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Based on
Bransden and Joachain: Physics of Atoms and
Molecules
and
Goldstein: Classical Mechanics
09.11.2013
Lagrange equations
d
dt
L
ri
L
=0
ri
i = 1, 2, ....
For conservative systems, i.e. with usual forces from potential energy
L(ri , ri , t) = T (ri ) V (ri )
but the Lorentz force depends on velocity. Lagrange function L(ri , ri , t) must
be modified.
Lorentz force
1
F = q E + [v B]
c
With and A the scalar and vector potentials
E =
1 A
c t
B=A
With only the scalar potential (r, t) the Lagrange function would be
L(r, r , t) =
m
r r q(r, t) =
2
1
m v2 q(r, t)
2
1
q
m v2 q(r, t) + v A(r, t)
2
c
=0
i = 1, 2, 3
dt ri
ri
This is because the term v[ A] can be expressed without vector products.
3
= vx
+ vy
+ vz
dt
t
x
y
z
Take now x-component of v [ A]
Ay Ax
Ax Az
vz
{v [ A]}x = vy
x
y
z
x
and now re-arrange - adding and subtracting (and compare with above)
vx
Ax
Ay
Az
+ vy
+ vz
x
x
x
vx
Ax
Ax
Ax
vy
vz
x
y
z
dAx Ax
(vx Ax + vy Ay + vz Az )
+
x
dt
t
dA A
+
dt
t
= 0 i = 1, 2, ....
dt ri
ri
1
q
m r 2 q(r, t) + r A(r, t)
2
c
q
q
m r + A
r L = qr + r (r A)
c
c
L(r, r , t) =
r L =
d
(r L) (r L) = 0
dt
L
ri
p = r L
H = r p L
q
1
m r 2 q + r A
2
c
p = r L
p=
m r +
q
A
c