CHEMISTRY PAPER2ND YEARTEST#6CH.

11 + 12 (1ST JAN 2011) (REPEATER)

Name: _____________________

Time: 100 Min

Roll No. ____________________

Marks: 45

Session/Section:______________

Date: 09022011

Time: 10 Min.

PAPER OBJECTIVE

Marks: 17

Note: Cutting, Over-writing, Re-Writing and Use of Lead Pencil or Ink Remover is not
allowed. Questions attempted in this way will be considered wrong.
Q:1 Four possible options have been given. Tick () mark the correct option.
(i)
The enzyme which converts glucose into ethanol during fermentation process is
(a) Invertase
(b) zymase
(c) diastase
(d) maltase
(ii)
The carbon atom of a carbonyl group is
(a) sp hybridized
(b) sp2-hybridized
(c) sp3 hybridized
(d) dsp2
(iii)
Denaturing of alcohol is done by adding
(a) 10% methanol
(b) 10% glucose
(c) 10% formaldehyde
(d) 10% acetic acid
(iv)
Which of the following has the highest boiling point
(a) methanal
(b) ethanal
(c) propanal
(d) 3-hexanone
(v)
Which of the following compounds will not give iodoform test on treatment with I2/NaOH
(a) 2-pentanone
(b) acetone
(c) butanone
(d) 3-pentanone
(vi)
When alcohol reacts with phosphorus halides, it give
(a) alkyl halides
(b) alkyl amine
(c) alkanes
(d) alkynes
(vii) The aldehydes form _______ precipitates when boiled with Fehlings solution
(a) pink
(b) red
(c) orange red
(d) brick red
(viii) Reaction of alcohols with carboxylic acids is called
(a) acylation
(b) esterification
(c) dimerization
(d) polymerization
(ix)
When phenol is heated with nitric acid, the product is
(a) Picric acid
(b) Nitrobenzene
(c) 2, 4, 6-trinitro benzene (d) benzene
(x)
Base catalyzed reactions make
(a) attacking nucleophile more reactive
(b) substrate more reactive
(c) both (a) and (b)
(d) remain itself active
(xi)
Cannizzaros reaction is not given by
(a) Formaldehyde
(b) acetaldehyde
(c) benzedehyde
(d) trimethyl acetaldehyde
(xii) Nitration of phenol produces an explosive called
(a) Nitrophenol
(b) Picric acid
(c) Nitroglycerine
(d) carbolic acid
(xiii) Which of the following tests is shown by aldehyde and ketones
(a) Reaction with sodium bisulphite
(b) reaction with Grignard reagent
(c) reaction with HCN
(d) all of the above
(xiv) Which one of the following alcohol has greater boiling point
(a) ethanol
(b) ethylene glycol (c) glycerol
(d) methanol
(xv) Tollens reagent will react with
(a) Glucose
(b) fructose
(c) phenol
(d) both a and b
(xvi) The carbon atom in carbonyl group is hybridized
(a) sp
(b) sp2
(c) sp3
(d) dsp3
(xvii) Reduction of acetone gives product
(a) primary alcohol (b) secondary alcohol (c) tertiary alcohol
(d) all

CHEMISTRY PAPER2ND YEARTEST#6CH. 11 + 12 (1ST JAN 2011) (REPEATER)

PAPER SUBJECTIVE
Time: 70 Min.
Q:2
(i)
(ii)
(iii)
(iv)
(v)
(vi)
Q:3
(a)
(b)
(c)
Q:4
(a)
(b)
(c)

Marks: 28
SECTION I
Give answers to the following questions.
(62=12)
Define Disproportionation reaction with an example
Fermentation can not produce ethanol more than 12%. Why?
Write structural formula of
(i) benzophenone
(ii) crotonaldehyde
How ethers are prepared by Williamsons synthesis?
What products are formed when ethyl magnesium bromide reacts with acetone?
Distinguish between ethanol and methnol by means of chemical tests.
SECTION II
How will you distinguish between primary, secondary and tertiary alcohols?
What products are obtained when ethyl alcohol reacts with?
(i) Na-metal
(ii) acetic acid
(iii) H2SO4
Why phenol is acidic in nature?

(3)
(3)

Define aldol condensation. Give its mechanism.

How will you distinguish between
(i) Acetone and ethyl alcohol
(ii) propanone and propanal
Compare the reactivity of aldehydes and ketones. Also, Justify.

(3)
(3)

(2)

(2)

CHEMISTRY PAPER2ND YEARTEST#6CH. 11 + 12 (1ST JAN 2011) (REPEATER)

PAPER SUBJECTIVE
Time: 70 Min.
Q:2
(i)
(ii)
(iii)
(iv)
(v)
(vi)
Q:3
(a)
(b)
(c)
Q:4
(a)
(b)
(c)

Marks: 28
SECTION I
Give answers to the following questions.
(62=12)
Define Disproportionation reaction with an example
Fermentation can not produce ethanol more than 12%. Why?
Write structural formula of
(i) benzophenone
(ii) crotonaldehyde
How ethers are prepared by Williamsons synthesis?
What products are formed when ethyl magnesium bromide reacts with acetone?
Distinguish between ethanol and methnol by means of chemical tests.
SECTION II
How will you distinguish between primary, secondary and tertiary alcohols?
What products are obtained when ethyl alcohol reacts with?
(i) Na-metal
(ii) acetic acid
(iii) H2SO4
Why phenol is acidic in nature?

(3)
(3)

Define aldol condensation. Give its mechanism.

How will you distinguish between
(i) Acetone and ethyl alcohol
(ii) propanone and propanal
Compare the reactivity of aldehydes and ketones. Also, Justify.

(3)
(3)

(2)

(2)