CBSE TEST PAPER-03

CLASS - XII CHEMISTRY (Chemical Kinetics)

Topic: -Determination of order of a reaction.

1.

2.

3.

4.

5.

Identify the reaction order for from each of the following rate constant
a) k = 2.3 10-5 L mol-1 s-1
b) k = 3.1 10-4 s-1

[1]

Consider the equation 2 NO (q) + 2H2 (g) N2 (g) + 2H2O (g)

The rate law for this equation is first order with respect to H2 and second
order with respect to NO. write the rate law for this reaction.

[1]

The rate Law for the reaction A+B C is rate = K [A]2 [B] . What would the
reaction rate be when concentration of both A and B are doubled?

[2]

Write the integrated rate equation for

i) zero order reaction.
ii) first order reaction.

[2]

From the graph below

i) Identify the order of reaction.
ii) What will be the unit of rate constant?

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[2]

6.

The reaction 2N2O5 (g) 2NO2 (g) +O2 (g) was studied and the following data were
collected :
[N2O5] mol L-1

s.no
(mol/L/min
1.

Rate of disappearance of [N2O5]

1.1310-2

3410-5

2.

0.84 10-2

2510-5

3.

0.6210-2

1810-5

Determine
i)
The order
ii) The rate law.
iii) Rate constant for the reaction.
7.

The following experimental data was collected for the reaction:

Cl2 (g) + 2NO (g) 2 NOCl(g)
Trial
1
2
3

8.

9.

[3]

Intial conc. Of Cl2 (mol/L)

0.10
0.10
0.20

[NO] mol/L
0.010
0.030
0.030

Initial Rate,(mol/L/s)
1.2 X 10-4
10.8 X 10-4
21.6 X 10-4

Construct the rate equation for the reaction.

[3]

Draw a graph for

a) Concentration of reactant against time for a zero order reaction.
b) Log [Ro]/ [R] against time for a first order reaction.

[2]

What is the use of integrated rate equation?

[2]

10. For first order reaction

A B
Write (1) Differential rate law.
(2) Integrated rate law.

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[2]