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Reaction Rates
Chemical kinetics is the study of the reaction rates, how reaction rates
change under different conditions.
Chemical rate of reactions:
Chemical reactions require varying lengths of time for completion, depending
on the characteristics of the reactants and products and the conditions under
which the reaction takes place. Many reactions take few seconds, others take
more.
The study of the rate, or the speed, of a reaction has important applications.
For eg. In the manufacture of ammonia from nitrogen and hydrogen you want
to know the conditions that will help the reaction proceed in a commercially
length of time. Also we want to know if the NO gas will destroy the ozone in
the stratosphere faster than the ozone is produced. To answer these
questions we must have knowledge of the rates of reactions.
Reaction rate:
It is the increase in the amount (molar conc.) of product of a reaction per unit
time or the decrease of the amount (molar conc.) of the reactants per unit
time.
The rate of a reaction =
Negative sign indicate a decrease in conc. and to give a positive value for
the rate. Thus because [N2O5] decreases, [N2O5] is negative and (- [N2O5]/
t) is positive.
[O2]
0.0000
0.0021
0.0036
0.0048
0.0057
0.0063
0.0068
0.0072
0.0075
Note:
Rate of formation of oxygen = the rate of decomposition of N 2O5 as there
are 2 moles of N2O5 which decompose to only one mole of O2.
[O 2]/ t= -1/2 [ N2O5]/ t
Example:
Consider the reaction of nitrogen dioxide with fluorine to give nitryl fluoride.
2 NO2(g) + F2(g) 2 NO2F(g)
How is the rate of the formation of NO2F related to the rate of reaction of
fluorine?
Solution:
Rate of formation of NO2F = [NO2F]/ t
Rate of reaction of F2 = - [F2]/ t
Then divide each rate by corresponding coefficient and then equate them.
(1/2 ) [NO2F]/ t = - [F2]/ t
Example:
Calculate the average rate of decomposition of N2O5, by the reaction2 N2O5 (g)
4 NO2(g) + O2 (g)
During the time interval from t = 600 s to t= 1200 s. use the following data
Time
600s
1200s
[N2O5]
1.24x 10-2 M
0.93X10-2 M
[I-]
0.00169
0.00101
reaction rates:
1-Concentration of reactants:
The rate of reaction increases as the concentration of reactant increases.
A piece of steel wool burns difficulty in air(20% O 2)but bursts in pure oxygen.
2- Concentration of catalyst:
A catalyst is a substance that increases the rate without being consumed in
the overall reaction. It doesn`t appear in the balanced chemical equation
but can be written over the arrow.
2H2O2(aq)
2H2O(l) + O2(g)