Magnetic anisotropy in Nuclear Magnetic Resonance (NMR)

In studies of NMR, atoms play an important role because when an

atom was placed in a magnetic field, its electrons circulate about the
direction of applied magnetic field. The circulation causes a small
magnetic field at the nucleus which opposes the externally applied field.
Which means magnetic field at nucleus was flow oppositely compare to
outer applied field. Meanwhile in magnetic anisotropy, the chemical shift
was decrease where to the right of spectrum due to circulation of
electrons around Hydrogen. Example was electron became stronger when
magnetic field was perpendicular to the plane of benzene or any aromatic
ring. It causes very large shielding where it towards the right of spectrum
thus, increasing magnetic field at fixed frequency and also shielding by
extranuclear electrons but decreasing frequency at fixed magnetic field.
Furthermore, it will affect the protons which placed above the ring thus
producing smaller deshielding effects for protons at the side of it. The
orientation of molecule of electron circulation was stronger in magnetic
field than the others. Relationship between functional groups and nearby
proton was depended by the chemical shift changes. Magnetic anisotropy
may lead to give a stereochemical element to the chemical shift of a
nucleus.