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VANE TYPE AIR REF. SYSTEM
AIRCRAFT REF.SYSTEM
Requirement :
Heat released from occupants, air resistance, ramming of air, control devices & solar radi.
Advantages:
1. Cheap.
2. Main compr. Is used thus require no extra space and no vib. Problem.
3. Air is directly used there is a saving of evaporator.
4. Leakage of ref.(air) can be affordable non toxic & inflammable..
5. Pr. in the system is low thus easy design, fabricate and maint.
6. No complicated parts involve low maint.
7. Weight of the system is very low as compare to VCRC.
Disadv. : COP of the system is very low.
DART (Dry air rated temp.) :
- Comparison of air ref. done on basis of this. Temp. of air after expander before cabin.
- Temp. of discharge air from the expander if there is no condensed moisture present.
- Rating of aircraft unit is given in terms of KG of air per unit time at a design DART.
AIR REF. SYSTEMS:
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Calc: -
Calc: -
Reduced ambient air ref. cycleRam air is expanded with aux. turbine
to suction pr. of the blower pr. thus air
is further cooled before expansion. As
a result very low temp. after
expansion is obtained at state 5.
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4 Effect of liquid sub cooling :
-
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-
Pull down test:At ambient 43 Deg. The refrigeration temp-7 deg. .the time noted to achieve
Ice making time0.5 kg of water at 30 Deg+-1. Is keep for 3 hrs. running time of unit is noted.
MULTI STAGE VAPOUR COMPRESSION
Compression ratio above 8 is not efficient in single stage. Improve COP .
Advantages:
1. Energy saving:- due to cooling in inter stage
2. .Volumetric Efficiency : decrease in vol. eff with increase in compression ratio and become
zero for large compr. Ratio.
3. Saving in materal : as use thigh thickness in HP and low in Lp . whereas in single use same
thickness.
4. Leakage across piston : as pr drop across pistion is high leakage is high in single stage.
5. Flywheel size : less due to proper balancing .
6. Less temp in compressor thus lubrication is good.
7. Size of condenser is less due to less heat inlet vapour in condenser.
Disadv: High maintenance due to large no of moving parts and high initial cost.
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CASCADE REFRIGERATION- Use of 2 refrigeration cycles due to limitations:
Evaporator of high temp. system becomes the condenser of low temp. system known as
cascade condenser. Use where very low temp. is required as
1. Liquification of petroleum vapours , atmospheric gases, dry ice manufacturing, blood storage
(-80 Deg.C),Hardening of special alloys (-90 Deg.C)
R-12 & R-22 are used in high temp. side and R-13 is used in low temp. side
REFREGERANTS
- Organic refrigerants are chlorofluorocarbons CFCs .
- Those contain H with C and F are called Hydro-chlor-flurocarbons HCFCs.
- Those contain no Cl atom called Hydro-flurocarbons HFCs.
- F atom make the substance physiologically more favorable.
-Cl is responsible for depletion of Ozone layer, H implants flammability.
Nomenclature
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Properties of Refregereants
A) Thermodynamic properties:
1) Critical Temp & Pr.: Temp. High as possible , for high heat transfer at const. temp.,
reduce power consumption.
Pr. should be moderate and +ve. High can make system bulky and low will make air leakage
into the system.
2) Specific Heat:
Sp. Heat of liquid should be small . Less irreversibility during throttling & greater subcooling.
Sp. Heat of vapour should be high for less superheat of vapour.
3) Enthalpy of Vaporization:
This should be as large as possible to minimize the area under superheat and the area reduction due to
throttling . Also, the higher value of enthalpy of vaporization lowers the required flow rate per ton of
refrigeration.
4 ) Conductivity :
The conductivity of the refrigerant should be as high as possible so that the size of the evaporator and
condenser is manageable. ammonia has a better conductivity than that of R12 or R22 and is more But,
ammonia is toxic .
5 ) Evaporator and Condenser Pressure
Both the evaporator and condenser pressures need to be above atmospheric pressure otherwise air leaking into
the system.
6) Compression Ratio
as small as possible , leakage of refrigerant occurs across the piston. Also, the volumetric efficiency is affected.
7 ) Freezing Point
low as possible , blockage of passages during flow of fluid through evaporator.
8) Volume of Refrigerant Handled Per Ton of Refrigeration
small as possible in order to have a small size of the compressor. The type of compressor is decided by this
value. For refrigerants like R12, R500, R22 etc., a reciprocating compressor is suitable. For others like R11 and
water, a centrifugal compressor is required to handle the large volume.
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9) Coefficient of Performance
Higher the magnitude of COP, lower will be the running cost. Since, the COP of any refrigeration system is
limited by the Carnot COP, for large operating pressures a multi-stage refrigeration system should be
employed. CO2 has a very low COP. Hence, it is not suitable for use as a refrigerant.
10) Density
large as possible. In reciprocating compressors, the pressure rise is accomplished by squeezing the entrapped
fluid inside the piston-cylinder assembly. Hence, density decides the size of the cylinder. Again in centrifugal
compressors pressure rise is related to the density of the vapor. A high value of density results in high pressure
rise.
11) Compression Temperature
compressed, there is a rise in the temperature of the refrigerant Refrigerants having lowest compression
temperatures are thus better than others.
Chemical Properties
Chemical Stability and Inertness
It should be chemically stable for the operating ranges of temperature. Also, it should not react with the
materials of the refrigeration system or with which it comes into contact. Further, it should be chemically inert
and must not undergo polymerization reactions at either the lower or higher ranges of temperatures.
Action on Rubber or Plastics
Rubber and plastics are used extensively in the refrigeration system. These materials are mostly used in the
seals and gaskets of the refrigeration system. They help to prevent the leakage of the refrigerant and ensure the
smooth functioning of the compressor. The refrigerant should not react with them or else there might be
leakage of refrigerant from the system or loss of functioning of the compressor.
Flammability
The refrigerant should be inert and not catch fire when subjected to high temperatures. From this viewpoint
CO2 is the most suitable as it is not only non-flammable, but also acts as a fire-extinguisher. Ethane, butane,
isobutene are highly undesirable as they catch fire quickly.
Effect on Oil
The refrigerant should not react with the lubricating oil else, there is a possibility of loss of lubricating action
due to either thickening or thinning of the oil. It should not be soluble in the oil else there will be reduction in
the viscosity of the lubricating oil.
Effect on Commodity
If the refrigerant is directly used for chilling, then it should not affect the commodity kept in the conditioned
space. Also, in case where direct cooling is not employed, the refrigerant should still not affect the commodity
if there is any leakage.
Toxicity
The refrigerant used in air conditioning, food preservation etc. should not be toxic as they will come into
contact with human beings.
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COMMON REFRIGERANTS
Air
free of cost, is non-toxic and non-flammable and does not affect the commodity if pure. Air contains moisture
and this reacts with the material of the evaporator and condenser , blocked by the formation of ice from this
moisture. The COP of air is of the order of 0.6 and thus, not suitable for use in refrigeration systems on a
Ammonia
Use where toxicity effects were of secondary importance. Its advantages are its low cost, low specific volume,
high COP (of the order of 4.0) and high refrigeration effect per unit mass of the refrigerant. Its primary
drawback is its toxicity which prevents its use in air-conditioning and food preservation systems. Ammonia has
a boiling point of -33 0C at atmospheric pressure.
Carbon Dioxide
non-toxic and non-poisonous refrigerant. Also, it is not only non-flammable but and is an excellent
extinguishing agent as well. Its other advantages are that it is chemically stable, immiscible with the lubricating
oil and does not affect the metal used in the system. It has a low specific volume and this requires volume
displacement per ton of refrigeration. However, its critical pressure is too high. Also, its critical temperature is
only 31 0C which makes it unsuitable for use in countries with a hot climate like India. It is an excellent
refrigerant for low temperature refrigeration.
Sulphur Dioxide
suffocating and irritating gas and is twice as heavy as air at atmospheric conditions. It was mostly used as a
household refrigerant in the older days, but has since been discarded for better refrigerants. It suffers from a lot
of disadvantages. Sulphur dioxide reacts with water forming sulphurous acid, which in presence of oxygen
becomes sulphuric acid, a corrosive compound for metals. It is non-flammable but attacks foodstuff on coming
in contact with it. It is also partially miscible with the lubricating oil.
Hydrocarbons
This group consists of colourless fluids normally in gaseous state and made up of various combinations of
carbon and hydrogen. Most of the refrigerants from this category are suitable for low temperature refrigeration.
Isobutane falls in this category and has been suitable for domestic refrigeration. They are non-poisonous, but
are flammable and highly explosive when exposed to air. The molecular weight and boiling point of each gas
varies according to the number of hydrogen and carbon atoms. The larger the number of hydrogen and carbon
atoms, the heavier is the gas and higher is its boiling point.
Halocarbon Refrigerants
The halocarbon refrigerants are formed by replacing one or more of hydrogen atoms of methane or ethane by
one or more atoms of the three halogens: fluorine, chlorine or bromine. Some of the refrigerants coming under
this category are mentioned below:
Refrigerant R12
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The refrigerant R12 is the most widely used refrigerant in the domestic and large commercial establishments.
Its chemical formula is CCl2F2 and its boiling point is -300C at 1 bar. It is a non-flammable, non-explosive,
non-irritating, non-toxic and odourless refrigerant. It remains chemically stable up to 5500C. Also, it does not
affect the material of the refrigeration system. It is available in abundance and is quite cheap. However, its use
is being discontinued nowadays for its contribution to ozone depletion which will be discussed later.
Refrigerant R13
Its chemical formula is CClF3. it is a non-flammable, non-toxic and stable refrigerant. It is very suitable for
achieving low temperatures in a cascade refrigeration system. Its specific volume is high and therefore, it is
suitable for centrifugal compressors. However, it also has a negative effect on ozone depletion.
Refrigerant R22
Its chemical formula is CHClF2. it is also a non-toxic, non-flammable, non-corrosive and non-irritating
refrigerant. It is the most common refrigerant for use in large refrigeration systems and is preferred to R12.
Refrigerant R114
Its chemical formula is C2Cl2F4. Its boiling point corresponding to 1 bar is about 30C. It has properties very
similar to those of R12 with respect to water and oil combination. It is not suitable for low temperature
refrigeration since it has negative evaporator pressure even at around 9 0C. It is non-toxic, non-explosive and
non-corrosive even in the presence of water.
AzeotropeWhenever two components are mixed the resultant mixture behaves according the theory of mixture.However
in some situations in a particular ratio the mixture behaves as a single has a fix boiling point correspond to that
pr.such mixtures are called azeotrope mixtures.in 500 series like R-500 ( 73.8% R-12 and 26.2 R-152 by wt.)
From refrigerant point of view Low temp. and high pr achieve by these.
OZONE DEPLETION AND GLOBAL WARMING POTENTIAL
The main culprits in this case are the chlorine containing halogenated hydrocarbons, commonly known as
chlorofluorocarbons or CFC which are being used as refrigerants.
The layer just above the Earths surface is known as the troposphere. The troposphere extends up to 10 km
from the surface. The ozone layer is just above the troposphere and located in the stratosphere.
Chlorofluorocarbon + UVwithIrradiated
free Cl
Cl + O3 ClO + O2
ClO + O Cl + O2 (Free Cl atom which again rect woth O3 and again recation starts)
Along with ozone depletion, CFC refrigerants also contribute to a large extent in the global warming of the
planet. These gases create a greenhouse effect which traps the heat in the lower atmosphere. This makes the
Earth warmer because the green house gases do not allow infrared radiation to pas through tem. The earth
emits IR rays during its cooling when sun is not there. CO2 is the most important green house gas but one
molecule of CFC has warming potential which is more than 1000 times the warming potential of one molecule
of CO2. Suns rays are allowed into the lower atmosphere, but the heat from these rays is not allowed to
escape.
SECONDARY REFRIGERANTS
In some refrigeration systems, the refrigerant is not put into direct use. in home air- conditioning and home
refrigeration systems. Also, in some cases the size of the refrigerated space may be so large that direct
refrigeration may be uneconomical. In such case, an indirect way is employed. The refrigerants used in this
way do not pass through the cyclic process and are referred to as secondary refrigerants. The refrigerants
commonly used in this way are water and brine solutions of calcium or sodium. This
therefore allows the use of a smaller size refrigerator with a considerably less amount of refrigerant. Also,
since the refrigerant does not come in direct contact, cheaper grade materials can be used for the heat
exchanger.
Due to its toxicity, ammonia cannot be used as a refrigerant in residential air conditioners. Therefore, the usual
practice is to chill brine over the evaporator coil and then air is cooled by passing over the brine coil. This
method eliminates the dangers of toxification on account of ammonia leakage into the air streams.
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Sodium chloride brine solutions are most common up to 15 0C while calcium chloride brine solutions can be
used up to 50 0C. However, these solutions are very corrosive to metals such as brass, copper and aluminium.
In place of them, sometimes certain chemicals known as antifreeze are used with water to prevent clogging.
THEORY OF BRINE
CA is the concentration .
- As conc. Increases the freezing point of
sol. Reduces
- For a given conc. A point of min. temp.
without solidification is known as eutectic
point
THEORY OF MIXTURE
Required for determination of HT in absorber, condenser & evap.
Mixture is a mixing of homogeneous ( same properties like density ,temp.) or heterogeneous
component without chemical chemical reaction.
Homogeneous mix. are in thermodynamic equilibrium and not separated by mec. Means . change in
properties like sat. pr, ,sp. vol,etc.
When 2 components are mixed
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Throttling process
Throttling is isoenthalpic
process h1=h2
State 2 lies above sat. line
corresponding to pr. P2
Shows after throttling mixture
consists of liquid and vapour at
diff. conc.
To obtain the conc. Of liquid
and vapour isotherms are
drawn by hit and trial passing
through point 2.
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Water Refrigeration System
- Use for precooling of vegetables, vacuum drying of veg. , chilling drinking water, concentrating fruit juices.
- Centrifugal compr. Are use due to large sp. Vol. of water.
Principle:
Sat . temp. of water depends on the pr. as pr reduces sat temp. reduces which causes evaporation of water at lower temp
and take heat of vaopurisation creating ref. effect.
-The COP of the system depends on : condenser pr, flash chamber pr. , makeup water temp. and compressor eff.
- Pr. in flash chamber should not below 0.008 bar (sat. temp. 4 Deg C).
- Multstage ejectors can be use.
Steam-Jet Refrigeration System
- Flash chamber is insulated.
- Motive steam (1.7 to 8 bar ) is expands
through a nozzle imparts momentum to
the vapour.
- Process of momentum exchange and
carrying of vapour by the motive steam
is called entrainment.
- Steam and water mixture is passed
through the venturie and compressed P &
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Advantages:
- Direct cooling can be achieved. Chilling of vegetables , transportation of veg.in navy & cargo ships.
- Less maintenance , use waste steam,
- Above 75 Ton cost is 50 % of Compression system.
Limitaions:
- Chilling upto 2 Deg C can be achieved
- Large size system, Centrifugal compr. Are costlier and eff. Of nozzles is less.
- COP is very low 0.4 to 0.6
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Effect on COP
.
3. Variation of COP with condensate temp.: The chilling temp. is taken as parameter.As Condensing
temp. inc. as COP dec .for a giving chilling temp.
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Advanantage:
- Minor leakages are insignificant.
- Simple design , less maint.
- Less space and less bulky.
Disad :
- Cop is very less upto 0.23
Application
1.
2.
3.
4.
5.
6.
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--
Linde Process:
- Gas enter at state 1 and compressed
isothermally in a multistage compr.
Upto 2.
- Yied = Mass of liquid produced
Mass of air compressed
- Yied is more as much inlet temp. is
less.
-
Cryogenics
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Fluids which are meant for temp. below 113 K are termed as
Cryogenic Fluids.
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Claude System :
- 10 % of compressed gas is
expanded reversibily and
adiabatically in a expander.
- Use to drive the compressor.
Hydrogen and Helium
Liqui.
Hydrogen:
-Cooling is done in two HE A & B
for effective cooling with
vapours.
-Cooling is done by liquid
nitrogen in HEC.
-Cooling by vapour of hydrogen
is done in HE .
Helium :
-Require more HE and
expanders as it Liquefy at
very less temp.
-It require 45 KW to yield 32 to
45 liter of helium per Hr.
-
Air separation
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THERMOELECTRIC Refrigeration
1. Seebeck effect:
Two junctions of dissimilar wires
maintained at diff. temp. generation of
emf is there.
Seebeck coefficient depends on pair of
metals.
2. Peltier Effect:
DC current is passed with a pair of
dissimilar wires heating at one end and
cooling at other.
Advantages :
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1.
2.
3.
4.
5.
6.
7.
Disadv.
1. Unavailibilty of suitable material with higher figure of merit.
2. Initial and running cost is higher.
3. COP in the range of 0.1- 0.2.
-High manufacturing cost, Non- toxic , Non
corrosive., Easily handle and cut.
Tripple point is -56.6 C and 5.78 bar.
At lower pr. below triple point solid
directly conevt into gas,
Power required is 400-500 Hp per Hr. Per MT
of Solid co2 due to high pr. ratio around 70.
- Problem of blockage of expansion device dur to
formation of dry Ice. Thus first liquid Co2 is
produce at pr. slightly above triple point. Then
pr. reduce in snow chamber.
DRY ICE
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