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Cooling curves
Jason Pechardo
Mary GericcaDol
I. INTRODUCTION
A phase diagram is a chart used in various fields of
science and engineering that shows the relationship of
temperature and all the thermodynamically distinct phases
of the substance of interest. Moreover, it is highly helpful as
it provides information about the melting, solidification,
casting and other physical and thermal phenomena of the
material [1].The phase diagram also shows the eutectic
temperature for a mixture of two or more substances. The
eutectic point is important as it shows the composition and
lowest temperature for a mixture to completely melt.
As the phase diagram is essentially a cooling/heating
curve for a mixture of a number of component substances, it
is helpful that a similar curve be observed for each
component as a pure substance. Figure 1 shows the cooling
curve of pure lead (Pb). The horizontal region at 327C
describes the solidification of the liquid Pb. In this region,
the cooling is counterbalanced by the heat release upon
solidification.
Pechardo, J., Dela Merced, M.S., Dol, M.G., Del Rosario, M.A.J.V. (2015)
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400
350
300
250
200
150
100
50
0
0
100
400
B. Procedure
300
A. Materials
In this experiment, the alloy was prepared from Pb and
Sn metal samples. For the 90%-10% Pb-Sn alloy, 9 g of Pb
was weighed and mixed with 1 g Sn. 8 g Pb and 2 g Sn were
mixed for the 80%-20% composition, 6 g Pb and 4 g Sn for
the 60%-40%, 4 g Pb and 6 g Sn for 40%-60%, and 2 g Pb
and 8 g Sn for the 20%-80% composition. The mixtures
were placed in a crucible and heated with a Bunsen burner
until melting.
200
Time (s)
Pechardo, J., Dela Merced, M.S., Dol, M.G., Del Rosario, M.A.J.V. (2015)
400
350
300
250
200
150
100
50
0
0
100
200
Time (s)
300
400
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350
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250
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Sn (%)
Melting
Temperature(C)
Eutectic
point(C)
10
304
183
20
268
181
40
243
187
60
212
189
80
252
189
150
100
50
0
0
200
Time (s)
400
600
Temperature
350
300
250
200
150
100
50
0
0
150
10 20 30 40 50 60 70 80 90 100
% Sn
100
50
0
0
200
Time (s)
400
600
200
Time (s)
400
600
Pechardo, J., Dela Merced, M.S., Dol, M.G., Del Rosario, M.A.J.V. (2015)
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IV. CONCLUSION
In this experiment, the phase diagram of Lead-Tin (PbSn) system of varying compositions was derived from the
different cooling curves that were determined using a
thermocouple. Results showed that most of the cooling
Pechardo, J., Dela Merced, M.S., Dol, M.G., Del Rosario, M.A.J.V. (2015)
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Appendix
Pechardo, J., Dela Merced, M.S., Dol, M.G., Del Rosario, M.A.J.V. (2015)
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