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BAB VIII
PROBLEMS
1. In the molecule OClO < OclO is 116 ; both Cl O distances are 1.49 . Calculate
the between the Cl atoms.
Answer :
Cl
dCl-Cl / 2 = 1.49 sin 98
dCl-Cl / 2 = 1.264
O
2.
1.15 and the
Answer :
dCl-Cl = 2.53
N
2.14
111111
1.15
Br
(d O O) / 2 = (1.24 ) sin 63
= 1,105 2 = 2.21
4.
N
c
H
O
With a = 0.98 , b= 1.46 , c = 1.20 , < ONO = 116 , < NOH = 104 , calcualte
the distance from the hydrogen atom to the oxygen atom at the other end of the
molecule.
Answer :
(d H O ) = (0.98 ) cos 76 + 1.46 + 120 cos 64
= 0.24 + 1.46 + 0.53
= 2.2
5.
A square piece of metal foil with a surface area of one cm2 is
covered with a monolayer of argon, which has an atomic radius of 1.54 . if one
assumes that the argon atoms are lined up as :
How many argon atoms are there at the surface? What fraction of the surface is
actually covered by argon atoms?
Answer :
n( 3.08 10-8 cm) = 1 cm
n= 3.25 107 cm
total number of atom n2 = (3.25 107)2
= 1.06 1015
Area occupid by argon atom = r2
= 3.14 ( 1.54 10-8)2
= 7.44 10-16 cm2
Fraction covered = (7.44 10-16 ) ( 1.06 1015) / 1
= 7.89 10-1 = 0.789
6.
In the arrangement shown in problem 5, what whould be the radius
of an atom which would just fit into the space between touching argon atoms?
Answer :
S = 1.54 2 = 3.08
D2 = s2 + s2
D2= 2s2
D2 = 2((3.08)2 )
D2 = 2 ( 9.48) = 18.96
D = = 4.35
Diagonal of cubes = a = 4r
a= 4r / = (4r / ) ( / )
a= 2r
b.
c.
A simple cube : 2r = a
2r = 3.00
r =3/2 = 1.5
A body centered cube : 4r = a
4r = 3 (1.73)
4r = 5.19
r =1.3
A face centered cube : 4r = a
4r = 3 (1.41)
4r = 4.23
r =1.0575
10.
In the methane molecule, what is the distance from the carbon atom
to the center of the equilateral triangle formed by there hydrogen atoms? ( C H
bond distance = 1.09 ).
Answer :
H
D= 1.09 COS 70.5
= 1.09 (0.33)
= 0.36
109.5
C
H
11.
Cl
Cl
Cl
Cl
2
(d Cl) = (2.33) + (2.33)
= 5.43 + 5.43
= 10.86
(d Cl ) = = 3.29
12.
How many geometri isomers are there in octahedral species which
have the formulae :
a.
Ab5c
b.
Ab3c3
c.
Ab2c2d2
d.
Abcd4
e.
Abcdefg
2
Answer :
a.
b.
c.
d.
e.
Ab5c = 1
Ab3c3 = 2
Ab2c2d2 = 5
Abcd4 = 2
Abcdefg = 15