Aiits 2016 HCT Vii Jeem Jeea Advanced Paper 1 Solutions Solutions

1
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AIITS-HCT-VII (Paper-1)-PCM (Sol)-JEE(Advanced)/16
JEE(Advanced)-2016
ANSWERS, HINTS & SOLUTIONS
HALF COURSE TESTVII
(Paper - 1)
Q. No.
PHYSICS
CHEMISTRY
MATHEMATICS
1.
2.
3.
4.
5.
6.
7.
8.
A, C
A, B, D
A, B, C
9.
A, C
A, B, C, D
A, C
10.
B, C, D
A, B, C, D
A, B, C, D
11.
A, B, C, D
A, B, C, D
A, B
12.
13.
14.
15.
16.
1.
(A p); (B q); (C
s); (D p)
(A s); (B p); (C
q); (D r)
7
(A t); (B s); (C
p); (D q, r)
(A q, r); (B p); (C
s); (D t)
7
(A q); (B r); (C
p) (D s)
(A s) (B p); (C
q); (D r)
4
2.
3.
4.
5.
6.
1.
2.
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website: www.fiitjee.com
2
Physics
PART I
Hints & Solution

SECTION A
1.
2.
Pressure in the air inside the column of mercury is equal to the weight of mercury over the air divided
by the internal cross sectional area of the tube. When the temperature increases, the weight of the
upper part of the mercury column does not change. That is why the pressure in the air is also
constant. For the isobaric process, the change in volume is proportional to the change in temperature.
The same is true for the lengths of the air column.
lT
l
T
l = 0 = 11 cm.
l0 T0
T0
v w u
Frequency received by car B is f1
f
v w u
Now the car B will be treated as a source of frequency f1
wavelength of reflected sound received by the driver of car A is
v w u v w u v w u
f1
v w u f
330 5 25 330 5 25 31 m
36
330 5 25 300
'
3.
Hence (B) is correct

vmax
F
F
a 0 e Kx v dv 0 e Kx dx
m
m0
0
v max 2
F
F
0 K max 0
2
mK
K
4.
Let initial location of center of mass is 0 then find location of cm

(90 cm)(5 cm) (10 cm)(45)
Xcm =
= 9 cm
(90) (10)
5.
As escape velocity is
6.
The power developed by the man = power required in the reference frame of the man
= Force velocity = m(g + a).(h/t)
Hence, (A) is correct.
7.
x + y = 100
Heat lost = Heat gained
5
5
y 3.36 10 = x 21 10
y
21
=
x
3.36
336y = 21x 100
Using (1) & (2)
210000
y =
= 86.21
2436
2 times of orbital velocity.
(1)
(2)
3
8.
9.
10.
For a plane wave intensity (energy crossing per unit area per unit time) is constant at all point
For spherical wave
p
1
I=
2
2
r
4r
2
Acceleration of block is = 10 m/s
1 2 1
4
Displacement s = at =
10
= 2m
2
2
10
Tension in the string is 40 N
N 20 N
N = 50 20 = 30 N
Limiting friction force = N = 12 N and applied force in horizontal direction
is less than the limiting friction force, therefore the block will not slide.
For equilibrium in horizontal direction, friction force must be equal to 5 N.
5N
mg = 50 N
From the top view, it is clear that = 37 i.e. 127 from the x-axis that is
the direction of the friction force. It is opposite to the applied force.
Contact force =
N f
925 N
53
3i 4j
11.
P = 3 V3 , for ideal gas

PV = nRT
(A) relation between V and T
nR
V (3V3 ) = nRT V4 =
T
3
(B) Relation between P and T
PV = nRT
V4 T
1/ 3
12.
So
P
P = nRT P4/3 T
3
(C) For expansion
V increases
work-done : positive
internal energy : increases
Hence, heat will have to supplied to the gas.
(D) As T V4
with increase in temperature, volume increases
Hence work done is positive.
2 2
So = 0.8 and effective length of air column = 0.99 + 0.01 = 1m.
0.8
l = 5 , so five half loops will be formed

4
= 5 so second overtone
4
4
13.
Pex = B
d
dx
2
2
= (5 105) (0.1 103 )
sin
(y + 1cm) cos 2(400) t
0.8
0.8
2
= (125 N/m2) sin
(y + 1cm) cos 2(400t)
0.8
14- 16.
m 2
m 2
m 2
. .v 0
v1
4 3
3
4
3
3v 0
8
2v 0
3
4
2
v1
v0
3
v
v1 0
2
mg
1
1 cos I2
2
2
SECTION C
1.
2.
3.
0.16 10 6
0.16 106
3
6
=
1000 4.2 80 10
1000 2.3 10 = 7 watt.
60
60
h
h
T N > 0
2
4
N
T
>0
2
Mg
Tmin =
2
2
a = g/2 = 5 m/s .
mg T = m(g/2)
Mg
g
= m
mg
2
2
Mg mg
=
2
2
m
=1
M
The acceleration of center of mass of the system
m a m2 a 2 m3 a 3
acm = 1 1
m1 m2 m3
The net force acting on the system
= m1a1 m2 a2 m3 a3
a3
a2
a1
A
m1
m2
m3
Fnet = (m 1 a1 + m 2 a 2 m 3 a 3)
1
= (1)(1) (2)(2) (4) N = 3 N.

2
5
4.
Rmax
u2
g
2
So, maximum area covered = Rmax
.
5.
u4
4m2
g2
Velocity of block w.r.t. ground
V1G = 20i 15j
V1P = 15j
Velocity of block w.r.t. ground after 10 sec. is zero (since block will stop w.r.t. board after 5 sec.)
V '1P = V1P gt j 0 (t = 5 sec)
6.
V '1G = 20 i
Area under graph =
v dx t
6
Chemistry
1.
2.
PART II
Molecular weight
= 98/1 = 98
Re placed H
He
B :
He
C :
+
2+
Sr , Ba are relatively easily formed in order to achieve completely filled valence shell orbitals.
2
3.
Ag NH3
K c 1
Ag NH3
2
K sp NH3
1
K sp Ag Cl
K c Ag NH3 Cl
4.
XeOF 2 :
Xe
Hence,
or
5.
h
6.626 10 34
= 3.321 1010 m
31
6
mv
9.1 10 2.19 10
CH3
6.
H3C
CH2 C
CH3
HC
CH CH3
3
HBr / H2 O2 or HO _ Br H H2O Br
CH2 C
CH CH3
Br
HBr
CH3
H3C
CH2 C
H
7.
CH CH3 Br
Br
1
O2 g
CO2 g
2
1
G0 G0 CO2 G0 CO G0 O2 = 394.4 137.2 0 = 257.2 kJ

2
CO g
Spontaneous (ve sign)

But G0 H0 TS0
257.2 = H0 298 K 0.094
7
0
H 285.2 kJ exothermic ( ve sign)
8.
Allyl carbocation is less stable than benzyl carbocation due to less number of resonating structures.
9.
In (A) Cl and O
In (B) S and O
In (C) only O
In (D) P and O
10.
OH
Br
(A)
11.
(B)
(C)
(D) CHI3
(E) CH3COO
(E) CH3COOH
The balanced equation is

K 2Cr2O7 14HCl
2KCl 2CrCl3 7H2O 3Cl2
14 36.5 g
294 g
3 71g
Mass of K2Cr2O7 =
96
61.3 58.848g
100
30
320 1.15 110.4g
100
Hence, K2Cr2O7 is limiting reagent.
Mass of Cl2 produced = 42.63 g
M
Also equivalent of K2Cr2O7 =
6
7M
Equivalent of HCl =
3
Mass of HCl =
16.
All the given molecules are cyclic isomers with molecular formula = C5H10
Number of pairs of diastereomers
= total number of pairs of stereomerms number of pairs of enantiomers = 3C2 1 = 2
CH3
H C
3
is th missing cyclic isomer.
SECTION C
1.
OH
OH
OH
OH
HO
HO
HO
OH
OH
OH
OH
HO
OH
OH
x = 14 so x/2 = 7
8
2.
O Pure
Cr
Cr
O
O
O
As these two does not participate in resonance.
3.
It will produce most stable free radical.
4.
meq of KOH = 20 meq = meq of acid

20
0.45
n factor
1000
90
n-factor for acid = 4 = number of replaceable proton.
5.
[H2CO3] in blood = 4M
[NaHCO3] = 10 M
Volume of blood = 10 mL
Let the volume of NaHCO3 used = x mL
4 10
H2 CO3 in mixture x 10
NaHCO3 in mixture
pH pK a log
10 x
x 10
salt
acid
7.4 7 log 4 log
10 x x 10
x 10 4 10
7.4 6.4 log
10x
40
10x
10x
1 so
10
40
40
x = 40 mL
Hence x/10 = 4
2NH3 g
N2 g 3H2 g
log
6.
0
0
2
Ratio of initial and final volumes = 4/2 = 2
9
Mathematics
PART III
SECTION A
1.
2.
3.
4.
C
Since O(0, 0) does not lie on 11x + 7y = 9
hence it is the equation of AC,
2 7
M
7x+2y=0
solving OC with AC we get C ,
3 3
5 4
A
solving OA with AC we get A ,
3 3
A
(0, 0)
1 1
4x+5y=0
hence M = mid point of C & A ,
2 2
hence equation of OB y = x.
The curve remains unchanged when y & x are interchanged.
1
2
2
Let the circle be x + y + 2gx + 2fy + c = 0, if mi , lies on it then
mi
4
3
2
m + 2gm + 2fm + cm + 1 = 0 and m 1 m 2, m 3, m 4 are its roots.
1 1 1
2 2 1 ... 2 r 1
r

2 r
Coefficient of x is

r!
r
5.
6.
7.
8.
11x+7y=9
1.3.5... 2r 1 1 1 2r 1.3.5... 2r 1 2r ! r
=
.
2
r!
r!
r!r!
2r
1
1 3 9
27
2

...
2.
3
2 8 32 128
1
4
x 1
1 a
1 a 1 a2 1 a4
1 a
i.e. 1 ax 1 1 x 8
(multiply by (1 a) on both the sides)
x = 7.
ABC can speak in 10C3 1 ways
other 7 in 7! ways
10!
so totally 10C3 . 7! ways
.
6
Putting x = in the equation,
0 = a0 + a1 +a22 +a3 + . . .
Putting x = 2 in the equation,
2
0 = a0 + a1 +a2 + a3 + . . .
Putting x = 1 in the equation,
3n = a0 + a 1 +a2 + a 3 +
...
adding (1), (2) and (3),
n
3 = 3(a0 +a3 +a6 + . . . .)
a0 + a3 +a6 + . . . . = 3 n-1 (option C)
subtracting (2) from (1),
2
0 = ( - ) (a1 a2 + a4 a5 + . . . )
Since - 2 0 , a1 +a 4 + a7 +. . . = a2 + a5 +a8 +
.... (1)
.... (2)
.... (3)
.... (a)
...
. . . (4)
10
Also from (3) (a), a 1 + a2 +a4 +a5 + . . . . = 3n 3 n-1 = 2.3 n-1

. . . .(5)
n-1
From (4) and (5) , a1 +a 4 + a7 +. . . = a2 + a5 + a 8 + . . . = 3 = a0 + a3 + a6 + . .
9.
Clearly the inscried triangle is equilateral.

2
z2
i
i
z z0
z z0
2
e 3, 3
e 3
z1 z0
z1 z0
z2 = -1 +i(2 +
3 ) and z 3 = -1 + i(2 -
3)
z0(2i)
z3
10.
b is the H.M. of a and c and their G.M. = ac

G.M > H.M
ac > b
n
n
n
n
And A.M. of a and c > G.M. of a and c
an c n
an c n
2
an c n 2
11.
12.
ac
2bn
Put n = 100, 3, 5, 2
A
A
A
A
A
A
=sin
cos
if sin
cos
1 sin A = sin cos
2
2
2
2
2
2
A 5
A
ie

0 .
4 2
4
2 2
6 can be written in the following ways using 1s and 2s only.
Six 1s in 1 way
5!
Four 1s and one 2s in
= 5 ways
4!
Two 1s and two 2s in
13.
z1(2 +2i)
4!
= 6 ways
2! 2!
Three 2s in 1 way.
So f(6) = 1 + 5 + 6 + 1 = 13.
We have f(6) = 13, so f{f(6)} = f(13).
Now 13 can be expressed in the following ways:
Thirteen 1s in 1 way
12!
Eleven 1s and one 2s in
= 12 ways
11!
Nine 1s and two 2s in
11!
= 55 ways
9! 2!
Seven 1s and three 2s in

Five 1s and four 2s in
9!
= 126 ways
5! 4!
Three 1s and five 2s in

One 1s and six 2s in
10!
= 120 ways
7! 3!
8!
= 56 ways
3! 5!
7!
= 7 ways.
6!
f(13) = 377.
1416. x y + 2(1 + ) = 0 (x + 2) (y 2) = 0 pass through ( 2, 2)
x y + 2(1 ) = 0 (x 2) (y 2) = 0 pass through (2, 2).
11
Clearly these represent the foci of ellipse, so 2ae = 4.

2
The circle x + y 4y 5 = 0 x + (y 2) = 9 represents auxiliary circle thus a = 9 e =
2
and
3
b = 5.
SECTION B
(A). |a + ib| |z| = |z| |(a 1) + ib|
1
1
2
2
2
a 1 b2 and a + b =
2
2
1
1 2a = 0 a =
2
1
1
2
and b =
b=
4
2
a b = 0.
(B) We must have either
6a > 2a . 3b or 6b > 2a . 3b.
If b = 0, then 6a > 2a a = 1, 2, 3, 4.
b
If a = 0, then 6b > 3 b = 1, 2
suppose a > 0 and b > 0 if 6a > 2a . 3b
thus 6 a > 2a . 3 so 2a > 2a (not possible)
a
b
b
similarly if 6b > 2 . 3 than 3b > 3 not possible
only solutions are 2, 4, 8, 76, 3, 9.
z
z
(C). Re 0, 1 , Im 0, 1
4
4
means that if z = a + ib than a, b (0, 4)
4
4a
4bi
Now
a ib a2 b 2 a2 b 2
a 2 b2
0 < a, b <
4
(a 2)2 + b 2 > 4 and a2 + (b 2)2 > 4
so we want area inside the square and outside the two circles
area = 16 4 + (2 4)
12 2.
(D). 3x + 4y + z = 5
let a 3i 4j k
b xi yj zk

a b a b
5
9 16 1 x 2 y 2 z2
26 x 2 y 2 z 2
2
25
26
(A)
sin cos x = sin(cosx) 0

2n cosx (2n + 1)
0 cosx 1
x 2n , 2n .
2
2
(B)
cos sin x
cos(sinx) > 0
12
sin x x R.
2
2
(C) tan( sinx)
sinx
2
1
sinx
2
x n
6
x R n .
6
(D) ln(tanx)
tanx > 0
0 < x<
2
n < x < n .
2
SECTION C
1.
2.
4.
1
log 5
2
1
4
1/ 4 1
5 log5
4

1 2
5
1
2
7
c
7
, 2 2
2
2
4
7
7 49
7
i.e. i.e.
2x c = 6.
4
2 4
4
The given expression can be written as
k3
= k 3 sin3 A cos B C
sin2 A sin 2B sin2C
2
= k 3 sin A sinB sin A cosB cos A sinB
x
5.
6.
= k 3 sin A sinB sinC k 3 3 sin A sinB sinC 3 ab c .

Line L passes through the centre of second circle.
a 1 1
1 b 1 0 a(b 1)(c 1) (b 1)(1 a) (c 1)(1 a) = 0
1 1 c
a
1
1
0.
1 a 1 b 1 c

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1

AIITS-HCT-VII (Paper-1)-PCM (Sol)-JEE(Advanced)/16

Hints & Solution

Hence (B) is correct

Let initial location of center of mass is 0 then find location of cm

2 times of orbital velocity.

P = 3 V3 , for ideal gas

l = 5 , so five half loops will be formed

The acceleration of center of mass of the system

The net force acting on the system

= (1)(1) (2)(2) (4) N = 3 N.

Velocity of block w.r.t. ground

V1G = 20i 15j

V '1P = V1P gt j 0 (t = 5 sec)

Area under graph =

G0 G0 CO2 G0 CO G0 O2 = 394.4 137.2 0 = 257.2 kJ

Spontaneous (ve sign)

The balanced equation is

is th missing cyclic isomer.

It will produce most stable free radical.

meq of KOH = 20 meq = meq of acid

7.4 7 log 4 log

7.4 6.4 log

Also from (3) (a), a 1 + a2 +a4 +a5 + . . . . = 3n 3 n-1 = 2.3 n-1

Clearly the inscried triangle is equilateral.

b is the H.M. of a and c and their G.M. = ac

Seven 1s and three 2s in

Three 1s and five 2s in

Clearly these represent the foci of ellipse, so 2ae = 4.

The circle x + y 4y 5 = 0 x + (y 2) = 9 represents auxiliary circle thus a = 9 e =

sin cos x = sin(cosx) 0

= k 3 sin A sinB sinC k 3 3 sin A sinB sinC 3 ab c .

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