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POLYMETRON 9210
SILKOSTAT 9210
Marking
Products contain toxic or hazardous substances or elements.
Part Name
Hexavalent
Lead Mercury Cadmium Chromium
(Cd)
(Pb)
(Cr VI)
(Hg)
Polybrom
Biphenyls
(PBB)
Transmitter box
CPU PCB
(with battery)
Power PCB
RS 485
Profibus
PCB CAN
PCB Measure
PCB Pumps
PCB Mixer
PCB Channel
Polybrom
Diphenyls
(PBDE)
O: Indicates that this toxic or hazardous substance contained in all homogeneous material for
this part is below the limit requirement
X: Indicates that this toxic or hazardous substance contained in at least one of the
homogeneous materials used for this part is above the limit requirement
SILKOSTAT 9210
Safety Precautions
Please read this entire manual before unpacking, setting up, or operating this
instrument. Pay particular attention to all danger and caution statements.
Failure to do so could result in serious injury to the operator or damage to the
equipment.
To ensure the protection provided by this equipment is not impaired, do not
use or install this equipment in any manner other than that which is specified
in this manual.
Precautionary Labels
Read all labels and tags attached to the instrument. Personal injury or
damage to this instrument could occur if not observed.
ii
SILKOSTAT 9210
!
!
Maintenance
The integrity of electrical connections and protection instruments of the
system should be checked periodically. All necessary measures should be
taken to remedy any inadequate condition.
iii
SILKOSTAT 9210
CONTENTS
Page
1.
2.
3.
Installation .............................................................................................................................................. 13
Unpacking ................................................................................................................................................ 13
Inspection................................................................................................................................................. 13
Pre-installation ......................................................................................................................................... 13
Presentation of the analyser .................................................................................................................... 14
Positioning the canisters .......................................................................................................................... 15
Connecting the sample ............................................................................................................................ 16
Connecting the evacuation (drain) tube................................................................................................... 16
Mains power connection .......................................................................................................................... 17
RS485 connections (optional extra)......................................................................................................... 19
User signals connections ......................................................................................................................... 20
4.
Starting-up .............................................................................................................................................. 23
Reagent preparation ................................................................................................................................ 23
Reagent concentrations (by type).................................................................................................. 23
Reagent preparation (makes 2 litres) ............................................................................................ 23
Calibration solution ........................................................................................................................ 24
Positioning the canisters .......................................................................................................................... 25
Using the menu........................................................................................................................................ 27
Language programming........................................................................................................................... 28
Time and date programming.................................................................................................................... 28
Starting up the analyser ........................................................................................................................... 29
Starting a measurement........................................................................................................................... 30
5.
Analyser programming.......................................................................................................................... 31
Analyser configuration flow chart............................................................................................................. 31
User Interface .......................................................................................................................................... 32
Main display................................................................................................................................... 32
Definition of the display screen 2 (Disp2) ...................................................................................... 33
Definition of the display screen 3 (Disp3) : alarms ........................................................................ 34
Definition of the display 4 (Disp 4) : trend curve............................................................................ 35
Modification of a value ................................................................................................................... 35
Main menu ............................................................................................................................................... 36
Calibration menu............................................................................................................................ 37
Execution primary sub menu ................................................................................................. 38
Execution manual sub menu.................................................................................................. 39
Programming sub menu (automatic execution) ..................................................................... 40
Calibration parameters sub menu.......................................................................................... 42
Calibration historic sub menu................................................................................................. 42
Manual automatic calibration results sub menu.................................................................. 43
Maintenance menu ........................................................................................................................ 45
Start up sub menu.................................................................................................................. 45
Reagents refill sub menu ....................................................................................................... 46
Adjust volumes....................................................................................................................... 46
Tubes priming ........................................................................................................................ 47
Extended stop sub menu ....................................................................................................... 47
Page 1
SILKOSTAT 9210
7.
Troubleshooting..................................................................................................................................... 75
Possible sources of the problem.............................................................................................................. 75
Possible solutions .................................................................................................................................... 76
Typical measurement values during calibration....................................................................................... 78
Page 2
SILKOSTAT 9210
Page 3
SILKOSTAT 9210
1.
Figure 1
Page 5
SILKOSTAT 9210
Operation
The 9210 can analyse up to six different samples. The sample to be
analysed circulates in a fast loop permitting rapid renewal of the sample.
Adjustment of the flow is carried out with the help of a needle valve (2). At
the beginning of the analysis, the sample is introduced into the
measurement cell (4) with the help of a solenoid valve (5).
The 1st reagent is added with the pump (9). The silica contained in the
sample now reacts with the molydate and forms the silicomolybdic
complex. The reagent time is relatively long.
Oxalic acid is then added to avoid the interference of phosphates and to
intensify the colour.
The silicomolybdic complex is reduced to a blue molybdenum complex by
means of ferrous ions. A photometric measurement is carried out at the
end of the reaction.
Figure 2
Working principal
3
3
3
3
3
9
5
11
12
4
7
13
10
8
12345-
6789-
Mixing motor
Magnetic bar
Drain
Reagent pump
10 11 12 13 -
Calibration
In order to ensure correct functioning, the analyser should be calibrated
periodically. The zero is realised chemically and internally in the analyser.
The system slope is controlled in comparison to a standard solution of
known concentration.
Page 6
SILKOSTAT 9210
2.
Technical specifications
Specifications
Measurement range (two different versions) :
- 0 1000 ppb
- 0 5000 ppb
This instrument complies with the following standards :
- Immunity to
interference
- Electromagnetic emissions
EN 50081-1 et EN 50081-1
IEC61010-1
SAMPLE
Number of channels
16
Measurement cycle
Sample pressure
0.2 to 6 bar
(3 to 87 psi)
Temperature
5 - 50 C (41 122F)
Sample flow
10 to 20 l / hour
CONNECTIONS
Sample admission
tube PE 4/6
Sample evacuation
CONDITIONS OF USE
Ambient temperature
- use inside
- fluctuations 10 % of the power
supply voltage
- overvoltage category 2
- degree of pollution 2 (according
to CEI 664)
Altitude
2000 m
Relative humidity
10 to 80 %
WEIGHT
Panel analyser without canister
13 kg
65 kg
Full canisters
8 kg
Page 7
SILKOSTAT 9210
ANALYSIS
Value measured
dissolved SiO2
Measurement field
0 1000 ppb
0 5000 ppb
Repeatability
2 % or 0,5 ppb
2 % or 2 ppb
Detection limit
0,5 ppb
2 ppb
Cycle time
INPUTS / OUTPUTS
Alarms
Number : 8
Functions :
- 6 threshold relays
/ lack of sample /
active channel
- System alarm
3 contacts
- 1 warning relay
Number : 12
Remote clearance
Inhibition of samples
Outputs 4 / 20 mA
Number : 8
4/20 mA / 0/20 mA
programmable.
Galvanically insulated
Maximum charge of 800 ohms
Page 8
Transmitter
Polystyrene
IP 65
IP 54
Plexiglas
SILKOSTAT 9210
MAINTENANCE
Calibration
Maintenance
No particular maintenance is
necessary. Cleaning can be done
with a soft non-aggressive cloth.
Reagent consumption
CR 1220 (3 V)
Caution :
There are risks of explosion if the replaced battery does not
correspond to the correct model.
Do not throw away used batteries in the dustbin. Send to a
recycling centre.
TRANSMITTER
Display
Programming by menu.
Concentration of 6 samples.
Analyser status.
Alarms.
Trend curves.
Concentration historic
Calibration parameters historic
(date, slope and offset).
Page 9
SILKOSTAT 9210
A : Mains power supply cable gland, drilled 11, 5 to 10mm, 100240V, 50-60Hz, 25VA
B : Field bus cable gland, drilled 13, 6 to 12mm
C : 5 to 7 mm cable gland
* Alarm signals : 30V, 0.5A max.
* Logic inputs : Inhibition on channels 1 to 6, acknowledgement of alarm signals
* Analogue outputs : 0-20 mA or 4-20 mA
D : Samples inlets, (channels 1 to 6), QR coupling for semi-rigid tubing, 6mm
5 to 50 C (40 to 120 F), P 0.2 to 6bar (3 to 87 PSI)
E : Drain tube : silicon tubing, 12 x 17mm, at atmospheric pressure
Page 10
SILKOSTAT 9210
Figure 4
Page 11
SILKOSTAT 9210
3.
Installation
Unpacking
Inspection
The instrument has been tested and checked at the factory before
shipping, however it is advisable to carry out a visual inspection to be
sure that it has not suffered any damage. Damaged packaging could
mean the presence of damage not immediately visible. Keep the
packaging in case of complaints. For any missing parts or accessories,
please contact your distributor.
Pre-installation
Before installing the analyser, think about the following precautions:
Place the analyser close to a sample point. The sample should be
homogenous and representative. This will allow the response time to
be reduced. The temperature of the sample should be between 5 and
50C. The pressure of the sample should be between 0.2 and 6 bar
and remain relatively stable. The solution should be free of particles.
The sample lines should be in PE/PTFE/FEP ( 4 x 6 mm).
Avoid any location with a corrosive atmosphere or subject to liquid
spills.
Chose a dry and dust-free location.
The ambient temperature of the analyser should not exceed 45C. If
the temperature is below 5C, the analyser should be installed in a
heated cabinet.
Page 13
SILKOSTAT 9210
12345-
Figure 6
Page 14
SILKOSTAT 9210
Figure 7
Canister replacing
In all cases, respect the maximum height between the measurement cell
and the canister.
Page 15
SILKOSTAT 9210
exterior :
Material :
Pressure :
Temperature :
At this stage of the installation, make sure that the flow valves (2) are all
closed.
The connection of pipes is done by insertion into the quick release
connections found under the sampling block.
Figure 8
123-
Solenoid valve
Solenoid valve flow adjustment screw
Sample input 1 to 6
Page 16
SILKOSTAT 9210
4
1
1234-
Danger :
No intervention should be carried out on the instrument without
first switching off the power.
Page 17
SILKOSTAT 9210
Figure 10
earth
N
L
Fuse
T2 AL 250 V
according to CEI 127
Page 18
neutral
line
In
mains
SILKOSTAT 9210
Figure 11
Page 19
SILKOSTAT 9210
Rel 12
Rel 11
Rel 10
Rel 9
Rel 8
Rel 7
Rel 6
Rel 5
Rel 4
Rel 3
Rel 2
Rel 1
Iout 1
Iout 2
Iout 3
Iout 4
Iout 5
Iout 6
Iout 7
Iout 8
Vout 12
Vout 11
Vout 10
Vout 9
Vout 8
Vout 7
Vout 6
Vout 5
Vout 4
Vout 3
Vout 2
Vout 1
Figure 12
+
+
+
+
+
+
+
GND
TDI
TMS
TCK
TDO
Vcc
!
Page 20
Heater
Mixer
In 1
In 2
In 3
In 4
In 5
In 6
In 7
In 8
In 9
In 10
In 11
In 12
Pt 100
FIX2
Danger :
The relay outputs can only supply power in very low safety voltage
(30 VAC Or 42.4 Vdc maximum) and limited to 0,5 A.
SILKOSTAT 9210
Max.
voltage
Max.
current
Mixer control
24 Vac
1A
Heater control
24 Vdc
1A
5 Vdc
1 mA
30 Veff ou
42.4 Vdc
0,5 A
resistive
charge
5 Vdc
5 mA
24 Vdc
23 mA
30 Vdc
1A
Connections
Re1 to Re6
Re7 to Re10
Re11
Re12
In1 to In6
Function
In7 to In10
In11
In12
Iout1 to Iout6
Iout7
Iout8
Vout1
Vout2 to Vout7
Vout8
Vout9 to Vout11
Vout12
Note :
The system alarm relay (12) is in the positive safety position for
informing in case of a cut-off or an analyser error.
Page 21
SILKOSTAT 9210
4.
Starting-up
Reagent preparation
Danger :
Read the precaution and security appendix and wear protective
goggles and clothes before use chemical products.
50 g/L
45 mL/L
40 g/L
12.5 mL/L
20 g/L
100 g
90 mL
Page 23
SILKOSTAT 9210
80 g
25 mL
40 g
Calibration solution
CONCENTRATED SOLUTION
Use of Titrisol (Merck) cartridge
Dillute one cartridge of Titrisol Merck 109947 solution into one litre of demineralised water
will give a concentration of 1000 mg/litre of Si, ie, 2139 mg/litre of SiO2.
Dillute this solution, 100 times, ie, 10 ml in one litre. This will give a concentration of
10 mg/litre of Si, ie, 21.39 mg/litre SiO2.
Page 24
SILKOSTAT 9210
CALIBRATION SOLUTION
By diluting an appropriate volume of the concentrated solution (at 21.39 mg/litres) with
demineralised water, various calibration solutions with a known concentration of SiO2 may
be prepared :
Suggestion for calibration solution preparation (for 2 litres)
ml of concentrated
solution 21.39 mg/l
calibration
solution
ppb Si
calibration
solution
ppb SiO2
Instrument
Measuring range
10
50
107
0-200 ppb
20
100
213.9
0-200 ppb
25
125
267.4
0-500 ppb
50
250
534.8
0-1000 ppb
Page 25
SILKOSTAT 9210
Page 26
SILKOSTAT 9210
Unit concentration.
10
Function key
ESC :
cancels a data input or goes back to the
previous screen
Enter :
validate and go to the next step
14:00
10.00 ppb
Last calibration
Sample 5
P:date
Sampling
O:date
j
DISP2
START
MENU
Esc
function keys
Go to display 2.
10
Modification of a value
The highlighted digit may be modified with the key
. Each digit can
be modified by pressing ENTER. Repeat both operations for each digit.
On the first digit : possibility to display the sign "-"
On the others digits : possibility to display the sign "."
Note :
If you do not use the keyboard for at least 10 minutes, the
instrument returns to the measuring mode except for the
calibration and maintenance mode.
An access code may be required for the calibration, programming
and service menu (see CODE menu).
Page 27
SILKOSTAT 9210
Language programming
SERVICE
DISPLAY
TIME
AFFICHAGE
CODE
SOFT ISSUE
DEFAUT VALUES
ADJUST mA
CONFIGURATION
FACTORY
select
Esc
DISPLAY
LANGUAGE : F
CONCENTRATION : ppb/ppm
CUSTOMIZE
Select
Esc
French
English
GB
German
Spanish
Sp
Italian
Select
Esc
Note :
See menu "customize" for the customization of the name of
the measuring channels.
Page 28
SILKOSTAT 9210
MAINTENANCE
START UP
DEMARRAGE
REAGENTS REFILL
EXTENDED STOP
TUBES CLEANING
PHOTOMETER TEST
PUMPS-OTHERS
SOLENOID VALVES
RELAYS
LOGICAL INPUTS
Select
Esc
START UP
Adjust flow
Sample x
OK
Esc
Caution :
Dont completelly unscrew the flow adjust screws. There is no
stop screw, so it will provoke a sample leak
Pumps priming :
START UP
Pumps priming
Verify immersion
OK
Esc
Page 29
SILKOSTAT 9210
Starting a measurement
Sample 1
14:00
10.00 ppb
CAL
Sample 5
P : 02/02/02
Sampling
14:30:00
Z : 03/02/02
14:30:00
DISP2
Esc
Page 30
START
MENU
With the help of the "Esc" function key, go back to the main
screen and press "START" key.
SILKOSTAT 9210
5.
Analyser programming
MAINTENANCE
CALIBRATION
PROGRAMMING
EXECUTION PRIMARY
EXECUTION MANUAL
PARAMETERS
HISTORIC
EXECUTION MANUAL
EXECUTION ZERO
EXECUTION SLOPE
EXECUTION ZERO+SLOPE
PROGRAMMING
OFFSET INTERVAL : xxx h
AUTOMAT SLOPE CAL. : YES / NO
CAL. SOL : xxx,x ppb
AUTOMAT CAL: NO
MAINTENANCE
START UP
REAGENTS REFILL
TUBES CLEANING
EXTENDED STOP
PUMPS-OTHERS
SOLENOID VALVES
REAGENTS REFILL
ADJUST VOLUMES
TUBES PRIMING
BOTTLES FULL : yes/no
ADJUST VOLUMES
REAGENT 1 VOL : x.xx l
REAGENT 2 VOL: x.xx l
REAGENT 3 VOL: x.xx l
REAGENT 4 VOL: x.xx l
PUMPS
PUMP 01 : off/on
SOLENOID VALVES
VALVE 01 : off/on
VALVE 07 : off/on
PUMP 04 : off/on
Drain : on/off
Mixer : on/off
Heater : on/off
RELAYS
RELAYS
RELAY 01 : off/on
PHOTOMETER TEST
LOGICAL INPUTS
MEASURE
MEASURE
MEASURING MODE
GRAB SAMPLE
PROGRAMMING
MODE : Normal
CYCLE : IN LOOP
HISTORIC
PROGRAMMING
READ
HISTORIC
ADC VALUES
ALARMS
ALARMS
WARNING ALARM
SYSTEM ALARM
ALARM : yes/no
SYSTEM ALARM
mA OUTPUTS
WARNING ALARM
ALARM : yes/no
ACCEPT : manual
RELAYS : NO/NC
mA OUTPUTS
AFFECT
AFFECT
OUTPUT X
OUTPUT 1
OUTPUT 2
OUTPUT 3
OUTPUT 4
OUTPUT 5
OUTPUT 6
AFFECT : Channel x
TYPE: 0-20
MODE : Linear
LOW : xxx.x ppb
UP : xxx. ppb
SPECIAL PROG.
MAINTENANCE
CALIBRATION
GRAB SAMPLE
SYSTEM ALARM
WARNING ALARM
SPECIAL PROG.
CALIBRATION
MODE : Last
TEST
TEST
SEQUENCE
PROGRAMMING
FROM : xx/xx/xx
AT : xx:xx:xx
CH : A11
ALARMS : yes
ALARM X
MOD : limit
AFFECT : Channel 1
LIMIT : xxx.x ppb
DIRECTION : Down
HYSTERESIS : xx%
RELAYS : NO/NC
ALARM 1
ALARM 2
ALARM 3
ALARM 4
ALARM 5
ALARM 6
COMMUNICATION
RELAY 12 : off/on
VALUE : xx mA
COMMUNICATION
N : xx
BAUD : 300/600/1200/2400/4800/9600
PARITY : no/even/odd
BIT STOP : 1/2
SERVICE
SERVICE
TIME
DISPLAY
CODE
SOFT ISSUES
DEFAULT VALUES
ADJUST mA
FACTORY
SEQUENCE
CHANNEL ACTIVATION
SEQUENCE
TIME
DAY : xxxxx
DATE : JJ/MM/AA
TIME : xx/xx/xx
CODE
PROGRAMMATION: xxx
CALIBRATION : xxxx
SERVICE : xxxx
CONFIGURATION
CHANNEL ACTIVATION
CHANNEL 1 : On / Off
...
CHANNEL 6 : On / Off
DISPLAY
LANGUAGE : F/GB/D/Sp/I
CONCENTRATION : ppb-ppm / ug-mg/l
CUSTOMIZE
mA ADJUST
OUTPUT 1
OUTPUT 8
...
Page 31
SILKOSTAT 9210
User Interface
The interface consists of 5 keys and a graphic backlet display screen
providing a display of the data, operational settings and trend curves.
Informations are available from several screens.
Main display
Sample 1
Last calibration
Sample 5
P : 02/02/02
Sampling
Unit concentration.
Function key
ESC :
cancels a data input or goes back to the
previous screen
Enter :
validate and go to the next step
14:30:00
10
Z : 03/02/02
14:30:00
14:00
10.00 ppb
DISP2
START
MENU
Esc
Programming mode.
Go to display 2.
10
Page 32
function keys
SILKOSTAT 9210
d
Last measures with next indications:
e
Sample 1 : XXX XX:XX:XX
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
DISP3
Sample name.
Esc
Page 33
SILKOSTAT 9210
S1S6 :
Threshold function
parameters,
S1 : OK
.
.
.
.
.
.
S6 : OK
Esc
following
OK :
Disable:
: OK
the
W : disable
DISP4
with
Warning alarm.
System alarm.
DISP4 :
Go to the display 4.
The following table indicates the different messages which may appear in
case of default.
Displayed message
(english)
System
System
System
System
System
System
System
Warning
Warning
Warning
Warning
Cal.time over
Warning
Category
No sample
Sample x missing
Reagent < 250 ml
Page 34
Description
System
Warning
Warning
Warning
System
Warning
Warning
System
System
Threshold
Warning
Warning
Warning
SILKOSTAT 9210
30/08/01
5,00
concentration scale
programmed scale.
Sample name.
equals
to
analogue
output
0,00
c0
24
Main
Graph+
Esc
Function key :
Main :
Graph+ :
Modification of a value
The highlighted digit may be modified with the key
. Each digit can
be modified by pressing ENTER. Repeat both operations for each digit.
On the first digit : possibility to display the sign "-"
On the others digits : possibility to display the sign "."
Note :
If you do not use the keyboard for at least 10 minutes, the
instrument returns to the measuring mode except for the
calibration and maintenance mode.
An access code may be required for the calibration, programming
and service menu (see CODE menu).
Page 35
SILKOSTAT 9210
Main menu
Sample 1
14:00
10.00 ppb
CAL
Sample 5
P = 02/02/02
Sampling
14:30:00
Z = 03/02/02
14:30:00
DISP2
STOP
MENU
Esc
Sample 1
14:00
10.00 ppb
CAL
Sample 5
P = 02/02/02
Sampling
Press "MENU"
14:30:00
Z = 03/02/02
14:30:00
Esc
Sample 1
14:00
10.00 ppb
CAL
ANALYSER
P = 02/02/02
STOPPED
14:30:00
Z = 03/02/02
14:30:00
DISP2
Esc
Page 36
STOP
MENU
SILKOSTAT 9210
MENU
CALIBRATION
MAINTENANCE
MEASURE
ALARMS
mA OUTPUTS
COMMUNICATION
SEQUENCE
SERVICE
Select
Esc
Calibration menu
CALIBRATION
PROGRAMMING
EXECUTION PRIMARY CAL
EXECUTION MANUAL CAL
PARAMETERS
Esc
HISTORIC
Select
is
performed
by
the
Page 37
SILKOSTAT 9210
Select
Esc
Slope calibration
Cal sol sampling
Press "Esc" if you want to quit the calibration menu : and go back
to the "CALIBRATION" menu.
CALIBRATION
Sample preparation.
Conditioning
Measure.
Rinse.
Page 38
SILKOSTAT 9210
PRIMARY CALIBRATION
Default values :
S = 760.0
O = 0.0
Primary calibration
S = XXX
O = XXX
Esc
Select
the
"select"
Esc
CALIBRATION
EXECUTION ZERO
EXECUTION SLOPE
EXECUTION ZERO + SLOPE
Select
Esc
Page 39
SILKOSTAT 9210
The calibration of the zero and the slope can be carried out
automatically at adjustable frequencies.
Press "CALIBRATION" menu.
Sub-menu "PROGRAMMING" and validate by pressing
"Enter".
Choose "PROGRAMMING" sub-menu and validate by pressing
Enter.
Esc
PROGRAMMING
OFFSET INTERVAL : 200 h
CAL. SOL.: 010.0 ppb
AUTO. CAL. : Non
Select
Esc
Page 40
< 5 ppb
24 hours
48 hours
> 50 ppb
> 72 hours
SILKOSTAT 9210
PROGRAMMING
OFFSET INTERVAL : 200 h
CAL.: 010.0 ppb
AUTO SLOPE CAL. : Yes
BASE : Day
WEEK : SMTWTFS
HOUR : 15:00:00
Select
Esc
OR
PROGRAMMING
OFFSET INTERVAL : 200 h
CAL. : 010.0 ppb
AUTO SLOPE CAL.. : Yes
BASE : Hour
INTERVAL : XXXX
Select
Esc
Page 41
SILKOSTAT 9210
Default values :
S = 760.0
O = 0.00
Primary calibration :
S = 694.0
01/01/01
O = 0.00
01/01/01
Last calibration :
S = 694.0
01/01/01
O = 0.00
01/01/01
Esc
auto
09:18:01
O = -5
19:28:51
O = -5
02/09/00
manu
10 :01 :05
O = -4
S = 560
12/09/00
manu
15 :01 :05
o = -6
S = 561
Select
Esc
Page 42
SILKOSTAT 9210
Confirmation
zone
Rejection zone
O : (mAbs)
- 50
- 30
150 %
180 %
Confirmation
zone
Zone ok
30
Rejection zone
50
Zone ok
XXX
Primary calibration :
S = XXX
XX:XX:XX
O = XXX
XX:XX:XX
Last calibration
S = XXX
50 %
Primary
calibration master
S : (%)
XX:XX:XX
O = XXX
XX:XX:XX
C = XXX
XX:XX:XX
Actual calibration
S = XXX
O = XXX
Calibration OK
OK
Esc
Page 43
SILKOSTAT 9210
Confirmation zone
XXX
Primary calibration :
S = XXX
XX:XX:XX
O = XXX
XX:XX:XX
Last calibration
S = XXX
XX:XX:XX
O = XXX
XX:XX:XX
C = XXX
XX:XX:XX
Actual calibration
S = XXX
O = XXX
Calibration error
Conf
Cancel
Esc
XXX
Primary calibration :
S = XXX
XX:XX:XX
O = XXX
XX:XX:XX
Last calibration
S = XXX
XX:XX:XX
O = XXX
XX:XX:XX
C = XXX
XX:XX:XX
Rejection zone
Parameters are abnormal. There is material problem or an
important error like bad calibration solution preparation. (see
troubleshooting).
In automatic mode, the analyser stops and emits an alarm system.
In manual mode, you can cancel (turn to the measure with
previous parameters) or restart a calibration.
Actual calibration
Note :
S = XXX
O = XXX
Calibration error
Cancel Remake
Esc
Page 44
SILKOSTAT 9210
Maintenance menu
MAINTENANCE
START UP
REAGENTS REFILL
Starting procedure.
EXTENDED STOP
TUBES CLEANING
PHOTOMETER TEST
Reagents refill
PUMPS / OTHERS
SOLENOID VALVES
RELAYS
Extended stop
LOGICAL INPUTS
Select
Tubes cleaning
In case of reagent tubings clogging.
Esc
Note :
When one of the maintenance procedure is released, the analyser
automatically stops
Dont forget to restart
operations are realized.
the
instrument
when
maintenance
START UP
Adjust the first sample flow with the help of the screws placed in
the front panel of the face (see figure 3.4 item. 2) to have a
perpetual overflowing in the top of the overflow vessel.
Adjust flow
Sample X
OK
Esc
Warning :
Do not unscrew completely the flow rate set screw. It has no
stop and may get out of its housing and provoke a sample leak.
Page 45
SILKOSTAT 9210
Pump priming :
START UP
Press OK when the pump tubing are full of reagent. The display
goes back to the menu Maintenance.
Pump priming
OK
Esc
Select
Esc
Select
Esc
Page 46
Warning
Alarm system
Reagents
< 250ml
< 150ml
Cal solution
< 300ml
SILKOSTAT 9210
Tubes priming
REAGENTS REFILL
Please wait
Esc
REAGENTS REFILL
At the end of the tubes priming you can quit the procedure by
pressing "ESC".
After the pump operation, check visually the tubings are full. If it is
not the case, return to the menu "pump".
ESC = quit
Esc
Note :
It is recommended to calibrate the zero after each reagent
refill.
Put tubes in
demineralised water
Accept with OK
OK
Esc
Page 47
SILKOSTAT 9210
OK
Esc
TUBES CLEANING
Put pumps tubes
In demineralised water
Accept with OK..
OK
Esc
Page 48
SILKOSTAT 9210
Reference : 3.50
Led current : 9000
Measure : 3.10
Absorbance : 52.7
Bck
ref
With this menu, technicians can verify the good running order of
the photometer.
meas
Displayed parameters
Dark current :
Measurement value which corresponds to the
emitter LED.
Reference :
reference signal after LED current adjustment.
Led current :
current of the LED.
Measure :
Continuous photometric measure signal.
Absorbance :
Absorbance in milli-Abs.
Esc
Function key
Bck :
allows to begin the measure which corresponds to the
switching off of the LED.
Ref. :
allows to adjust the led current and to measure the
reference voltage.
Mes :
> OFF
Pump 02
OFF
Pump 03
OFF
Pump 04
OFF
Drain
OFF
Mixer
OFF
Heater
OFF
Select
Esc
On
Off
This screen allows to test the good running order of the pumps,
the mixer, the drain and the heater.
Utilize the "Select" key to control an element and press the "On"
key to operate it or "Off" key to stop it.
The following table shows the nominal flow rates for each pump :
Pumps 01
Pumps 02
Pumps 03
Pumps 04
Reagent 1
Reagent 2
Reagent 3
Cal. solution
1,5ml/mn
1,5ml/mn
1,5ml/mn
10l/h
Page 49
SILKOSTAT 9210
OFF
Solenoid valve 03
OFF
Solenoid valve 04
OFF
Solenoid valve 05
OFF
Solenoid valve 06
OFF
Solenoid valve 07
OFF
Select
Off
On
Esc
> OFF
Relay 02
OFF
Relay 03
OFF
Relay 04
OFF
Relay 05
OFF
Relay 06
OFF
Relay 07
OFF
Relay 08
OFF
Relay 09
OFF
Relay 10
OFF
Relay 11
OFF
Relay 12
Select
Note :
See the relays functions on page 21.
OFF
On
Off
Esc
0 0 0 0 1 1
2 4 6 8 0 2
------------------------Status * 1 * 1 * * * * * * *
ESC : exit
This screen displays the status of the logical inputs and allows to
test the good running order of the inputs In1 to In12.
Status : 1 : short circuited input
* : open input
Example : in the above example, measurements on channels
3 and 6 are inhibited.
The analyser goes directly to the next channel
Esc
Page 50
SILKOSTAT 9210
Measure Menu
MEASURE
MEASURING MODE
GRAB SAMPLE
HISTORIC
ADC values
Select
Esc
Select
Esc
OR
PROGRAMMING
MODE : Normal
CYCLE : In loop
Select
Esc
Page 51
SILKOSTAT 9210
Please wait
Esc
GRAB SAMPLE
Fill sample
About 200 ml
Esc
"Esc" key allows to stop the measure and comes back to the
previous screen.
Historic sub menu
HISTORIC
PROGRAMMING
READ
Select
Esc
Page 52
SILKOSTAT 9210
Programming
PROGRAMMING
FROM :
01/01/01
AT :
00/00/00
CH :
all
ALARMS :
yes
Allows to choose the date and the time when the historic will be
displayed and the measure channels desired.
CH : all or individually (1 to 6)
ALARMS (yes or no) : display of the system and
warning alarms .
Select
Esc
Read
HISTORIC
18/05/01
13:30 # 1
12.6
13:40 # 2
103
Date : day/month/year.
Hour, sample n (#n) and concentration or default.
Select
Esc
meas :
S : XXXX
XXXX
O : XXXX
XXXX
LAST CALIBRATION
Ref:
meas :
S : XXXX
XXXX
O : XXXX
XXXX
LAST MEASUREMENT
ref :
XXXX
meas :
XXXX
Esc
Page 53
SILKOSTAT 9210
Alarms Menu
This screen allows to assign alarms and parameters to each relay.
ALARMS
ALARM 1
ALARM 2
ALARM 3
ALARM 4
ALARM 5
ALARM 6
WARNING ALARM
SYSTEM ALARM
Select
Esc
MODE
Value
Description
Limit
Active
channel
Level
sample.
AFFEC
Channel 1 to 6
LIMIT
XXXX
DIRECTION
HYSTERESIS
XX %
RELAYS
N.O
N.C
Relay type
Up
Down
Page 54
SILKOSTAT 9210
ALARM 1
MODE : Limit
AFFECT : Channel 2
LIMIT : 100.0 ppb
DIRECTION : Up
HYSTERESIS : 00 %
RELAY : N.O
Select
OR
ALARM X
MODE : active channel
RELAY : NO
Select
Esc
OR
ALARM X
MODE : level sample
RELAY : NO
Select
Esc
Page 55
SILKOSTAT 9210
WARNING ALARM
ALARM : yes
ACCEPT : Manual
Description
ALARM
Yes
No
ACCEPT
Manual
Auto
RELAY : N.O
Select
Esc
RELAY
Type of relay
N.O
N.C
ALARM : yes
Value
RELAY : N.O
ALARM
Select
Yes
No
RELAY
N.O
Esc
Description
N.C
NB:
The alarm system can only be acknowledged manually, either
by holding down the <Enter> key or, remotely, by using the
digital input, In 11, on the I/O card (see Section 3, figure 3.12).
Page 56
SILKOSTAT 9210
Displayed message
(english)
Reset mod. Measure
Reset module LC
Description
Reference error.
Incorrect reference
measurement
Category
System
System
System
System
System
System
System
Warning
Warning
Warning
Warning
Warning
System
Warning
Warning
Warning
System
Warning
Warning
System
System
Warning
Warning
Warning
Warning
Page 57
SILKOSTAT 9210
mA outputs menu
mA OUTPUTS
AFFECT
SPECIAL PROG
TEST
select
Esc
AFFECT :
SPECIAL PROG:
TEST :
Select
Esc
Page 58
SILKOSTAT 9210
OUTPUT 1 to 6
AFFECT : X
TYPE
: 0-20
MODE
: Linear
LOW
: 000.0 ppb
UP
: 01.00 ppm
Select
Esc
TYPE :
MODE :
FIRST :
MIDDLE :
END :
OR
OUTPUT 1 to 6
AFFECT :
Channel 1
With output 1
TYPE
: 0-20
MODE
: Linear
FIRST
: 000.0 ppb
: 000.0 ppm
Select
Esc
The following curve indicates the result of the 4-20 current in terms of the
scale programming type and the first, middle and end value of the scale.
Current
0..20mA/4..20m
Linear
20 / 20 mA
Dual
12 / 10 mA
4 / 0 mA
FIRST
MIDDLE
END
Concentration
Page 59
SILKOSTAT 9210
SPECIAL PROG
MAINTENANCE
CALIBRATION
GRAB SAMPLE
SYSTEM ALARM
WARNING ALARM
Maintenance.
Calibration.
Grab sample analysis.
System alarm.
Warning alarm.
With the help of the CHOICE function, choose the event for which
the output n7 can be programmed.
Select
Esc
Storage :
MAINTENANCE
MODE : Last
Select
Esc
OR
SPECIAL PROG
MODE : Preset
VALUE : XXX mA
Note :
Select
Esc
Esc
Page 60
SILKOSTAT 9210
Communication menu
COMMUNICATION
N : 00
BAUD : 9600
PARITY : No
STOP BIT : 1
SWAP WORD : No
Select
Esc
N :
Baud :
Parity :
Stop bit:
1 or 2
Swap word
CHANNEL ACTIVATION
SEQUENCE
Select
Esc
CHANNEL 1 : On
CHANNEL 2 : Off
CHANNEL 3 : On
CHANNEL 4 : On
CHANNEL 5 : Off
CHANNEL 6 : On
Select
Esc
Page 61
SILKOSTAT 9210
SEQUENCE : 123562141131
Delete
Esc
The "Delete" key replaces the digit by the symbol "*". This symbol
indicates the inhibition of the step in the sequence.
Press "Enter" to validate and go to the next digit.
Sequences examples:
1)
123456******
456321******
These two sequences allow to analyse samples (1 to 6) in
different order.
2)
12 12 12 12 12 12
or 12 ** ** ** ** **
or 1* 2* ** ** ** **
These 3 sequences are the very same and allow to
analyse alternately the samples 1 and 2.
Page 62
SILKOSTAT 9210
Service menu
SERVICE
TIME
DISPLAY
CODE
SOFT ISSUES
DAFAULT VALUES
mA ADJUST
FACTORY
Select
Esc
This screen allows to change the date and the time of the
instrument.
DAY : Monday
DATE (JJ MM AA) : 09/05/01
TIME: 14:43:16
Select
Esc
Select
Esc
English :
GB
German :
Spanish :
Sp
Italian :
Page 63
SILKOSTAT 9210
Customize
Allows to choose the letter
CUSTOMIZE
Ch 1 : anion1
Ch 2 : anion2
Ch 3 : mixed bed
Ch 4 : ball
Ch 5 : condens
Note
Ch 6 : vapour
Select
Esc
: 0000
Select
Esc
XX
I/O Module
XX
Module Colo.
XX
Esc
Page 64
SILKOSTAT 9210
Loading
Note :
Default values ?
YES
Esc
ADJUST mA
OUTPUT 1
OUTPUT 2
OUTPUT 3
OUTPUT 4
OUTPUT 5
OUTPUT 6
OUTPUT 7
OUTPUT 8
Select
Esc
Utilize the "-" and "+" key to adjust the current value to 4 and 20
mA, validate (press Enter ) and press Esc to come back to the
previous screen.
ADJUST mA
4 mA
VALUE : 0000
Esc
OR
ADJUST mA
20 mA
VALUE : 0000
Esc
Page 65
SILKOSTAT 9210
Note :
Personal constructor menu. An access code is required
to enter . Switch off the instrument to have access.
Esc
FACTORY
CHANNEL NUMBER : X
SOLENOID VALVES
PUMPS
MEASURE
CONFIGURATION
Esc
Solenoid valves
SOLENOID VALVES
Ton SAMPLE
: XXX
Toff SAMPLE
: XXXs
: XXX
: XXXs
Esc
Page 66
SILKOSTAT 9210
Pumps
Ton : number of impulses.
PUMPS
PUMP 1 Ton
: XXX
PUMP 1 Toff
: XXXs
PUMP 2 Ton
: XXX
PUMP 2 Toff
: XXXs
PUMP 3 Ton
: XXX
PUMP 3 Toff
: XXXs
Esc
Measure
MEASURE
RANGE
LINEAR COEFF.
WAITING TIME
MEASURE TIME
Measure time
ZERO CONC
reserved
FILTER
reserved
NEGATIVE VAL.
HEATER
RANGE : XXX
LINEAR COEFF. : XXX
WAITING TIME
: XXXs
MEASURE TIME
: XXXs
Esc
CONFIGURATION
MAINS FREG
: 50 Hz
REFERENCE FREQ :
BLACK FREQ :
: 0020
Select
Esc
Page 67
SILKOSTAT 9210
6.
Reagent refills
The analyser monitors the reagents and calibration solution consumption.
Messages are displayed when the canister levels are low.
Messages
Signification
Relays on
Short reagent
Reagent canister
volume < 150ml
Short cal.
Calibration solution
canister volume
< 150ml
ADJUST VOLUMES
TUBES PRIMING
CANISTERS FULL yes/no
Select
Esc
Page 69
SILKOSTAT 9210
ADJUST VOLUMES
REAGENT 1 VOL : 2.00
REAGENT 2 VOL : 2.00
REAGENT 3 VOL : 2.00
SOL CAL
VOL : 2.00
Select
Esc
REAGENTS REFILL
Warning
Alarm system
Reagents
< 250 ml
< 150 ml
Calibration
solution
< 300 ml
Please wait
REAGENTS REFILL
At the end of the tubes priming you can quit the procedure by
pressing "ESC".
ESC = quit
Esc
Note :
It is recommended to calibrate zero after each reagent
refill.
Page 70
SILKOSTAT 9210
Prolonged stopping
In case of an extended stop longer than 1 week, it is recommended
to clean the tubes and the measuring cell.
Provide 250 ml of demineralised water.
Submerge the 3 tubes in the beaker and start the rinsing operation:
Stop the instrument by pressing "STOP".
Press the "MENU" key.
EXTENDED STOP
Put tubes in
demineralised water
Accept with OK
OK
Esc
Page 71
SILKOSTAT 9210
MAINTENANCE / START UP
This screen allows to adjust the samples flow.
START UP
Set the flow-rate for the first sample using the adjusting screws on
the front panel (see Figure 3.3, serial 4) in such a way that a
constant overflow takes place over the top of the overflow vessel.
Adjust flow
Sample 1 (to 6)
OK
Warning :
Esc
START UP
After the pump operation, check visually the tubings are full. If it is
not the case, return to the menu pump ".
PIPE START
Verify immersion
OK
Esc
Page 72
SILKOSTAT 9210
Tube cleaning
TUBES CLEANING
Put pumps tubes
in demineralised water
Accept with OK
OK
Esc
TUBES CLEANING
Put pumps tubes
In demineralised water
Accept with OK..
OK
Esc
Page 73
SILKOSTAT 9210
7.
Troubleshooting
Problem
Possible cause
Problem
N
Cal
Tubes
Photometer
Valves
Pump
5
3
8
4
2
Wrong calibration
Pump
Tubes
Valves
Cal solution
Calibration program
Reagents
Photometer
2
3
4
6
7
7
8
Photometer
Page 75
Possible solutions
Problem
Symptom
Solution
1. START / STOP
Analyser stopped
2. PUMP
Doesnt run
Irregular
3. TUBES
4. SOLENOID
VALVES
5. CAL.
Page 76
Defective tube
Clogged tube
Solenoid valves
leak
The solenoid
valves cant open
The solenoid
valves cant close
Dirty
Diminution of the
flow
Verify and adjust the flow (10 l/h), change the sample tube if it
is clogged.
SILKOSTAT 9210
Problem
Symptom
Solution
6. CALIBRATION
Reprogram
the
concentration (SiO2)
Verify
the
flow
of
the
circuit
"MAINTENANCE/PUMPS-OTHERS" menu.
Wrong concentration
7. REAGENTS
8. PHOTOMETER
calibration
solution
of
the
Page 77
Page 78
Sample concentration
107 ppb
214,9 ppb
267,4 ppb
534,8 ppb
Measure (mV)
2515
1754
1472
603
Sample concentration
1000 ppb
3000 ppb
Measure (mV)
1400
300
SILKOSTAT 9210
Part Number
Accessories / Options :
0,5 6 bar adaptation kit for six sample selection solenoid
valves
09210=A=0100
621=192=010
621=092=010
621=292=010
621=492=010
621=592=010
09200=A=5000
09200=A=1001
09200=A=1010
09200=A=1011
09200=A=2000
09125=A=0485
09200=A=5500
370=302=034
370=304=034
370=307=034
09210=A=1500
09210=A=1510
09210=A=1520
151575,00006
689=118=016
689=118=008
O-ring, 4 x 1
356099,05040
09210=A=0105
09210=A=0250
Page A1
SILKOSTAT 9210
DESCRIPTION
Part Number
Viton O-ring 38 x 2 mm
356099,35380
689=118=024
09210=A=1234
09210=A=0400
226=003=013
Heating element
09097=C=0560
359000,40780
09210=A=0500
09210=C=0340
425=210=022
09210=C=0330
356099,05220
09210=C=0310
09210=C=7000
590=050=060
151065.08699
151575.00006
695=114=001
695=004=004
2 litres PE cap
495=020=001
Strainer
09210=A=0600
589=011=040
589=010=015
Caution :
Page A2
SILKOSTAT 9210
1. dihydrate
2. anhydrous
CAS N144-62-7
PHYSICAL PROPERTIES
1. 101 C
MELTING POINT
2. 190 C
SOLUBILITY IN WATER
About 14%
HEALTH HAZARD
EYES
Irrigate thoroughly
attention
with water ;
obtain
medical
LUNGS
INGESTION
STABILITY
Stable
SPECIAL HAZARDS
WASTE DISPOSAL
Page B1
SILKOSTAT 9210
PROTECTIVE MEASURES
RESPIRATOR
GLOVES
Rubber or plastic
EYE PROTECTION
Goggles
SPILLAGE HANDLING
SMALL SPILLAGE
LARGE SPILLAGE
The information on this sheet is believed to be correct at the time of collation. The details should be reviewed
periodically and should be checked for special uses.
Page B2
SILKOSTAT 9210
Formula : H2 SO4
Hazard class : 8
UN N : 1830
CAS N 7664-93-9
PHYSICAL PROPERTIES
MELTING POINT
10 C
BOILING POINT
330C
SPECIFIC GRAVITY
1,8
HEALTH HAZARD
EYES
LUNGS
MOUTH
SKIN
Page B3
SILKOSTAT 9210
Acetonitrile.
Perchlorates.
Nitro-organic compounds.
Alkali metals.
Potassium permanganate
Metal halogenates.
The information on this sheet is believed to be correct at the time of collation. The details should be reviewed
periodically and should be checked for special uses.
Page B4
SILKOSTAT 9210
CAS N 16893-85-9
PHYSICAL PROPERTIES
White granular powder
Density (20 C) approx. 2,7 g cm-3
Slightly soluble in water (6g 1-1 to 20C)
FIRE AND EXPLOSION HAZARD
HEALTH HAZARD
long
term
EYES
LUNGS
MOUTH
SKIN
Page B5
SILKOSTAT 9210
Dust respirator.
VENTILATION
Extraction hood.
GLOVES
Rubber or plastic.
EYE PROTECTION
OTHERS MEASURES
PRECAUTIONS
WASTE DISPOSAL
The information in this sheet is believed to be correct at the time of callation. The details should be reviewed
periodically and should be checked for special uses.
Page B6
SILKOSTAT 9210
7783-85-9 233-151-8
FORMULA
(NH4)2Fe(SO4)2, 6H2O
MOLECULAR WEIGHT
392,14 AMU
ALTERNATIVE NAMES
FORM
Solid
COULOUR
Greenish blue
ODOUR
Nil
MELTING POINT
100C
DENSITY
1.86 g/cm
Non-combustible.
Likelihood of dangerous vapours being given off if
close to a fire.
SAFETY MEASURES
EYES SKIN
RESPIRATORY TRACT
IF SWALLOWED
STABILITY
CONDITIONS TO AVOID
PRODUCTS TO AVOID
Page B7
SILKOSTAT 9210
Iron oxides.
DANGEROUS DECOMPOSITION PRODUCTS
Ammonia.
Sulphur oxides.
PREVENTIVE MEASURES
Safe Handling Instructions: Do not breathe the dust.
Avoid contact with the eyes, skin or clothing. Avoid
prolonged or repeated exposures.
HANDLING
UK:
Source - category - value
OEL - LTEL - 1 mg (Fe)/m
OEL - STEL - 2 mg (Fe)/m
EXPOSURE LIMITS
BREATHING EQUIPMENT
Essential.
GLOVES
EYE PROTECTION
FOLLOWING INHALATION
Page B8
SILKOSTAT 9210
SPECIAL RISKS
The information contained in this document is reviewed at regular intervals and checked for special cases.
Page B9
SILKOSTAT 9210
Formula: Na2MoO4.2H2O
CAS N 10102-40-6
PHYSICAL PROPERTIES
MELTING POINT
687C
SOLUBILITY IN WATER
840 g/L
No information available
HEALTH RISKS
EYES
LUNGS
INGESTION
STABILITY
Stable
SPECIFIC RISKS
No information available
DISPOSAL
RESPIRITORY
GLOVES
Not necessary
EYES
PERSONAL
ENVIRONMENT
CLEANING
The information listed above must be reviewed periodically and should not be considered a substitute for the
MSDS for this product.
Page B10
SILKOSTAT 9210
SUBSTANCE
SUPPLIER
Phone
: (33) 02.31.15.37.10
Fax N
: (33) 02.31.15.37.30
Emergency : (33) 02.31.15.37.35 (Unit of production)
: (33) 01.45.42.59.59 (N ORFILA)
COMPOSITION / INFORMATION ABOUT THE COMPONENTS
Preparation
CHEMICAL PROPERTIES
HAZARDOUS COMPONENTS
CAS NUMBER
213-653-7
10102-40-6
7664-93-9
SOLUTION
Water
Sodium molybdate
Sulphuric acid
QUANTITY
90 %
5%
5%
CLASSIFICATION
IDENTIFICATION OF HAZARDS
Product not considered as dangerous according to the 67/548/CEE directive
FIRST AID
SKIN CONTACT
EYE CONTACT
SPECIFIC HAZARDS
Page B11
SILKOSTAT 9210
ENVIRONMENT PROTECTION
CLEANING
PRECAUTIONS TO TAKE
USEAGE ADVICE
STORAGE RECOMMENDATIONS
HAND PROTECTION
EYE PROTECTION
OTHER PROTECTION
Acid-proof clothing
HYGIENE MEASURES
FORM
Liquid
COLOR
Light yellow
ODOR
Odorless
pH
<1
STABILITY AND REACTIVITY
CONDITIONS TO BE AVOIDED
Heating
SUBSTANCES TO BE AVOIDED
DANGEROUS BY-PRODUCTS
ACUTE TOXICITY
Causes burns
Causes burns
Page B12
SILKOSTAT 9210
ECOLOGICAL INFORMATION
ECOTOXIC
No specific indications
DISPOSAL CONSIDERATIONS
There are as yet no uniform regulations concerning
the disposal of chemicals and their residues within
the European Union.
PRODUCT
PACKAGING
Corrosive
R Sentences
35
Causes burns
S Sentences
26 - 30 - 36/37/39-45
OTHER INFORMATION
Updated version : November 2005 Issue A
Page B13
SILKOSTAT 9210
SUBSTANCE
SUPPLIER
Phone
: (33) 02.31.15.37.10
Fax N
: (33) 02.31.15.37.30
Emergency : (33) 02.31.15.37.35 (Unit of production)
: (33) 01.45.42.59.59 (N ORFILA)
COMPOSITION / INFORMATION ABOUT THE COMPONENTS
Preparation
CHEMICAL PROPERTIES
HAZARDOUS COMPONENTS
CAS NUMBER
213-653-7
6153-56-6
SOLUTION
Water
Oxalic acid
QUANTITY
95 %
5%
CLASSIFICATION
Xn ; R21/22
IDENTIFICATION OF HAZARDS
Injurious on contact with skin or by ingestion
FIRST AID
SKIN CONTACT
EYE CONTACT
SPECIFIC HAZARDS
Page B14
SILKOSTAT 9210
ENVIRONMENT PROTECTION
CLEANING
STORAGE RECOMMENDATIONS
HAND PROTECTION
EYE PROTECTION
HYGIENE MEASURES
FORM
Liquid
COLOR
Colorless
ODOR
Odorless
pH
<1
STABILITY AND REACTIVITY
CONDITIONS TO BE AVOIDED
Strong heating
SUBSTANCES TO BE AVOIDED
Bases
DANGEROUS BY-PRODUCTS
No available information
TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
Slight irritation
Slight irritation
Injurious
Page B15
SILKOSTAT 9210
ECOLOGICAL INFORMATION
ECOTOXIC
Damage :
DCO : 0.18 g/g (compared to the pure substance)
DThO : 0.18 g/g (compared to the pure substance)
DBO : 0.16 g/g (compared to the pure substance)
Do not pour in sewer or in the rivers.
DISPOSAL CONSIDERATIONS
There are as yet no uniform regulations concerning
the disposal of chemicals and their residues within
the European Union.
PRODUCT
PACKAGING
Injurious
R Sentences
21/22
S Sentences
36/37
OTHER INFORMATION
Updated version : November 2005 Issue A
Page B16
SILKOSTAT 9210
SUBSTANCE
SUPPLIER
Phone
: (33) 02.31.15.37.10
Fax N
: (33) 02.31.15.37.30
Emergency : (33) 02.31.15.37.35 (Unit of production)
: (33) 01.45.42.59.59 (N ORFILA)
COMPOSITION / INFORMATION ABOUT THE COMPONENTS
Preparation
CHEMICAL PROPERTIES
HAZARDOUS COMPONENTS
CAS NUMBER
213-653-7
7783-85-9
7664-93-9
SOLUTION
Water
Ammonium iron (III) sulphates
Sulphuric acid
QUANTITY
96 %
2%
2%
CLASSIFICATION
IDENTIFICATION OF HAZARDS
Product not considered as dangerous according to the 67/548/CEE directive
FIRST AID
SKIN CONTACT
EYE CONTACT
SPECIFIC HAZARDS
Page B17
SILKOSTAT 9210
ENVIRONMENT PROTECTION
CLEANING
PRECAUTIONS TO TAKE
USEAGE ADVICE
STORAGE RECOMMENDATIONS
HAND PROTECTION
EYE PROTECTION
OTHER PROTECTION
Acid-proof clothing
HYGIENE MEASURES
FORM
Liquid
COLOR
Colorless
ODOR
Odorless
pH
<1
STABILITY AND REACTIVITY
CONDITIONS TO BE AVOIDED
Strong heating
SUBSTANCES TO BE AVOIDED
DANGEROUS BY-PRODUCTS
ACUTE TOXICITY
Causes burns
Causes burns
Page B18
SILKOSTAT 9210
ECOLOGICAL INFORMATION
ECOTOXIC
No specific indications
DISPOSAL CONSIDERATIONS
There are as yet no uniform regulations concerning
the disposal of chemicals and their residues within
the European Union.
PRODUCT
PACKAGING
Corrosive
R Sentences
35
Causes burns
S Sentences
26 - 30 - 36/37/39-45
OTHER INFORMATION
Updated version : November 2005 Issue A
Page B19
SILKOSTAT 9210
The lithium battery on the Datalyt Microprocessor p.c.b does not constitute a serious hazard
providing the following instructions are observed :
NEVER :
Attempt to recharge the battery.
Crush, puncture, open or dismantle the battery.
Store or operate equipment above the temperature specified.
Short-circuit the battery.
Dispose of the battery in a fire.
Try to repair faults on the control p.c.b.
In the event of a p.c.b fault or battery leakage :
ALWAYS :
Wear suitable protective clothing.
Remove the equipment to a well ventilated area.
Contact your local agent.
Refer to Health and Safety Notes on Lithium batteries.
Page B20
SILKOSTAT 9210
Function
offset interval
cal. sol
auto. cal
base
week
hour
Frequency
Concentration
Auto calibrate
Default/Values
Possible values
Selected values
Date
CALIBRATION / PROGRAMMING
24 h
214 ppb
No
Day
Mtwtfs
00:00:00
16
Xxxxx
yes/no
Day/hour
Calendar Mtwtfs
Hours
MAINTENANCE/REAGENTS REFILL
Reagents vol. 1
Reagents vol. 2
Reagents vol. 3
Reagents vol. 4
2,00 l
2,00 l
2,00 l
2,00 l
Xx
Xx
Xx
Xx
MEASURE/MEASURE MODE
Cycle
Interval
Interval
15 mn
interval/in loops
xx hour/minute
ALARMS / ALARM 1
Mode
Affect
Limit
Direction
Hysteresis
Relay
Limit
Channel 1
1000 ppb
Low
0%
N.O.
Conc
Xxx
low/high
Xx
N.O./N.C.
ALARMS / ALARM 2
Mode
Affect
Limit
Direction
Hysteresis
Relay
Limit
Channel 2
1000 ppb
Low
0%
N.O.
Conc
Xxx
low/high
Xx
N.O./N.C.
ALARMS / ALARM 3
Mode
Affect
Limit
Direction
Hysteresis
Relay
Limit
Channel 3
1000 ppb
Low
0%
N.O.
Conc
Xxx
low/high
Xx
N.O./N.C.
ALARMS / ALARM 4
Mode
Affect
Limit
Direction
Hysteresis
Relay
Limit
Channel 4
1000 ppb
Low
0%
N.O.
Conc
Xxx
low/high
Xx
N.O./N.C.
Page C1
SILKOSTAT 9210
Users configuration
Order
Selected values
Selected values
Possible values
ALARMS / ALARM 5
Mode
Affect
Limit
Direction
Hysteresis
Relay
Limit
Channel 5
1000 ppb
Low
0%
N.O.
Conc
Xxx
low/high
Xx
N.O./N.C.
ALARMS / ALARM 6
Mode
Affect
Limit
Direction
Hysteresis
Relay
Limit
Channel 6
1000 ppb
Low
0%
N.O.
Conc
Xxx
low/high
Xx
N.O./N.C.
Yes
Manual
N.O.
yes/no
Manual/automatic
N.O./N.C.
Yes
Manuel
N.C.
Oui/non
Manual/automatic
N.O./N.C.
Channel 1
0-20 mA
Linear
0 ppb
100 ppb
1 ppm
Channel 1Channel 6
0/20 mA ou 4/20 mA
Linear / dual
XXX
XXX
XXX
Channel 2
0-20 mA
linear
0 ppb
100 ppb
1 ppm
Channel 1Channel 6
0/20 mA ou 4/20 mA
Linear / dual
XXX
XXX
XXX
Page C2
Channel 3
0-20 mA
Linear
0 ppb
100 ppb
1 ppm
Channel 1Channel 6
0/20 mA ou 4/20 mA
Linear / dual
XXX
XXX
XXX
Selected values
Date
SILKOSTAT 9210
Users configuration
Order
Selected values
Selected values
Possible values
Selected values
Date
Channel 4
0-20 mA
Linear
0 ppb
100 ppb
1 ppm
Channel 1Channel 6
0/20 mA ou 4/20 mA
Linear / dual
XXX
XXX
XXX
Channel 5
0-20 mA
Linear
0 ppb
100 ppb
1 ppm
Channel 1Channel 6
0/20 mA ou 4/20 mA
Linear / dual
XXX
XXX
XXX
Channel 6
0-20 mA
Linear
0 ppb
100 ppb
1 ppm
Channel 1Channel 6
0/20 mA ou 4/20 mA
Linear / dual
XXX
XXX
XXX
Last
0 mA
Last/preset/live
Xx
Last
0 mA
Last/preset/live
XX
Last
0 mA
Last/preset/live
XX
Last
0 mA
Last/preset/live
XX
Last
0 mA
Last/preset/live
Xx
COMMUNICATION
N
Baud
Parity
Stop bit
n of Monec
Speed communication
0
9600
No
1
0 33
300,600,1200,2400,4800,9600
No, odd, even
1 or 2
Swap word
No
Yes/no
Page C3
SILKOSTAT 9210
Users configuration
Order
Selected values
Selected values
Possible values
On
On
On
On
On
On
on / off
on / off
on / off
on / off
on / off
on / off
SEQUENCE / PROGRAMMING
Sequence
Sequence programming
123456123456
123456*
SERVICE/TIME
Day
Date
Time
Monday
01/01/01
09:25:55
Monday Friday
SERVICE/DISPLAY
Language
concentration
GB
Ppb
F/GB/D/SP/I
ug/l / ppb
SERVICE/CUSTOMIZE
Sample 1
Sample 2
Sample 3
Sample 4
Sample 5
Sample 6
name
name
name
name
name
name
Sample 1
Sample 2
Sample 3
Sample 4
Sample 5
Sample 6
SERVICE / CONFIGURATION
Mains freq.
Reference freq.
Freq. noir
60 Hz
0
9999
50/60 Hz
Xx
Xx
SERVICE/ FACTORY
Channel number
1 to 6
3
180 s
3
180 s
Pump 1 Ton
Pump 1 Toff
Pump 2 Ton
Pump 2 Toff
Pump 3 Ton
Pump 3 Toff
Impulses number
Waiting time
Impulses number
Waiting time
Impulses number
Waiting time
Type
0-1000 ppb
Linear coeff.
Waiting time
Measure time
Conc. zero
Filter
Heating
Negative values
Coefficient of non-linearity
0
1s
10 s
0 ppb
50 mV
Yes
no
xx
xx s
xx
xx s
Xx
xx s
Xx
xx s
Xx
xx s
SERVICE/ FACTORY/MEASURE
Page C4
0-1000 ppb
0-5000 ppb
0---XXX
xx s
xx s
Yes/no
Yes/no
Selected values
Date
SILKOSTAT 9210
Page D1
SILKOSTAT 9210
Page D2
SILKOSTAT 9210
6 mm
1/4
5/16
7,3 0,5
0,33 0,02
0,36 0,02
Place the tube in the tube-cutter and set the knurl on the mark.
Fasten the knurl a quarter turn.
Turn the tool around the tube and check the presence of a slot all
around the turn.
Remove the tube-cutter.
Page E1