52° mol! Kg). Hence mole-fraction of urea in this solution is: (1) 0.982 (2) 0.0367 (3) 0.943 (4) 0.018 Cc 47. Following are the values of £, and 4H for three reactions carried out at the same temperature: 1 £,=20kI mol", 4H = - 60 kJ mot! I £,= 10K) mol", 4H = -20kJ mot" I £,=20 kJ mol!, 4H = £15k) mol! If all the three reactions have same frequency factor then fastest and slowest reactions are Fastest Slowest Option @ I U - Q) U TL G) 1 WM 4) cannot be predicted LJ = kA]. At a time when t = aay ae 1 concentration) 48. For reaction 2A +B — product, rate law 4, concentration of the reactant is; (Co = ce 1 @ 2 ae Co 1 Oa a |ESCH 49. Acid hydrolysis of ester is first-order reaction and rate constant is given by = 2823 fgg YoomMe t OF Vg-V where Vo, V; and V.. are the volumes of standard NaOH to neutralize acid present at a given time; if ester is 50% hydrolysed then: (1) Vor Ve (2) Vo= (Vi Vo) GB) Ve=2Vi-Vo @) Va= 2M. + Vo 50, ‘Temperature of 1 mol of gas is increased by 1° at constant pressure. Work done: GR (2)2R R BOF (4)3R O 51. Kyof Mg(OH)p is 1.8 x 10"' at 30°C. Its molar solubility is ........at pl=12 (1) 1.8x107'M (2) 1.8x10°M. (3) 1.34x10M (4) 1.8x10" M 52. For the half cell CI’ / Pt(Cl,), the value of (E - E”): (1)- increases as [CI'] increases (2) decreases as [CI'] increases (3) remains constant as [CI'] increases (4) cannot be predicted 1853. 54. a 56. ESCH If Epis the zero point energy of a harmonic oscillator of frequency v and h is the planck’s constant than its energy in the 1 = 2 state will be (1) (+hv) @) 26 GB) 42 (4) (Ey + 2h) Cl The molecules which are IR inactive but raman active is: (1) N 2) Hel (3) So, (4) Protein A thermos bottle containing coffee is vigorously shaken and thereby the temp of the cofite rises. Regard the coffee as system () Q=0 ; W=-ve; AU is +ve Q) W-=+ve; 4Uis te @) W =-ve; AU is -ve (4) Q=0;W=+e; AV is-ve Conjugate base of Hy is: a) a Q) Hy GB) HO (@) He57. 58. 59. 60. ESCH Lithium selenide can be described as a closest-packed array of selenide ions with lithium ions in all the tetrahedral holes. Formula of lithium selenide is: (1) Lise (2) LinSe (3) LiSe (4) LisSe = ‘The pk, of an amino acid is 9.15. At what pH amino acid is 5% dissociated? q) 915 Q) 485 @) 9.44 (4) 7.87 For the equilibrium = NH»COONH4(s) = 2NH3(g) + CO2(g) Peo, = !atm at 100 °C. Hence equilibrium constant is: (1) atm? 2) 2atm® GB) 4atm? (4). 3am’ C] For the following equilibrium NH,CO;NH,(s) @ 2NHs(g) +CO2 (g) K, is found to be 0.5 at 500 K. hence the partial pressure of NH; and CO, are respectively: (1) 2.0 and 1,0 atm (2) 1.0and2.0 atm (3) 1.0and 0.5 atm (@) 0S and 1.0 atm CO 20 -M.Sc. Chemistry Entrance, Exam 2015 Answer key for multiple choice questions ‘Question No ‘Answer Question No | Answer Question No Answer 1 3 2 T 3 a a 2 1 2D 1 a 2 3 2 23 2 a 4 4 3 ma 3 a 1 5 4 25 3 45 Fa 6 1 26 3 46 4 7 5 Fy] a 7 2 8 1 28 4 48 1 9 3 28 1 49 3 10 2 30 1 50 1 it 2 31 2 31 a 12 3 32 4 52 2 3B 4 33 1 53 4 14 1 34 3 34 1 15 4 35 3 35 1 16 2 36 1 56 3 v7 2 7 4 7 dor2 18 1 38 3 58 4 19 3 398 2 59 3 20 2 40 3 60 3 In case of any discrepancy or query please contact the Department of Chemistry within 24 hrs at admission@chemistry.du.ac.in