MSDS-EU1907/2006

Page1of5

Material Safety Data Sheet

Date
Version

11-03-16
1.0

AccordingtoEURegulation1907/2006inthecurrentversion

SODIUM BICARBONATE
1.Identificationofthesubstance/preparationandthecompany
Tradename:
Utilization:
Suppliercompany
identification:
Emergency:

Sodiumbicarbonate
Cosmeticaddtive
Elemental SRL,PiataCazarmiino.15,410188-Oradea,jud.Bihor,Romania
Tel/Fax:+40259-436.755,office@elemental.eu
RO:numarnationalpentrucazurideurgenta:0213183606InstitutuldeSanatate
PublicaBucuresti.Internationalemergencynumber:+491802273-112

2.HazardsIdentification
2.1Classificationofthesubstanceormixture
ClassificationaccordingtoRegulation(EC)No1272/2008ThesubstanceisnotclassifiedaccordingtotheCLP
regulation.
ClassificationaccordingtoDirective67/548/EECorDirective1999/45/ECnotapplicable
Informationconcerningparticularhazardsforhumanandenvironment:AccordingtocurrentEuropeanlawsand
regulationstheproductisnotdangerousortoxicmaterial(basedontheavailabledata).Nohazardstobeparticularly
mentioned.
2.2Labelelements
LabellingaccordingtoRegulation(EC)No1272/2008:Void.Hazardpictograms:Void
Signalword:Void.Hazardstatements:Void
2.3Otherhazards
ResultsofPBTandvPvBassessment:PBT:Substancecharacteristicsdonotmeetscreeningcriteria.vPvB:Substance
characteristicsdonotmeetscreeningcriteria.
3.Composition/Informationoningredients
Substances
Sodiumhydrogencarbonate
Chemicalname:
144-55-8
CAS-number:
205-633-8
EINECS-number:

Molecularweight:84.02g/mol

4.FirstAid
4.1.Inhalation
Removethesubjectfromdustyenvironmentandlethimblowhisnose.
4.2.Eyecontact
Rinsethoroughlywithplentyofwater,alsoundertheeyelids.Ifeyeirritationpersists,consultaspecialist.
4.3.Skincontact:Washoffwithplentyofwater.
4.4.Ingestion
Thefollowingactionsarerecommended:
Ifalargeamountisswallowed,getmedicalattention.Ifswallowed,rinsemouthwithwater(onlyifthepersonis
conscious).Ifvictimisunconsciousbutbreathing:notapplicable
5.Fire-fightingMeasures
5.1.Suitableextinguishingmedia
Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthesurrounding
environment.
5.2.Extinguishingmediawhichmustnotbeusedforsafetyreasons
None.

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Material Safety Data Sheet

Date
Version

11-03-16
1.0

AccordingtoEURegulation1907/2006inthecurrentversion

SODIUM BICARBONATE
5.3.Specialexposurehazardsinafire
Notcombustible.
5.4.Specialprotectiveequipmentforfire-fighters
Nospecialprecautionsrequired.
6.Accidentalreleasemeasures:
6.1.Personalprecautions
Refertoprotectivemeasureslistedinsections7and8.
6.2.Environmentalprecautions:Donotflushintosurfacewaterorsanitarysewersystem.Preventanymixturewithan
acidintothesewer/drain(gasformations).
6.3.Methodsforcleaningup
Sweepupandshovelintosuitablecontainersfordisposal.
Avoiddustformation.Keepinproperlylabelledcontainers.Keepinsuitable,closedcontainersfordisposal.
Treatrecoveredmaterialasdescribedinthesection"Disposalconsiderations".
7.HandlingandStorage
7.1.Handling
KeepawayfromIncompatibleproducts.
7.2.Storage
Keepinadryplace.Storeinoriginalcontainer.Keepcontainerclosed.KeepawayfromIncompatibleproducts.
7.3.Specificuse(s)
Apartfromtheusesmentionedinsection1nootherspecificusesarestipulated.
7.4.Otherinformation
Avoiddustformation.Refertoprotectivemeasureslistedinsections7and8.
8.ExposureControlsandPersonalProtection
8.1.ExposureLimitValues
Sodiumbicarbonate:TWA=10mg/m3
8.2.Exposurecontrols
Ensureadequateventilation.Provideappropriateexhaustventilationatplaceswheredustisformed.Referto
protectivemeasureslistedinsections7and8.Applytechnicalmeasurestocomplywiththeoccupationalexposure
limits.
8.2.1.Occupationalexposurecontrols
8.2.1.1.Respiratoryprotection:Useonlyrespiratoryprotectionthatconformstointernational/nationalstandards.In
caseofdustclouds/fog/fumes,dustmasktypeP1.
8.2.1.2.Handprotection:Wearsuitablegloves.
8.2.1.3.Eyeprotection:Dustproofgoggles,ifdusty.
8.2.1.4.Skinandbodyprotection:None.
8.2.1.5.Hygienemeasures:Whenusingdonoteat,drinkorsmoke.Washhandsbeforebreaksandattheendof
workday.Handleinaccordancewithgoodindustrialhygieneandsafetypractice.
8.2.2.Environmentalexposurecontrols:Disposeofrinsewaterinaccordancewithlocalandnationalregulations.
9.PhysicalandChemicalProperties
Appearance:
Colour:
Odour:

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crystalline,powder
white
odourless

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Material Safety Data Sheet

Date
Version

11-03-16
1.0

AccordingtoEURegulation1907/2006inthecurrentversion

SODIUM BICARBONATE
pH:
Meltingpoint:
Boilingpoint&range:
Flashpoint:
Relativedensity:
Solubility:
Viscosity:
Bulkdensity:
Segregationcoeficient:
Explosiveproperties:
Decompositiontemperature:

8,6at52g/l
notapplicable
notapplicable
notapplicable
2.22
inwater96g/lat20C;slightlysolubleinalcohol
1,2mPa.s
from0.5-1.2kg/dm3
7.05-8.23logPOW
productnotexplosive
>60C

10.StabilityandReactivity
10.1Reactivity
10.2Chemicalstability:Stable.Thermaldecomposition/conditionstobeavoided:Nodecompositionifusedand
storedaccordingtospecifications.
10.3Possibilityofhazardousreactions
Astheproductissupplieditisnotcapableofdustexplosion.
10.4Conditionstoavoid:Nofurtherrelevantinformationavailable
10.5Incompatiblematerials:Acids
10.6Hazardousdecompositionproducts:Nohazardousdecompositionproductsifinstructionsforstorageandhandling
arefollowed.
11.ToxicologicalInformation
11.1Toxicologicaldata
Acuteoraltoxicity:LD50,rat,>4,000mg/kg
Acuteinhalationtoxicity:LC50,rat,>4.74mg/l
Acutedermaltoxicity:-LD50,Remarks:nodataavailable
Skinirritation-rabbit,Mildskinirritation
Eyeirritation-rabbit,Mildeyeirritation
Sensitization-nodataavailable
Chronictoxicity-noobservedeffect
Genetictoxicityinvitro-Genotoxicityinvitro,Testsonbacterialormammaliancellculturesdidnotshowmutagenic
effects.
Teratogenicity-Oralroute(gavage),10days,Variousspecies,330mg/kg,Didnotshowteratogeniceffectsinanimal
experiments.
Possiblehazards(summary)-Healthinjuriesarenotknownorexpectedundernormaluse.
11.2.Healtheffects
Inhalation-Mechanicalirritationfromtheparticulatesgeneratedbytheproduct.
Eyecontact-Mechanicalirritationfromtheparticulatesgeneratedbytheproduct.
Skincontact-Mechanicalirritationfromtheparticulatesgeneratedbytheproduct.
Ingestion-Ingestionmaycausegastrointestinalirritation,nausea,vomitinganddiarrhoea.
12.EcologicalInformation
12.1.Ecotoxicityeffects
Acutetoxicity
-Fishes,Oncorhynchusmykiss,LC50,96h,7,700mg/l.-Fishes,Oncorhynchusmykiss,NOEC,96h,2,300mg/l

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Material Safety Data Sheet

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11-03-16
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AccordingtoEURegulation1907/2006inthecurrentversion

SODIUM BICARBONATE
-Fishes,Lepomismacrochirus,LC50,96h,7,100mg/l.-Fishes,Lepomismacrochirus,NOEC,96h,5,200mg/l
-Crustaceans,Daphniamagna,EC50,48h,4,100mg/l.-Crustaceans,Daphniamagna,NOEC,48h,3,100mg/l
12.2.Mobility
-Water,Soil/sediments.Remarks:Solubility.-Water,Soil/sediments.Remarks:Mobility
12.3.Persistenceanddegradability
Abioticdegradation-Water,hydrolyses
Result:acid/baseequilibriumasafunctionofpH.Degradationproducts:carbonicacid/bicarbonate/carbonate
Biodegradation
-Remarks:Themethodsfordeterminingthebiologicaldegradabilityarenotapplicabletoinorganicsubstances.
12.4.Bioaccumulativepotential-Result:notapplicable
12.5.Otheradverseeffects-nodataavailable
12.6.Possiblehazards(summary)-Ecologicalinjuriesarenotknownorexpectedundernormaluse.
13.DisposalConsiderations
13.1.Wastefromresidues/unusedproducts
-Contactwastedisposalservices.Ifrecyclingisnotpracticable,disposeofincompliancewithlocalregulations.Or
dilutewithplentyofwater.Neutralisewithacid.Inaccordancewithlocalandnationalregulations.
13.2.Packagingtreatment
Toavoidtreatments,asfaraspossible,usededicatedcontainers.Or:Cleancontainerwithwater.Disposeofrinse
waterinaccordancewithlocalandnationalregulations.Theemptyandcleancontainersaretobereusedinconformity
withregulations.Or:Mustbeincineratedinasuitableincinerationplantholdingapermitdeliveredbythecompetent
authorities.
14.TransportInformation
Notclassifiedasdangerousinthemeaningoftransportregulations
Generalrecomandations:
UNno:
notclassified
Road(ADR/RID):
notclassified
Air(IATA/ICAO):
notclassified
Sea(IMDG):
notclassified
Specialprecautionsforuser:
Seesection6-8
TransportinbulkaccordingtoAnnexIIofMARPOL73/78andtheIBC:n/a
15.AdditionalRegulatoryInformation
15.1.ECLabel-NotclassifiedaccordingtoDirective67/548/EEC.
15.2.Otherregulations
EuropeanWasteCatalogue,Decision(2000/532/EC),Wastecodesshouldbeassignedbytheuserbasedonthe
applicationforwhichtheproductwasused.
16.OtherInformation
Disclaimer:
Thismaterialsafetydatasheetdoesnotconstituteaguaranteeofthepropertiesoftheproductandisnota
contractuallegalreport.Theinformationisgiveningoodfaithonthebasisofourbestknowledgeoftheproductatthe
indicatedtime.However,wecannotacceptresponsibilityorliabilityforanyconsequencesarisingfromitsuse,no
warrantyforcorrectnessandcompletenessisgiven.Wecautiontheusersagainsttheincurredpossibleriskswhenthe
productisusedatotherendsthantheuseforwhichitwasinitiallyplanned.Itistheusersresponsibilityduring
handling,storageandproductusetoconsultthemainregulatorytextsinforceregardingworkersandenvironment

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Material Safety Data Sheet

Date
Version

11-03-16
1.0

AccordingtoEURegulation1907/2006inthecurrentversion

SODIUM BICARBONATE
handling,storageandproductusetoconsultthemainregulatorytextsinforceregardingworkersandenvironment
protection.
Abbreviationsandacronyms:
RID:Rglementinternationalconcernantletransportdesmarchandisesdangereusesparchemindefer(Regulations
ConcerningtheInternationalTransportofDangerousGoodsbyRail)
ICAO:InternationalCivilAviationOrganization
ADR:AccordeuropensurletransportdesmarchandisesdangereusesparRoute(EuropeanAgreementconcerningthe
InternationalCarriageofDangerousGoodsbyRoad)
IMDG:InternationalMaritimeCodeforDangerousGoods
IATA:InternationalAirTransportAssociation
GHS:GloballyHarmonizedSystemofClassificationandLabellingofChemicals
EINECS:EuropeanInventoryofExistingCommercialChemicalSubstances
CAS:ChemicalAbstractsService(divisionoftheAmericanChemicalSociety)
DNEL:DerivedNo-EffectLevel(REACH)
PNEC:PredictedNo-EffectConcentration(REACH)
LC50:Lethalconcentration,50percent
LD50:Lethaldose,50percent

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