Laporan Absorpsi-1

P1
LEMBAR PERHITUNGAN
A. PERHITUNGAN REAGEN
Larutan NaOH 0.3 N sebanyak 15 liter
m 1000
N=
x
xvalensixkadar
BM
V
0,3=
m 1000
x
x 1 x 0,98
40 15000
m=180 gr
NaOH 0.2 N
Sisa V NaOH 0.3 N= 3 L
V1.N1=V2.N2
0.3 x 3 = 0.2 V2
V2= 4.5 L
(V aquades yang ditambahkan= 1.5 L)
NaOH 0.1 N
Sisa V NaOH 0.3 N= 4 L
V1.N1=V2.N2
0.2 x 4 = 0.1 V2
V2= 8 L
(V aquades yang ditambahkan= 4 L)
Larutan HCl 0,25 N dalam 100 ml
HCl=1,137
N=
gr
ml
xVx 1000 xvalensixkadar

BMxvolume
0,25=
1.137 xVx 1000 x 1 x 0,25

36.5 x 100
V =3.2 mL
B. PERHITUNGAN FRAKSI KOSONG

3
V void =100 c m
D=3,3 cm ; H=30,3 cm
V t=
x D2 xH 3,14 x 3,3 x 30,3

=
=259,16 c m3
4
4
3
V void
100 c m
=
=
=0,3857
3
Vt
259,26 c m
A-1
P1
C. OPERASI ABSORBSI
Variabel Tetap
5 kg
: 5,5 5,5 x 10 m s2
Tekanan CO2
Z1
Z2
Z3
: 0,012 m
: 0,009 m
: 0,007 m
Q1 NaOH
6 3
: 3 mL/s = 3 x 10 m /s
Variabel Berubah
N1 NaOH
: 0.3 N
N2 NaOH
: 0.2 N
N3 NaOH
: 0.1 N
D. PERHITUNGAN LAJU ALIR CO

Hg = 13.554 kg/m
CO = 1.264 kg/m
D1 = 3,2 cm
D2 = 2,1 cm
4
S1 = 0,25 x 3,14 x (3.2 cm) = 8,0384 cm = 8,04 x 10
m
4
S2 = 0,25 x 3,14 x (2,1 cm) = 3,4619 cm = 3,46 x 10
g
P1= Z 1 ( raksa co )
gc
kg
m N s2
N
(
)
0,0 12m 13.5541.264 3 .9,8 2 .1
=14.45 2 =14.45 Pa
m
s kg m
m
Vco =
2
2 xgcx (
P
F )
co
2
s1
1
s2
()
14.45
0)
1.264
=1,011 m/s
0,0008084
1
0,0003462
2x 1x 1x(
Qc o =V c o x S 2=1,011 x 0,0001768=0.00035 m /s
2
2
g
gc
0,0 09 m ( 13.5541.264 )
kg
m N s2
N
.9,8
.1
=10,84 2 =10,84 Pa
3
2
m
s kg m
m
A-2
P1
Vco =
2
2 xgcx (
P
F )
co
2
s1
1
s2
()
10,84
0)
1.264
=3,59 m/s
0,0008084
1
0,0003462
2x 1x 1x(
Qc o =V c o x S 2=3,59 x 0,0001768=0.000634
2
2
g
gc
0,0 07 m ( 13.5541.264 )
Vco =
2
2 xgcx (
m3
s
P
F )
co
2
s1
1
s2
()
kg
m N s2
N
.9,8
.1
=8,43 2 =8,43 Pa
3
2
kg
m
m
s
m
14.45
0)
1.264
=3.16 m/s
0,0008084
1
0,0003462
2x 1x 1x(
Qc o =V c o x S 2=3.16 x 0,0001768=0.000559 m /s
2
E. PERHITUNGAN LAJU ALIR UDARA DARI KOMPRESOR

Hg = 13.554 kg/m
Udara = 1,2 kg/m
D1 = 3.2 cm
D2 = 2.1 cm
4
S1 = 0,25 x 3,14 x (3.2 cm) = 8,0384 cm = 8,04 x 10
m
4
S2 = 0,25 x 3,14 x (2.1 cm) = 3,4619 cm = 3,46 x 10
g
P= Z 1 ( raksa Udara )
gc
0,0 12m ( 13.5541,2 )
V Udara=
2 xgcx(
kg
m N s2
N
.9,8
.1
=1.453 2 =1.453 Pa
3
2
kg
m
m
s
m
P
F)
Udara
s1
1
s2
()
1.453
0)
1,2
=1.353 m/s
0,00030384
1
0,00034619
2 x 1 x 1 x(
QUdara=V Udara x S 2=96,17 x 0,00034619=0.00033 m /s
A-3
P1
F. PENENTUAN KADAR CO2
QCO =0.00035 m3 /s
2
QUdara=0.00033m3 / s
Mencari y 2 (CO2)
PV =nRT
n
p
=
; P P gauge C O2
V RT
83.14 c m3
83.14 c m
x 303 K =2,18 x 104 mol /m3

mol K
5.5
n
P
y 2= =
=
V RT
4
3
x 303 K =2,58 x 10 mol / m
mol K
6.5
(CO2 di atmosfer)
n
P
y 1= =
=
V RT
Mencari y 3 (campuran)
Q3 x y 3=Q1 x y 1+ Q2 x y 2
y 3=
y 3=
Q1 x y 1+Q2 x y 2
Q3
( 0.00033 x 2,58 x 104 ) +(0.00035 x 2,18 x 104 )

0.00033+ 0.00035
y 3=0.00034 mol/m
G. PERHITUNGAN ABSORBSI CO
N N a 2 C O3 =N C O2 terserap
N N a 2 C O3 =
2b xNHCl
valensix V titrasi
Variabel 1 ( NaOH 0.3 N )
A-4
P1
t
(menit)
b (ml)
1.5
7.8
1.5
0.2
6.9
0.3
6.7
0.2
6.5
0.2
6.5
0.3
6.3
0.3
0.3
5.9
0.4
10
5.6
0.4
6.65454
5
0.50909
1
avg
a (ml)
N Na2CO3
N CO2
terserap
terserap
0.0375
0.0375
0.0375
0.0375
0.005
0.005
0.0075
0.0075
0.005
0.005
0.005
0.005
0.0075
0.0075
0.0075
0.0075
0.0075
0.0075
0.01
0.01
0.01
0.01
0.012727
0.01272
7
Variabel 2 (NaOH 0.2 N )

t
(menit)
avg
a (ml)
b (ml)
1.5
0.6
5.9
0.4
5.6
0.4
5.5
0.1
5.3
0.3
5.3
0.4
0.3
4.8
0.2
0.5
10
4.7
5.55454
5
0.4
0.46363
6
N Na2CO3
N CO2
terserap
terserap
0.0375
0.0375
0.015
0.015
0.01
0.01
0.01
0.01
0.0025
0.0025
0.0075
0.0075
0.01
0.01
0.0075
0.0075
0.005
0.005
0.0125
0.0125
0.01
0.01
0.011591 0.011591
A-5
P1
Variabel 3 (NaOH 0.2 N )

t
(menit)
avg
a (ml)
b (ml)
5.6
0.3
0.4
3.6
0.2
3.5
0.3
3.4
0.2
3.3
0.2
3.3
0.2
3.3
0.3
3.2
0.2
3.1
0.2
10
2.8
0.2
3.64545
5
0.24545
5
N Na2CO3
N CO2
terserap
terserap
0.0375
0.0375
0.01
0.01
0.005
0.005
0.0075
0.0075
0.005
0.005
0.005
0.005
0.005
0.005
0.0075
0.0075
0.005
0.005
0.005
0.005
0.005
0.005
0.008864
0.00886
4
H. PERHITUNGAN HARGA kGa

mol CO 2
k G a=
AxZxxP
dimana :
A
luas
kolom
absorbsi
1
1
x D2 x =3,14 x 3,32 x =8,548 c m2=8,548 x 104 m2
4
4
Z
= tinggi packing = 30,3 cm = 0,303 m

= fraksi ruang kosong = 0,3857

P= Z 1+760 mmHg
1.2 cm+76 cmHg=77.2 cmHg=1,0158 1,0158 x 10 5
N
m2
A-6
P1
mol
mol CO 2
menit
mol
k G a=
=
=0,00125
4 2
5
AxZxxP 8,548 x 10 m x 0,303 m x 0,3857 x 1,0158 x 10
Nm s
0.0127
P= Z 2+ 760mmHg
5
0,9 cm+ 76 cmHg=76.9 cmHg=1,0158 1,0118 x 10
N
m2
mol
0.0116
mol CO 2
menit
mol
k G a=
=
=0,00114
4 2
5
AxZxxP 8,548 x 10 m x 0,303 m x 0,3857 x 1,0118 x 10
Nm s
P= Z 3+760 mmHg
N
0.7 cm+76 cmHg=76.7 cmHg=1,0158 1,0092 x 105 2
m
mol
0.0089
mol CO 2
menit
mol
k G a=
=
=0,00088
4 2
5
AxZxxP 8,548 x 10 m x 0,303 m x 0,3857 x 1,0092 x 10
Nm s
I. PERHITUNGAN HARGA kLa

6
C O (T =30 C )=15 x 10 kg /ms
2
Massa jenis CO2 ( T =30 C ) = 1.264 kg/m3

3
NaOH ( T =30 C ) =3,95 x 10 kg/ms

Massa jenis NaOH ( T =30 C ) = 969,9 kg/m3
9 2
DA = 2,1 x 10-5 cm2/s = 2,1 x 10 m / s
a=
6 ( 1 ) 6 ( 10,3857 ) 3,686
=
=
dp
dp
dp
A-7
P1
C O .Q CO
k G a . d p2
=4,0777 x
DA
C O .a
1,4003
C O
x
C O . D A
) (
1,4003
0,00882 xd p
1264 x 3,5 x 10
=4,0777 x
9
6 3,686
2,1 x 10
15 x 10 x
dp
6
1,4003
4,2 x 10 d p =4,0777 x 518631,95 d p

8,098 d p
1
3
15 x 10
x
9
1264 x 2,1 x 10
1
3
1
3
x 1,78
0,5997
=7,26
dp=0,833
a=
3,486 3,486
=
=4,18
dp
0,833
k L a .dp
.Q
=0,2258 x NaOH NaOH
DA
NaOH .a
k L a x 0,833
9
2,1 x 10
k L a x 0,833
2,1 x 109
0,3
) (
x
0,5
NaOH
NaOH . D A
969,9 x 3 x 10
=0,2258 x
3
3,95 x 10 x 4,18
0,3
) (
3,95 x 10
x
9
969,9 x 2,1 x 10
0,5
=0,2258 x 0,594 x 44,04
k L a=1,49 x 108 m3 / s

C O .Q CO
k G a . d p2
=4,0777 x
DA
C O .a
1,4003
C O
x
C O . D A
) (
0,00741 xd p
1264 x 6,3 x 10
=4,0777 x
9
6 3,686
2,1 x 10
15 x 10 x
dp
1,4003
1
3
15 x 10
x
9
1264 x 2,1 x 10
3,52 x 106 d p2=4,0777 x 519797,34 d p1,4003 x 1,78

6,8 d p 0,5997=7,26
dp=1,114
A-8
P1
a=
3,686 3,686
=
=3,13
dp
1,114
k L a .dp
.Q
=0,2258 x NaOH NaOH
DA
NaOH .a
k L a x 1,114
2,1 x 109
k L a x 1,114
2,1 x 109
=0,2258 x
0,3
NaOH
x
NaOH . D A
) (
969,9 x 5 x 10
3,95 x 103 x 3,13
0,3
) (
x
0,5
0,5
3,95 x 103
969,9 x 2,1 x 109
=0,2258 x 0,648 x 44,04
k L a=1,21 x 108 m3 / s

C O .Q CO
k G a . d p2
=4,0777 x
DA
C O .a
1,4003
C O
x
C O . D A
) (
0,00479 xd p
1264 x 5,59 x 10
=4,0777 x
9
6 3,686
2,1 x 10
15 x 10 x
dp
6
2,28 x 10 d p =4,0777 x 520380,32 d p
1,4003
1
3
1,4003
15 x 10
x
9
1264 x 2,1 x 10
x 1,78
4,39 d p 0,5997 =7,26

dp=2,307
a=
3,686 3,686
=
=1,51
dp
2,307
k L a .dp
.Q
=0,2258 x NaOH NaOH
DA
NaOH .a
k L a x 2,307
9
2,1 x 10
k L a x 2,307
2,1 x 109
=0,2258 x
0,3
NaOH
x
NaOH . D A
) (
969,9 x 7 x 10
3
3,95 x 10 x 1,51
0,3
) (
x
0,5
3,95 x 10
9
969,9 x 2,1 x 10
0,5
=0,2258 x 0,806 x 44,04

8
k L a=0,729 x 10 m /s
J. PERHITUNGAN HARGA k2
4
H=2,88 x 10
gmol
Pa .m 3
A-9
1
3
P1
D A =2,1 x 10 m / s
C 02 (T =30 C)=1264 kg /m 3
Variabel 1 ( NaOH 0,3 N )

a=5,9 x 106
k G a=0,00882
mol
Nm s
O H
Ra=Q NaOH x nCO =3 x 106 m3 /s x 0.0895 mol=2,69 x 107

2
k 2=
[
[
Ra
0.5
a x H x D0.5
A x ( OH ) x C O
Ra
kG a
mol m3
s
2,69 x 107
2,69 x 107
k 2=
0.5
0.5
0,00882
5,9 x 10 6 x 2,88 x 104 x ( 2.1 x 109 ) x ( 0,15 ) x 1264
k 2=9,3 x 1010 m3 /mol . s
Variabel 2 ( NaOH 0,2 N )

a=0,37 x 106
k G a=0,00741
mol
Nm s
O H
mol m3
Ra=Q NaOH x nCO =3 x 10 m /s x 0,075 mol=2,25 x 10
s
6
k 2=
Ra
0.5
a x H x D0.5
A x ( OH ) x C O
Ra
kG a
A-10
P1
7 2
2,25 x 10
2,25 x 10
k 2=
0.5
6
4
9 0.5
0,0074
0,37 x 10 x 2,84 x 10 x ( 2.1 x 10 ) x ( 0,13 ) x 1264
k 2=9,16 x 1010 m3 /mol . s

a=0,62 x 106
k G a=0,00479
mol
Nm s
O H
Ra=Q NaOH x nCO =3 x 10 m /s x 0,0486 mol=1.46 x 10

2
k 2=
[
[
Ra
0.5
a x H x D0.5
A x ( OH ) x C O
Ra
kG a
mol m
s
1.46 x 107
1,46 x 107
k 2=
0.5
0.5
0,00479
0,62 x 10 6 x 2,84 x 104 x ( 2.1 x 109 ) x ( 0,085 ) x 1264
k 2=9,26 x 1010 m3 /mol . s
A-11

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P1

xVx 1000 xvalensixkadar

1.137 xVx 1000 x 1 x 0,25

B. PERHITUNGAN FRAKSI KOSONG

x D2 xH 3,14 x 3,3 x 30,3

D. PERHITUNGAN LAJU ALIR CO

E. PERHITUNGAN LAJU ALIR UDARA DARI KOMPRESOR

0,0 12m ( 13.5541,2 )

QUdara=V Udara x S 2=96,17 x 0,00034619=0.00033 m /s

F. PENENTUAN KADAR CO2

x 303 K =2,18 x 104 mol /m3

( 0.00033 x 2,58 x 104 ) +(0.00035 x 2,18 x 104 )

Variabel 1 ( NaOH 0.3 N )

Variabel 2 (NaOH 0.2 N )

Variabel 3 (NaOH 0.2 N )

H. PERHITUNGAN HARGA kGa

= tinggi packing = 30,3 cm = 0,303 m

Variabel 1 ( NaOH 0.3 N )

Variabel 2 ( NaOH 0.2 N )

0,9 cm+ 76 cmHg=76.9 cmHg=1,0158 1,0118 x 10

Variabel 3 ( NaOH 0.1 N )

I. PERHITUNGAN HARGA kLa

Massa jenis CO2 ( T =30 C ) = 1.264 kg/m3

NaOH ( T =30 C ) =3,95 x 10 kg/ms

Variabel 1 ( NaOH 0.3 N )

4,2 x 10 d p =4,0777 x 518631,95 d p

=0,2258 x 0,594 x 44,04

Variabel 2 ( NaOH 0.2 N )

3,52 x 106 d p2=4,0777 x 519797,34 d p1,4003 x 1,78

=0,2258 x 0,648 x 44,04

Variabel 3 ( NaOH 0.1 N )

2,28 x 10 d p =4,0777 x 520380,32 d p

4,39 d p 0,5997 =7,26

=0,2258 x 0,806 x 44,04

Variabel 1 ( NaOH 0,3 N )

Ra=Q NaOH x nCO =3 x 106 m3 /s x 0.0895 mol=2,69 x 107

Variabel 2 ( NaOH 0,2 N )

k 2=9,16 x 1010 m3 /mol . s

Variabel 3 ( NaOH 0.1 N )

Ra=Q NaOH x nCO =3 x 10 m /s x 0,0486 mol=1.46 x 10

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