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Vapour pressure
Boiling point
Freezing point
Osmotic pressure
Learning objectives
Physical vs Chemical
Vapor pressure of solvent in solution containing nonvolatile solute is always lower than vapor pressure of
pure solvent at same T
In solution vapor
pressure is reduced
compared to pure
solvent
Liquid boils when
vapor pressure =
atmospheric pressure
Must increase T to
make vapor pressure
= atmospheric
Raoults Law
Solution Deviants
Incomplete dissociation
Not all ionic
substances dissociate
completely
Vant Hoff factor
accounts for this
Van t Hoff factor:
i = moles of particles in
soln/moles of solute
dissolved
Magnitude of elevation
particles
Magnitude of depression
T f K f m
T f K f m i
A semi-permeable membrane
discriminates on the basis of molecular
type
Osmotic pressure
osmotic pressure
PV nRT
MRT
12.5mmHg 1
RT
760mmHg
M
6.68 104 M
L atm
0.0821
300K
mol K
Ptotal PA PB
Ptotal P X A P X B
ben
tol
Purification in stages