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03.09.2013
M. Nur Alam
Content
pH test
Test Method
Fail properties analysis
Solution
pH Value
pH:
the negative logarithm of the effective hydrogen ion concentration or
hydrogen ion activity in gram equivalents per liter used in expressing
both acidity and alkalinity on a scale whose value runs from 0-14
with 7 representing neutrality, numbers less than 7 increasing acidity
and numbers greater than 7 increasing alkalinity
pH = - log [H+]
pH value
Less than 7
Acidic
Equal to 7
Neutral
Greater than 7
Alkaline
pH Value
Human skin pH value is between 4.5 to 6.0. The slightly acidic pH can
protect skin against bacteria and virus attack.
New born baby has a skin pH closed to neutral (pH 7.0), but its quickly
turn acidic. When people become older, the skin gradually becomes
neutral and it cannot kill bacteria as before.
Residual chemicals in textile/leather give the pH value.
Too high or low pH value of textile/leather articles will cause
IRRITANT TO SKIN.
units.
Analytical balance capable of weighing to 0.01g
Hot plate
Water Chiller / water bath
100 mL Graduated Measuring cylinder
Glass rod
QC preparation
1. Potassium hydrogen phthalate (CRM)
2. Sodium tetraborate decahydrate (CRM)
METHOD(AATCC 81)
Preparation of the aqueous extract:
(i) Boil 250 mL of water in a 400 mL beaker at a moderate rate for 10 min.
Note: Begin timing when the water starts to boil.
(ii) Immerse the test sample into the beaker, cover with the watch glass
and boil gently for an additional 10 min.
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METHOD(AATCC 81)
Preparation of the aqueous extract:
(iii) Allow the covered beaker and contents to cool
to the room temperature for 2 hours ( water
chiller /ice water bath can be used)
(iv) Stir the extract with a glass rod. Remove the
specimen with tweezers and allow the excess
liquid to drip back into the extract.
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Method Blank
Preparation of the method blank
Transfer 250 mL of water in a 400 mL beaker and follow the procedures
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Calibration
Calibration of pH meter
Pour in sufficient amount of the buffer solution to cover the bulb of the
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measurement.
2. Record the temperature of the extract to be measured.
3. Measure and record the pH of the method blank.
4. Rinse the pH electrode with the water.
5. Immerse the pH electrode in the aqueous extract of sample.
6. Stand the pH electrode in the extract until the pH value stabilizes.
7. Record the pH value of the extract to the nearest 0.1 pH-units.
8. If the alkali side of pH value of the extract is greater than the clients
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QUALITY CONTROL
BV maintain the below quality control parameter for pH test to ensure correct result.
QC-Buffer
QC-4,9
Method Blank
Duplicate Analysis
If any result is over or less than Client limit, recheck is performed to issue result
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Litmus paper
Litmus paper
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GYMBOREE requirement
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Weaving
processing
Yarn
Cotton
Processed Fabric
tailoring
Sizing
Printing
Finishing
Dyeing
Finished Garment
Trims
Coating
Pre-treatment
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pH
69
Suspended solids
150
BOD5 at 20 deg C
100
Sulfide (as S)
10
2100
30
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Parameters
in a unit of mg/l
6.5 9
pH
Suspended solids
100
BOD5 at 20 deg C
150
10
2100
Wastewater flow
Note: BOD limit of 150 mg/l implies only with physico chemical processing.
Sulfide, as S
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Bureau Veritas Presentation _ Date
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GER
pH
Temp
TSS
BOD
COD
Color
Foam
Hg
Cd
Pb
As
Cu
Ni
Cr
Zn
Acceptable:
Lower Limit
(GER Limit)
6.0 - 9.0
37.0 C
30 mg/l
30 mg/l
Test, Monitor and Report
Qualitative observation
Not persistent
0.01 mg/l
0.01 mg/l
0.10 mg/l
0.01 mg/l
0.25 mg/l
0.20 mg/l
0.10 mg/l
1.0 mg/l
Co
0.02 mg/l
CN-
0.20 mg/l
Bureau Veritas Presentation _ Date
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Q&A Section
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Practical session
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ICPMS
31
Digestion/wet process
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GCMS section
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LCMS section
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Fume hood
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Breakdown,
Preparation
3-> Lab
Wet process
& Analysis
Result Review
(1st stage)
4
Data
Consolidation
Report
Generation
Result Review
(2nd stage)
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Bureau Veritas Presentation _ Date
Log out
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