ANSWER - SOLUTION Adva PI PDF

1
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ANSWERS, HINTS & SOLUTIONS
CRT III
(Paper-1)
PHYSICS
ALL INDIA TEST SERIES
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CHEMISTRY
MATHEMATICS
1.
2.
3.
4.
5.
6.
7.
8.
A, D
A, B, D
B, C
9.
A, B
A, D
A, C, D
10.
C, D
A, D
B, C
11.
B, C
A, B, C
B, C, D
12.
13.
14.
15.
16.
1.
2.
3.
4.
5.
6.
7.
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website: www.fiitjee.com
2
Physics
PART I
4.
Apply superposition of currents in each resistor due to each cell to get

current in two resistors zero, E/R in rest four, current drawn from each
cell is 2E/R
5.
One particle t/2 before max height, other t/2 after max height
Relative velocity perpendicular to line joining them = gt
Relative separation = ut
Relative angular velocity = gt/ut = g/u
6.
Intensity in absence of lens = P/4r2

So intensity at P before placing lens is of intensity at optical center of lens
After crossing lens light becomes parallel rays to intensity does not change further along that ray
7.
apply work-energy theorem

2
2
1 mg
1 mg
mgz K
z K
Fz 0
2 K
2 K
z = 2F/K.
8.
= MB sin

ii
f 12
r2
9.
a = kx2
1
da
2kx tan 60 = 2k 3 k
dx
2
x2
a
2
dv x2
v 2 x3
v
C1 at x = 0, v = 3 m/s
dx 2
2
6
9
C1
2
x3
v2
9
3
hence a = 1.5 and v
10.
Capillary height h
3 9
2T cos
rg
h = 59.6 mm
3
here 59.6 mm is greater than the protruding part hence water will rise in the capillary of
insufficient height 25 mm.
2T
Now, R
0.6 mm
hrg
11.
Fluid particles passing through the bend are in circular motion. The
centripetal acceleration is provided by the variation in pressure. In the
section as shown
P1A P2 A maC
maC
P2A
2
P1A
P1 P2
applying Bernoulli theorem at 1 and 2
1
1
i.e., P1 1v12 gh1 P2 v 22 gh2
2
2
1
1
P1 1v12 P2 v 22 as h1 h2
2
2
P1 P2
v1 v 2
12.
In CM frame
M,Q,2u
2M,2Q,u
C
2b/3
b
13.
At closest approach velocity perpendicular to line joining particles

Conserve kinetic + electric potential energy from large separation to closest approach
16.
System rotates about CM i.e. middle of 4M and M(Q)

For problem 3, work done by electric field = QLE = I2
Initial torque by electric field = QLE = I
r/2r =
SECTIONC
1.
For circular motion of a body tied to a string on a horizontal plane

mv 2
T
r
here, T mg
O T
r
mv 12 / r1 M1g
mv 22 / r2 M2 g
v 12r2 8
(i)
v 22r1 1
Now as angular momentum is conserved about pt 0.
mv1r1 mv 2 r2
(ii)
from (i) and (ii)
r1
2
r2
4
further
2 v 2 r1 r1

1 v1 r2 r2
2 1
1

1 2
4
2 1 2
1
3
1 1
2
1
4
4
2.
Q
dT
KAA
t
dx
dT
in conductor A = slope of graph = 3
dx
Since both conductors are connected in series, same heat current will flow in A and B.
Q
1
1
=
200 3 J/m-secC
KB
dT
t
t A tan 45
A
dn
3.
For lens L1, ray must move parallel to the axis after refraction
4.
f = ma2
2f
=
I mR
a2 = F/4m, f = F/4
1 w 1
x = 10 cm
x
R1
a1
f
a2
f
5.
In steady state potential difference across each capacitor = E
6.
mAg sin = 5 10 sin 37 = 5 10
3
= 30 N
5
fmax AB (mC mB )gcos 48 N

hence f = 30 N
7.
sin 1
n
1 2
1 1
40
or 20 n 60
Hence number of maxima = 60 20 = 40
5
Chemistry
PART II
1.
Go RTlnK p
46.5 1000 = - 2 298 lnKp
Kp = 1.3 10 34
2.
C6H6
15
O2 6CO2 3H2 O;Q1
2
C O2
CO2 ;
Q2
1
O2 H2 O;
Q3
2
Required equation: 6C s 3H2
C6H6 ; H 6Q2 3Q3 Q1
H2
3.
Cl
KOH
C2H5 OH
Cl2 ,h
4.
Mole fraction of A in vapour YA =
14.
H
O
H
X APAo
X APAo XBPBo
X A 1 PAo 1
&
XB 3 PBo 3
YA
6.
O3 / Zn
H2 OH
1
1
0.1
o
XB PB 1 3.3
1
XA PAo
[Cu(CN)4]3 is square planar and contains Cu (I) which is colourless

[NiCl4]2 is tetrahedral and contains Ni(II) which is coloured.
[BF4] is tetrahedral and colourless
SO 2 PCl5
SOCl2 POCl3
A
SOCl2 H2 O
SO 2
A
15.
HCl
pungent smelling
5.95
5 102 mol / l
119 1
H2 O SOCl2 2AgNO3
2AgCl 2HNO 3 SO 2
MSOCl2
Moles of AgCl formed = 2 molarity of SOCl2 in 100 ml = 2 5 102
100
102 moles
1000
Wt. of AgCl = 143.5 102 = 1.435 g

16.
IInd part was treated with dil. HCl/BaCl2/H2O2.

SOCl2 H2 O
SO2 2HCl
H2 O 2 SO2
SO3 H2 O
6
SO3 H2 O
H2 SO4
BaCl2 H2SO 4
BaSO 4 2HCl
ppt.
10
in 100 ml solution
100
Wt. of BaSO4 formed = 5 10 3 233 1.165 g.
Mole of BaSO4 formed = 5 102
SECTION C
Br
2.
Br2 / h
CH3 CH2 CH2 CH3

H3C CH CH2
(enantiomers)
H3C
Br
H3C
CH CH2
CH3
3.
cis CH2 CH CH2 CH3
CH3
Let x% be the decrease in density of Ge crystals. Let a be the total no. of Ge atoms missing and
b be the no. of boron atoms replacing Ge atoms.
b
100 2.376
(i)
a
72.6a 11b
1
1 0.01x
NAV
NAV
72.6a 11b
0.01x
NAV
NAV
(ii)
150NAV
1 0.01x
106 11
Solving (i), (ii) and (iii)
x = 4%
Also, b =
4.
H
C
Alcoholic
KOH
CH3 CH3 CH2 CH2 CH2Br
(iii)
Ksp = [Zn2+][S2-]
10 21
[S2-]
10 19
0.01
2
For K a1 .K a2
H S 2

H2 S
2
H 1019
10
H 0.1
0.1
or pH = 1
20
5.
3Cu + 10HNO3 3Cu(NO3)2 + 3NO2 + NO + 5H2O
6.
Only CO and CH4 react with O2, N2 remain uncreative
7.
OH
OH
P
O
P
O
OH
O
OH
6
3
2
7
Mathematics
PART III
1.
A, B, D are always true but C is true only if the triangle is equilateral
2.
f(x) = cos x + cos(x + 2) + cos(x + ) = (2 cos + 1) cos(x + )

As cos (x + ) can take any real value from 1 to 1 x R
But f(x) is constant so (2 cos + 1) = 0 must hold
2

and C = 0
3
2
Hence [C + ] = 0
2
3
3.
2sin3x cos x 2sin3x cos3x

2cos2 x 2cos x cos5x
sin3x cos x cos 3x
dx
cos x cos x cos 5x
2sin3x sin 2x sin x
dx
2cos x cos 3x cos 2x
dx
tan3x tan2x tan x dx = tan3x tan2x tan x dx

2
4.
1 sin tdt
1 sin tdt
1 sin tdt
2 1
1 sin tdt
Put t = + x, 2 1
1 sin xdx
5.
cos
x
x
x
x
sin dx = 2 sin cos 4

2
2
2
2 0
We have sin
12
42
r
K Let
PA PB PC
A
12
B
42
C
r
P
So K(PB PA) = 42 12 = 30
K(AB) = 30
K[54] = 30
30 5
K=
54 9
8
Now K(PC PB) = r 42

K(BC) = r 42
K[r + 42] = r 42
On solving r = 147
t
6.
Let g t f x dx
g(t) = f(t)
Now apply Lagranges mean value theorem in [0, 2], we get
g 2 g 0
g' c where c (0, 2)
20
2
f x dx 2g' c where c (0, 2)

0
7.
Vector perpendicular to 2i j k and i 3j k is

i
2 1 1 2i j 5k
1 3 1
Any general point on the line is (1 + 2, 1 + , 1 ) at the point of intersection. This point satisfy
equation of plane (1 + 2) + 3(1 + ) (1 ) = 9
=1
x3 y2 z
Point of intersection (3, 2, 0) and required line
2
1
5
8.
(A) f(x) = cos(sin x)

As f(x + ) = cos(sin( + x)) = cos(sin x) = cos(sin x) = f(x)
(B) As 1 sin x 1
cos 1 cos(sin x) 1

(C) lim f x f x
x / 2 2
2
= lim 2cos cos x 2

x / 2
(D) Clearly f(x) is even function

9.
Let the number be (a d), a, (a + d)

3a = 24
a=8
Also (8 d)(8)(8 + d) = 384
d2 = 16
d = 4 or 4
Hence series is 4, 8, 12, ..
Sn = 2n(n + 1) or 12, 8, 4, ..
Sn = 14n 2n2
10.
f(x) > 0 and f(x) > 0 for x < 0

f(x) < 0 for x > 0
1
Now g x
1
f
x
(0, 1)
1
1 x2
9
1
1 1
f ' 2
x x
1
f2
x
So for x < 0 g(x) > 0
x > 0 g(x) < 0
g' x
11.
As ac = 3 and bc = 4
b 4
ba 43 1
(B > A)
a 3
ba 43 7
C
B A ba
tan
cot
2 ba
2
1 cos B A 4 3
C
cot
1 cos B A 4 3
2
C
3
On solving cot 7 cosC
2
4
cos C = cos(A B) or cos C = cos(B A)
C=AB
C=BA
(A + B) = A B
(A + B) = B A
A (rejected)
B
2
2
b 4
b a
But
K
a 3
4 3
1
Now ac = 3 3 7K 2 3 K 1/ 4
7
2
R 2K 1/ 4
7
12.
6 = 4K
3K
A
B
7
y = f(x) = (ln x)2 + 2 ln x

dy
2lna 2 2
1 lna
dx A a, f a
a
a a
dy f a 0
Also
dx
a0
f a 2
1 lna f(a) = 2(1 + ln a)
a
a
So (ln a)2 + 2 ln a = 2 + 2 ln a
(ln a)2 = 2 a e
Hence a e
So ab = 1
13.
or e
and b e
2
2
5x f(x) x ln 10 10 = 0
2ln x 2
5x
x ln10 10 0
x
x
10 ln x + 10 x ln 10 10 = 0
10 ln x = x ln 10
ln x ln10
,x>0
x
10
ln x
As y
x
10
y'
1 ln x
so two values of x are possible
x2
ex
14.-16 We have f x lim 4
0
et 1 ln2 1 t
0 2t3 3
dt form
0
e x e 1 ln2 1
= lim
2 3 3 43
e 1 ln2 1
1
2
0
4 2 3 3
= e x lim
=
ex
12
14.
Clearly f(ln 2) =
15.
We have
eln 2 1
12
6
g t dt 3x cos2 t g t dt
On differentiating both side w.r.t x

g(x) = 3 cos2 x g(x)
3
g x
1 cos2 x
3
3
Clearly
3
2 1 cos2 x
/2
16.
Let I
g x dx
0
/2
1 cos
0
/2
3 sec 2 x
tan2 x 2
dx
dx
3
2 2
SECTION C
1.
8
Tk tan1 2
k
1 2
tan 2
k
4
1
tan 2
1 k 1
k
k
1 1
= tan1 2 2
1 k 1 k 1
2 2
k
k
= tan1 1 tan1 1
2
2
11
2.
a
c sin 200
d
cos 200 cos 200
b
dsin 200
c
cos 200 cos 200
a = d cos(200) + c sin(200)
b = c cos(200) d sin(200)
a2 + b2 = c2 + d2
2
2
2
2
2
2
(a + b + c + d ) = 2(c + d )
2
ac dc cos 200 c sin 200
Also
.. (1)
.. (2)
.. (3)
.. (4)
bd cdcos 200 d2 sin 200

__________________________
ac bd c 2 d2 sin 200
a2 b2 c 2 d2
2 c 2 d2
2 cosec 200
ac bd
c 2 d2 sin 200
p=2
So
3.
4.
AB BD 2
AC DC 1
Using since law in ABC we get
1
2
2
sin sin 3 sin3

3 4 sin2 = 2
1
1
sin2 sin
= 30 2 = 60
4
2
1
3
Area of ABC = 2 1 sin 60 =
2
2
3
2
Hence 12 12 9
4
Since
2 2
3
D
Since diagonal is a member of both the families so it will pass through (1, 0) and (1, 1)
Equation of diagonal AC is x + 2y 1= 0
Since one of the vertex (3, 2) which does not be on AC, so equation of BD is 2x y = 4
2
9
Point of intersection of AC and BD is P ,
5
5
14
12 5
3
If vertex B is (3, 2) then vertex D is , also BD
(say d1)
5
5
5
1
Area of rhombus = d1 d2
2
1 12 5
d2 12 5
2 5
d2 = 10
5.
We have f(x) = f(3 x) on integrating w.r.t. x

f(x) = f(3 x) + c
Put x = 0
f(0) + f(3) = c
32 + 46 = c
c = 14
12
3
Now let I f x dx
.. (1)
I f 3 x dx
.. (2)
Adding (1) and (2), we get 2I f x f 3 x dx 14dx 42
6.
a3 b3
sin3 20 sin3 80
ab2
sin20 sin2 80
3 sin 20 sin60 3 sin80 sin240
4 sin 20 cos2 10
3 sin20 sin80
3 cos30
=
2
4
sin
40
sin 20 sin80
4 sin 20 sin 80
3
cos 30
=
4 sin 20 sin 60 20 s sin 60 20

3 cos 30
=
3
4 1
sin60
4
7.
f(x) = 6P 4P cos 4x 5 3 cos 3x > 0

5 3cos3x
2P >
3 2cos 4x
5 3cos3x
2P > max value of
3 2cos 4x
53
2P >
32
P>4
Smallest P is 5

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1

ALL INDIA TEST SERIES

Apply superposition of currents in each resistor due to each cell to get

Intensity in absence of lens = P/4r2

apply work-energy theorem

At closest approach velocity perpendicular to line joining particles

System rotates about CM i.e. middle of 4M and M(Q)

For circular motion of a body tied to a string on a horizontal plane

from (i) and (ii)

In steady state potential difference across each capacitor = E

mAg sin = 5 10 sin 37 = 5 10

fmax AB (mC mB )gcos 48 N

Mole fraction of A in vapour YA =

[Cu(CN)4]3 is square planar and contains Cu (I) which is colourless

Moles of AgCl formed = 2 molarity of SOCl2 in 100 ml = 2 5 102

Wt. of AgCl = 143.5 102 = 1.435 g

IInd part was treated with dil. HCl/BaCl2/H2O2.

Mole of BaSO4 formed = 5 102

CH3 CH2 CH2 CH3

cis CH2 CH CH2 CH3

CH3 CH3 CH2 CH2 CH2Br

3Cu + 10HNO3 3Cu(NO3)2 + 3NO2 + NO + 5H2O

Only CO and CH4 react with O2, N2 remain uncreative

A, B, D are always true but C is true only if the triangle is equilateral

f(x) = cos x + cos(x + 2) + cos(x + ) = (2 cos + 1) cos(x + )

2sin3x cos x 2sin3x cos3x

tan3x tan2x tan x dx = tan3x tan2x tan x dx

sin dx = 2 sin cos 4

Now K(PC PB) = r 42

f x dx 2g' c where c (0, 2)

Vector perpendicular to 2i j k and i 3j k is

(A) f(x) = cos(sin x)

= lim 2cos cos x 2

(D) Clearly f(x) is even function

Let the number be (a d), a, (a + d)

f(x) > 0 and f(x) > 0 for x < 0

y = f(x) = (ln x)2 + 2 ln x

so two values of x are possible

On differentiating both side w.r.t x

bd cdcos 200 d2 sin 200

sin sin 3 sin3

We have f(x) = f(3 x) on integrating w.r.t. x

Adding (1) and (2), we get 2I f x f 3 x dx 14dx 42

4 sin 20 sin 60 20 s sin 60 20

f(x) = 6P 4P cos 4x 5 3 cos 3x > 0

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