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Department of Physics and Astronomy, University College London, Gower Street, London WC1E 6BT, UK
Accepted 2015 March 3. Received 2015 February 14; in original form 2015 January 15
ABSTRACT
INTRODUCTION
2+
The spectral lines of doubly-ionised oxygen, O , are important diagnostic tools in a variety of astronomical and
astrophysical situations, such as solar and nebular studies,
due to the abundance of this ion in these environments and
the brightness of a number of its lines (Aggarwal & Keenan
1999). They are used for instance to determine the oxygen abundance and other physical conditions in the Milky
Way and other galaxies out to substantial cosmological distances (Maiolino et al 2008). There has been a recent advocation (Nicholls et al 2012, 2013) of the use of non MaxwellBoltzmann (MB) electron energy distributions in the analysis of the spectra of planetary nebulae (PNe) and H ii regions. It has been proposed that the discrepancy between the
results for elemental abundance and electron temperature
obtained from the optical recombination lines (ORLs) and
those obtained from the collisionally-excited lines (CELs)
could be resolved if the free electron energies are described
by a -distribution (Vasyliunas 1968) rather than a MB one.
Storey & Sochi (2013) attempted to test this hypothesis using a subset of dielectronic recombination lines to directly
sample the free electron energy distribution. No evidence
was found for departures from a MB distribution in a small
sample of PNe but the uncertainties in the observational
data made it impossible to rule out such departures. Zhang
et al (2014) modelled the shape of the Balmer continuum
in the spectra of a sample of PNe and concluded that both
a model comprising two MB distributions of different tem-
E-mail: t.sochi@ucl.ac.uk
c 0000 RAS
COLLISION STRENGTHS
THEORETICAL BACKGROUND
(
)
f (j ) dj
(2)
ji
ij j
2 0
j
2
fMB (, T ) = q
e kB T
(3)
(kB T )3
based on a thermodynamic equilibrium state. Similar
thermal-averaging procedures with respect to other electron distribution functions can also apply to reflect nonequilibrium states. The most widely used non-equilibrium
distribution function is the distribution which is given, in
one of its common forms, by (Vasyliunas 1968; Summers &
Thorne 1991)
2 ( + 1)
f (, T, ) = q
+1 (4)
(kB T )3 ( 23 )3 ( 12 ) 1 + ( 3)k T
2
R
8.629 106 s
2 ca20
qij =
s '
, (cgs units)(6)
i
kB T
i T
where i is the statistical weight of state i, c is the speed
of light in vacuum, is the fine structure constant, a0 is
the Bohr radius, and R is the Rydberg energy constant and
where the temperature is in Kelvin. Similarly, the collisional
de-excitation rate coefficients, qji , can be obtained from the
Downsilons, , using the following formula
s
2 ca20
R
8.629 106
qji =
'
(cgs units) (7)
j
kB T
j T
s = e
Eij
k T
B
(5)
In Figure 2 we show contour plots of s / T as a function of T and 1/ for three representative transitions. In this
and subsequent contour plots the values are base 10 logarithms of the relevant quantity, normalised to the value for
an MB distribution at 104 K, which we will refer to as the
standard PN conditions. The plotted quantity is proportional to the excitation rate coefficient for each transition.
The 1-4 transition is one of the means of exciting level 4, the
1
D2 level, which gives rise to the important 4959, 5007
lines. The plot for this transition shows that the 1-4 excitation rate coefficient at 104 K is largely insensitive to the
value of for values of larger than about 3. The picture
is different for the 1-5 transition which excites the 4363
line which, by comparison with the 4959, 5007 lines is a
temperature diagnostic. The contour plot for this transition
shows that the excitation rate coefficient is sensitive to in
such a way that the standard PN value can occur at lower
temperatures as decreases. Hence we can expect that the
ratio of the intensities of the lines from level 4 and 5, which
are commonly used as a temperature diagnostic, will also be
sensitive to the value of .
In Figure 3 we show a contour plot of the principal
[O iii] temperature diagnostic, the ratio of the sum of the
emission coefficients, , of the two lines 4959, 5007 to the
4363 line at an electron number density of 104 cm3 . The
emission coefficients were computed using a model atom
Table 1. The five lowest energy levels of O2+ with their experimental energies, Eex , in wavenumbers (cm1 ). These values were
obtained from the National Institute of Standards and Technology database (www.nist.gov).
Level
1
2
3
4
5
1s2
1s2
1s2
1s2
1s2
2s2
2s2
2s2
2s2
2s2
Eex
2p2
2p2
2p2
2p2
2p2
3P
3P
3P
1D
1S
0.00
113.18
306.17
20273.27
43185.74
Percentage Difference
Index
80
60
40
20
0
CONCLUSIONS
In the present paper, the effective collision strengths for electron excitation and de-excitation between the lowest five
levels of O2+ are computed with a electron energy distribution using a previously published set of collision strengths.
Extensive tabulations of the effective collision strengths as
a function of temperature and are provided. We also illustrate and discuss the general behaviour of the most commonly used [O iii] visible lines as a function of these two variables, and the effect on abundance determinations of adopting non-Maxwellian distributions for the free electrons. This
work is intended to provide the data required for modelling
and analysing optically thin plasma found mainly in planetary nebulae and H ii regions, where it has been suggested
that a non-MB electron distribution may apply and could
provide a solution to the long standing problem in nebular
physics of the contradiction between the results of elemen-
-20
0
0.5
1.5
2.5
T4[K]
ACKNOWLEDGMENT
REFERENCES
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Aggarwal K.M., 1985, A&A, 146, 149
Aggarwal K.M., 1993, ApJS, 85, 197
Aggarwal K.M., Keenan F.P., 1999, ApJS, 123, 311
Aggarwal K.M., Keenan F.P., 2015, arXiv:1501.00808
Baluja K.L., Burke P.G., Kingston A.E., 1980, J. Phys. B,
13, 829
Berrington K.A., Eissner W.B., Norrington P.H., 1995,
Comp. Phys. Comm., 92, 290
Fern
andez-Menchero L., Del Zanna G., Badnell N.R., 2014,
A&A, 566, A104
Fischer C.F., Tachiev G., 2004, At. Data. Nucl. Data Tables, 87, 1
Griffin D.C., Badnell N.R., Pindzola M.S., 1998, J. Phys.
B, 31, 3713
Lennon D.J., Burke V.M., 1994, A&AS, 103, 273
Maiolino R., Nagao T., Grazian A., et al, 2008, A&A, 488,
463
Mendoza C., Bautista M.A., 2014, ApJ, 785, 91
Nicholls D.C., Dopita M.A., Sutherland R.S., 2012, ApJ,
752, 148
c 0000 RAS, MNRAS 000, 000000
(a) 12
.10
0
0
0
0.
0.5
0.90
0.85
0.80
0.80
1/
0.50
0.10
0.25
0.25
0.40
0.00
0.50
0.10
0.1
0.
0
0.
5
1.0 0
0
2.50
6.00
2.5
3
log10T[K]
3.5
Figure
3.
A
contour
plot
of
log10 [((4959) +
(5007))/(4363)] as a function of log10 T in K and 1/,
normalised to the MB value at T = 104 K.
.5
0.6
0.2
5
1/
00
0
0.5
0.00
0.25
0.
0.50
1.00
5
3.
1/
0.50
1.7
2.5
1.00
3
log10T[K]
00
3.5
0.50
4
.
.00
2.5
1.00
6
.00
0.00 50
0.
.00
1 0
.5
1
0
0 .5
.0 2
8.0
0
4
.00
00
8
2
00
7.0
2.5
3
log10T[K]
3.5
0.50
0.00
0.1
.50
0
0
.0
1
0
.5
.0
0
2
.50
6.
0.2
11.0
19.00
.50
0.3
0
5.
0.1
0.5
0.4
7.0
.00
1
.5
0
.0
0
3.
5
0.2
(c) 15
1.00
0.3
0
3.5
0.6
1.7
50
3
log10T[K]
1.00
2.5
50
5.0
0.50
.00
76.0
.00 0
0.5
3.
0.00
0.4
2.
50
0.
0.5
0.00
1/
2.50
00
0.1
0.50
6
7. .00
00
0
1.5
.00
2
0
00 .5
.50 3. 3
2
0.2
.0
0
3
.5
0
4
.
5
.00
50
1.0
1.
.5
4
.0
0.3
.00
2
0.4
1.
0
.0
1.75
0.5
3
0.0
2.50
.00
.50
1
0
2.5
2.00
0.50
1.00
6.00
(b) 14
0.6
0.00
0.50
1.00
0
0.60.50
0.40
0.2
3.5
0.25
0.00
3
log10T[K]
0
.60
0
.50
0.50
0.50
0.3
2.5
0.60
0.60
.2
0.7
0.1
0.70
0.80
0.5
0.4
0.00
0.4
0.25
0.2
5
0.40
0.1
.80
0.70
0.7
0.2
0.85
0.85
5
0.8
0.4
1/
25
0.
0.90
0.6
0.2
0.1
0.5
0.3
0.4
0
0.4
0.6
Table 2. Maximum and average error in interpolating the logarithmic values of scaled Upsilon and Downsilon in T and
where MET=maximum absolute percentage error in T interpolation, AET=average absolute percentage error in T interpolation,
MEK=maximum absolute percentage error in interpolation, and AEK=average absolute percentage error in interpolation.
Upsilon
Downsilon
Transition
MET
AET
MEK
AEK
MET
AET
MEK
AEK
1-2
1-3
1-4
1-5
2-3
2-4
2-5
3-4
3-5
4-5
0.069
0.178
0.464
0.586
0.112
0.461
0.584
0.459
0.581
0.455
0.012
0.025
0.074
0.088
0.018
0.074
0.088
0.074
0.088
0.078
0.562
0.562
0.563
0.872
0.562
0.563
0.868
0.563
0.860
0.571
0.021
0.024
0.072
0.093
0.022
0.072
0.093
0.071
0.093
0.075
0.012
0.017
0.017
0.014
0.017
0.017
0.014
0.017
0.014
0.017
0.002
0.001
0.002
0.002
0.001
0.002
0.002
0.002
0.002
0.005
0.367
0.308
0.319
0.313
0.312
0.319
0.313
0.319
0.313
0.304
0.024
0.020
0.021
0.021
0.021
0.021
0.021
0.021
0.021
0.020
Table 3. Sample log10 of scaled Upsilon data for the 1-5 transition.
T
2.000
2.025
2.050
2.075
2.100
2.125
2.150
2.175
2.200
2.225
2.250
2.275
2.300
1.600
1.625
1.650
1.675
1.700
1.725
1.750
1.775
1.800
1.825
1.850
1.875
1.900
1.925
1.950
1.975
2.000
-7.085
-7.063
-7.056
-7.061
-7.073
-7.091
-7.113
-7.138
-7.167
-7.197
-7.230
-7.264
-7.300
-7.336
-7.374
-7.412
-7.452
-7.045
-7.022
-7.015
-7.019
-7.031
-7.048
-7.069
-7.094
-7.122
-7.152
-7.184
-7.217
-7.252
-7.288
-7.325
-7.363
-7.402
-7.005
-6.981
-6.974
-6.977
-6.988
-7.005
-7.025
-7.050
-7.077
-7.106
-7.137
-7.170
-7.205
-7.240
-7.277
-7.314
-7.352
-6.965
-6.941
-6.933
-6.935
-6.946
-6.961
-6.982
-7.005
-7.032
-7.061
-7.091
-7.124
-7.157
-7.192
-7.228
-7.264
-7.302
-6.925
-6.900
-6.892
-6.894
-6.903
-6.918
-6.938
-6.961
-6.987
-7.015
-7.045
-7.077
-7.110
-7.144
-7.179
-7.215
-7.252
-6.885
-6.860
-6.850
-6.852
-6.861
-6.875
-6.894
-6.917
-6.942
-6.969
-6.999
-7.030
-7.062
-7.096
-7.130
-7.166
-7.202
-6.845
-6.819
-6.809
-6.810
-6.818
-6.832
-6.850
-6.872
-6.897
-6.924
-6.953
-6.983
-7.015
-7.048
-7.082
-7.117
-7.152
-6.805
-6.778
-6.768
-6.768
-6.776
-6.789
-6.807
-6.828
-6.852
-6.878
-6.906
-6.936
-6.967
-7.000
-7.033
-7.067
-7.102
-6.765
-6.738
-6.727
-6.726
-6.733
-6.746
-6.763
-6.784
-6.807
-6.833
-6.860
-6.889
-6.920
-6.952
-6.984
-7.018
-7.052
-6.725
-6.697
-6.685
-6.684
-6.691
-6.703
-6.719
-6.739
-6.762
-6.787
-6.814
-6.843
-6.872
-6.904
-6.936
-6.969
-7.002
-6.685
-6.657
-6.644
-6.642
-6.648
-6.660
-6.676
-6.695
-6.717
-6.741
-6.768
-6.796
-6.825
-6.855
-6.887
-6.919
-6.952
-6.645
-6.616
-6.603
-6.601
-6.606
-6.617
-6.632
-6.651
-6.672
-6.696
-6.722
-6.749
-6.778
-6.807
-6.838
-6.870
-6.902
-6.605
-6.575
-6.562
-6.559
-6.563
-6.574
-6.588
-6.606
-6.627
-6.650
-6.675
-6.702
-6.730
-6.759
-6.790
-6.821
-6.853
2.000
2.025
2.050
2.075
2.100
2.125
2.150
2.175
2.200
2.225
2.250
2.275
2.300
1.600
1.625
1.650
1.675
1.700
1.725
1.750
1.775
1.800
1.825
1.850
1.875
1.900
1.925
1.950
1.975
2.000
-1.123
-1.145
-1.166
-1.185
-1.203
-1.219
-1.233
-1.246
-1.258
-1.269
-1.279
-1.289
-1.297
-1.305
-1.313
-1.320
-1.326
-1.117
-1.140
-1.162
-1.182
-1.200
-1.217
-1.231
-1.245
-1.257
-1.268
-1.278
-1.288
-1.297
-1.305
-1.312
-1.319
-1.326
-1.111
-1.135
-1.158
-1.179
-1.198
-1.215
-1.230
-1.244
-1.256
-1.267
-1.278
-1.287
-1.296
-1.304
-1.312
-1.319
-1.325
-1.105
-1.131
-1.155
-1.177
-1.196
-1.213
-1.228
-1.242
-1.255
-1.266
-1.277
-1.286
-1.295
-1.303
-1.311
-1.318
-1.325
-1.100
-1.128
-1.153
-1.175
-1.194
-1.212
-1.227
-1.241
-1.254
-1.266
-1.276
-1.286
-1.295
-1.303
-1.311
-1.318
-1.324
-1.096
-1.124
-1.150
-1.173
-1.193
-1.210
-1.226
-1.240
-1.253
-1.265
-1.275
-1.285
-1.294
-1.302
-1.310
-1.317
-1.324
-1.091
-1.121
-1.148
-1.171
-1.191
-1.209
-1.225
-1.240
-1.252
-1.264
-1.275
-1.285
-1.294
-1.302
-1.310
-1.317
-1.324
-1.088
-1.119
-1.146
-1.169
-1.190
-1.208
-1.224
-1.239
-1.252
-1.264
-1.274
-1.284
-1.293
-1.302
-1.309
-1.317
-1.323
-1.084
-1.116
-1.144
-1.168
-1.189
-1.207
-1.224
-1.238
-1.251
-1.263
-1.274
-1.284
-1.293
-1.301
-1.309
-1.316
-1.323
-1.081
-1.114
-1.142
-1.167
-1.188
-1.206
-1.223
-1.238
-1.251
-1.263
-1.274
-1.284
-1.293
-1.301
-1.309
-1.316
-1.323
-1.078
-1.112
-1.141
-1.165
-1.187
-1.206
-1.222
-1.237
-1.250
-1.262
-1.273
-1.283
-1.292
-1.301
-1.309
-1.316
-1.323
-1.075
-1.110
-1.139
-1.164
-1.186
-1.205
-1.222
-1.237
-1.250
-1.262
-1.273
-1.283
-1.292
-1.301
-1.309
-1.316
-1.323
-1.073
-1.108
-1.138
-1.163
-1.185
-1.204
-1.221
-1.236
-1.250
-1.262
-1.273
-1.283
-1.292
-1.301
-1.308
-1.316
-1.322