r40/2014

llhich among lhe lollowing

3et of

2.

3.

a.

(Z 1,

T18.fl*tiv nu.ler.h.8 in the.ldren in

(A)

(E 1.?

lhe valu's ot

He rrom ie

1.r5

(C)

{D)

@ 8]lration of !*+ it:

(A) lArt3ds 45r (B) lAll3d64J (c) IArl3# 6r

r'65

Theebdrm

fte radts Elio betwm

0O25

0.'lla

tavd6

tne

cddidtion

(D) t^d 3dt ko

numbcr or

(D)

(c]5

(B) I

(A) S

5-

(Bl 0, o, L +r/2)
lD) 143' '1' -r/4

1,2)
tq QL\ +1/4
(A)

qu.ntuh numbcE i! not allos.d

.dntemat oI hybrid otbilals,

6ulll in
(c) t Eah<lta! (D) lind'
(A) Eidrtirl.r {B) Pt'did.l

5pr

hyb.idibtion

6. Th. shaF of NH3 i3:

(B) Ptnmid.I
. (A) .n8!l.r
7. Eth*
(A)

s.

(C) tetrahadEl {D)

p' bonds'

ei8m3 bonds.nd

h.s

Lr

(B)

41

linear

(c)

co

Wldc!.mdg the loUowiry i! lhe ardtt lal ErudctiE

sid

(A) Uani!6 5ed6

G)

(c) N.Ptuni!6sdi6

(D) Thoinn sei'

{D)

tr

Ac!^tun sdir

lP.T.O.l

litu3 in .n

9.

dkEt

lild b <all.d

(E
10.

Which

(A)

.rmg

co

It. whlch.!Mt

Ftiiigdtit

rh. follosing b

(B)

No

PhotoeleEi. errect

d-

(c)

(D) dr

d toE i.brmlatl{ hydDth bon llrg ?

(a) beEo|c el<l (B) w.ter
(c) c.lLophe.ol (D) pnlt'oplEnol

12.

Phoroekdc

th. iolowti8

.fl*t d.tunrtr.r$

(A) erc
(q bo.n p.dcle.

.l

13. In. |*Fible ection,

lc)
ra,

utlf

rll.

Eve

.t!yllat lelnpffiof

TIEnt of! clt miel wtton

<LoubL.

i! ifufued by @C, th. Fr. of th.

(8)

Neg.ti!.

(D)

Cln

(^) I
r7.

Eml3rid ot lbhl

for.try lCC ri*

2aIEr

rL

(B) 2
a . l6lt

of

poddv. or

Egldw

in ternDeEtuE,

qcrio !EtE6 by.ldrt;

(c)
16. QMt6 yi.ld of lh. tadm

bc

ffiof watdL._otdrE
(c) F.udo nd (D) .ond

(B) rn*

t5.

(B) p.rricl
(D) mith6 prd<te M {.w

lh. Edion Dc ot the b.clw.ftl @ctld

zqo

HydrolFl! of

of llght,

+&,

.h.hiol tucrion i,

(D)

15 :

(c)

(c) ch.n'jlunjtm

rtim
0.5

(D)

tlon

18.

reactiod are
Substa.es whlch tedrce the quantun yield oi Phot"hemical
'aled

(A)

19. wiich

20.

(B)

Phoro

iniiLrm (c) 'atalvsis

of tlE following is a

.otftt

notanon for

phoro

hhibito6

4p

Na+

* i*llrenic witn :

(o)

whi.h of

hybritl"to'

the {ollowing

Ends ro g|vt n'dimum

(B)
(D)

(^) .p.
(c)
"?3
22,

Whi.h of lho loUowing

tu a

Pblak elemdt

(Bj
23,

as

l(Fo reEativitv fo! tn aton

sP

AII hav' the

s3ft efidt

cs

The hybriJr.rhon ot.hlonnL In

(D) cr-

(B) AP*
21.

Photo sensihreE

tn orbittl with n=t and l=2

(c) 4d

P) 4r

(A)

(D)

(g

(D)

s.

sb

CIIr is:

{B) 'p'd
24, {,hich

1e)
25.

n"i

A mol6ule

(A)
26.

of thc lollowing is unstable accordinS

The

(B)
hrvi.8,ll

Pcl5

hYbdiation of

c:

0) cHr
Col

N(o lhdry

(c)

rhP bond tnAcls

'arbon

bo

equ'l

t'o

He,

(D) o;

90's

(c) sF6

(D)

Becl2

is :

!40/2074
lPT,O.)

27,

W11j.h oI lhe rouowinS and :45i30 aE hobores

(A)
23,

Ille stable nd prcduct of Urdniu

(A)

2r.

sBl':oe
qua

(B)

(B)

(a) E=z
TIE

dil

(A) ohn_t

cm

(c)

or

3s,

Th. botope u!d

(D)

(tstt. tutaiat

rli

Bo6rb

(2) ot an

ir,

(A) EDTA

!t#

(c) ,rPaar

0.tu4

(D') zd35

(9 E:F

(o) cr@

etaMt b r.trbd

b r.quivard tlB

(E ole-!

on3

mol-r

(D) oh6-r

d-r !El-l

p.dct6 k

(B)
lq

tfatnar
(B) sr,

rhe

(B)

rfta

,!r"4

Wrich oI the following i, mt

110/2014

19 a2ffi

6sp3

nDl I

Which of th. folbwng

(A)

(D)

(g

ot

tst Ptqttib

lwrim
(o) rsl

in tEmtErdb4r

lh)'rcid disotdd t!

(g r!:

.helatlnS UE.n t

lthylene

nbl-r

(9 onl

(D)

co6o

dr.Mjre (c) oxrtar. (D)

Dy

z/E_e55oo

@detlc i!:

(r) rH,
:,4.

(q 16$1

(B) E=965Ooz {c) z-96s(xlE ([r)

of holar

ohm_l

,orha,

31. TheddrftlEnrial .quivi6l

33-

b.

IlE nuchar hrel u*d in the N.E

(r) nus

32.

*rt6

P) !rl,bro,

wlli.h oI rh.lollowina nulid.

(A)

30.

(3) r3Arre

,rP3.

Annonia

*E

36. V*rnin 612 i5 n C@dimtid .ompoufti

(B) CO
(A) MB

37

tnti sysrm

(A)

(q
,8.

an

39, Ilow
(A)

40.

ar examPre oi

(q

a sel

many siSnifi.anl

figua

(B)

2.0s

Th term

$.{

(B)
ro

are Prsenr in th

Closdess lo lhc msured value to th

mnet

(B) Ac.!!acv

tn the Erhtion ot N.oH aE irct

otlic

(A) PhenolFhthalein

( ) rMnr)a

Pota$irm

(D)

F rhe (oftct

mill'8rJr whr\

nuntu'l

(D) 200ma

Relative

dor

MobmY
value is

(c)

acid, ihe

"lled

srandard

ts

lador (D) Quotieni

indi':b' u*d

is

(B) Methvl oBngc

(O) Iodine

dichotrrry tirtilim h

tcdo.yanidc
(c) Nlphntl anih.2nili. dcid
(A)

nurb'r 0'{[33

(c) Mortlily

in

(Dr .liqu'daffid

*o$l

(c) 20008

2.m8
(B)
(D)

14. Thentetul,ndk rd ud

.soud

(c) 2

rPres Ptfisi6n

(a) Pr.ision
43.

Chemilumine<.nce

(A) stand/d deviation

tI2.

(D) zn

(D)

(B)

odsi6

A we,Bhrg brl.ttP a J-urJtc lo t\e nerrlst

Eprestaton for th EeiSht n

(A)
41,

esnlial fo

is

Ph6Phor6ance
PnotGmlirization

Smok is

(A)

.Esing

ol

(B)

l'otassiun fdi'yanid

(D)

KMnOa

!4n/2014
IP.T.O.l

45.

The unit lor

nqh,ation which

(A) Molanry

t6.

The

a?.

Pdm!ry

. slurton

rmpeatlF

(c) Nomtig

(B) Molality

3ub.r.fte u*d to prcpaE

(A)

is inde?en<t6t of

ot known

(D)

@n6hatim

id

3tandard (B) tndiGror (c) Bufier

Picl out dE odd

(D) An

(B) Astrctog)| {c) p}wnoiottr (D) Adprn.tun

18.

lEs .ll challenging !.srs, ir premoled b :

(A) sciddftc hypothsc
(B) Nulthyporh6i'
(c) rheory
(D) turi .ry h,"oin6it

!9.

Th.

A ht?othGie it

best

*|@n riotific nsthod i6:

(A) Pcitivi'm (3) Ehpni.isn (c) Inducdon (D)

lbt m.nr'
(A) Ir i! . nude FoFry
wr'tch of dE touowlit

G)
(C)
(D)

5r,

ryr.

(A) Altrdmy

50.

tndi@ror

..tiviy i!

rhe rarc k .fi.r.<t by chan6. ot redlddruE

difi.B

atom

xotnmic.h.n6.
(c) A nuctear pE6r
An

. .hEhi..t

@cr

Are rej4ied

(D) C.ry

'140/20ra

wh6

rl$

p6@
pr4

G)

(D)

A rnd ord. rdcrid

tighr tals on .crive

ch.rte opF3it. in

.hange in betng :

'pdr.nsus

(A) H.ve Er.ter iodzjig pd.r rhan atph. Fys

{B) Po*$ t@ter p6F.rinE power rhan E tu

(c)

tror

tl d@ mt involv .ny mmn8enMr of ekrctl!

It is tbt afiel.d by rhe ptwN or othd elmr3

Radloaciire dislnr%Edon

(A)

.bour radio

rei'ts

but equ.l In
8

Rys

m.Er ude rh.n

prcbn

D.du.rion

53.

AlPha t.Js coNr$ ota sham

of:

(c)

(A) H'
54,

Unit ofradie.hvnY:

(B)

(A) Rad

Only

cl(trqs (o)

(c) BftqueFl

GreY

55. Whd PassLrS thdgh a ffignetic field' th lattd dell{tim

(c) Favs
F) 9j'v5
(A) atays

s6.

(D)

Cune

is erpendced by :

(D)

All qlal

disi'tegation :
Wnh dE pasge ol rime, the htc o{ radio*dv

P) Dde's

(A) rdeas

{c)

R@ins

(D)

eN

Mdt

inea*

o' d@'s

@ti6 4Be9+X+3BP+'v X it:

(B) D'ulercN (c) Positrcn
(A) Prctons

57.

In rhe

5s,

the a'ttlt
which of th. Iouowi'E Prcj{liles is ih h6r for bomb'di!8

(A) a pannk
59.

60.

si's hat Abmuth !! nd Pro<tu't

(c)
(B) '{n+1
'n+2

dvtt:ri 's
Ih lowst htric der8v adong thc lollosl'E

(B) KCI

(A) Nacl

6r.

Th

Bon exPonent of AE+ ion tyPe is

iA)
62.

(g ddtercs

(B) proto"

which of lht ta<tidcriw

(A) !n

The

(B)

cordt or.l.r

(A)

OnlY neurrons

Cl, Br,

F,I

{D)

reuEoro

(D) 4n+3

(D)

Cacl

(c)

(D)

10

(D)

I' Br'

Cl' I' Br'

(C) Rbcl

of dsteasinE Polarisibllitv ol lhe lons

(B)

{D) NsEoB

(c)

F
9

B!'

i'3 :

!'

t'

Cl

cl

r40/20r4,
lP.r'o l

63.

Whicn of rhe lolowjnS has the hi8h6t

jonialio.

(A) Na)Na++ (B) ar+^lr +e (c)

energy ?

^l+,Ar2r+e

54. ]lE ruBnitude ot latne energy oI a sotid in@!*s ji the rons are
:
(A) Large
(B) sma|l
(c) liqudr sire
65,

Bo..-Habd cycle h u*d to dcicrmi@

(B)
(D)

is:

6z

DE

Anri

turimd elftror

{a} 2

The

tudion

op.ciry oI any orhjl.t

(3) 3
lh

{A) Boren
59-

(B) Anli pydis

(r)) Trdqu j ie6

dePftgnrs

63. wllid tung

rE amve

(A) Hypmric

{c)

is :

(qs

(B) C.rbo.

of the arom bomb is

(A) dcreases

71.

.emains

on

oa

an

{D)

orygen

and chah reactiotu

.ldrolyrrc aoturjon

(B)

unchnn8ed

(c) N rog.n

b.*d

with dilurjor the mol,r conduclrne

(c)

(D)6

MjnB htu tn. high6r idrnlion mrEy

(a) mruDl .adiorctiviry

(B) nrcld ,r$id
(c) sro.knous .hehj.,t naojons (D) nlcrcar,uid
70.

No ffecr

Enr,opy

^ll
Par.celamol

(D)

(A) EtetloneEanvjry
(c) tlttie 6er8r
65.

(D) AF+jAt3++e

inclcaxs

(D) d..pscs onndeaes

Baurrteis an orc or:

(^) coppp.
140/2014

(B) Atuminium (c) znr.

10

(D)

rjtanium

?2.

The

ldtron .tfinity or groP

(A) zdo
(C) larg6 th.n
?3.

13

elemnts is

P)
alk li

ldl8n dEn

(D) ltr8q

rrElale

tut l<lon8atir elmnl 's :

(B) nitiosm
(A) oxrcm

halogens

in the Fnod o'

eleMls

The

74.

The

+
@tttiDtion numbi of .ob.lt in ko(m)?Orl 6

75,

t6,

Bo*Habt E clc G {*d to.alolate:

{A) pfradive lndx (B) dssity
sllphide ims arc onenh.td

(D)6

(c) s

(B) 4

(A) 3

(D) nldine

(c) chloin'

bY

(c)

&

(D) r'$ie

v'lue

'ner8v

(D)

rugnetic

*P.ratid

(A) .tloPatos (D) tetohex@ (c) aldoh'x@ (D) *'ioFntce

78.

Nunbr ol

l.MG

(A) 8
?9.

The nost slable

(A) chan

in th 4$ Petiod ot th Psiodic bble

(B) 10
torh of cy.loh*tu h

(B)

hau

i'3 :

(cJ 13

(D)

32

lc) boar

(D)

1wi5r bott

(D)

IJV

chan

80. ldotily the sPsha rhar.or6P@ds to lh' frquftv 690 m-r

(c) IR
(A) Micrcwdve (B) NMR

'l4o/6L

lrT.o,l

El.

whch amng tha ioUowina st ie fufttl@ b an

(A) !.mp...ture (B) volune

82. lt photo

(A)
83.

Tte

of mvlenErn a& nm

cn-r (B)

20000

p.Ear u*d

(A)

Por.sium

The shifi of

6*cyddd.

() r
aZ

cm-r (D)

w.t{

Ftld

k .alled

(c) yIN lhifr (D)

{8) rd {nft

-tfi hithst .l6Ed

(8) c|

Boililg poinr ol

(D) retEdire indd

al6ntry

.!Mg halogd

(c)

I! mch highd th.n

(g

Both (A) atd (B)

(D)

cov.lent bonding

Conducdd .tu. !o the

diRt

rhe

ir

mm

8'

(D)

dF.r.d v!tu.

now ol

I<hos b *noM !J

Tni! i! dle to

(A) tnn @ndu.do.

(E

(c) .ldr6n.ondu.iid

(D) holell.r @ndlcrid

74O/20ra

radid is :
(B) Alcls
(D) znch

(A) Intr. mol@lrJ hy&oAd bddinE

(E Inte @|(dd hyd! 6 hodirE

88.

40.000.m-r

MSenl

.n .boqption band to dtr ldEe w.wlent$

(q rq
l.tlHi

SO000

(B) DMG
(D) N*l./e

Th. c.r.lFr lrd 60r F iedrl C!rl!,

The

(9

6-t

25,000

{a) Anhyd@ Alcll

85.

(g vi@iy

rhe syetem ?

tor the iddtifi.ation of nkk l i6n in q!.lltati@ atulyeir ir

(^) bru.lhfr
85.

Bi@ prcpdty of

orelpords to :

(g EDIA
84.

4t

.ldrotyri. ondu.rid

orde

39, Ite quanlun nunber 't' d.noler

(A) principal mrgy level

(c)
90.

92.

(B) dqFnmc-v.t orbitale

(D) spi. o.inratim oran el.chon

nodcs

Th @mpounds H2O

(A)
(C)

9r-

nunb' of

.nd HzO, can

be ueed

proponion
multiptc prcpolrid

to illusbate lhe law of

(B) rdprtrar pop6tion

coclanr

(o)

fct b:nsition *rics bBint Fith l

(A) titanium (3) scindiun

Sseus volum*

Th

(c) vanadiM

A triang{lar anangedent of atoru aiies due ro

(D) rungee*

(D) sfd hybridiation

93,

lh ditical tcmperatur. T. is l.td to Vandetraal's rcNtant by ihe laiion:

\q 'r<-a/z/bz (c) T.=3al27Rb {D) T.-2b

(A) Tc=3b
9,1. cive

the

(A) 1
95.

^!mbq

of

md6

libarioN

possible tor Co? :

(c) 3

(B) 2

Thc hydtulyris oI sdium acelalc nsulle in a solution which is

(A) acidic
95,

oI

Ostwald dilution Lw is apptioble ro

(A) rcak ehbol/tcr

(c)

(c) neutral

(B) b.si.

{D)

(D)

@nnol Prdicl

(B)

both

wdk

and st ong clecholyl6

strds clcbolytes

13

t4o/2014
lP.T.O.l

97,

Th.

Frdd.l

ot stuhled @JodEI

(3)

9t

NaCl

IR

0.3315

sF.tn

25'c

(c)

ia

0.2422 V

(D) 1v

(g

(E -bic

e u.Uy t kB bv @xh8 tlE lsPtt tlth '

(D)
(c) KBr
(E B.@E

ol lolid sm?ls

(a) Tllrs

r0o. cllEta|rnP $&r. re dErdeted b,

(A) ldgnng.dda

(c) .,irobopY

rttll2014

al

teLdtt b du oYtt l tYsb&:

(A) hA.so.l
99.

clet$d.

(B)

.hdP nEldnS P"tn

(D) a! dE.rnE

1a

wat!