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What is the sum of all coefficients when the following equation is balanced using the smallest
possible whole numbers?
__ C2H2 + __O2 __CO2 + __H2O
A.
B.
C.
11
D.
13
R.
2.
1.7 g of NaNO3 (Mr = 85) is dissolved in water to prepare 0.20 dm of solution. What is the
0.01
B.
0.1
C.
0.2
D.
1.0
R.
3.
How many molecules are present in a drop of ethanol, C 2H5OH, of mass 2.3 10 g?
23
(L = 6.0 10 mol )
19
A.
3.0 10
B.
3.0 10
20
C.
6.0 10
20
D.
6.0 10
26
R.
4.
1 mol of SO2
B.
2 mol of N2O
C.
2 mol of Ar
D.
4 mol of NH3
(Total 1 mark)
R.
B
[1]
IB Questionbank Chemistry
5.
The relative molecular mass of a gas is 56 and its empirical formula is CH 2. What is the
molecular formula of the gas?
R.
A.
CH2
B.
C2H4
C.
C3H6
D.
C4H8
6.
Ethanol is used as a component in fuel for some vehicles. One fuel mixture contains 10 % by
mass of ethanol in unleaded petrol (gasoline). This mixture is often referred to as Gasohol E10.
(a)
Assume that the other 90 % by mass of Gasohol E10 is octane. 1.00 kg of this fuel
mixture was burned.
CH3CH2OH(l) + 3O2(g) 2CO2(g) + 3H2O(l)
1
C8H18(l) + 12 2 O2(g) 8CO2(g) + 9H2O(l)
(i)
H = 1367 kJ mol
H = 5470 kJ mol
Calculate the mass, in g, of ethanol and octane in 1.00 kg of the fuel mixture.
...........................................................................................................................
...........................................................................................................................
(1)
(ii)
Calculate the amount, in mol, of ethanol and octane in 1.00 kg of the fuel mixture.
...........................................................................................................................
...........................................................................................................................
(1)
(iii) Calculate the total amount of energy, in kJ, released when 1.00 kg of the fuel
mixture is completely burned.
...........................................................................................................................
...........................................................................................................................
...........................................................................................................................
...........................................................................................................................
...........................................................................................................................
(3)
(b) If the fuel blend was vaporized before combustion, predict whether the amount of energy
released would be greater, less or the same. Explain your answer.
IB Questionbank Chemistry
......................................................................................................................................
......................................................................................................................................
......................................................................................................................................
......................................................................................................................................
(2)
(Total 7 marks)
R.
(a)
(i)
(ii)
(iii)
total energy released = (2966 + 43104) = 4.61 10 (kJ);Award [3] for correct
final answer.
Accept answers using whole numbers for molar masses and rounding.
(b)
greater;
fewer intermolecular bonds/forces to break / vaporization is
endothermic / gaseous fuel has greater enthalpy than liquid fuel / OWTTE;M2 cannot be
scored if M1 is incorrect.
7.
What mass, in g, of hydrogen is formed when 3 mol of aluminium react with excess
hydrochloric acid according to the following equation?
2Al(s) + 6HCl(aq) 2AlCl3(aq) + 3H2(g)
A.
3.0
B.
4.5
C.
6.0
D.
9.0
R.
8.
What is the total number of hydrogen atoms in 1.0 mol of benzamide, C 6H5CONH2?
A.
B.
6.0 10
23
C.
3.0 10
24
D.
4.2 10
24
R.D
9.
What is the sum of the coefficients for the equation when balanced using the smallest possible
whole numbers?
__N2H4(g) + __O2(g) __NO2(g) + __H2O(g)
A.
IB Questionbank Chemistry
B.
C.
D.
10.
R.D
4.00
B.
8.00
C.
10.0
D.
20.0
R.A
11. A fixed mass of gas has a certain volume at a temperature of 50 C. What temperature is
required to double its volume while keeping the pressure constant?
A.
100 K
B.
323 K
C.
373 K
D.
646 K
R.D
3
12. What is the concentration of NaCl, in mol dm , when 10.0 cm of 0.200 mol dm NaCl
3
3
solution is added to 30.0 cm of 0.600 mol dm NaCl solution?
13.
14.
A.
0.450
B.
0.300
C.
0.500
D.
0.800
R.C
Which amount of the following compounds contains the least number of ions?
A.
2 mol of NaOH
B.
1 mol of NH4Cl
C.
2 mol of CaCl2
D.
1 mol of Al2O3
R.B
1
120
B.
130
IB Questionbank Chemistry
15.
C.
138
D.
246
R.D
C5H12
B.
C5H10
C.
C4H8
D.
C4H10
R.A
16. 12 molecules of hydrogen gas, H2(g), and 5 molecules of oxygen gas, O2(g), were mixed
together under conditions which allowed the reaction to go to completion, according to the following
equation.
2H2(g) + O2(g) 2H2O(g)
The following diagram represents the mixture of reactants.
Which diagram represents the reaction mixture when the reaction was complete?
A.
B.
IB Questionbank Chemistry
C.
D.
R.A
17.
Brass is a copper containing alloy with many uses. An analysis is carried out to determine the
percentage of copper present in three identical samples of brass. The reactions involved in this
analysis are shown below.
+
2+
2+
(i)
Deduce the change in the oxidation numbers of copper and nitrogen in step 1.
Copper:
...........................................................................................................................
Nitrogen:
...........................................................................................................................
(2)
(ii)
(b)
A student carried out this experiment three times, with three identical small brass nails,
and obtained the following results.
IB Questionbank Chemistry
0.00
0.00
0.00
28.50
28.60
28.40
28.50
28.60
28.40
28.50
(i)
(ii)
(v)
The manufacturers claim that the sample of brass contains 44.2 % copper by mass.
Determine the percentage error in the result.
...........................................................................................................................
...........................................................................................................................
(c)
With reference to its metallic structure, describe how brass conducts electricity.
......................................................................................................................................
......................................................................................................................................
(1)
(Total 10 marks)
IB Questionbank Chemistry
R.
(a)
(i)
Copper:
0 to +2 / increases by 2 / +2 / 2+;
Allow zero/nought for 0.
Nitrogen:
+5 to +4 / decreases by 1 / 1 / 1;
+
Penalize missing + sign or incorrect notation such as 2+, 2
or II, once only.
(ii)
(b)
(i)
0.100 0.0285;
3
2.85 10 (mol);
Award [2] for correct final answer.
(ii)
2.85 10 (mol);
(iii)
0.181
100
0
.
456
39.7 %
44.2 39.7
100
44
.
2
10/10.2 %;
Allow 11.3 % i.e. percentage obtained in (iv) is used to
divide instead of 44.2 %.
(iv)
(v)
(c)
1
3
Brass has:
delocalized electrons / sea of mobile electrons / sea of electrons
free to move;
No mark for just mobile electrons.
1
[10]
18. What is the coefficient of Fe3O4 when the following equation is balanced using the lowest
whole numbers?
__ Al(s) + __ Fe3O4(s) __ Al2O3(s) + __ Fe(s)
A.
B.
C.
D.
R.B
(Total 1 mark)
IB Questionbank Chemistry
19.
3.0 10
23
B.
5.0 10
23
C.
30
D.
1.8 10
25
R.B
(Total 1 mark)
20.
PCl3
B.
C2H4
C.
H2O2
D.
C6H12O6
R.A
(Total 1 mark)
21.
A.
P
T = constant (V, n constant)
B.
V
T = constant (P, n constant)
C.
D.
V
n = constant (P, T constant)
R.D
(Total 1 mark)
22. The percentage by mass of calcium carbonate in eggshell was determined by adding excess
hydrochloric acid to ensure that all the calcium carbonate had reacted. The excess acid left was then
titrated with aqueous sodium hydroxide.
(a)
A student added 27.20 cm of 0.200 mol dm HCl to 0.188 g of eggshell. Calculate the
amount, in mol, of HCl added.
......................................................................................................................................
......................................................................................................................................
3
(b) The excess acid requires 23.80 cm of 0.100 mol dm NaOH for neutralization.
Calculate the amount, in mol, of acid that is in excess.
......................................................................................................................................
......................................................................................................................................
IB Questionbank Chemistry
(c)
Determine the amount, in mol, of HCl that reacted with the calcium carbonate in the
eggshell.
......................................................................................................................................
......................................................................................................................................
(d)
State the equation for the reaction of HCl with the calcium carbonate in the eggshell.
......................................................................................................................................
......................................................................................................................................
(e)
Determine the amount, in mol, of calcium carbonate in the sample of the eggshell.
......................................................................................................................................
......................................................................................................................................
......................................................................................................................................
(f)
Calculate the mass and the percentage by mass of calcium carbonate in the eggshell
sample.
......................................................................................................................................
......................................................................................................................................
......................................................................................................................................
......................................................................................................................................
(g)
Deduce one assumption made in arriving at the percentage of calcium carbonate in the
eggshell sample.
......................................................................................................................................
......................................................................................................................................
R.
(a)
(b)
1
3
(c)
(d)
2+
10
2+
(e)
n(CaCO3) = ( 2 n(HCl)) =
1
2
0.00306;
3
100
= 81.4 % / 81.5 %
%CaCO 0.188
3
1
[11]
23. 6.0 mol of aluminium reacts with oxygen to form aluminium oxide. What is the amount of
oxygen, in mol, needed for complete reaction?
4Al(s) + 3O2(g) 2Al2O3(s)
A.
24.
1.5
B.
3.0
C.
4.5
D.
6.0 R.C
B.
6.02 10
23
C.
1.20 10
24
D.
2.41 10
24
R.D
IB Questionbank Chemistry
11
IB Questionbank Chemistry
12
25.
On analysis, a compound with molar mass 60 g mol1 was found to contain 12 g of
carbon, 2 g of hydrogen and 16 g of oxygen. What is the molecular formula of the compound?
A.
CH2O
B.
CH4O
C.
C2H4O
D.
C2H4O2
R.D
(Total 1 mark)
26. Equal masses of the metals Na, Mg, Ca and Ag are added to separate samples of excess
HCl(aq).
Which metal produces the greatest total volume of H2(g)?
27.
A.
Na
B.
Mg
C.
Ca
D.
Ag
R.B
The graph below represents the relationship between two variables in a fixed amount of gas.
R.
x-axis
y-axis
A.
pressure
temperature
B.
volume
temperature
C.
pressure
volume
D.
temperature
volume
IB Questionbank Chemistry
13
IB Questionbank Chemistry
14
28.
correct?
29.
8.5 g of NH3 are dissolved in H2O to prepare a 500 cm3 solution. Which statements are
I.
II.
III.
A.
I and II only
B.
C.
D.
I, II and III
R.C
(a)
The alkane contains 81.7 % by mass of carbon. Determine its empirical formula, showing
your working.
(3)
(b)
Equal volumes of carbon dioxide and the unknown alkane are found to have the same
mass, measured to an accuracy of two significant figures, at the same temperature and
pressure. Deduce the molecular formula of the alkane.
(1)
(c)
(i)
(ii)
(e)
(ii)
Explain the mechanism of this reaction using curly arrows to show the movement
of electron pairs, and draw the structure of the transition state.
(3)
(Total 16 marks)
IB Questionbank Chemistry
15
R.
81.7
18.3
nC = 12.01 = 6.80 and nH = 1.01 = 18.1;
ratio of 1: 2.67 /1: 2.7;
C3H8;
No penalty for using 12 and 1.
(b)
C3H8;
(c)
(i)
(a)
(ii)
Br2 /bromine;
UV/ultraviolet light;
Accept hf/hv/sunlight.
2
2
+
(d) Initiation:
Br2 2Br;
Propagation:
Br + RCH3 HBr + RCH2;
RCH2 + Br2 RCH2Br + Br;
Termination: [1 max]
Br + Br Br2;
RCH2 + Br RCH2Br;
RCH2 + RCH2 RCH2CH2R;
Award [1] for any termination step.
Accept radical with or without throughout.
Do not penalize the use of an incorrect alkane in the mechanism.
(e)
(i)
4 max
(ii)
16
3
[16]
30. 300 cm of water is added to a solution of 200 cm of 0.5 mol dm sodium chloride. What is
the concentration of sodium chloride in the new solution?
3
A.
0.05 mol dm
B.
0.1 mol dm
C.
0.2 mol dm
D.
0.3 mol dm
3
3
3
R.C
1
31. The molar mass of a compound is approximately 56 g mol . Which formula is possible for this
compound?
A.
NaNO3
B.
AgOH
C.
MgO
D.
KOH
R.D
(Total 1 mark)
IB Questionbank Chemistry
17
32.
Which compound has the empirical formula with the largest mass?
A.
C2H6
B.
C2H4
C.
C2H2
D.
C3H6
R.A
33. What is the coefficient for O2(g) when the equation for the combustion of 1 mole of pentane is
balanced?
C5H12(g) + _O2(g) _CO2(g) + _H2O(g)
A.
B.
C.
D.
16
R.C
34. What is the maximum mass, in g, of magnesium oxide that can be obtained from the reaction of
oxygen with 2.4 g of magnesium?
A.
2.4
B.
3.0
C.
4.0
D.
5.6 R.C
3
35. 5 dm of carbon monoxide, CO(g), and 2 dm of oxygen, O2(g), at the same temperature and
pressure are mixed together. Assuming complete reaction according to the equation given, what is the
3
maximum volume of carbon dioxide, CO2(g), in dm , that can be formed?
2CO(g) + O2(g) 2CO2
R.
A.
B.
C.
D.
B
[1]
IB Questionbank Chemistry
18
36.
R.
When vitamin D dissolves in fat, vitamin D is the solvent and fat is the solute.
B.
In a solution of NaCl in water, NaCl is the solute and water is the solvent.
C.
D.
37. Biodiesel makes use of plants ability to fix atmospheric carbon by photosynthesis.
Many companies and individuals are now using biodiesel as a fuel in order to reduce their carbon
footprint. Biodiesel can be synthesized from vegetable oil according to the following reaction.
(a)
Identify the organic functional group present in both vegetable oil and biodiesel.
......................................................................................................................................
(b)
For part of her extended essay investigation into the efficiency of the process, a student
reacted a pure sample of a vegetable oil (where R = C 17H33) with methanol.
The raw data recorded for the reaction is below.
Mass of oil
Mass of methanol
Mass of sodium hydroxide
Mass of biodiesel produced
= 1013.0 g
= 200.0 g
=
3.5 g
= 811.0 g
The relative molecular mass of the oil used by the student is 885.6. Calculate the amount
(in moles) of the oil and the methanol used, and hence the amount (in moles) of excess
methanol.
......................................................................................................................................
......................................................................................................................................
......................................................................................................................................
(c) The reversible arrows in the equation indicate that the production of biodiesel is an
equilibrium process.
(i)
IB Questionbank Chemistry
19
...........................................................................................................................
...........................................................................................................................
(1)
(ii)
(iv) State and explain the effect that the addition of the sodium hydroxide catalyst will
have on the position of equilibrium.
...........................................................................................................................
...........................................................................................................................
...........................................................................................................................
(d) The reactants had to be stirred vigorously because they formed two distinct layers in the
reaction vessel. Explain why they form two distinct layers and why stirring increases the rate of
reaction.
......................................................................................................................................
......................................................................................................................................
......................................................................................................................................
(e)
(f)
When biodiesel is combusted it produces carbon dioxide. Explain why the use of
biodiesel as a fuel does not significantly contribute to global warming.
......................................................................................................................................
......................................................................................................................................
R.
(a)
(b)
ester;
1013.0
amount of oil = 885.6 = 1.144 mol;
200.0
amount of methanol = 32.05 = 6.240 mol;
since three mol of methanol react with one mol of vegetable oil the
amount of excess methanol = 6.204 (3 1.144) = 2.808 mol;
IB Questionbank Chemistry
20
(c)
(i)
rate of the forward reaction is equal to the rate of the reverse reaction /
forward and reverse reactions occur and the concentrations of the
reactants and products do not change / OWTTE;
[glycerol] [biodiesel] 3
(ii)
(iii)
(iv)
(d)
(e)
(f)
3
Kc = [ vegetable oil] [methanol] ;
1
[14]
2+
38. The percentage of iron(II) ions, Fe , in a vitamin tablet can be estimated by dissolving the
tablet in dilute sulfuric acid and titrating with standard potassium manganate(VII) solution,
KMnO4(aq). During the process iron(II) is oxidized to iron(III) and the manganate(VII) ion is reduced
2+
to the manganese(II) ion, Mn (aq). It was found that one tablet with a mass of 1.43 g required 11.6
3
2
3
cm of 2.00 10 mol dm KMnO4(aq) to reach the end-point.
(a)
(i)
(ii)
State the half-equation for the reduction of the MnO 4 ions in acidic solution.
...........................................................................................................................
21
..........................................................................................................................
(b)
(i)
2+
...........................................................................................................................
...........................................................................................................................
(iii)
2+
...........................................................................................................................
...........................................................................................................................
R.
(a)
2+
Fe
3+
(i)
Fe
(ii)
MnO4 + 8H + 5e Mn
(iii)
MnO4 + 5Fe
+e ;
+
2+
2+
+ 8H Mn
+ 4H2O;
2+
+ 5Fe
3+
4H2O;
(b)
Accept e instead of e .
(i)
11.6
4
amount of MnO4 = 1000 0.0200 = 2.32 10 mol;
(ii)
amount of Fe
(iii)
mass of Fe
2+
2+
2
[7]
39.
B.
C.
6.0 10
23
D.
5.4 10
24
R.D
(Total 1 mark)
IB Questionbank Chemistry
22
40.
A.
B.
C.
D.
1.7 10 g of iron
24
2
R.C
(Total 1 mark)
3
41. What volume of sulfur trioxide, in cm , can be prepared using 40 cm sulfur dioxide and 20 cm
oxygen gas by the following reaction? Assume all volumes are measured at the same temperature and
pressure.
2SO2(g) + O2(g) 2SO3(g)
A.
20
B.
40
C.
60
D.
80
R.B
(Total 1 mark)
42.
43.
Which sample of nitrogen gas, N2, contains the greatest number of nitrogen molecules?
A.
1.4 g N2
B.
C.
1.4 10 N2 molecules
D.
1.4 mol N2
23
R.D
Aspirin, one of the most widely used drugs in the world, can be prepared according to the
equation given below.
(a)
IB Questionbank Chemistry
23
......................................................................................................................................
(3)
(b)
A student reacted some salicylic acid with excess ethanoic anhydride. Impure solid
aspirin was obtained by filtering the reaction mixture. Pure aspirin was obtained by
recrystallization. The following table shows the data recorded by the student.
(i)
3.15 0.02 g
2.50 0.02 g
(ii)
(iv) State the number of significant figures associated with the mass of pure aspirin
obtained, and calculate the percentage uncertainty associated with this mass.
...........................................................................................................................
...........................................................................................................................
...........................................................................................................................
...........................................................................................................................
(2)
(v) Another student repeated the experiment and obtained an experimental yield of
150 %. The teacher checked the calculations and found no errors. Comment on the result.
...........................................................................................................................
IB Questionbank Chemistry
24
...........................................................................................................................
(1)
(Total 11 marks)
R.
(a)
(b)
(i)
Mr(C7H6O3) = 138.13;
3.15
2
n = 138.13 2.28 10 (mol);
Award [2] for the correct final answer.
(ii)
Mr(C9H8O4) = 180.17;
2
(iii)
(iv)
(v)
2.50
(percentage yield = 4.11 100 =) 60.8 %;
Accept 6061 %.
3;
0.02
(percentage uncertainty = 2.50 100 =) 0.80 %;
Allow 0.8 %
1
[11]
44. Smog is common in cities throughout the world. One component of smog is PAN
(peroxyacylnitrate) which consists of 20.2 % C, 11.4 % N, 65.9 % O and 2.50 % H by mass.
Determine the empirical formula of PAN, showing your working.
................................................................................................................................................
................................................................................................................................................
................................................................................................................................................
................................................................................................................................................
IB Questionbank Chemistry
25
................................................................................................................................................
................................................................................................................................................
................................................................................................................................................
R.
C
20.211.4
12.0114.01
= 1.68= 0.814
1.68
0.814 = 2
N
65.9
16.00
= 4.12
0.814
0.814 = 1
O
2.50
1.01
= 2.48
4.12
0.814 = 5
H
;
2.48
0.814 = 3 ;
C2NO5H3;
No penalty for use of 12, 1 and/or 14.
Award [1 max] if the empirical formula is correct, but no working shown.
3
[3]
45.
Which non-metal forms an oxide XO2 with a relative molecular mass of 60?
A.
B.
C.
Si
D.
S R.C
(Total 1 mark)
46.
How many oxygen atoms are there in 0.20 mol of ethanoic acid, CH 3COOH?
A.
1.2 10
23
B.
2.4 10
23
C.
3.0 10
24
D.
6.0 10
24
R.B
93. 4.00 mol of a hydrocarbon with an empirical formula of CH 2 has a mass of 280 g. What is the
molecular formula of this compound?
48.
A.
C2H4
B.
C3H6
C.
C4H8
D.
C5H10
R.D
What will be the concentration of sulfate ions in mol dm when 0.20 mol of KAl(SO4)2 is
3
0.2
IB Questionbank Chemistry
26
B.
1.0
C.
2.0
D.
4.0 R.D
3
48. The volume of an ideal gas at 27.0 C is increased from 3.00 dm to 6.00 dm . At what
temperature, in C, will the gas have the original pressure?
A.
13.5
B.
54.0
C.
327
D.
600 R.C
(Total 1 mark)
50. The data below is from an experiment used to determine the percentage of iron present in a
2+
sample of iron ore. This sample was dissolved in acid and all of the iron was converted to Fe . The
resulting solution was titrated with a standard solution of potassium manganate(VII), KMnO 4. This
procedure was carried out three times. In acidic solution, MnO 4 reacts with Fe
and Fe
3+
2+
ions to form Mn
2+
1.00
23.60
10.00
24.60
46.10
32.50
3.682 10
2.152 10
Deduce the balanced redox equation for this reaction in acidic solution.
......................................................................................................................................
......................................................................................................................................
(b)
(c)
......................................................................................................................................
IB Questionbank Chemistry
27
......................................................................................................................................
......................................................................................................................................
......................................................................................................................................
(e)
......................................................................................................................................
......................................................................................................................................
......................................................................................................................................
......................................................................................................................................
(Total 9 marks)
2+
2+
3+
R.
(a) MnO4 (aq) + 5Fe (aq) + 8H (aq) Mn (aq) + 5Fe (aq) + 4H2O(l)
Award [2] if correctly balanced.
+
Award [1] for correctly placing H and H2O.
Award [1 max] for correct balanced equation but with electrons shown.
Ignore state symbols.
(b)
(c)
(d)
2+
Fe / iron(II);
Do not accept iron.
n = 2.152 10 2.250 10 ;
4
4.842 10 (mol);
Award [1] for correct volume
Award [1] for correct calculation.
2
2+
2
[9]
21.
HCl
MnCl2
Cl2
H2O
A.
B.
IB Questionbank Chemistry
28
C.
D.
2
(Total 1 mark)
R.C
3
52. What volume of carbon dioxide, in dm under standard conditions, is formed when 7.00 g of
ethene (C2H4, Mr = 28.1) undergoes complete combustion?
A.
22.4 28.1
7.00
B.
22.4 7.00
28.1
C.
2 22.4 28.1
7.00
D.
2 22.4 7.00
28.1
R.D
(Total 1 mark)
53.
1.0010
23
B.
3.6110
24
C.
5.00
D.
6.00
R.B
(Total 1 mark)
54. What is the coefficient for H2SO4(aq) when the following equation is balanced, using the
smallest possible integers?
__Mg3N2(s) + __H2SO4(aq) __MgSO4(aq) + __(NH4)2SO4(aq)
A.
B.
C.
D.
7 R.C
(Total 1 mark)
55.
Air bags in cars inflate when sodium azide decomposes to form sodium and nitrogen:
2NaN3(s) 2Na(s) + 3N2(g)
Calculate the amount, in moles, of nitrogen gas produced by the decomposition of 2.52 mol of
NaN3(s).
A.
1.68
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B.
2.52
C.
3.78
D.
7.56 R.C
(Total 1 mark)
[1]
3
56. What volume, in cm , of 0.200 mol dm HCl(aq) is required to neutralize 25.0 cm of 0.200
3
mol dm Ba(OH)2(aq)?
A.
12.5
B.
25.0
C.
50.0
D.
75.0
R.C
(Total 1 mark)
57. 0.600 mol of aluminium hydroxide is mixed with 0.600 mol of sulfuric acid, and the following
reaction occurs:
2Al(OH)3(s) + 3H2SO4(aq) Al2(SO4)3(aq) + 6H2O(l)
(a)
(c)
(d)
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.....................................................................................................................................
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(e)
H2SO4(aq) is a strong acid. State the name and the formula of any weak acid.
.....................................................................................................................................
.....................................................................................................................................
(1)
(Total 8 marks)
R.
(a) 0.600 mol Al(OH)3 (1.5)(0.600) mol H2SO4/0.900 mol H2SO4
needed, but only 0.600 mol used;
H2SO4 limiting reactant;
0.200 mol;
1
Use ECF from (a).
(d)
(e)
58. A toxic gas, A, consists of 53.8 % nitrogen and 46.2 % carbon by mass. At 273 K and
5
3
1.0110 Pa, 1.048 g of A occupies 462 cm . Determine the empirical formula of A.
Calculate the molar mass of the compound and determine its molecular structure.
(Total 3 marks)
R.
Mr = 51.9 (g mol );
:N
C C
N:;
3
[3]
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