Chapter6

Topic:Enthalpy
Section6.1
DifficultyLevel:Medium
1. Estimatetheenthalpychangeofthefollowingreactionunderstandardconditions.
Ans:+8kJ/mol
Topic:Enthalpy
Section6.1
DifficultyLevel:Medium
2. Estimatetheenthalpychangeofthefollowingreactionunderstandardconditions.

Ans:+29kJ/mol
Topic:Enthalpy
Section6.1
DifficultyLevel:Medium
3. Estimatetheenthalpychangeofthefollowingreactionunderstandardconditions.
Ans:8kJ/mol
Topic:Enthalpy
Section6.1
DifficultyLevel:Easy
4. Whichofthefollowingistheenthalpychangeofthefollowingreactionunder
standardconditions?
A.8kJ/mol
B.+8kJ/mol
C.+222kJ/mol
D.+79kJ/mol
Ans:B
Topic:Enthalpy
Section6.1
DifficultyLevel:Medium

5. Whichofthefollowingistheenthalpychangeofthefollowingreactionunder
standardconditions?

A.8kJ/mol
B.+8kJ/mol
C.506kJ/mol
D.+63kJ/mol
Ans:A
Topic:Enthalpy
Section6.1
DifficultyLevel:Medium

6. Laterinthecourse,wewillcomparethehalogenationofdifferentlysubstituted
carbons,comparingreactionsliketheonesbelow.Whichofthefollowing
statementsistrueaboutreactionsAandB?

A.Bothreactionshaveapositiveheatofreaction(Ho)
B.Neitherreactionhasapositiveheatofreaction(Ho)
C.OnlyreactionAhasapositiveheatofreaction(Ho)
D.OnlyreactionBhasapositiveheatofreaction(Ho)
Ans:B
Topic:Enthalpy
Section6.1
DifficultyLevel:Medium

7. Laterinthecourse,wewillcomparethehalogenationofdifferentlysubstituted
carbons,comparingreactionsliketheonesbelow.Whichofthefollowing
reactionshasamoreexothermicheatofreaction(Ho)?

A.ReactionAhasamoreexothermicheatofreaction(Ho)
B.ReactionBhasamoreexothermicheatofreaction(Ho)

C.Bothreactionshavethesameheatofreaction(Ho)
Ans:B
Topic:Enthalpy
Section6.1
DifficultyLevel:Hard

8. Youareworkinginaresearchlaboratoryandhavedevelopedanewreagentthat
cleavesCHbondshomolytically.Unfortunately,thisreagentcanachieveonlyone
ofthetransformationsshownbelow.Inlightofbonddissociationenergies,which
transformationismostlikelytobeachieved?

Ans:A
Topic:Enthalpy
Section6.1
DifficultyLevel:Easy
9. Whattypeofbondcleavagedoesthefollowingreactioninvolve?
A.homolytic
B.heterolytic
Ans:A
Topic:Enthalpy
Section6.1
DifficultyLevel:Easy
10. Whattypeofbondcleavagedoesthefollowingreactioninvolve?
Ans:heterolytic
Topic:Entropy

Section6.2
DifficultyLevel:Easy
11. PredictthesignofSofthefollowingreaction.

A.positive
B.negative
C.nochange
Ans:B
Topic:Entropy
Section6.2
DifficultyLevel:Easy
12. PredictthesignofSofthefollowingreaction.

A.positive
B.negative
C.nochange
Ans:A
Topic:Entropy
Section6.2
DifficultyLevel:Easy
13. PredictthesignofSofthefollowingreaction.

A.positive
B.negative
C.nochange
Ans:B
Topic:Entropy
Section6.2
DifficultyLevel:Medium
14. PredictthesignofSofthefollowingreaction.

Ans:positive
Topic:Entropy
Section6.2
DifficultyLevel:Medium
15. PredictthesignofSofthefollowingreaction.

Ans:negative

Topic:Entropy
Section6.2
DifficultyLevel:Hard
16. Whyistheentropychangenegativeforringclosures?
A.Closingaringresultsinfewermolecules.
B.Closingaringresultsinmoremolecules.
C.Closingaringreleasesenergy.
D.Closingaringrestrictstherotationaroundindividualcarboncarbonbonds.
Ans:D
Topic:Entropy
Section6.2
DifficultyLevel:Hard
17. WhichofthefollowingwouldyouexpecttohavethemostnegativeS?

Ans:D
Topic:Entropy
Section6.2
DifficultyLevel:Hard
18. Offollowingreactions,whichone(s)wouldyouexpecttohaveanegativeS?

Ans:AandB

Topic:GibbsFreeEnergy
Section6.3
DifficultyLevel:Easy
19. PredictthesignofGforanexothermicreactionwithanincreaseinentropy.
A.positive
B.negative
C.nochange
D.cannotpredictwithoutadditionalinformation
Ans:B
Topic:GibbsFreeEnergy
Section6.3
DifficultyLevel:Easy
20. PredictthesignofGforanendothermicreactionwithanincreaseinentropy.
A.positive
B.negative
C.nochange
D.cannotpredictwithoutadditionalinformation
Ans:D
Topic:GibbsFreeEnergy
Section6.3
DifficultyLevel:Easy

21. PredictthesignofGforanexothermicreactionwithadecreaseinentropy.
A.positive
B.negative
C.nochange
D.cannotpredictwithoutadditionalinformation
Ans:D
Topic:GibbsFreeEnergy
Section6.3
DifficultyLevel:Easy
22. PredictthesignofGforanendothermicreactionwithadecreaseinentropy.
A.positive
B.negative
C.nochange
D.cannotpredictwithoutadditionalinformation
Ans:A
Topic:Equilibria
Section6.4
DifficultyLevel:Easy
23. DoesareactionwithapositiveGfavorreactantsorproducts?
Ans:Reactants
Topic:Equilibria
Section6.4
DifficultyLevel:Easy
24. DoesareactionwithanegativeGfavorreactantsorproducts?
Ans:Products
Topic:Equilibria
Section6.4
DifficultyLevel:Hard
25. DoesareactionwithapositiveSandapositiveHfavorreactantsorproducts?
Ans:Cannotdeterminewithoutadditionalinformation
Topic:Equilibria
Section6.4
DifficultyLevel:Hard

26. DoesareactionwithapositiveSandanegativeHfavorreactantsorproducts?
Ans:Products
Topic:Equilibria
Section6.4
DifficultyLevel:Easy
27. DoesareactionwithaKeq=10favorreactantsorproducts?
Ans:Products
Topic:Equilibria
Section6.4
DifficultyLevel:Hard
28. DoesareactionwithaHof14kJ/molandaSof150J/molKat298Kfavor
reactantsorproducts?
Ans:Products
Topic:Equilibria
Section6.4
DifficultyLevel:Hard
29. DoesareactionwithaHof20kJ/molandaSof10J/molKat298Kfavor
reactantsorproducts?
Ans:Reactants
Topic:Kinetics
Section6.5
DifficultyLevel:Easy
30. Giventhefollowingratelaw,whatistheorderofthereactionwithrespectto
MeI?
Ans:first
Topic:Kinetics
Section6.5
DifficultyLevel:Easy
31. Giventhefollowingratelaw,whatistheorderofthereactionwithrespectto
tertbutyliodide?

Ans:first

Topic:Kinetics
Section6.5
DifficultyLevel:Easy
32. Giventhefollowingratelaw,whatistheorderofthereactionwithrespectto
sodiumcyanide?
Ans:second
Topic:Kinetics
Section6.5
DifficultyLevel:Easy
33. Whatistheenergyofactivationforthefollowingreaction?

Ans:10kJ/mol
Topic:Kinetics
Section6.5
DifficultyLevel:Hard
34. Whatistheenergyofactivationforthefollowingreaction?

Ans:10kJ/mol
Topic:Kinetics

Section6.5
DifficultyLevel:Easy
35. Basedonthefollowingenergydiagram,isthereactionexothermicor
endothermic?

Ans:exothermic
Topic:Kinetics
Section6.5
DifficultyLevel:Easy
36. Basedonthefollowingenergydiagram,isthereactionexothermicor
endothermic?

Ans:endothermic
Topic:Kinetics
Section6.5
DifficultyLevel:Hard
37. Whatistheeffectofacatalystonareaction?
A.Itincreasestherate.
B.Itdecreasestheentropy.
C.Itchangestheequilibrium.
D.Itmakestheproductsmorestable.
Ans:A

Topic:Kinetics
Section6.5
DifficultyLevel:Easy
38. Whichofthefollowingdescribestheeffectofacatalystonareaction?
A.Itlowersthefreeenergyoftheproducts.
B.Itmakesthereactantslessstable.
C.Itchangestheequilibriumconstant.
D.Itlowerstheenergyofactivation.
Ans:D
Topic:ReadingEnergyDiagrams
Section6.6
DifficultyLevel:Medium
39. Whichofthefollowingisanenergydiagramforathreestepreaction?

Ans:B
Topic:ReadingEnergyDiagrams
Section6.6
DifficultyLevel:Medium
40. Whichofthefollowingisanenergydiagramforatwostepreaction?

Ans:B
Topic:ReadingEnergyDiagrams
Section6.6
DifficultyLevel:Medium
41. Drawanenergydiagramforanendothermicreactionwithtwosteps.

Ans:
Topic:ReadingEnergyDiagrams
Section6.6
DifficultyLevel:Medium
42. Drawanenergydiagramforathreestepreaction.

Ans:
Topic:ReadingEnergyDiagrams
Section6.6
DifficultyLevel:Hard
43. Drawanenergydiagramforaconcertedexothermicreaction.

Ans:
Topic:ReadingEnergyDiagrams
Section6.6
DifficultyLevel:Medium
44. Whichofthefollowingenergydiagramsshowsaconcertedendothermicreaction?

Ans:D
Topic:ReadingEnergyDiagrams
Section6.6
DifficultyLevel:Medium
45. Whichofthefollowingenergydiagramsshowsthereactionwiththesmallest
energyofactivation?

Ans:A
Topic:ReadingEnergyDiagrams
Section6.6
DifficultyLevel:Easy
46. Whatisatransitionstate?
A.Anisolableintermediateinareaction.
B.Thestartingmaterialsofthereaction.
C.Alocalmaximumontheenergydiagram.
D.Alowenergypointbetweenthestartingmaterialsandtheproduct.
Ans:C
Topic:ReadingEnergyDiagrams
Section6.6
DifficultyLevel:Easy
47. Whatisanintermediate?
A.Alocalmaximumontheenergydiagram.
B.Apointonthereactionpathwaythathasadiscretelifetime.
C.Apointhalfwaybetweenthestartingmaterialsandproducts.
D.Thehighestenergycompoundonanenergydiagram.

Ans:B
Topic:ReadingEnergyDiagrams
Section6.6
DifficultyLevel:Easy
48. Whichofthefollowingenergydiagramsisofareactionwithonetransitionstate?

Ans:A
Topic:ReadingEnergyDiagrams
Section6.6
DifficultyLevel:Easy
49. Whichofthefollowingenergydiagramsisofareactionwithoneintermediate?

Ans:B
Topic:NucleophilesandElectrophiles
Section6.7
DifficultyLevel:Easy
50. Identifythenucleophilicsiteinthefollowingmolecule.

Ans:

Topic:NucleophilesandElectrophiles
Section6.7
DifficultyLevel:Easy
51. Identifythenucleophilicsiteinthefollowingmolecule.

Ans:
Topic:NucleophilesandElectrophiles
Section6.7
DifficultyLevel:Hard
52. Identifythenucleophilicsite(s)inthefollowingmolecule.

Ans:
Topic:NucleophilesandElectrophiles
Section6.7
DifficultyLevel:Medium
53. Identifythenucleophiliccentersinthefollowingmolecule.

Ans:
Topic:NucleophilesandElectrophiles
Section6.7
DifficultyLevel:Easy
54. Identifythenucleophilicatominthefollowingmolecule.
A.P

B.C
C.H
D.Me
Ans:A
Topic:NucleophilesandElectrophiles
Section6.7
DifficultyLevel:Hard
55. Identifytheelectrophilicsiteinthefollowingmolecule.

Ans:
Topic:NucleophilesandElectrophiles
Section6.7
DifficultyLevel:Easy
56. Identifytheelectrophilicsiteinthefollowingmolecule.

A.H
B.Cofcarbonyl
C.Cotherthancarbonyl
D.Oofcarbonyl
Ans:B
Topic:NucleophilesandElectrophiles
Section6.7
DifficultyLevel:Medium
57. Identifytheelectrophilicsiteinthefollowingmolecule.

Ans:
Topic:NucleophilesandElectrophiles

Section6.7
DifficultyLevel:Easy
58. Identifytheelectrophilicsiteinthefollowingmolecule.

Ans:
Topic:NucleophilesandElectrophiles
Section6.7
DifficultyLevel:Hard
59. Identifytheelectrophilicsiteinthefollowingmolecule.

A.C
B.O
C.B
D.Noelectrophilicsite
Ans:C
Topic:NucleophilesandElectrophiles
Section6.7
DifficultyLevel:Easy
60. Whichofthefollowingcannotbeanucleophile?

Ans;A
Topic:NucleophilesandElectrophiles
Section6.7
DifficultyLevel:Easy
61. Whichofthefollowingcannotbeanelectrophile?

Ans:D
Topic:MechanismsandArrowPushing
Section6.8
DifficultyLevel:Easy
62. Whichofthefollowingishydride?
A.H+
B.H
C.H
D.H2
Ans:C
Topic:MechanismsandArrowPushing
Section6.8
DifficultyLevel:Medium
63. Drawthestructureofhydride.
Ans:
Topic:MechanismsandArrowPushing
Section6.8
DifficultyLevel:Easy
64. Whichofthefollowingisthemoststablecation?

Ans:C
Topic:MechanismsandArrowPushing
Section6.8
DifficultyLevel:Easy
65. Forthefollowingreactionstep,indicatewhichpatternofarrowpushingit
represents.

A.Protontransfer
B.Lossofleavinggroup

C.Nucleophilicattack
D.Rearrangement
Ans:A
Topic:MechanismsandArrowPushing
Section6.8
DifficultyLevel:Easy
66. Forthefollowingreactionstep,indicatewhichpatternofarrowpushingit
represents.

A.Protontransfer
B.Lossofleavinggroup
C.Nucleophilicattack
D.Rearrangement
Ans:C
Topic:MechanismsandArrowPushing
Section6.8
DifficultyLevel:Medium
67. Forthefollowingreactionstep,indicatewhichpatternofarrowpushingit
represents.

Ans:Nucleophilicattack
Topic:MechanismsandArrowPushing
Section6.8
DifficultyLevel:Easy
68. Forthefollowingreactionstep,indicatewhichpatternofarrowpushingit
represents.

A.Protontransfer
B.Lossofleavinggroup
C.Nucleophilicattack

D.Rearrangement
Ans:B
Topic:MechanismsandArrowPushing
Section6.8
DifficultyLevel:Easy
69. Forthefollowingreactionstep,indicatewhichpatternofarrowpushingit
represents.

A.Protontransfer
B.Lossofleavinggroup
C.Nucleophilicattack
D.Rearrangement
Ans:A
Topic:MechanismsandArrowPushing
Section6.8
DifficultyLevel:Easy
70. Forthefollowingreactionstep,indicatewhichpatternofarrowpushingit
represents.

A.Protontransfer
B.Lossofleavinggroup
C.Nucleophilicattack
D.Rearrangement
Ans:D
Topic:MechanismsandArrowPushing
Section6.8
DifficultyLevel:Easy
71. Forthefollowingreactionstep,indicatewhichpatternofarrowpushingit
represents.

A.Protontransfer
B.Lossofleavinggroup
C.Nucleophilicattack
D.Rearrangement
Ans:C
Topic:MechanismsandArrowPushing
Section6.8
DifficultyLevel:Medium
72. Melphalan,adrugusedinchemotherapy,reactswithitselfinthebodybefore
bindingwithitstarget,asillustratedinthemechanismbelow.Whichtwopatterns
ofarrowpushingareseeninthisreaction?

Ans.Nucleophilicattackandlossofleavinggroup

Topic:MechanismsandArrowPushing
Section6.8
DifficultyLevel:Medium
73. Melphalan,adrugusedinchemotherapy,reactswithitselfbeforebindingwithits
targetinthebody,asillustratedbelow.Drawinthecurvedarrowsthataccount
forthistransformation.

Ans.

Topic:MechanismsandArrowPushing
Section6.8
DifficultyLevel:Medium
74. Thefollowingreactionhasthreemechanisticsteps.Drawallcurvedarrows
necessarytocompletethemechanism.

Ans.
Topic:MechanismsandArrowPushing
Section6.8
DifficultyLevel:Easy
75. Whatiswrongwiththefollowingmechanism?

A.Thereisnoleavinggroup,sothereshouldbenoarrows.
B.ThearrowshouldberemovingaprotonfromtheH2Ogroup.
C.Anarrowisalsoneededtoindicatethelossoftheleavinggroup.
D.Thearrowisbackwards.
Ans:C
Topic:MechanismsandArrowPushing
Section6.8
DifficultyLevel:Hard
76. Whatiswrongwiththefollowingmechanism?

A.Thereisnoleavinggroup,sothereshouldbenoarrows.
B.ThearrowshouldberemovingaprotonfromtheH2Ogroup.
C.Anarrowisalsoneededtoindicatethelossoftheleavinggroup.
D.ThearrowindicatingtheformationoftheCBrbond(nucleophilicattack)shouldstart
atthebromideanion.
Ans:D
Topic:MechanismsandArrowPushing
Section6.8
DifficultyLevel:Easy
77. Whichofthefollowingmechanisticstepsrepresentsanucleophilicattack?

Ans:B
Topic:MechanismsandArrowPushing
Section6.8
DifficultyLevel:Easy
78. Whichofthefollowingmechanisticstepsrepresentsthelossofaleavinggroup?

Ans:C

Topic:CombiningPatterns
Section6.9
DifficultyLevel:Easy
79. Identifythesequenceofcurvedarrows(electronmovement)inthestepsofthe
followingreaction.

A.Protontransfer,protontransfer
B.Protontransfer,lossofleavinggroup
C.Nucleophilicattack,protontransfer
D.Protontransfer,nucleophilicattack
Ans:A
Topic:CombiningPatterns
Section6.9
DifficultyLevel:Medium
80. Thefollowingreactionhasthreemechanisticsteps.Identifythepatternofarrow
pushingstepsineachstep.

Ans.Protontransfer;lossofleavinggroup,nucleophilicattack

Topic:CombiningPatterns
Section6.9
DifficultyLevel:Hard
81. Identifythesequenceofcurvedarrows(electronmovement)inthestepsofthe
followingreaction.

A.Protontransfer,protontransfer,nucleophilicAttack
B.Protontransfer,lossofleavinggroup
C.Nucleophilicattack,protontransfer,lossofleavinggroup
D.Protontransfer,nucleophilicattack,protontransfer
Ans:D
Topic:CombiningPatterns
Section6.9
DifficultyLevel:Hard
82. Identifythesequenceofcurvedarrows(electronmovement)inthestepsofthe
followingreaction.

A.Protontransfer,protontransfer,nucleophilicattack
B.Protontransfer,lossofleavinggroup,nucleophilicattack,protontransfer
C.Nucleophilicattack,protontransfer,lossofleavinggroup
D.Protontransfer,lossofleavinggroup,protontransfer,nucleophilicattack
Ans:B
Topic:CombiningPatterns
Section6.9
DifficultyLevel:Easy
83. Identifythesequenceofcurvedarrows(electronmovement)inthestepsofthe
followingreaction.

A.Protontransfer,protontransfer
B.Protontransfer,lossofleavinggroup
C.Nucleophilicattack,protontransfer
D.Protontransfer,nucleophilicattack

Ans:D
Topic:CombiningPatterns
Section6.9
DifficultyLevel:Hard
84. Whatpatternofcurvedarrowpushingisthesecondstepofthisreaction?

A.Protontransfer
B.Lossofleavinggroup
C.Nucleophilicattack
D.Rearrangement
Ans:B
Topic:CombiningPatterns
Section6.9
DifficultyLevel:Easy
85. Whatpatternofcurvedarrowpushingisthefourthstepofthisreaction?

A.Protontransfer
B.Lossofleavinggroup
C.Nucleophilicattack
D.Rearrangement
Ans:A
Topic:CombiningPatterns
Section6.9
DifficultyLevel:Easy

86. Whatpatternofcurvedarrowpushingisthesecondstepofthisreaction?

A.Protontransfer
B.Lossofleavinggroup
C.Nucleophilicattack
D.Rearrangement
Ans:C
Topic:CombiningPatterns
Section6.9
DifficultyLevel:Easy
87. Whatpatternofcurvedarrowpushingisthesecondstepofthisreaction?

A.Protontransfer
B.Lossofleavinggroup
C.Nucleophilicattack
D.Rearrangement
Ans:B
Topic:CombiningPatterns
Section6.9
DifficultyLevel:Hard
88. Whatpatternofcurvedarrowpushingisthesecondstepofthisreaction?

Ans:Nucleophilicattack
Topic:DrawingCurvedArrows
Section6.10
DifficultyLevel:Hard
89. Drawarrowsforeachstepofthefollowingreaction.

Ans:

Topic:DrawingCurvedArrows
Section6.10
DifficultyLevel:Hard
90. Drawcurvedarrowsforeachstepofthefollowingreaction.

Ans:

Topic:DrawingCurvedArrows
Section6.10
DifficultyLevel:Hard
91. Drawcurvedarrowsforthefollowingmechanisticstep.

Ans:
Topic:DrawingCurvedArrows
Section6.10
DifficultyLevel:Medium
92. Identifythenucleophilicandelectrophilicsitesinthereactantsofthefollowing
reaction.

Ans:

Topic:DrawingCurvedArrows
Section6.10
DifficultyLevel:Easy
93. Whichofthefollowingisthenucleophilicsiteinthereactantsofthefollowing
reaction?

A.Cofthecarbonyl
B.O
C.Li

D.MeofLiMe
Ans:D
Topic:DrawingCurvedArrows
Section6.10
DifficultyLevel:Easy
94. Whichofthefollowingistheelectrophilicsiteinthereactantsofthefollowing
reaction?

A.Cofthecarbonyl
B.O
C.Li
D.Me
Ans:A
Topic:DrawingCurvedArrows
Section6.10
DifficultyLevel:Medium
95. Identifythenucleophilicandelectrophilicsitesinthesubstrateandreagentofthe
followingreaction.

Ans:

Topic:DrawingCurvedArrows
Section6.10
DifficultyLevel:Easy
96. Whichofthefollowingistheelectrophilicsiteinthereactantsofthefollowing
reaction?

A.Cofcarbonyl
B.Oofcarbonyl
C.Cl
D.Oofalcohol
Ans:A
Topic:CarbocationRearrangements
Section6.11
DifficultyLevel:Easy
97. Whichofthefollowingcationsismostlikelytoundergorearrangement?

Ans:B
Topic:CarbocationRearrangements
Section6.11
DifficultyLevel:Easy
98. Willthefollowingcationundergorearrangement?

Ans:Yes
Topic:CarbocationRearrangements
Section6.11
DifficultyLevel:Easy
99. Willthefollowingcationundergorearrangement?
Ans:No
Topic:CarbocationRearrangements
Section6.11
DifficultyLevel:Easy
100.

Willthefollowingcationundergorearrangement?

Ans:Yes
Topic:CarbocationRearrangements
Section6.11
DifficultyLevel:Easy
101.

Willthefollowingcationundergorearrangement?

Ans:Yes
Topic:CarbocationRearrangements
Section6.11
DifficultyLevel:Easy
102.
Whichofthefollowingisthemostlikelystructureofthefollowingcation
afterrearrangement?

Ans:D
Topic:CarbocationRearrangements
Section6.11
DifficultyLevel:Easy
103.
Whichofthefollowingisthemostlikelystructureofthefollowingcation
afterrearrangement?

Ans:A
Topic:CarbocationRearrangements
Section6.11
DifficultyLevel:Easy
104.
Whichofthefollowingisthemostlikelystructureofthefollowingcation
afterrearrangement?

Ans:B
Topic:CarbocationRearrangements
Section6.11
DifficultyLevel:Medium
105.
Drawthestructureofthemostlikelyfollowingcationafterithas
rearranged.

Ans:
Topic:CarbocationRearrangements
Section6.11
DifficultyLevel:Medium
106.
Drawthemostlikelystructureofthefollowingcationafterithas
rearranged.

Ans:
Topic:CarbocationRearrangements
Section6.11
DifficultyLevel:Hard
107.
Drawthemechanismandmostlikelyproductforthefollowingcation
rearrangement.

Ans:

Topic:CarbocationRearrangements
Section6.11
DifficultyLevel:Hard

108.
Drawthemechanismandmostlikelyproductforthefollowingcation
rearrangement.

Ans:

Topic:CombiningPatterns+Spectroscopy
Section6.9+Spectroscopy
DifficultyLevel:Medium
109.
Considertheproductofthefollowingmechanism.Howmanydistinct
resonanceswouldappearinthe(protondecoupled)13CNMRspectrumforthe
product?

A.2
B.3
C.4
D.5
Ans:C
Topic:Integrated
Section6.2and6.9
DifficultyLevel:Medium
110.
Considerthefollowingreaction.Whatpatternsofarrowpushingare
likelyinvolvedintheformationoftheproduct?WouldyouexpecttheSforthe
reactiontobepositiveornegative?

Ans:Protontransferandlossofaleavinggroup;Sisexpectedtobepositive.