Académique Documents
Professionnel Documents
Culture Documents
Product: 10029...
1.2
1.3
Product Identifier
10029...
Product Name:
CARBOCRYLIC 1290 - A
CARBOCRYLIC 1290 - B
Revision Date:
Supercedes Date:
7/1
StonCor Europe
9, Rue du Travail - 1400 Nivelles, Belgium
Manufacturer:
2. Hazard Identification
2.1
HAZARD STATEMENTS
H226
H315
H319
H335
H336
04/12/2015
New SDS
Product: 10029...
H373
H412
Label elements
Symbol(s) of Product
Signal Word
Warning
Named Chemicals on Label
Heptan-2-one, n-butyl acetate, crystalline cristobalite, Aromatic-hydrocarbons,-C8
HAZARD STATEMENTS
Flammable Liquid, category 3
Skin Irritation, category 2
Eye Irritation, category 2
STOT, single exposure, category 3, RTI
STOT, single exposure, category 3, NE
STOT, repeated exposure, category 2
H226
H315
H319
H335
H336
H373
H412
P210
P260
P280
P304+340
P337+313
P314
2.3
Other hazards
No Information
Results of PBT and vPvB assessment:
No information
3. Composition/Information On Ingredients
3.2
Mixtures
Hazardous Ingredients
CAS-No.
EINEC No.
13463-67-7
110-43-0
123-86-4
90989-38-1
64742-95-6
14464-46-1
203-767-1
204-658-1
292-694-9
265-199-0
238-455-4
918-668-5
1330-20-7
78-83-1
215-535-7
201-148-0
905-562-9
100-41-4
202-849-4
Page 2 / 13
%
10-25
10-25
2.5-10
2.5-10
2.5-10
2.5-10
2.5-10
1.0-2.5
1.0-2.5
1.0-2.5
0.1-1.0
CAS-No.
13463-67-7
110-43-0
123-86-4
90989-38-1
64742-95-6
14464-46-1
1330-20-7
78-83-1
100-41-4
108-65-6
203-603-9
918-668-5
Product: 10029...
hydrocarbons, c9-c12, n-alkanes, isoalkanes,
cyclics, aromatics (2-25%)
2-methoxy-1-methylethyl-acetate
hydrocarbons, c9, aromatics
Additional Information:
0.1-1.0
0.1-1.0
0.1-1.0
CLP Symbols
GHS02-GHS07
GHS02-GHS07
GHS02-GHS07-GHS08
GHS02-GHS07-GHS08-GHS09
GHS08
GHS02-GHS07-GHS08-GHS09
GHS02-GHS07
GHS02-GHS05-GHS07
GHS02-GHS07-GHS08
GHS02-GHS07-GHS08
GHS02-GHS07-GHS08-GHS09
GHS02
GHS02-GHS07-GHS08-GHS09
H226-302-315-332-335-336
H226-336
H226-304-312-315-319-332-335-373
H226-304-319-332-335-336-411
H372
H226-304-335-336-411
H226-312-315-332
H226-315-318-332-335-336
H226-304-312-315-319-332-335-373
H225-304-315-319-332-373
H226-304-336-411
H226
H226-304-335-336-411
M-Factors
The text for CLP Hazard Statements shown above (if any) is given in Section 16.
4. First-aid Measures
4.1
Irritating to eyes. Irritating to respiratory system. Irritating to skin. Danger of serious damage to health by prolonged
exposure.
4.3
5. Fire-fighting Measures
5.1
Extinguishing Media:
Carbon Dioxide, Dry Chemical, Foam
FOR SAFETY REASONS NOT TO BE USED: Alcohol, Alcohol based solutions, any other media not listed above.
5.2
5.3
Page 3 / 13
Product: 10029...
6.2
Environmental precautions
6.3
Do not allow material to contaminate ground water system. Prevent product from entering drains.
Methods and material for containment and cleaning up
6.4
Prevent further leakage or spillage if safe to do so. Contain spillage, soak up with non-combustible absorbent material, (e.g.
sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations
(see section 13).
Reference to other sections
FURTHER INSTRUCTIONS: Please refer to EU disposal requirements or country specific disposal requirements for this
material. See Section 13 for further information.
7.2
7.3
Control parameters
CAS-No.
titanium dioxide
13463-67-7
Heptan-2-one
110-43-0
50
100
n-butyl acetate
123-86-4
150
Aromatic-hydrocarbons,-C8
90989-38-1
50;100
64742-95-6
crystalline cristobalite
hydrocarbons, c10, aromatics, <1%
naphthalene
Xylene
14464-46-1
1330-20-7
2-methylpropan-1-ol
78-83-1
Reaction mass of ethylbenzene and m-xylene
and p-xylene (Benzene < 0,01%)
Ethylbenzene
100-41-4
hydrocarbons, c9-c12, n-alkanes, isoalkanes,
cyclics, aromatics (2-25%)
2-methoxy-1-methylethyl-acetate
108-65-6
LTEL ppm
LTEL mg/m3
10 (total dust)
4 (resp. dust)
475
237
200
966
724
100;125
441;552
220;441
OEL Note
Xilen /EtBenzen
100 mg/m3
50
100
441
220
50
75
231
154
100
125
552
441
Sk
Sk
100
50
100
548
274
Sk
100
FURTHER ADVICE: Refer to the regulatory exposure limits for the workforce enforced in each country. Some components may
not have been classified at the EU level under the dangerous substances and preparations regulation.
Page 4 / 13
Product: 10029...
Exposure controls
Personal Protection
RESPIRATORY PROTECTION: Respirator with combination filter for vapour/particulate (EN 141). Wear respiratory
protection with combination filter (dust and gas filter, EN 141) during spraying operations: Gas filter type A1 (organic
substances). Dust filter P3 (for fine dust). Use only with ventilation to keep levels below exposure guidelines reported in this
document. User should test and monitor exposure levels to ensure all personnel are below guidelines. If not sure, or not able
to monitor, use State or federally approved supplied air respirator. For silica containing coatings in a liquid state, and/or if no
exposure limits are established above, air-supplied respirators are generally not required.
EYE PROTECTION: Tightly fitting safety goggles.
HAND PROTECTION: Rubber or plastic gloves. Take note of the information given by the producer concerning permeability
and break through times, and of special workplace conditions (mechanical strain, duration of contact). Long sleeved clothing.
Remove and wash contaminated clothing before re-use. Protective gloves complying with EN 374: Butyl rubber. Nitril rubber.
OTHER PROTECTIVE EQUIPMENT: No Information
ENGINEERING CONTROLS: Avoid contact with skin, eyes and clothing. Ensure adequate ventilation, especially in confined
areas.
Chemical Name:
titanium dioxide
EC No.:
CAS-No.:
13463-67-7
Acute effect
local
Consumers
Chronic effects
systemic
Acute effect
local
Acute effects
systemic
Chronic
effects local
Chronic effects
systemic
700 mg/kg/d
PNEC
0.127
1000
1
100
1667
100 mg/l
100
Chemical Name:
n-butyl acetate
EC No.:
CAS-No.:
204-658-1
123-86-4
Acute effect
local
960 mg/m3
Consumers
Chronic effects
systemic
Acute effect
local
Acute effects
systemic
Chronic
effects local
480 mg/m3
859.7 mg/m3
859.7 mg/m3
PNEC
0.18 mg/l
0.981 mg/kg
0.018 mg/l
0.0981 mg/kg
35.6 mg/L
0.0903 mg/kg
Page 5 / 13
Chronic effects
systemic
Product: 10029...
Chemical Name:
Aromatic-hydrocarbons,-C8
EC No.:
CAS-No.:
292-694-9
90989-38-1
Acute effect
local
Consumers
Chronic effects
systemic
Acute effect
local
Acute effects
systemic
77 mg/m3
180 mg/kg
Chronic
effects local
Chronic effects
systemic
1.6 mg/kg
14.8 mg/m3
PNEC
0.327 mg/l
12.46 mg/kg
0.327 mg/l
12.46 mg/kg
2.31mg/kg
Chemical Name:
Solvent naphtha (petroleum), light arom.
EC No.:
CAS-No.:
265-199-0
64742-95-6
Acute effect
local
Inhalation
Dermal
Consumers
Chronic effects
systemic
Acute effect
local
Acute effects
systemic
150 mg/m3
25 mg/kg bw/day
PNEC
Page 6 / 13
Chronic effects
systemic
32 mg/m3
11 mg/kg bw/day
Chronic
effects local
11 mg/kg bw/
day
Product: 10029...
Chemical Name:
Xylene
EC No.:
CAS-No.:
215-535-7
1330-20-7
Consumers
Route of
Exposure
Oral
Acute effect
local
Chronic effects
systemic
Acute effect
local
Acute effects
systemic
Inhalation
Dermal
289 mg/m
289 mg/m
77 mg/m
180 mg/kg bw/
day
174 mg/m
174 mg/m
Chronic
effects local
Chronic effects
systemic
1.6 mg/kg bw/
day
14.8 mg/m
108 mg/kg bw/
day
PNEC
0.327 mg/L
12.46 mg/kg
0.327 mg/L
12.46 mg/kg
6.58 mg/L
2.31 mg/kg
Chemical Name:
2-methylpropan-1-ol
EC No.:
CAS-No.:
201-148-0
78-83-1
Acute effect
local
Consumers
Chronic effects
systemic
Acute effect
local
Acute effects
systemic
Chronic
effects local
55 mg/m3
PNEC
0,4 mg/l
1,52 mg/kg
0,04 mg/l
0,152 mg/kg
10 mg/l
0,0699 mg/kg
Page 7 / 13
Chronic effects
systemic
25 mg/kg
Product: 10029...
Chemical Name:
Reaction mass of ethylbenzene and m-xylene and p-xylene (Benzene < 0,01%)
EC No.:
CAS-No.:
905-562-9
Acute effect
local
Consumers
Chronic effects
systemic
Acute effect
local
77 mg/m3
180 mg/kg
Acute effects
systemic
Chronic
effects local
174 mg/m3
Chronic effects
systemic
1.6 mg/kg
14.8 mg/m3
108 mg/kg
PNEC
0.327 mg/l
12.46 mg/kg
0.327 mg/l
12.46 mg/kg
2.31 mg/kg
Chemical Name:
2-methoxy-1-methylethyl-acetate
EC No.:
CAS-No.:
203-603-9
108-65-6
Acute effect
local
Consumers
Chronic effects
systemic
Acute effect
local
Acute effects
systemic
Chronic
effects local
275 mg/m
153.5 mg/kg
PNEC
0.635 mg/L
3.29 mg/kg
0.0635 mg/L
0.329 mg/kg
100 mg/L
0.29 mg/kg
LIQUID
Odor
SOLVENT
Odor threshold
Not determined
pH
N/A
Not determined
108 - N.D.
23
Page 8 / 13
Chronic effects
systemic
1.67 mg/kg
33 mg/m
54.8 mg/kg
Product: 10029...
Evaporation rate
Not determined
Not determined
Not determined
Vapour Pressure
N/D
Vapour density
Not determined
Relative density
Not determined
N/D
Not determined
Not determined
Not determined
Viscosity
9.2
Explosive properties
Not determined
Oxidising properties
Not determined
Other information
VOC Content g/l:
Grams of VOC per liter of coating product as applied per ISO 11890-1 and/or ISO 11890-2.
Specific Gravity (g/cm3)
1.23
No information available.
Corrosivity:
No information available.
Sensitization:
No information available.
No information available.
Page 9 / 13
Product: 10029...
Carcinogenicity:
No information available.
Mutagenicity:
No information available.
No information available.
STOT-single exposure:
No information available.
STOT-repeated exposure:
No information available.
Aspiration hazard:
No information available.
If no information is available above under Acute Toxicity then the acute effects of this product have not been tested.
Data on individual components are tabulated below:
CAS-No.
Oral LD50
Dermal LD50
13463-67-7
titanium dioxide
110-43-0
Heptan-2-one
123-86-4
90989-38-1
n-butyl acetate
Aromatic-hydrocarbons,-C8
64742-95-6
3592 mg/kg
1330-20-7
Xylene
78-83-1
2-methylpropan-1-ol
100-41-4
108-65-6
2-methoxy-1-methylethyl-acetate
3592 mg/kg
Vapor LC50
1105 mg/m3/4H
> 6193 mg/m3
Additional Information:
This product may contain Ethyl Benzene, which is listed by IARC as possibly carcinogenic to humans (Group 2B). This listing is
based on inadequate evidence of carcinogenicity in humans and sufficient evidence in experimental animals. This product may
contain Titanium Dioxide, which is listed by IARC as possibly carcinogenic to humans (Group 2B). This listing is based on inadequate
evidence of carcinogenicity in humans and sufficient evidence in experimental animals. This classification is relevant when exposed
to titanium dioxide in dust or powder form only, including cured product that is subject to sanding, grinding, cutting, or other surface
preparation activities.
Toxicity:
EC50 48hr (Daphnia):
IC50 72hr (Algae):
No information
No information
No information
12.2
No information
12.3
Bioaccumulative potential:
No information
12.4
Mobility in soil:
No information
12.5
No information
Page 10 / 13
Product: 10029...
CAS-No.
No information
EC50 48hr
IC50 72hr
LC50 96hr
13463-67-7
titanium dioxide
110-43-0
Heptan-2-one
No information
No information
123-86-4
n-butyl acetate
No information
No information
18 mg/L (Pimephales
promelas)
90989-38-1
Aromatic-hydrocarbons,-C8
No information
No information
2.6 mg/l
64742-95-6
No information
No information
14464-46-1
crystalline cristobalite
No information
No information
No information
No information
1330-20-7
Xylene
2 - 11 mg/L (Roccus
saxatilis), 8.2 mg/L (Salmo
3 - 5 mg/L (Selenastrum
gairdneri), 13.5 mg/L
sp.)
(Lepomis macrichirus), 21.0
mg/L (Pimephales promelas)
78-83-1
2-methylpropan-1-ol
1799 mg/L
(Scenedesmus
subspicatus)
No information
No information
No information
Ethylbenzene
No information
No information
No information
No information
No information
No information
2-methoxy-1-methylethyl-acetate
408 mg/L
No information
161 mg/L
No information
No information
100-41-4
108-65-6
64742-95-6
WASTE TREATMENT METHODS: Do not burn, or use a cutting torch on, the empty drum. If recycling is not practicable,
dispose of in compliance with local regulations. Empty containers should be taken to an approved waste handling site for
recycling or disposal.
080111
150110
Page 11 / 13
Product: 10029...
UN number
UN proper shipping name
UN1263
.PAINT
Technical name
14.3
Packing group
14.5
Environmental hazards
Special precautions for user
14.6
14.7
III
Marine Pollutant : NO
Not applicable
EmS-No.:
F-E, S-E
Not applicable
WGK Class:
No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.
H225
H226
H302
H304
H312
H315
H318
H319
H332
H335
H336
H372
H373
H411
Page 12 / 13
Product: 10029...
Page 13 / 13