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1.

Copper reacts with nitric acid according to the following reaction:


3 Cu (s) + 8 HNO3 (aq) 3 Cu(NO3)2 (aq) + 2 NO (g)

+ 4 H2O
(l)
If an pre 1982 copper penny contains 3.10 grams of copper, what volume of 8.00
M nitric acid is required to exactly consume it? What volume of nitrogen
monoxide gas measured at STP would be produced? (Remember that 1 mole of
any gas measured at STP = 22.4 dm3)

2.

Hydrogen peroxide decomposes slowly to produce oxygen gas and water.


Write a balanced equation for the decomposition of hydrogen peroxide. What
mass of hydrogen peroxide (H2O2) must decompose to produce 0.77g of
water?

3.

Carbon monoxide is an air pollutant found in automobile exhausts. It slowly


reacts with oxygen in the atmosphere to produce carbon dioxide. Write a
balanced equation for this process. What mass of carbon dioxide would be
produced from 10.00 grams of carbon monoxide? What mass of oxygen
is required to convert the carbon monoxide to carbon dioxide?

Suppose that 50.0 cm3 of 2.00 M hydrochloric acid are added to 4.00 grams
of zinc metal.
What it the limiting reagent? How many grams of zinc are actually consumed?
What is the concentration of the hydrochloric acid solution after the reaction has
occurred? What mass of hydrogen will be produced?
4.

Zn (s)

+ 2 HCl

(aq) ZnCl2 (aq)

H2 (g)

5.

6.

Consider the reaction:


2 VO + 3 Fe2O3 6 FeO + V2O5
If 609.5 grams of vanadium (II) oxide, VO, and 832 grams of iron(III) oxide,
Fe2O3, are put into a container and allowed to react according to the equation
above, which substance(s) and how many grams of each would be present in
the container after the reaction is complete?

Methyl alcohol (wood alcohol), CH3OH, is produced via the reaction


CO(g) + 2 H2(g) CH3OH(l)
A mixture of 1.20 g H2(g) and 7.45 g CO(g) are allowed to react.
(a) Which reagent is the limiting reagent?
(b) What is the yield of CH3OH? [Assume theoretical yield in g is what is
wanted here.]
(c) How much of the reagent present in excess is left over?
(d) Suppose the actual yield is 7.52 g of CH3OH. What is the % yield?

7.

A 0.32570 gram sample of NaClO3 is decomposed to form oxygen gas


according to the following reaction:
2 NaClO3 (s) 2 NaCl (s) + 3 O2 (g)
The gas is collected over water at a total pressure of 742 torr at 23.0 oC.
What volume of oxygen will be collected? (The vapor pressure of water at 23.0
o
C is 20.65 torr)

8.

Hydrogen is produced when zinc reacts with sulfuric acid according to the
following reaction
Zn (s) + H2SO4 (aq) ZnSO4 (aq) + H2 (g)
If 159 cm3 of wet hydrogen is collected over water at 23.0o C and a total
pressure of 738 torr, how many grams of zinc are consumed? (The vapor
pressure of water at 23.0 oC is 20.65 torr)

Ans: 1)0.0163 L of HNO3 0.729 L NO gas 2) 1.5 g H2O2 3) 15.71 g CO2, 5.712 g
O2 4) HCl is limiting, 3.27 g Zn consumed, 0M HCl, 0.101 g H2 5) c)377.54 g d)0
e)748.7 g FeO, 315.86 g V2O5 6) b)8.52 g CH3OH c) 0.13 g H2 left over d) 88% 7)
0.11751 L 8) 0.404 g Zn

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