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400MHz Solid State NMR

Application:

Solid State Nuclear Magnetic Resonance is the widely used technique for studying the structural properties of a vast variety of materials, including amorphous and crystalline solids. This technique is based on the behavior of the magnetic moments of some atomic nuclei under an external magnetic field, which is modulated by both the surrounding nuclei and the distribution of the electronic charge around them. Typical spectra display absorption intensity values versus resonance frequencies. The position, line shape and intensity of the signals inform of the chemical environment of the studied nuclei. This information is complementary to those obtained from other more conventional techniques employed in the characterization of condensed phases.

400MHz Solid State NMR Application: Solid State Nuclear Magnetic Resonance is the widely used technique for

Detail:

Model of Instrument : Bruker AVANCE 400 MHz solid-state NMR The equipment are equipped with Broker multinuclear NMR spectrometer, CP/MAS probe, 4 mm and 7 mm with double channel, 1H and BB (frequency range 15N - 31P) Pneumatic unit, that allows to spin under magic angle up to 30000 Hz, 20000 Hz and 7000 Hz, respectively. Purchasing of the instruments was RM 1.8 million (2002) and has started to utilize on January 2003.

300MHz Liquid NMR Introduction:

The High Resolution NMR facility is a research instrument managed by Institute Ibnu Sina to provide support to magnetic resonance research related activities at the Institute and UTM. The instrument is available 24 hours per day to be used by trained researchers. The spectrometer was fully installed and commissioned in December 2002.

300MHz Liquid NMR Introduction: The High Resolution NMR facility is a research instrument managed by Institute

Detail :

Model of Instrument: Bruker AVANCE 300 MHz HR NMR SpectrometerThe instrument is a narrow bore, high resolution liquid spectrometer operating at a magnetic field strength of 7 Tesla (300 MHz for 1H observation). It is equipped with single and a tunable 5 mm quad probe with pulse field gradient coil allowing the observation of Proton, Carbon- 13, Nitrogen-15, Phosphorus-31 and Fluorine- 19 nuclei. The spectrometer is fully automated and is controlled by a Windows NT workstation interface. Spectrum print-out is done on a LazerJet plotter. Other features include a Bruker NMR Suite 2.6 Software Packages and a TOPSPIN Software Packages for off-line processing.

Function:

The instrument is a dedicated solution NMR spectrometer for structural characterization, dynamic studies and physical properties measurement of small organic, inorganic molecules including biomolecules dissolvable in water or organic solvents. Experiments that can be conducted are as follows: 1D Spectroscopy. Standard 1H, 13C, or any other nuclei specified above. 13C-

Editting for Multiplicity Discrimination (DEPT, APT etc) Relaxation Measurement, Chemical Exchange, NOE Measurement, etc2D Spectroscopy H-H Correlation:

COSY, NOESY, TOCSY H-C Correlation: HMQC, HMBC, HETCOR,