Proprieta 1butene

CRITICAL PROPERTIES AND ACENTRIC FACTOR

MW
TF
FORMULA NAME
g/mol K
Zc
OMEGA
C4H8
1-BUTENE
56.107 87.80
0.276 0.187
HEAT CAPACITY OF GAS
Cp = A + B T + C T^2
FORMULA NAME A B C D
C4H8 1-BUTENE 24.915

- ORGANIC COMPOUNDS
TB
TC
PC
K
K
bar

VC
RHOC
cm3/mol g/cm3

266.90 419.59 40.20

239.9

0.2338

- ORGANIC COMPOUNDS
+ D T^3 + E T^4 (Cp - joule/(mol K), T - K)
E TMIN TMAX
2.0648E-01 5.9828E-05 -1.4166E-07 4,7053E-ll 200 1500

HEAT CAPACITY OF LIQUID - ORGANIC COMPOUNDS

Cp =A+BT+CT^2 +DT^3 (Cp - joule/(mol K), T - K)
FORMULA NAME A B C D TMIN TMAX Cp @25C
C4H8 1-BUTENE 74.597 3.3434E-01 -1.3914E-03 3.0241E-06 89 378 130.74
HEAT CAPACITY OF SOLID - ORGANIC COMPOUNDS
Cp = A + B T + C T^2 (Cp - joule/(mol K), T - K)
FORMULA NAME A B C
TMIN TMAX Cp@25C Cp@TMIN Cp@TMAX
C4H8 1-BUTENE -11.985 1.1487E+00 -3.5829E-03
40
88 ------- 26.231 61.263
ENTHALPY OF VAPORIZATION - ORGANIC COMPOUNDS
HVAP = A (1 - T/Tc)^n (HVAP - kjoule/mol, T - K)
FORMULA NAME A Tc n TMIN TMAX Tb HVAP@Tb
C4H8 1-BUTENE 33.390 419.59 0.393 87.80 419.59 266.90 22.44
ENTHALPY OF FUSION - ORGANIC COMPOUNDS
MW TF HFUS@TF
NO FORMULA NAME g/mol K kjoule/mol kjoule/kg BTU/lb
C4H8 1-BUTENE 56.107 87.80 3.848 68.563 29.491
VAPOR PRESSURE - ORGANIC COMPOUNDS
log10 P = A + B/T + C log10 T + D T + E T^2 (P - mm Hg, T - K)
FORMULA NAME A B C D E TMIN TMAX
C4H8 1-BUTENE 27.3116 -1.9235E+03 -7.2064E+00 7.4852E-12 3.6481E-06 87.80 419.59
DENSITY OF LIQUID - ORGANIC COMPOUNDS
density = A B ^(-(1 - T/Tc)^n) (density - g/ml, T - K)
FORMULA NAME A B n Tc TMIN TMAX density @ 25 C
C4H8 1-BUTENE 0.23224 0.26630 0.28530 419.59 87.80 419.59 0.588
SURFACE TENSION - ORGANIC COMPOUNDS
sigma = A (1 - T/Tc)^n (sigma - dynes/cm, T - K)
FORMULA NAME A Tc n TMIN TMAX sigma@25C
C4H8 1-BUTENE 56.000 419.59 1.2341 87.80 419.59 12.12
ENTROPY ANO ENTROPY OF FORMATION OF GAS - ORGANIC COMPOUNDS

Molecular Weight
Entropy of Formation
FORMULA NAME
g/mol
Sf@ 298 K, joule/(mol K)
C4H8
1-BUTENE
56.107
-239.577

Entropy
S @ 298 K, joule/(mol K)
307.83

ENTHALPY OF FORMATION OF GAS - ORGANIC COMPOUNDS

Hf=A+BT+CT^2 (Hf - kjoule/mol, T - K)
FORMULA NAME A B C TMIN TMAX Hf@298K Hf@500K
C4H8 1-BUTENE 21.622 -6.5456E-2 3.6902E-5 296 1000 -0.13 -11.16
GIBBS ENERGY OF FORMATION OF GAS - ORGANIC COMPOUNDS
Gf=A+BT+CT^2 (Gf - kjoule/mol, T - K)
FORMULA NAME A B C TMIN TMAX Gf@298 K Gf@500K
C4H8 1-BUTENE -1.692 2.3442E-01 3.1582E-05 298 1000 71.30 123.42
VISCOSITY OF GAS - ORGANIC COMPOUNDS
ngas = A + B T + C T^2 (ngas - micropoise, T - K)
NO FORMULA NAME A B C TMIN TMAX ngas@25C ngas@TMIN ngas@TMAX
C4H8 1-BUTENE -9.143 3.1562E..o1 -8.4164E-05 175 800 77.48 43.51 189.49
VISCOSITY OF LIQUID - ORGANIC COMPOUNDS
log10 nliq = A + B/T + C T + C T^2
(nliq - centipoise, T - K)
FORMULA NAME A B C D TMIN TMAX nliq@25C nliq@TMAX
C4H8 1-BUTENE -4.9218 4.9503E+02 1.4390E-02 -2.0853E-05 160 420 0.150 0.042
THERMAL CONDUCTIVITY OF GAS - ORGANIC COMPOUNDS
kgas=A+BT+CT^2 (kgas - W/(m K), T - K)
FORMULA NAME A B C TMIN TMAX I kgas@25C kgas@TMIN kgas@TMAX
C4H8 1-BUTENE -0.00293 3.0205E-05 1.0192E-07 225 600 0.01514 0.00903 0.06646
THERMAL CONDUCTIVITY OF LIQUID - ORGANIC COMPOUNDS
log10 kliq = A + B [1 - T/C]^(2/7) (kliq - W/(m K), T - K)
FORMULA NAME A B C TMIN TMAX kliq@25C kliq@TMIN kliq@TMAX
C4H8 1-BUTENE -1.6539 0.9786 419.59 88 399 0.1078 0.1809 0.0222
EXPLOSION LIMITS IN AIR, FLASH POINT, ANO AUTOIGNITION
POUNDS
Lower Exploslve Limit
Flash Point
Autoignition Temperature
FORMULA NAME
Code
LEL,vol%
Code
F
Code
F
C4H8
1-BUTENE
1
1.6
1
-110
1
723
ENTHALPY OF COMBUSTION
Enthalpy of Combustion
FORMULA NAME
C4H8
1-BUTENE

- ORGANIC COMPOUNDS
@ 77 F
State kjoule/mol
gas
2541.2

TEMPERATURE - ORGANIC COM

Upper Explosive Limit
UEL,vol%
9.3

kjoule/kg
45292.0

BTU/lb
19475.6

COEFFICIENT OF THERMAL EXPANSION - ORGANIC COMPOUNDS

Bliq =a (1-T/Tc)^m (Bliq -1/C, T - K, densityliq - g/cm3)
FORMULA NAME a Tc m TMIN TMAX Bliq@25C density@ 25 C
C4H8 1-BUTENE 8.9970E-04 419.59 -0.7147 87.80 398.61 2.1820E-03 0.588