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Reliable Design of
Ammonia and Urea Plants
Authors
Pasquale Talarico
CASALE GROUP Switzerland
Andrea Scotto
CASALE GROUP Switzerland
Summary
During the design of ammonia and urea plants many aspects have to be taken into account
besides process performances. The plant reliability is a factor as important as process
performances in determining the future plant profitability. To design a reliable plant it is
necessary to take into account many aspects, such as the process mechanical design of all parts,
instrumentation, process control, and the plant layout. It is also essential to have a good quality
control in every phase of the project. This paper describes the design choices that are crucial in
order to reach the highest standard of reliability in these plants.
Reliable Design of
Ammonia and Urea Plants
During the design of ammonia and urea plants many aspects have to be taken into account besides
process performances. The plant reliability is a factor as important as process performances in
determining the future plant profitability. To design a reliable plant it is necessary to take into
account many aspects, such as the process mechanical design of all parts, instrumentation, process
control, and the plant layout. It is also essential to have a good quality control in every phase of the
project. This paper describes the design choices that are crucial in order to reach the highest standard
of reliability in these plants.
Pasquale Talarico
CASALE GROUP Switzerland
Andrea Scotto
CASALE GROUP Switzerland
Introduction
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Hydrogen Attack
The term hydrogen attack is used to indicate
several phenomena linked to the damages
caused by hydrogen. The most considerable
ones for ammonia plants are:
Nitriding
In the presence of a hot ammonia atmosphere,
above a certain temperature depending on the
type of steel, ammonia reacts with iron to form a
hard and brittle Fe-N inter-metallic layer. This
phenomenon is called Nitriding. Nitriding
develops on low alloy steels and on stainless
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ammonia
converter
and
downstream
exchangers, because they see the combined
highest temperatures and the highest ammonia
content.
Synthesis Sections
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Other Sections
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As for 316L-UG, since the introduction of 2522-2 CASALE has developed the relevant
specifications aimed to define the technical
requirements,
acceptability
criteria
and
qualification tests for base material to be used in
CASALE equipment as well as all the
requirements for welding 25-22-2. These
specifications are the result of CASALE
experience in the field of urea and are
continuously updated on the basis of the
improved experience and the technical progress.
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Stripper
The stripper is possibly the most critical
equipment in the urea process.
Carbamate Condenser
Urea Reactor
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Centrifugal Compressors
Material selection
Starting from the minimum process
requirements the compressor material
selection shall be properly checked
considering problems of corrosion (i.e. wet
CO2), but also allowable stresses. For this
last point special consideration shall be
given to impellers material. The tip speed
shall remain well inside the limits of the
applied material, of the references of the
selected vendor and of the applied
technology for the construction of the
impellers (i.e. welded, brazed or milled
from solid forgings).
Centrifugal Pumps
At least the last two of the above points (i.e.
Quality Control
and
Installation
and
Commissioning) are fully applicable also to the
centrifugal pumps.
Other key points for the pump selection are the
following:
Mechanical behavior
During the selection process the rotor
dynamic issues shall be carefully evaluated.
Quality control
The requirements for inspections and tests
shall be carefully defined during the design
phase.
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Operating point
A pump is properly selected when the
operating point will fall into the Preferred
Operating Region, in other words when it is
close to Best Efficiency Point (BEP).
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5. Electrical Design
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7. Conclusions
Piping Design
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