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h i g h l i g h t s
" Recycled glass waste can be used as a partial replacement of ne aggregate.
" Eighteen concrete mixes % of ne agg. replacement were 0%, 10%, 20%, 30%, 40%, and 50%.
" Slump ow of (SCC) increased with the increase of recycled glass content.
" Mechanical properties decreased with the increase in recycled glass content.
" Recycled glass aggregate can successfully be used for producing (SCC).
a r t i c l e
i n f o
Article history:
Received 3 June 2011
Received in revised form 12 April 2012
Accepted 29 April 2012
Available online 2 June 2012
Keywords:
Self compacting concrete
Recycled glass aggregates
Compressive strength
Tensile strength
Flexural strength
a b s t r a c t
Glass has been indispensable to mans life due to its properties, including pliability to take any shape with
ease, bright surface, resistance to abrasion, reasonable safety and durability. Waste glass creates serious
environmental problems, mainly due to the inconsistency of waste glass streams. With increasing environmental pressure to reduce solid waste and to recycle as much as possible, the concrete industry has
adopted a number of methods to achieve this goal. Self-Compacting Concrete (SCC) may lead to evolution
of a more quality controlled concrete, assuring a better workability and avoiding human errors with
regard to mixing and workability issues. On the other hand, it resolves the problem of noise and vibration
during installation. The object of this research work is to study the effect of using recycled glass waste, as
a partial replacement of ne aggregate, on the fresh and hardened properties of Self-Compacting Concrete
(SCC). A total of 18 concrete mixes were produced with different cement contents (350, 400 and
450 kg/m3) at W/C ratio of 0.4. Recycled glass was used to replace ne aggregate in proportions of 0%,
10%, 20%, 30%, 40%, and 50%. The experimental results showed that the slump ow increased with the
increase of recycled glass content. On the other hand, the compressive strength, splitting tensile strength,
exural strength and static modulus of elasticity of recycled glass (SCC) mixtures were decreased with
the increase in the recycled glass content. The results showed that recycled glass aggregate can successfully be used for producing self-compacting concrete.
2012 Elsevier Ltd. All rights reserved.
1. Introduction
Glass is one of the oldest man-made materials. It is produced in
many forms, including packaging or container glass, at glass, bulb
glass, and cathode ray tube glass, all of which have a limited life in
the forms in which they are produced. Hence, glass need to be reused/recycled in order to avoid environmental problems that can
be created, if they will be stockpiled or sent to landlls. Theoretically, glass is a 100% recyclable material; it can be indenitely recycled without any loss of quality, Sobolev et al. [1]. There are many
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E.E. Ali, S.H. Al-Tersawy / Construction and Building Materials 35 (2012) 785791
been performed. Park et al. [4] reported that the compressive, tensile, and exural strengths of concrete containing waste glass as
ne aggregate demonstrated a decreasing tendency with increase
in the mixing ratio of the waste glass. Shayan and Xu [5] found that
30% glass powder could be incorporated as aggregate or cement
replacement in concrete without any long term detrimental effects.
Topu and Canbaz [6] found that compressive, exural, and indirect tensile strengths have tendency to decrease with the increase
of waste glass content as coarse aggregate in concrete mixtures.
Corinaldesi et al. [7] also reported that no alkalisilica reaction
had been detected with particle sizes up to 100 lm, thus reecting
the feasibility of waste glass reuse as ne aggregate in mortars and
concrete. Chen et al. [8] observed a signicant improvement in the
compressive strength of waste E-glass concrete mixes at late ages,
but the workability decreased as the glass content increased.
Shayan and Xu [9] recommended using glass powder and glass
aggregate together in 40-MPa concrete mixtures without any adverse effect. Metwally [10] also reported that the use of nely
milled waste glass in concrete mixes has an adverse effect on
workability, but considerably improved the mechanical properties
of concrete at later ages. Topu et al. [11] recommended the usage
of over 20% y ash and 2% Li2CO3 replacements to reduce the
expansion of waste glass-mortars occurring due to ASR.
Emam and Sherif [12] reported that the use of self-compacting
concrete has gained a wider acceptance in recent years. It not only
reduces noise due to a vibration free environment, but also increases the quality of concrete as a result of minimizing of human
participation in workability works. The term Self-Compacting Concrete (SCC) refers to a new type of high performance concrete
mixture which ows under its own weight while maintaining sufcient resistance to segregation. Segregation resistance plays an
important role for SCC because weak segregation resistance would
cause poor deformability, blockage around congested reinforcement and non-homogeneous properties of the hardened concrete.
The lling ability and stability of self-compacting concrete in the
fresh state can be dened by four key characteristics: ow ability,
viscosity (assessed by rate of ow), passing ability and segregation
resistance. The concrete mixture will be classied as a self-compacting one, if all the mentioned characteristics are present. Such
properties are achieved by adding chemical additives to the concrete, such as superplasticators, most frequently combined with
the new type of additives for modication of viscosity and/or
through application of a certain amount of ne mineral additivepowder. Properties of self-compacting concrete depend on type
and amount of additives which are used. There are numerous research papers that dealt with that subject.
The objective of this research work is to examine the inuence
of waste glass when used as a direct replacement for natural ne
aggregate in concrete, and thereby to assess the fundamental engineering properties of recycled glass self compacting concrete.
2. Experimental program
2.1. Materials
2.1.1. Cement
The cement used in this investigation was delivered from El-Suez Cement
Company, Type CEM I 42.5N. Testing of cement was carried out per the Egyptian
Standard Specications ESS 2421/2005 [13]. The mechanical properties of the used
cement as determined by laboratory tests showed its suitability for concrete works.
The mechanical properties of the cement used in this investigation are given in
Table 1.
2.1.2. Aggregate
Local dolomite and sand from natural sources were used in the experimental
work. The used crushed dolomite has a nominal maximum size of 10 mm. Testing
of natural coarse aggregate and sand were carried according to the Egyptian Standard Specications ESS 1109/2002 [14]. The results are presented in Table 2.
Table 1
Mechanical properties of cement.
Properties
Measured values
1.2
120
165
21.8
50.5
2 days
28 days
Table 2
Properties of crushed dolomite, waste glass and sand.
Test
Crushed dolomite
Waste glass
Sand
Specic weight
Bulk density (t/m3)
Clay and ne dust content (%)
Abrasion (Los Anglos)
Water absorption
Impact value (%)
2.6
1.62
2.2
14.62
1.23
11.6
2.2
1.34
0.42
0.57
2.62
1.75
1.4
E.E. Ali, S.H. Al-Tersawy / Construction and Building Materials 35 (2012) 785791
787
800 50 mm, Fig. 2 [15]. L-box test consists of the L shaped box, of a rectangular
cross section, with a horizontal and vertical parts separated by the movable partition (exit) in front of which vertical rebars are arranged, Fig. 3. The vertical compartment is lled with concrete, then the partition is removed to allow the ow
of concrete at the end of the horizontal part and of the remaining concrete in the
vertical part are measured (H2/H1). That is an indicator of the capacity of concrete
to pass through the rebars, and it should be as close to one as possible (the lowest
permissible value is 0.8) [15].
V-funnel test, the funnel is lled with concrete, and the ow time, that is between opening the orice and the rst daylight appearing when looking vertically
down through the funnel recorded and then lled the funnel after 5 min and recorded the time (Fig. 4).
2.4.2. Determination of the hardened properties
In this research work, the following tests on hardened concrete were carried
out:
Table 3
Chemical composition of waste glass.
Chemical
composition
SiO2
Al2O3 + Fe2O3
CaO
SO3
Na2O + K2O
MgO
67.72
3.40
6.90
0.17
10.75
Table 4
Gradation of recycled glass.
Sieve
% of passing
5
2.36
1.18
0.6
0.3
0.15
0.075
100
99
64
35
20
10
1.4
(a) Compressive strength: The compressive strength test was carried out according to the Egyptian Standard Specications ESS 1658/2006 [16]. To evaluate
concrete compressive strength at test ages of 7 and 28 days, cubes specimens 150 150 150 mm were tested.
(b) Splitting tensile strength: The splitting tensile strength test was carried out
according to the Egyptian Standard Specications ESS 1658/2006 [16].
The splitting tensile strength of standard hardened concrete cylinders,
150 mm diameter and 300 mm long, was obtained to evaluate concrete
compressive strength at the age of 28 days.
(c) Flexural strength: The exural strength test was carried out according to the
Egyptian Standard Specications ESS 1658/2006 [16]. The exural strength
of standard hardened concrete beams 100 100 500 mm was tested to
evaluate concrete exural strength at the age of 28 days.
(d) Static modulus of elasticity: The static modulus of elasticity test was carried
out according to the ASTM C469 [17]. The static modulus of elasticity of
standard hardened concrete cylinders, (150 mm diameter and 300 mm
long), was determined at the age of 28 days.
Table 5
Properties of silica fume.
Properties
Item
Value
Physical properties
Color
Specic weight
Bulk density (kg/m3)
Specic area
Light gray
2.1
350
16.7
Chemical properties
SiO2
total
Fe2O3
Al2O3
CaO
MgO
K2O
Na2O
SO3
Cl
H2O
97
0.5
0.5
0.2
0.2
0.5
0.5
0.2
0.15
0.01
0.5
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E.E. Ali, S.H. Al-Tersawy / Construction and Building Materials 35 (2012) 785791
Table 6
Mix constituents for concrete mixtures.
Group
Designation
Group 1
M1-350-0%
M2-350-10%
M3-350-20%
M4-350-30%
M5-350-40%
M6-350-50%
Group 2
Group 3
M7-400-0%
M8-400-10%
M9-400-20%
M10-400-30%
M11-400-40%
M12-400-50%
M13-450-0%
M14-450-10%
M15-450-20%
M16-450-30%
M17-450-40%
M18-450-50%
W/C
0.4
0.4
0.4
C (kg/m3)
350
400
450
SF (%)
10
10
10
SP (%)
1.5
1.3
1.2
1.2
1.1
1.1
1.8
1.7
1.7
1.7
1.5
1.5
1.8
1.7
1.7
1.7
1.5
1.5
CDA (kg/m3)
936
890
846
FA (kg/m3)
Sand
WG
936
842.4
748.8
655.2
561.6
468
79.2
158.4
237.6
316.8
396
890
801
712
623
534
445
75.3
150.6
225.9
301.2
376.5
846
761.4
676.8
592.2
507.6
423
71.6
148.2
214.7
286.3
357.9
W/C = Water to cement ratio, C = cement content, SP = superplastizier percentage of cement content, SF = silica fume, CDA = crushed dolomite aggregate, FA = ne aggregate
(sand), NFA = natural ne aggregate, and WG = waste glass aggregate.
prolonged with increasing glass sand and this agree with Wang
[19], who stated that because the recycled glass SCC mixes unit
weight is less than that of SCC after replacing part of the sand with
waste glass, thus decreasing the unit weight. Hence, the compacting effect cannot be attained by its dead weight. As a result, the Vfunnel test time was 610 s longer than that of the control group.
However, the results still meet the owability standard time.
3.2. Hardened concrete properties
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E.E. Ali, S.H. Al-Tersawy / Construction and Building Materials 35 (2012) 785791
Table 7
Fresh properties of concrete mixtures.
Designation
Slump ow (mm)
L-box (%)
After mixing
After 5 min
Group 1
M1-350-0%
M2-350-10%
M3-350-20%
M4-350-30%
a
M5-350-40%
a
M6-350-50%
640
670
710
730
860
880
0.86
0.83
0.84
0.85
0.87
0.89
7
8
6
6
5
4
9
9
8
7
9
10
Group 2
M7-400-0%
M8-400-10%
M9-400-20%
M10-400-30%
M11-400-40%
M12-400-50%
660
670
690
710
730
740
0.84
0.86
0.86
0.87
0.87
0.88
8
8
9
6
8
7
10
11
11
8
10
10
Group 3
M13-450-0%
M14-450-10%
M15-450-20%
M16-450-30%
M17-450-40%
M18-450-50%
670
690
710
750
760
780
0.85
0.87
0.87
0.85
0.84
0.87
6
7
7
8
9
8
8
10
9
11
11
10
V-funnel
Compressive strength
(N/mm2)
Group
100
90
80
70
60
50
40
30
20
10
0
C.C=350
C.C=400
C.C=450
10
20
30
40
50
60
350, 400, and 450 kg/m , respectively. Where the high smoothness
of recycled glass waste leading to cracks was determined to lead to
Table 8
Hardened properties of concrete mixtures.
Compressive strength (N/mm2)
46.3
43.5
41.5
40.4
38.2
35.6
4.7
4.2
4.2
4.1
3.9
3.2
5.5
5.2
4.9
4.8
4.5
4.2
26047.3
25247.4
24660.2
24331.2
23659.4
22840.1
47.6
46.1
42.3
39.2
36.9
36.1
62.2
59.4
53.2
51.6
48.4
47.5
6.8
6.2
5.8
5.7
5.2
4.9
7.4
7.2
6.6
6.5
5.7
5.6
27761.2
27129.2
25674.3
25285.3
24488.7
24259.9
51.5
47.6
46.1
46.1
32.3
37.6
67.7
65.2
61.6
58.5
55.8
53.6
7.1
6.8
6.5
6.4
6.2
5.5
8.2
7.6
7.5
7.2
6.3
5.8
28962.6
28422.8
27626.9
26922.8
26294.2
25770.6
Group
Designation
7 days
28 days
Group 1
M1-350-0%
M2-350-10%
M3-350-20%
M4-350-30%
M5-350-40%
M6-350-50%
35.3
33.1
31.5
30.7
29.2
26.9
Group 2
M7-400-0%
M8-400-10%
M9-400-20%
M10-400-30%
M11-400-40%
M12-400-50%
Group 3
M13-450-0%
M14-450-10%
M15-450-20%
M16-450-30%
M17-450-40%
M18-450-50%
E.E. Ali, S.H. Al-Tersawy / Construction and Building Materials 35 (2012) 785791
790
10
9
8
7
6
5
4
3
2
1
0
C.C=350
C.C=400
C.C=450
10
20
30
40
50
60
10
9
8
7
6
5
4
3
2
1
0
C.C=350
C.C=400
C.C=450
10
20
30
40
50
60
Modulus of Elasticity
(N/mm2)
35000
C.C=400
C.C=350
30000
C.C=450
25000
20000
15000
10000
5000
0
0
10
20
30
40
50
Fig. 10. (a and b) SEM micrograph of concrete sample (without recycled glass).
E.E. Ali, S.H. Al-Tersawy / Construction and Building Materials 35 (2012) 785791
791
Fig. 11. (a and b) SEM micrograph of concrete sample (with recycled glass).
These results agree with those given by Kou and Poon [18] who
states that the static modulus of elasticity decreases with the increase of the recycled glass content.
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