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BIBLIOGRAPHIC INFORMATION
PB85-163343
Debonding and Pull-Out Processes in
Fibrous Composites,
1984
by J.
K. Wells,
PERFORMER:
and P.
W. R.
Cambridge Univ.
Beaumont.
(England).
Dept.
of
Engineering.
CUED/C-MATS/TR-l 10
*Fiber composites,
*Failure,
*Foreign technology.
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'7i
DEBONDING AND PUL!,-OUT PROCESSES IN
FIBROUS COMPOSITES
CUED/C/MATS/TR11O
(1984)
......... .'S..
S/
Weells
11
d P W R Benucont
ASTIRACT
The
described.
processes
of
debonding and
pull-out
in
fibrous composites
functions
then
out and
of
compared
debond
the
with
lengths
pull-out processes
is
fibre,
matrix
experiment
is
found.
and
and
An
interface
simple
*..
These lengths
properties.
relationship
understanding
of
Prediction
between
and
of fibre composites.
/
/
'II
*},;ow~ at L- iRes
pull-
the debonding
'
are
.roh Coiltr2,
C.h.e.,.tsev Rued,
Sunbur', on Thames,
Middlesex
I.
1NTRUDUCTION
The
higher
have
impact
than
toughne:;s
that
of
been propose~d
of
either
[i1
its
3]
fibre
reinforced
constituent
based
polymer
phases.
composite
A number of
is
reasons
on the processes
lengths
to be calculated.
These
processes
can operate
applied
load
(Fig.
Under
monotonic
small
crack
transferred
forces
fails.
a composite
loading
in
by
1).
eventually
A cylindrical
fibres
to the
the
at
material
forms.
to the
become
continuous
Perpendicular
the matrix
shear
of
so
crack
Load,
fibres
large
at
the
notch-tip
once
tarried
still
is
by
and
the matrix,
intact.
a
is
These shear
propagates
from
to an
a notch.
fractures
the interface
parallel
fibre direction
which are
that
aligned
the matrix
This process
called de'oneino.
Some
interfacial
ture.
fibre.
the
This
load
between
fibre
and
matrix
is
still
possible
by
Because
fibre is
transfer
of
produces
the
variable
non-uniform
strength
stress
of the
along
fibre
the
along
debonded
its
length
where
the stress is
highest.
After fracture,
the composite typically shjw:This process is
ea
from it
with fibres orotruding
matrix crack-pian
.....
...
..
I'
THE PROCESS OF DEBONDING
stress
and
the
rate
of
controlled
increase
by two parameters7
the fibre
stress
length
of
along
the
of
front
is
cd
and
the applied
fiLre
(debond)
stress when
*.
where
o(x)
f(x)
is
When o(x)
+ f(x)
(1)
reaches
the fibre
the ultimate
on its
caused by friction
st,.ength of
the fibre,
oaf
surface.
failure
occurs
/8
3.1
The
"Thc shear
load,
T ,
o
stress
can
be predicted
exceeded.
example,
occurs
shear-lag
analysis
[4
6].
the
shear strength
similar
results
of the
interface
are obtained,
for
(Zn)
2O (2
-
is
the
Young's
modulus
Other derivations
on T0O , E and G
o f
(2)
f
U'
modulus.
when
In references
Ef
where
assuming debonding
is
using
of
also agree
The function
the
fibre
and
the
in
on the dependence
matrix
of debond
r,
fn
denends
shear
stress
rzc~ise
stress concentration
at t,
crack
front
.nl
may..
therefore,
over-
alternative
approach
based
on
the
energetics
of
failure, is
for
interfacial
ad
G 2c
is
the
cracking.
since
load
Outwater
they do not
condition.
Clearly,
mode
critical
anU Murphy's
state whether
Wells
only if
strain
release
rate
rederived
[8]
there is
energy
is
their
is
confusing
to
clarify
this
point.
(3)
most
is
to
convenient
experimentally
on fibre radius.
Wells
wires
diameter
of
varying
shown in Fig.
way
2.
[8]
of
distinguishing
investigate
therefore
the
dependence
measured
embedded
in
between
equations
of
debond
(2)
stress
epoxy
resin,
and
the
results
are
3.2
frictional
to compressive
during
cure
stress
transfer
radial stres:.-,-
and
thermal
estimated
stresses
can
be
although
the
model
does
fibre
and
matrix
is
due
by
not
between
effects
simple
take
during
analysis
into
account
cooling.
developed
the
The
by
radial
Harris
constraining
[9]
effects
of-surrounding fibres.
3.2.1
Si!.ile Linear
MAodel
If
assumed
a fi,,re is
infi:i
-Jy stiff,
4
//,
there is
no Poisson contrac-
str;s
is
uniform.
The
stress
in
fibre embedded
to
a distance
x is therefore:
ff
r
f
a(x) =
A2
where Tf = uP and 4 is
i
[and
is
the
approximation
3.2.2
average
radial
compressive
stress
around
the
fibre.
This
Non-linear Model
Although
estimates
be
fibres are
generally
stiff,
the simple
ignored.
Full
allowance
for
this
effect
is
made
in
the
cannot
derivaticn
(a - a
(4)
where
where v
matrix
""
o f
and
E are
(subscripts
the
f
Poisson's
and
between
between
fibre
build-up will
2 fEm
fm
Er(l+v
f ff
B =
Vf
ratio and
m respectively),
rf the fibre
and matrix.
fall as
Equation
the
axial
(4)
fibre
Young's modulus
p
radius
the
coefficient
and c0
predicts
of
the
of
by frictional loading is
friction
'misfit
load increases.
fibre and
strain'
of stress
when
the Poisson
the
front at ..hicl
oricin
of
the
ld
c,(x)
/
co-ordinates
(op
d)-
is
taken
as
the
debond
becomes:
crack
3.3
that
portion
strength of
of
fibre of
fibre,
of
the
fibre,
debonded length,
dZ is
uniform
between
cr.
the
strength
matrix
when
occurs
the
surfaces,
crac,.
stress
reaches
to propagate
in
the
and
the
wC
dFz
f=
- (a
22
-)
f"p
"-nn
hence
2
(-0
d =
an Cp
f
p
is
where Z
(Fig. 3).
the
If
final debonded
length
on both
if
sides
of
CT
debonding
3.4
will
have a
03)
predicts
low debond
called 'bundle
that
stress.
low
Consequently,
or
large
fibres
radius
which may
phenomenon
be
can occur.
debonding'
stiffness
9the
""
The
Bundles
interfacial
strength
than
parameter
G2c,
single
will
fibre,
also
fibre
be
but
a
with
larger
combination
of
radius.
the
pure
After debonding,
fore
any
cause
interlocking
residual
the
small movement
single
bund'ie
fibre
may
be
these corrugations.
of
compressive
of
strain
case.
on
approximated
of
the relevant
an
air-gap
mater`al
properties.
accounts
which
for
the
of
(3)
and
'socket'
produce
fibres,
distribution
equations
by
to its
This will
the bundle
stress
The
respect
and there-
an effective
similar
and
debond
(5)
after
will
to that
stress
of
a
of
substitution
observed
in
debonded
glass
fibre composites.
3.4.1
Debond Lenath
The bundle stiff.ness
of-mixturcs
where
the
and strength
fracture
of
weak
fibres
of
bundle
volume fraction (v
The
is
=
that
of
typical
the
reduces
strength
prediction (10].
composite
of
of
Poisson's
appropriate
fibre
0.32).
interface
parameter,
G2c'
is
assumed
to be
linear
furction
cG
2
where
G
l
and
interface and
around
G are
2
,a
the
rf)
G2 1
critical
(7)
energy
a,
release
rates
is
If
,olumf-:
frac-ion
c~
of
tion:
w h ore V,,
for" fracture
[Irs
7-
in the bndle
(8]
Wells
measured
approximately
carbon
fibres
50,
500
2 and 60 Jm-'
epoxy
in
Jm-'
for
an
for E-glass,
respectively.
The
epoxy
rcsin
matrix
and
misfit
strain
between
bundle
rb,
Was
3.5
have
been
carried
out
on
model
composite
specimens
specimen
The specimens
consistcd
of
have
single
been described
layer
of
[3 1 .
previously
lass
inforcing
Brieflv,
to..s
clo Z
to the tensile side of a small epoxy beam loaded in three point bending.
TABLE 1:
~PE
SPECIMEN
No. OF
NOTE
30
"OBSERVFD
PREDICTED
2.7 0.2
3.9
Vf = 23%
rb = 0.5 m
90
5.8 + 0.6
8.7
7.1 1.0
10
7.9
Vf
40%
0.45 mn
As 1 with
G1=
The observed
resu't
eing
rer s~ecJ;en,.
(i)
the
lenoths of bundle
a,, !rage
R';ut.
of
a:
le..st
dobonding
100
are shown
measurements
in Table
(10
measurome'*'s
fibrts
holding
1 each
in n .1.
(ii)
Type
B had
the
bundle
small
number
together
and
of
light weft
reducing
the
fibres
present,
inter-fibre
holding
spacing.
This
Type C were specimens prepared as type B, but the fibres were sprayed
with mould relcase fluid, producing d weak fibre/matrix bond.
Table
(3),
(6),
(7)
also
and
shows
(8),
the
with
predicted
debond
substitution
of
lengths
material
using
equations
properties
listed
in Table 2.
TABLE 2:
FIBRE
RESIN
CARBON
GLASS
Strength
(MPa)
1650
2480
80
Young's Modulus
(GPa)
70
230
(11m)
0.2
0.2
Radius
Poisson's Ratio
Values
previous section,
that
case.
no
fibre-matrix
Agreement
0.35
bonding
between
occurred
observed
and
and
consequently
predicted
values
G
is
is
the
assumed
in
this
generally
good
in
although the predictions are typically 30% higher than the observed value.
Tl
The
PROCESS OF PULL-OUT
fundamcntal
the reinforciicT
Icc,-euln
fibre.
origin
of
In the
11.sence of
pull-cut
is
the
variable
strenoth
flaws
lw
of
a fibre
ir
would break in the region of mnximum stress (i.e. between the faces of
However, when a brittle
a matrix crack),
and no pull-out would result.
fibre
carries
fracture
at a
non-uniform
large
load
flaw in
case
fibre
fracture
along
region
of
This is
will
its
length
low
the
stress
fibre
at
point
'A'
either
or at a minor
shown schematically
occur
may
in
away
Fig.
from
flaw
4.
the
In
region
4.1
the matrix
tip increases
c'racks,
the
load
on
Friction
causing debonding.
a fibre
between
close
fibre
to
the
crack
of
flaws
along
of such material
is
well
the material up to a
in its
its
Experiments
show
that
the
stress d,
fra-tion
of
the fibrres
strength
On loading
P(a)
will
where ao is
Consider
debonded
fibre
to be non-uniformly loaded,
Fig.
with
sections of length 6x
th
The stress in the i
section increases
5.
series
secti6n
is
the matrix
at. the
point
crack.
The
of
maximum fibre
probability
of
of
stress,
failure
The n th
in
i.e.
loading
in
the plane
section
is
"ail;
simplest form:
P(a) = 1
from
length.
not
Howe'er,
the
simply
P(o. ).
highly stressed
probability
It
section has
alsQ
of
faElre
depe-
not brc..
-1.0 -
upon
occurring
the
before the
in
the
probability
th
that
flaw in the i
th
i
i.
of
from
).
segment
A more
section
This is
P(cr.)
for all
relative
probability
of
fracture
occurring
in
section
is
f, 1
Equation
P(o.)) 6x
(10)
to present an integral
form of
the cumula-
{ifkx
d/2 dx
P(o(x")) dxx
0P(a(xlf d1
F(x)
(11)
d/2
d/2
P(U(.X-)){r
f
0
1
xt
given by:
d
p
and F(x')
quently
is
the
probability
distribution
of
the
x'.
pull-out
Conselength
2
The
length of
This
is
model
p
assumes
fibre which
juqtlfied
since
that
is
the
the
flaw
small by comparison
average
entire
strength
It
spectrum
is
repeated
in
the fibres
changes
only
10-
is
4.2
For
certain
composites
the
occur because
behaviour
anticipated
or high
is
fibre stiffness,
in
debonding
is
greater than
materials
as found
in
a bundle of fibres
behaves
,/
as
with
fibre.
fibres
Although
fibres
is
does
not
This
strong
bond
fibre/matrix
fibre reinforced
large
single
carbon
--7
of
systems.
not possible,
but instead
composite,
the
In
bundle
fibres)
still
has
a variable
a Weibull
modulus
about
3.5
times
larger
The
stress
distribution
in
the
than
the
single
fibre
znd
bundle
is
similar
to
that
in
the
debonding process.
Glass
and
debonds
If
Kevlar*
then
the
should
bundle
and pull-out as a
predicted
The
of
process
this.
However,
away
intact
may
therefore
from
are made.
if
only
the matrix
composite;
analysed
be
controlled
by the
fracture
small piece
to do.
do
is
this
using
In general,
is
the bundle
crack
plane
what CFRP is
equation
(11)
when
4.2.1
*Although Kevlar
is
polymeric
fibre,
it
appears
Kevlar
49 and carbon
to behave as a brittle
material.
In the absence of any detailed information, the teibull distriis
bution (with a Weibull modulus equal to that of glass and carbon)
used to characterise the fibre stLength.
/
-
l1
(Grafil
in
EX-AS)
order
surface
to
verify
of a
individual
pull-out
the carbon
a scanning
above predictions.
unidirectional
fibre
By contrast;
the
in
or
(0/90]
with
Figure
or
fibre reinforced
no
'I/
are
in
agreement
variations
with
in
microscope
shows
Glass
matrix
and
between
epoxy shows a
laminate.
little
electron
the
fracture
Zcvlar
the
show
fibres.
the debonding
(SE!4)
behaviour
These
predicted
in
bond
4.3
P(a)
is
(eqn.
9)
has
been
distribution is:
OWx)
The
integral
aP
(aP
(equation
ad) e
11)
evaluated
numerically
for
various
4.3.1
for
fibre
strength
distribution.
The
average
of
lower modulus
the
Weibull
9
0
= 0.24
I'2
0.08 mm
2.2 0.42
This distribution
7?
is
shown
in
Fig.
7 and is
-12 -
comparcd
eqn.
using
(11),
Good agreement is
SIof
typical
E-glass/epoxy
which is
in
Table 2.
intuitively correct
By comparison,
listed
at small pull-out
Sexcept
lengths.
pull-out length
properties
since the
stress
maximised)
is
predicts
is
at Z
p
0,
of zero
length pull-outs.
4.3.2
[8].
Charac-
t=
0.47
0
M
1.9
0.03 m
o.i
This distribution is
from eqn.
(11)
in Fig.
8,
shown
strain
noted
in
of 3%.
Section
are
evident
in
shape
although
of the
agreement
4.4
of
and
the
bundle
bility
cumulative
pull-out
distribution
probability
cases.
is
However,
composite
has
beeor
properties
on
and
required.
the
and
of
an
position
between
-13-
\I
often
both
individual
the complete
average
value
fibre
probaof
the
shape
for
calculations
time-consuming
distributions
of
the
distribution
1.
4.4.1
any
in
parameters
the
Changes
length.
In
pull-out
values
in
distribution
the flaw
in most of these
is
affected
or stress
parameters
by
distributions
the
which
particular,
length
changes
Figure 9 shows
Weibull modulus,
using
the
(11),
which-reflect
fibre.
debond
eqn.
are
it
otherwise
should
be
typical of
noted
that
an
the
E-glass/epoxy
distribution
composite.
is
relatively
S4.4.2
/ i
S/
*1
several
Kevlar
the
fibre
parameters
debonn
vary.
length,
kd
The average
(as
calculated
pull-out length
eqn.
6)
when
and
6.8
stress,
4.4.3
is
lengths
to changring
Gl,
the debo~id
11
shows
typical
high
similar
fibre misfit
strain.
variation
strength
for
carbon
changes
as
noted
Li
using
14
in
between
fibre
of
ccr%,posite.
fibre
the
pull-out
strength,
previous
and
debond
There
radius
section,
is
a
and
changes
an
approximate
relationship
< Id < 12 mn)
may
be
found
in
the
Neverthe-
region
to an accuracy of 20%,
0.22
mm <
namely:
pd
p
35
/
5
SSU.MMARY
The
energy
of debonding
absorption
and
pull-out.
in
composites
These processes
study
fibre
shows
and
that
bundle
two
have
been
on
the
studied
length
to enable
types
debonding.
dependent
is
of
deboriding
Debond
are
lengths
possible,
have
been
namely
measured
result
of
otress,
the
proposed
predicting
two
types
of
probability
debonding
of
(single
fracture
fibre
and
under
sites.
As
bundle),
two
Acknowledgements
The authors
M F Ashby.
Engineering
wish
One of us
Research
to acknowledge
(JKW)
acknowledges
Council in
the
15 -
discussions
the support
form of a research
-.
helpful
with Professor
of the Science
and
studentship during
f
References
1
Kelly,
Kaelbe, D Uf,J.
Greszczuk,
Lawrence,
Takaku,
Wells,
Harris,
B, J. Mater.
10
Harlow,
0 G and Pheonix,
11
Beaumont,
A, Proc.
Roy.
Soc.
Adhesion,
P J,
J.
Mater.
A and Arridge,
J K, PhD dissertation,
P W R, J.
I
it
Ii.
S~~pwrb/r;not"2
S~13
Mater.
Sci.,
Phys.
D:
Appl.
Phys.,
6, (1973),
September-1982
173
Comp. Mater.,
P D, J.
(2978)
2197
Cambridge University,
S L, J.
13,
42
7 (1972),
13 (1978),
P W R and Anstice,
'"I
Sei.,
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R G C, J.
03 84
A282 (1964)
\~
/ *
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2619
2038
l/
Figure Captions
1
210 GPa,
and G 2 .
200 Jm-2
Pull-out in
plastic
10
(a)
glass,
(Parameter varied
o,
(b)
of;
+,
co; x, rf;
and A,
glass,
G])
11
LI
I!
/
Pre-existing
notch
Fibres
)c
d/
"f
i -.
ill
Pull-Out
Fibre fracture
-II
'U-
Fibres debonding
2000
Outwater and
8
Murphy
0l
."
rI
Takaku and
Arridge
1000
,I
500
WIRE RADIUS 9jm)
I
1000
,Ii
a x)=O.- (CrP-adO
c\
UP
.,
,
T
POSITION
XI
\Li
S.
Debonded [ength
Frction
he e,
FIBRE STRESS
FIBRE STRENGTH
FIBRE STRESS
.1A
Tar
El
<
2
cOP
-1
.4'..
I,
/1
-
,/,1
i.A
I
'h
!!j\/IK;
I.,
...
.4..
A
'S
.'*'
f
I
'1
L.
.4
I-
-t
-
.......
....
GLASS
a05
Thec.ry-=.
.,.Avrc,
best-fit Weibui[
distribution, to data
0.5
PULL-OUT LENGTH (mm)
I'-
f,-J
i\ICARBON
.ca
Theory
0
CL0
-5
Hw
D
0
,1
1-5
PULL-OUT LENGTH (mm)
-0
1~
m101
05
0.5
11-75
2-0
2-25 Gpa
iii
S10
LL
2-0
,/
Io
I<
rf6
S~
1*o
Icr_
K
H
--.
,! !
.i
I
I:i
2.0
...........
IGLASS
I4
0-70
p
-J
0-50-4-
-#
tI
*i
DEBONO
LENGTH (mmr)
~KEVLAR 49
-0.7E
x
I-.
~01
CL
0.2
0.1-
2j0312
DEODLNGH(m
-.
CARBONI
E 0-4-20
p =Ld/35
-20
A
D
A
0
0-2-
~O.1
-,
I1
fBUNDLE
01
10
12
14