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Warning concerning copyright restrictions The copyright law of the United States (Title 17, United States Code) governs the making of photocopies or other reproductions of copyrighted material. Under certain conditions specified in the law, libraries and archives are authorized to furnish a photocopy or other reproduction. One of these specified conditions is that the photocopy or reproduction is not to be “used for any purpose other than private study, scholarship, or research." If a user makes a request for, or later uses, a photocopy or reproduction for purposes in excess of “fair use," that user may be liable for copyright infringement. This institution reserves the right to refuse to accept a copying order if, in its judgment, fulfillment of the order would involve violation of Copyright Law. LINDA HALL LIBRARY 5109 CHERRY STREET KANSAS CITY, MISSOURI 64110-2498 PHONE (816) 363-4600 FAX: (816) 926-8785 SHIP TO: Library, ILL Portland State University 951 SW Hall Portland, OR 97201 ORZ Patron: Totten, George Fax: (503)-725-4527 Phone: Ariel: ariel.lib.pdx.edu Regular Ariel LHL cca Max Cost: $20.001FM Notes: AMON A 10/8/08DocSery #: 522018 16:28 Shelved as: Loe: journal of synthetic lubrication. Volume: 25 Issue: 3 Date: 2008 Article/Paper: N. H. Jayadas; Evaluation of the oxidative properties of vegetable oils as base stocks for industrial lubricants using spectroscopic and thermogravime Pages: 105-113, OCLC #: 11991940 ISSN: 0265-6582 Lender string: CSO,NJR,NJR,*LHL,MYG TL: 46861386 {AINA 4 DOCSERV / OCLC / PULL SLIP | 4 JOURNAL OF SYNTHETIC LUBRICATION J. Sythe Larication 2008; 25: 105-119 Pablshed online 9 July 2008 in Wiley InerScience {eo imerscience ly com) DOL O.1002)s1 55 Evaluation of the oxidative properties of vegetable oils as base stocks for industrial lubricants using spectroscopic and thermogravimetric analyses N. H. Jayadast” Depariment of Mechanical Engineering, Sch ‘Cochin of Engineering. Cichin University of Science and Technology 682 022, Kerala, Inds ABSTRACT This paper presents the study ofthe oxidative behaviour of vegetable oils using Fourier transform infrared (FTIR), huclear magnetic resonance (NMR) spectroscopic methods and thermogravimetre analysisliferental thermal analysis (TGA/DTA) techniques. The properties of vegetable oils were determined by their fatty acid (FA) com: Position. A high content of polyunsaturated FAS, lke linoleie and linolenic acids, decreases thermal-onidative stability. FTIR spectroscopy can be used as a quick method to measure the degree of unsaturation in vepetable oils in a qualitative manner. NMR spectroscopy can be used to quantitatively evaluate the degree of unsaturation in xegetable oils. TGA/DTA techniques were used to evaluate the oxidative properties of vegetable oils In the Present study, TGA/DTA analyses was performed on different vegetable olls under isothermal condiions at 150°C for 3 hours. TGA/DTA thermograms showed weight changes and thermal activities in terms of exothermic ‘or endothermic heat flows during the oxidative reactions, The oxidative devradation was evaluated in tems of ‘the weight gain by the respective vegetable oils under the test conditions. due to the formation of oxidative polymerization products and the value of exothermic peaks as obtained from the DTA. The comparative study ‘of the oxidative performance of diferent vegetable oils showed thatthe higher the degrees of unsaturation, the higher are the weight gains and the exothermic peaks. The evaluation ofthe effect ofa chosen antioxidant showed ‘marked improvement on the oxidative stability of vegetable ils. Copyright © 2008 John Wiley & Sons, Lid Key WoRDs: oxidation: stability; thermogravimetric analysis; FTIR; NMR INTRODUCTION ‘There has been a growing concern for the use of mineral oils as lubricants because of the worldwide interest in environmental issues [1]. This has promoted research into developing and using vegetable oils as alternative base oils for environmentally benign lubricants. Vegetable oils. in general, have excellent properties such as high viscosity index, high lubricity, high flash point, low evaporative loss, *Conespondence o: N. H,Jayada, School of Engineering. Cochin University of Science and Technology, Cochin 68202 Kerala, India. "sna: jayadasnh@cust ein Copyright © 2008 John Wiley & Sons, Lt,

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