CMT400 Assignment2 Chemical Drawing

Please submit a hardcopy of this assignment. The due date is 3rd June 2016.
Q1. Search the following structures using Chemspider. Fill in the information as in the following
table
No

Name

1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.

Q2.

Structure

Molar mass

Toluene
Nitrobenzene
Basketane
Pyridine
Vitamin C
LSD
Furan
3-methylheptane
Benzoic acid
Acetonitrile
Benzoyl acetate

Draw and give the correct name for the following:

OH

OH

a) Cl
b)

CH3

c)
O
CH3

SMILES

InChI

CH3

d) H3C
Q3.

Draw the following for the reactions of benzene

Ch
lo
ri n
at
io
n

Br
Bro
m

l
Su

inat

Hydrog
enation

Cl

Cr
dele
i
r
F

ion

ion
ylat
k
l
a
aft

Fr
ied
elCr
aft
ac
y

on
ati
n
o
f

Nitration

lat

ion

CH3

NO 2

Q4.

Q5.

Fill in the following table

No

Formula

A
B
C

CH4
C2H6
C2H2

C H bond
length

H C H bond
angle

C-C bond
length
-

Determine whether the following molecules are planar i.e all the atoms lie in the same
plane. Use Chemsketch to help you decide.
a)
b)
c)
d)
e)

Benzene
PtCl4
SF6 (octahedral)
Ethane
BCl3