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CLASIFICARI SI NOMENCLATURI
Consecintele proprietatii unice a carbonului se manifesta in cea mai simpla
clasa de substante organice, hidrocarburile.
Alcanii
Alchenele si Alcanii
Grupuri Functionale
Alti atomi, cum ar fi la clor, oxigen sau azot pot fi inlocuiti cu hidrogenul in
alcani.
Optical isomers have exactly the same chemical properties and all of the
same physical properties except one: the direction that each type of isomer
turns a plane of polarized light (see Optics). Dextro-lactic acid, or D-lactic
acid, turns the plane of polarized light to the right and levo-lactic acid, or
L-lactic acid, to the left. Racemic lactic acid (a 1:1 mixture of D- and Llactic acid that is found in sour milk) exhibits zero rotation because left and
right rotations cancel each other.
Double bonds in carbon compounds give rise to geometric isomerism (not
related to optical isomerism) if each double bond has different groups
attached. A molecule of 2-heptene, for example, may be arranged two ways
in space because rotation about the double bond is restricted. When the like
groups, hydrogen atoms in this case, are on opposite sides of the double
bonded carbon atoms, the isomer is called trans and when the hydrogens are
on the same side, the isomer is called cis.
double bonds belong to the entire hexagon and not to individual carbons at
the corners of the hexagon. Other aromatic compounds are shown in Fig. 14.
IV
Coal tar was once the only source of aromatic and some
DETERMINATION OF STRUCTURE
VI
COMPOUNDS
Chemists ordinarily
At a temperature of 80 C (176 F) the rate of reaction at the position is faster than the rate at the -position. Consequently, a
91 percent yield of -naphthalenesulfonic acid can be obtained at
80; at a higher temperature, the -isomer predominates. At 160
C (320 F) the -isomer desulfonates more rapidly than the -form,
so an 85 percent yield of -naphthalenesulfonic acid, the more
stable isomer, is obtained.