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Twig, 1980)
Ammonia synthesis
N2 + 3H2 2NH3
Methanation (ammonia and H2 plants)
CO/CO2 + H2 CH4 + H2O
Acetylene hydrogenation (front end)
C2H2 + H2 C2H4
Sulfuric acid manufacture
2SO2 + O2 2SO3
Methanol synthesis
CO + 2H2 CH3OH
Low-Temperatur CO shift
CO + H2O CO2 + H2
Operating
Conditions
450-470 oC
200-300 atm
250-350 oC
30 atm
30-150 oC
20-30 atm
420-600 oC
1 atm
200-300 oC
50-100 atm
200-250 oC
10-30 atm
Hydrocarbon hydrodesulfurization
R2S + 2H2 H2S + R2
300-400 oC
30 atm
High-Temperatur CO shift
CO + H2O CO2 + H2
Steam reforming, natural gas
CH4 + H2O CO + 3H2
Ethylene partial oxidation
2C2H4 + O2 2C2H4O
Butane oxidation to maleic anhydride
350-500 oC
20-30 atm
500-850 oC
30 atm
200-270 oC
10-20 atm
7
C4H10 + 2 O2 C4H2O3 + 4H2O
400-520 oC
1-3 atm
Reactions
Catalyst
Typical Life
(Years)
Catalyst Property
Affected
10-15
Slow sintering
Activity
Supported Nikel
5-10
Supported Palladium
5-10
Slow sintering
Activity/selectivity
1-10
1-4
1-3
1-3
Activity, selectivity
Vanadium phosphorus
oxide with transition
metal additives
1-2
Activity, selectivity
220-270 oC
100-300 atm
0,5-1
Activity or pressure
drop
5
2NH3 + 2 O2 2NO + 3H2O
800-900 oC
1-10 atm
0,1-0,5
selectivity
230-270 oC
1-10 atm
Copper chloride on
alumina (fluidized bed)
0,2-0,5
460-525 oC
8-50 atm
Platinum alloys on
treated allumina
0,01-0,5
5-10
2-5
2-4
Activity
Activity
500-560 oC
2-3 atm (fluid bad)
Synthetic zeolites
1-2 s